JPH04202708A - Method for injecting powdery fuel into blast furnace - Google Patents

Method for injecting powdery fuel into blast furnace

Info

Publication number
JPH04202708A
JPH04202708A JP33635590A JP33635590A JPH04202708A JP H04202708 A JPH04202708 A JP H04202708A JP 33635590 A JP33635590 A JP 33635590A JP 33635590 A JP33635590 A JP 33635590A JP H04202708 A JPH04202708 A JP H04202708A
Authority
JP
Japan
Prior art keywords
carrier gas
fuel
blast furnace
tuyere
powdery fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP33635590A
Other languages
Japanese (ja)
Other versions
JPH0694564B2 (en
Inventor
Hiroshi Shibuta
浩 紫冨田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP2336355A priority Critical patent/JPH0694564B2/en
Publication of JPH04202708A publication Critical patent/JPH04202708A/en
Publication of JPH0694564B2 publication Critical patent/JPH0694564B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Manufacture Of Iron (AREA)

Abstract

PURPOSE:To prevent stickness of ash components to a blow pipe and a tuyere by controlling an oxygen content in a carrier gas based on combustibility of powdery fuel and a peripheral temp. at the time of injecting the powdery fuel together with the carrier gas from the tuyere in a blast furnace. CONSTITUTION:The powdery fuel discharged from a powdery fuel supplying equipment 5 in the fixed quantity each, is fed into an injecting nozzle 3 from a supplying pipe 7 together with the carrier gas through a gas feeding pipe 6 and injected into the blast furnace from the tuyere 1 through a blow pipe 2. Then, the oxygen content in the carrier gas is measured with an oxygen concn. metal 9 based on the combustibility of powdery fuel and the peripheral temp., and by adjusting each of valves 10, 11 for adjusting flow rates, inert gas (N2 gas, etc.) is mixed into the carrier gas and controlled so that the oxygen concn. in the carrier gas becomes the prescribed value. By this method, the ash components from the powdery fuel are prevented from being stuck to inner faces of the blow pipe 2 and the tuyere 1, and thereby stable operation of the furnace and reduction of pig iron cost, are obtd.

Description

【発明の詳細な説明】 (産業上の利用分野〉 この発明は、高炉羽口より微粉炭、コークス粉等の粉体
燃料を吹込む方法において、粉体燃料キャリアガス中の
酸素含有量を制御することによって、粉体燃料に由来す
る灰分がブローパイプや羽目に付着するのを防止する方
法に関する。
[Detailed Description of the Invention] (Industrial Application Field) This invention controls the oxygen content in the powder fuel carrier gas in a method of injecting powder fuel such as pulverized coal or coke powder from the blast furnace tuyere. The present invention relates to a method for preventing ash derived from powdered fuel from adhering to blow pipes and siding.

(従来の技術) 近年の高炉操業においては、燃料原単位の低減、炉況安
定化のために、微粉炭等の粉体燃料を高炉に吹込む方法
か実用化されている。
(Prior Art) In recent blast furnace operations, a method of injecting powdered fuel such as pulverized coal into the blast furnace has been put into practical use in order to reduce the fuel consumption rate and stabilize the furnace condition.

第6図は従来の粉粒体燃料の吹込方法の一例を示す模式
図であり、高炉羽目(1)に連設したブローパイプ(2
)の壁を貫通して該ブローパイプ内に臨ませた燃料吹込
ノズル(3)より、微粉炭等の粉体燃料をキャリアガス
(主に空気)と共に炉内に吹込む方法が一般的である。
Figure 6 is a schematic diagram showing an example of a conventional method for blowing granular fuel, and shows a blow pipe (2) connected to the blast furnace siding (1).
A common method is to blow powdered fuel such as pulverized coal into the furnace together with a carrier gas (mainly air) through a fuel injection nozzle (3) that penetrates the wall of the blow pipe and faces into the blow pipe. .

(4)は送風温度低下を防ぐために羽口内面に装着され
た断熱リングである。
(4) is a heat insulating ring attached to the inner surface of the tuyere to prevent a drop in air temperature.

しかし、このような方法にて粉体を吹込む方法では、粉
体燃料に由来する灰分く5〜15%程度含有されている
)が燃焼熱等により溶融し、ブローパイプや羽目内周面
あるいは断熱リングの内周面にこの溶融物が付着堆積し
て送風通路を狭くし、羽目からの熱風および燃料の吹込
を困難ならしめるという問題があった。
However, in this method of injecting powder, the ash content derived from the powder fuel (which contains about 5 to 15%) is melted by combustion heat, etc. This molten material adheres and accumulates on the inner peripheral surface of the heat insulating ring, narrowing the air passage and making it difficult to blow hot air and fuel through the siding.

かかる対策として、従来は粉体燃料吹込ノズル(3)の
吹込み位置を変更したり、あるいは吹込角度を変更する
等の方法がこうじられている。
Conventionally, as a countermeasure against this, methods such as changing the blowing position of the powdered fuel blowing nozzle (3) or changing the blowing angle have been used.

粉体燃料吹込ノズルの位置を変更して粉体燃料を吹込む
方法としては、特開昭58−171509号等に記載さ
れており、吹込ノズルから羽口先端間の粉体燃料の燃焼
率を低下させることによって、羽目への灰分付着を軽減
する方法である。
A method of injecting powdered fuel by changing the position of the powdered fuel injection nozzle is described in Japanese Patent Application Laid-Open No. 171509/1983, etc., and the method is to change the combustion rate of powdered fuel between the injection nozzle and the tip of the tuyere. This is a method of reducing ash adhesion to the siding by lowering the amount of ash.

(発明が解決しようとする課題〉 しかし、従来の前記ノズル吹込位置の変更や吹込角度の
変更等の手段は、ブローパイプの改造に多大な工数を要
し制作費が高くつくという問題があり、また粉体燃料の
燃焼性はその種類によって大きく異なるため、これに対
応することができない欠点があり、さらに高炉操業条件
や羽口付近の設備、粉体燃料吹込設備の条件が異なる高
炉では、その効果が十分に発揮されないという欠点があ
る。
(Problems to be Solved by the Invention) However, the conventional means of changing the nozzle blowing position, changing the blowing angle, etc. have the problem of requiring a large amount of man-hours to modify the blow pipe and increasing production costs. In addition, the combustibility of powdered fuel varies greatly depending on its type, so there is a drawback that it is not possible to respond to this.Furthermore, blast furnaces have different operating conditions, equipment near the tuyere, and powdered fuel injection equipment. The drawback is that the effect is not fully demonstrated.

この発明は従来の技術のこのような実状に鑑みなされた
ものであり、ノズル吹込位置や角度を変更させる必要か
なく、また高炉操業条件や設備条件の制約を受けること
なく、粉体燃料に由来する灰分の付着堆積を効果的に防
止し得る粉体燃料吹込方法を提案しようとするものであ
る。
This invention was made in view of the current state of the conventional technology, and it is possible to use powdered fuel derived from powdered fuel without having to change the nozzle blowing position or angle, and without being constrained by blast furnace operating conditions or equipment conditions. The purpose of this paper is to propose a powder fuel injection method that can effectively prevent the adhesion and accumulation of ash.

(課題を解決するだめの手段) この発明は、高炉羽口より粉体燃料をキャリアガスと共
に吹込むに際し、粉体燃料の燃焼性と周辺温度に基づい
て前記キャリアガス中の酸素含有量を制御することによ
って、ブローパイプや羽目への灰分付着を防止する方法
を要旨とするものである。
(Means for Solving the Problem) This invention controls the oxygen content in the carrier gas based on the combustibility of the powder fuel and the ambient temperature when powder fuel is blown into the blast furnace tuyeres together with the carrier gas. The gist of this paper is a method of preventing ash from adhering to blow pipes and siding.

(作用) 微粉炭等の粉体燃料の気体輸送に用いられるキャリアガ
スとしては、空気が一般的である。粉体燃料は粉体燃料
供給装置から気送管を通じてキャリアカスと共に高炉へ
送給され、ブローパイプに装着した粉体燃料吹込ノズル
を介して羽目より炉内へ吹込まれる。
(Function) Air is generally used as a carrier gas for transporting powdered fuel such as pulverized coal. Powdered fuel is fed from a powdered fuel supply device to a blast furnace together with carrier scum through a pneumatic pipe, and is blown into the furnace through a powdered fuel injection nozzle attached to a blowpipe.

ここで、粉体燃料に由来する灰分のブローパイプや羽目
への付着防止方法として、キャリアガス中の酸素含有量
を変更する手段をこうじたのは、以下に示す理由による
Here, as a method for preventing the adhesion of ash derived from powdered fuel to the blowpipe and siding, the reason for using a means of changing the oxygen content in the carrier gas is as follows.

キャリアガス中の酸素含有量(酸素濃度〉を制御する方
法としては、例えはキャリアガスに空気を用いた場合は
、この空気にイナートガス(N2ガス等)を混合し、空
気とイナートガスとの混合比率を変えることによって制
御する方法を採用することかできる。
A method of controlling the oxygen content (oxygen concentration) in the carrier gas is, for example, when air is used as the carrier gas, inert gas (N2 gas, etc.) is mixed with this air, and the mixing ratio of air and inert gas is adjusted. It is possible to adopt a method of controlling by changing the

ここで、キャリアカス中の目標の酸素含有量は、粉体燃
料の燃焼性とその周辺温度tこ基づいて決定する。
Here, the target oxygen content in the carrier cassette is determined based on the combustibility of the powdered fuel and its surrounding temperature.

すなわち、各種粉体燃料A、B、Cの周辺温度〈送風条
件により決定される)と燃焼率の関係を第1図に、粉体
燃料酸素含有量と燃焼率の関係を第2図に、粉体燃料燃
焼率と灰分付着量との関係を第3図にそれぞれ示すごと
く、各種粉体燃料の燃焼率は粉体燃料周辺温度、および
粉体燃料酸素含有量によって異なり、その燃焼率によっ
て灰分付着量が決まるからである。
That is, the relationship between the ambient temperature (determined by the blowing conditions) and the combustion rate of various powdered fuels A, B, and C is shown in Figure 1, and the relationship between the oxygen content of the powdered fuel and the combustion rate is shown in Figure 2. As shown in Figure 3, which shows the relationship between the combustion rate of powdered fuel and the amount of ash deposited, the combustion rate of various powdered fuels varies depending on the ambient temperature of the powdered fuel and the oxygen content of the powdered fuel, and the ash content depends on the combustion rate. This is because the amount of adhesion is determined.

換言すれば、ブローパイプや羽目への灰分付着を生じな
い燃焼率となるように、高炉に吹込む粉体燃料の燃焼性
と送風条件に基づいてキャリアガス中の酸素含有量を決
定するのである。
In other words, the oxygen content in the carrier gas is determined based on the combustibility of the powdered fuel injected into the blast furnace and the blowing conditions, so as to achieve a combustion rate that does not cause ash adhesion to the blow pipe or siding. .

(実施例) 第4図はこの発明方法を実施するための粉体燃料吹込装
置の一例を示す概略図、第5図は同上装置におけるブロ
ーパイプと羽口の部分を拡大して示す概略図で、(5)
は粉体燃料供給設備、(6)は気送管、(7)はキャリ
アガス(ここでは空気を用いた)供給管、(8)はキャ
リアガス中酸素濃度制御用のイナートガス供給管、(9
)は酸素濃度計、<10)(11)は流量調整用バルブ
をそれぞれ示す。
(Example) Fig. 4 is a schematic diagram showing an example of a powder fuel injection device for carrying out the method of the present invention, and Fig. 5 is a schematic diagram showing an enlarged view of the blow pipe and tuyeres in the same device. , (5)
is powder fuel supply equipment, (6) is pneumatic pipe, (7) is carrier gas (air is used here) supply pipe, (8) is inert gas supply pipe for controlling oxygen concentration in carrier gas, (9) is
) indicates an oxygen concentration meter, and <10) and (11) indicate a flow rate adjustment valve, respectively.

すなわち、粉体燃料供給設備(5)から一定量ずつ切出
された粉体燃料は、輸送用空気と共に気送管(6)によ
って吹込ノズル(3)へ送られ、ブローパイプ(2)を
通して羽口(1)より高炉へ吹込まれる。
That is, a fixed amount of powdered fuel is cut out from the powdered fuel supply equipment (5) and sent along with transportation air to the blowing nozzle (3) via the pneumatic pipe (6), and then sent to the blower through the blowpipe (2). It is blown into the blast furnace through the mouth (1).

粉体燃料輸送用空気は、粉体燃料吹込設備の上流におい
て、灰分付着を生じない目標の酸素含有量となるように
イナートガスと所定の比率で混合されて気送管(6)へ
供給される。輸送用空気中の酸素含有量の調整は、酸素
濃度計(9)により輸送用空気の流量調整用バルブ(1
0)とイナートガス流量調整用バルブ(11)を調整し
て行う。
The air for transporting powdered fuel is mixed with inert gas at a predetermined ratio so as to have a target oxygen content that does not cause ash adhesion upstream of the powdered fuel injection equipment, and is supplied to the pneumatic pipe (6). . The oxygen content in the transportation air can be adjusted using the oxygen concentration meter (9) using the transportation air flow rate adjustment valve (1).
0) and the inert gas flow rate adjustment valve (11).

このようにして粉体燃料輸送用空気と共に吹込まれる粉
体燃料は、ブローパイプ(2)内の吹込ノズル先端から
羽目先端までの間で適正な燃焼が行われる結果、粉体燃
料に由来する灰分がブローパイプ(2)内および羽口(
1)内面へ付着することがなく、仮に付着しても高炉へ
の熱風および燃料の吹込に対する影響はほとんど無視し
得る程度であると考えられる。
The powdered fuel that is injected together with the air for transporting powdered fuel in this way is derived from powdered fuel as a result of proper combustion between the tip of the blowing nozzle and the tip of the blade in the blow pipe (2). Ash content is inside the blowpipe (2) and the tuyere (
1) It does not adhere to the inner surface, and even if it does, the effect on hot air and fuel injection into the blast furnace is considered to be almost negligible.

次に、この発明方法を実高炉に適用した場合の実施結果
について説明する。
Next, the results obtained when the method of this invention is applied to an actual blast furnace will be explained.

実施例1 内容積2700m3の高炉に、第1図に示す方法を適用
し、キャリアガスに空気を用い、該空気中の酸素含有量
調整用カスにN2を使用して、高炉内に微粉炭(灰分1
0.3%)を吹込んだ。その時の高炉操業条件を第1表
に示す。
Example 1 The method shown in Fig. 1 was applied to a blast furnace with an internal volume of 2700 m3, air was used as the carrier gas, N2 was used as the residue for adjusting the oxygen content in the air, and pulverized coal ( Ash content 1
0.3%) was injected. Table 1 shows the blast furnace operating conditions at that time.

本実施例では、キャリアガス中酸素含有量15%で微粉
炭を吹込んだ結果、ブローパイプ内および羽口内には灰
分の付着はほとんど認められなかった。一方、酸素含有
量を9%にしたところ、灰分の付着並びに成長が生じた
In this example, as a result of blowing pulverized coal with an oxygen content of 15% in the carrier gas, almost no ash was observed inside the blow pipe and the tuyere. On the other hand, when the oxygen content was set to 9%, ash adhesion and growth occurred.

実施例2 高炉操業条件を第2表に示すように変更(送風温度を1
200℃に変更)し、実施例1と同様の方法で微粉炭を
吹込んだ結果、本実施例においてもキャリアガス中酸素
含有量10%にてブローパイプおよび羽目への灰分付着
は認められなかった。一方、酸素含有量を4%にしなと
ころ、灰分の付着並びに成長が生じた。
Example 2 The blast furnace operating conditions were changed as shown in Table 2 (blow temperature was increased to 1
As a result of injecting pulverized coal in the same manner as in Example 1, no ash adhesion to the blow pipe or siding was observed even in this example when the oxygen content in the carrier gas was 10%. Ta. On the other hand, when the oxygen content was reduced to 4%, ash adhesion and growth occurred.

実施例3 第1表に示す高炉操業条件にて、実施例1と同様の方法
により微粉炭(灰分11.5%)を吹込んだ結果、キャ
リアガス中酸素含有量20%にてブローパイプおよび羽
目への灰分付着は認められなかったが、酸素含有量を1
3%にしたところ、灰分の付着並びに成長が生じた。
Example 3 Under the blast furnace operating conditions shown in Table 1, pulverized coal (ash content 11.5%) was injected in the same manner as in Example 1. As a result, the blowpipe and Although no ash was observed on the siding, the oxygen content was reduced to 1
When the content was set at 3%, ash adhesion and growth occurred.

以下余白 第1表 第2表 (発明の効果) 以上説明したごとく、この発明は高炉へ吹込む粉体燃料
のキャリアガス中の酸素含有量を調節することによって
吹込ノズル先端から羽口先端までの燃焼状況を制御し、
粉体燃料に由来する灰分のブローパイプや羽目への付着
を防止する方法であるから、高炉設備条件の制約を受け
ることなく粉体燃料の種類の変更や送風条件の変更に容
易に対応でき、高炉の安定操業、銑鉄コスト低減に大な
る効果を奏するものである。
Table 1 Table 2 (Effects of the Invention) As explained above, this invention improves the air flow from the tip of the injection nozzle to the tip of the tuyere by adjusting the oxygen content in the carrier gas of the powdered fuel injected into the blast furnace. Control the combustion situation,
Since this method prevents ash derived from powdered fuel from adhering to the blow pipe and siding, it can easily accommodate changes in the type of powdered fuel and ventilation conditions without being restricted by blast furnace equipment conditions. This has a great effect on stable operation of blast furnaces and reduction of pig iron costs.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明における各種粉体燃料の周辺温度と燃
焼率の関係を示す図、第2図は同じく各種粉体燃料の酸
素含有量と燃焼率の関係を示す図、第3図は同じく各種
粉体燃料燃焼率と灰分付着量の関係を示す図、第4図は
この発明方法を実施するための装置の一例を示す概略図
、第5図は同上装置におけるブローパイプと羽目の部分
を拡大して示す概略断面図、第6図は従来の粉体燃料吹
込方法の一例を示す概略図である。 1・・・羽口、2・・・ブローパイプ、3・・・燃料吹
込ノズル、5・・・粉体燃料供給設備、6・・・気送管
、7・・・キャリアガス供給管、8・・・イナートガス
供給管、9・・・酸素濃度計、10.11・・・流量調
整用バルブ。 特許出願人  住友金属工業株式会社 代 理 人  押  1) 良  久!1第1図 粉体燃料周辺温度(°C) 第2図 粉体燃料酸素含有量(%) 第3図 第4図 第5図 第6図
Figure 1 is a diagram showing the relationship between ambient temperature and combustion rate of various powdered fuels in this invention, Figure 2 is a diagram showing the relationship between oxygen content and combustion rate of various powdered fuels, and Figure 3 is the same. A diagram showing the relationship between the combustion rate of various powdered fuels and the amount of ash deposited. Fig. 4 is a schematic diagram showing an example of an apparatus for carrying out the method of the present invention. Fig. 5 shows the blow pipe and lining of the same apparatus. FIG. 6 is an enlarged schematic sectional view showing an example of a conventional powder fuel injection method. DESCRIPTION OF SYMBOLS 1... Tuyere, 2... Blow pipe, 3... Fuel injection nozzle, 5... Powdered fuel supply equipment, 6... Pneumatic pipe, 7... Carrier gas supply pipe, 8 ... Inert gas supply pipe, 9 ... Oxygen concentration meter, 10.11 ... Flow rate adjustment valve. Patent applicant Sumitomo Metal Industries Co., Ltd. Agent 1) Yoshihisa! 1 Figure 1 Ambient temperature of powdered fuel (°C) Figure 2 Oxygen content of powdered fuel (%) Figure 3 Figure 4 Figure 5 Figure 6

Claims (1)

【特許請求の範囲】[Claims] 高炉羽口より粉体燃料をキャリアガスと共に吹込む方法
において、粉体燃料の燃焼性と周辺温度に基づいて粉体
燃料キャリアガス中の酸素含有量を制御することを特徴
とする高炉への粉体燃料吹込方法。
A method of injecting powdered fuel together with a carrier gas from a blast furnace tuyere, characterized in that the oxygen content in the powdered fuel carrier gas is controlled based on the combustibility of the powdered fuel and the ambient temperature. How to inject body fuel.
JP2336355A 1990-11-30 1990-11-30 Injection method of powdered fuel into blast furnace Expired - Lifetime JPH0694564B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2336355A JPH0694564B2 (en) 1990-11-30 1990-11-30 Injection method of powdered fuel into blast furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2336355A JPH0694564B2 (en) 1990-11-30 1990-11-30 Injection method of powdered fuel into blast furnace

Publications (2)

Publication Number Publication Date
JPH04202708A true JPH04202708A (en) 1992-07-23
JPH0694564B2 JPH0694564B2 (en) 1994-11-24

Family

ID=18298273

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2336355A Expired - Lifetime JPH0694564B2 (en) 1990-11-30 1990-11-30 Injection method of powdered fuel into blast furnace

Country Status (1)

Country Link
JP (1) JPH0694564B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011523439A (en) * 2008-05-23 2011-08-11 ポール ヴルス エス.エイ. How to put pulverized coal into the blast furnace
WO2014045876A1 (en) * 2012-09-20 2014-03-27 三菱重工業株式会社 Blast furnace installation
CN104471081A (en) * 2012-09-20 2015-03-25 三菱重工业株式会社 Blast furnace installation
KR20170083023A (en) * 2014-08-18 2017-07-17 퀴트너 홀딩 게엠베하 운트 코. 카게 Method for blowing substitute reducing agents into a blast furnace

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JPS58181810A (en) * 1982-03-31 1983-10-24 Kobe Steel Ltd Injection of powdery fuel into blast furnace
JPH0254708A (en) * 1988-08-18 1990-02-23 Nippon Steel Corp Method for blowing finely pulverized coal into blast furnace
JPH02213406A (en) * 1989-02-15 1990-08-24 Kawasaki Steel Corp Method and injecting fuel from tuyere in blast furnace

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JPS58181810A (en) * 1982-03-31 1983-10-24 Kobe Steel Ltd Injection of powdery fuel into blast furnace
JPH0254708A (en) * 1988-08-18 1990-02-23 Nippon Steel Corp Method for blowing finely pulverized coal into blast furnace
JPH02213406A (en) * 1989-02-15 1990-08-24 Kawasaki Steel Corp Method and injecting fuel from tuyere in blast furnace

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011523439A (en) * 2008-05-23 2011-08-11 ポール ヴルス エス.エイ. How to put pulverized coal into the blast furnace
US8652395B2 (en) 2008-05-23 2014-02-18 Paul Wurth S.A. Method for feeding pulverised coal into a blast furnace
WO2014045876A1 (en) * 2012-09-20 2014-03-27 三菱重工業株式会社 Blast furnace installation
JP2014062279A (en) * 2012-09-20 2014-04-10 Mitsubishi Heavy Ind Ltd Blast furnace equipment
CN104471081A (en) * 2012-09-20 2015-03-25 三菱重工业株式会社 Blast furnace installation
CN104471079A (en) * 2012-09-20 2015-03-25 三菱重工业株式会社 Blast furnace installation
KR20170083023A (en) * 2014-08-18 2017-07-17 퀴트너 홀딩 게엠베하 운트 코. 카게 Method for blowing substitute reducing agents into a blast furnace
JP2017525857A (en) * 2014-08-18 2017-09-07 クットナー ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディットゲゼルシャフトKuttner Holding Gmbh & Co.Kg Method for blowing a displacement reducing agent into a blast furnace
US10472689B2 (en) 2014-08-18 2019-11-12 Küttner Holding GmbH & Co. KG Method for blowing substitute reducing agents into a blast furnace

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