JPH04288003A - Harmful animal repelling composition - Google Patents

Abstract

PURPOSE:To obtain a repelling composition having higher effect than a conventional harmful animal repellent, excellent long acting effect, having low toxicity to men and beasts and mild smell and further capable of feeling even aroma. CONSTITUTION:The objective composition consists essentially of a mixture of natural terpenoid monomer having low toxicity to men and beasts or terpenoid oligomer or cooligomer naturally metabolized in a natural plant body and copolymer compound of these terpene monomers and phenol, vinyl, styrene or maleic acid based monomer and having <=3000 molecular weight, usable to harmful animal whose range is wide, having low toxicity to men and beasts and capable of use jointly with other agricultural chemical. The composition suppresses ecospecies which is relatively harmful to men while existing together with harmful animals having same life system as human on the earth and can substantially bring out coexistence of human and these harmful animals.

Description

[Detailed description of the invention]

0001

[Industrial Application Field] The present invention is applicable to dogs, cats, rats, rabbits, wild boars, moles, deer, weasels, crows, crows, sparrows, pigeons, starlings, cockroaches, termites,
This invention relates to a repellent composition for harmful or unpleasant animals such as ants, burrs, mites, mussels, sea breams, snails, snakes, mosquitoes, flies, planthoppers, stink bugs, leafhoppers, aphids, sea fireflies, and slugs.

0002

[Prior art] Currently, global warming, ozone layer depletion, acid rain,
The environment is deteriorating due to global environmental pollution caused by human factors such as radiation pollution. As a countermeasure for this,
How the world should approach this issue is being discussed, and cooperation is being requested. This way of thinking is also called a type of global environmentalism, and it is becoming a United Nations movement that should be given priority over each country and nationalism. In other words, measures such as eliminating carbon dioxide to prevent global warming, banning the production of halon compounds to protect the ozone layer, and preventing over-deforestation are being considered. In order for humanity to continue to prosper and prosper peacefully in this era where global environmental protection is given priority, it is necessary to produce food, maintain a living environment, and interact with living things other than humans.
It is most desirable to coexist and co-prosper with living things, especially animals, and the research and application of the pest repellent of the present invention has the great advantage of meeting that purpose.

A mixture of fish oil and naphthalene has been used in Hokkaido since the Meiji era as a repellent for harmful animals such as rats, hares, and ducks on agricultural crops, and this is said to be the first repellent in Japan. Subsequently, creosote, cycloheximide, β-naphthol, turum, thiophenes, lemongrass oil, diallyl sulfide, and iron oxide powder have been used. Also, mosquitoes,
For blood-sucking insects such as ticks and fleas, dimethyl phthalate, ethylhexanediol, indalone, and diethyltoluamide are used.

Generally, repellents include olfactory repellents (
olfucory repellent) and gustatory repellent (gustatory repellent).
ENT), and the former includes essential oils.
oil), vegetable rubber resins, and the latter include organic acids, alcohols, alkaloids, tannins, glycosides, etc. In addition, tactile repellents such as adhesive
It is also effective to use a function such as ``pellent''.

[0005] In the living world, for the sake of self-preservation, animals that attack from the outside usually have unpleasant odors and tastes. This is particularly seen in plants, where essential oils, alkaloids, and glycosides have this significance, and formic acid, butyric acid, salicylaldehyde, mercaptans, allyl compounds, etc. also play a role in preserving species between animals. There is.

[0006] Conventionally, monoterpenoids (Japanese Patent Application Laid-Open No. 1983-1999) have been used as pest repellents for cockroaches.
86021 Publication), unsaturated alcohols and aldehydes for birds (Japanese Patent Application Laid-open No. 53-101531), higher ketones and green leaf alcohols, cinnamaldehyde, ketones for dogs, cats, birds, and animals (Japanese Patent Application Publication No. 57-25521) ), guasazine for rats and rabbits (Japanese Unexamined Patent Publication No. 57-67507),
Guasazine and chulum for harmful birds and animals (Unexamined Japanese Patent Publication No. 59-25
306 Publication), cyclic turpentine alcohol (
JP-A-57-179101), prothiophos and tulum for birds (JP-A-59-10504), menthol and ethyltoluamide for dogs and cats (JP-A-60-1)
42903 Publication), creosote and pyridine (for bird damage),
(Japanese Unexamined Patent Publication No. 61-56110), thurum and animal and vegetable oils for forest pests (Japanese Unexamined Patent Publication No. 61-12005), and ethylene-vinyl acetate copolymer beads impregnated with lemongrass oil, etc. for dogs, cats, etc. JP-A-61-172801), glycol ethers for dogs, cats, etc. (JP-A-61-172801);
No. 194001, Japanese Patent Application Laid-open No. 1986-267501), glycol ether (Japanese Patent Application Laid-open No. 1982-267501), glycol ether for ticks, snakes, etc.
No. 289002), higher ketones, alcohols, and aldehydes for dogs, cats, etc. (Japanese Unexamined Patent Publication No. 61-289003), shikimic acid and mustard glycosides for rats (Japanese Unexamined Patent Publication No. 61-289)
91507), limonene for flies and mosquitoes (Japanese Unexamined Patent Publication No. 1982
-409 Publication), bis-(2-chloroisopropyl ether) for dogs and cats (Japanese Unexamined Patent Publication No. 12702/1982),
Mole, shikimi and mustard glycosides (Unexamined Japanese Patent Publication No. 62-4550
8), limonene for pigeons, flies, etc. (JP-A-62-1)
64602), and polycyclic terpenoid glycosides found in barnacles and mussels (Japanese Patent Laid-Open No. 63-41495). In addition, as a pest repellent that is a basic patent related to the present invention, a combination of a specific terpenoid compound monomer and a low polymer or low copolymer with an average molecular weight of 1,000 or less (Japanese Patent Application Laid-Open No. 1-294601, chem.abs
t, vol. 113 (1990) 73059n), brassylic acid (JP-A-1-96101), cashew nut oil (JP-A-1-96102), thiazole compounds (JP-A-64-3
No. 8003), cinnamaldehyde (
JP-A-1-261303), a polyethylene bag containing mica powder mixed with black weevils (JP-A-1-203303)
Publication No. 2-454), l-menthon by Keyari et al.
01 Publication), amide compounds such as propyl-methyl-pentenamide for general pests (JP-A-2-53758, JP-A-2-56455, JP-A-2-62852), and lemongrass compatible with Styrofoam. to repel harmful animals (Japanese Unexamined Patent Publication No. 2-56402), and to prevent flies and cockroaches from using terpenoid monomers such as linalool (Unexamined Japanese Patent Publication No. 2-6
7202) and benzyl ether (Japanese Patent Application No. 1-273144) for repelling pests. As a pest repellent, there is a combination of one or more of alkylbenzene, diphenyl, alkylphenol, diethylene glycol alkyl ether acetate, and a terpenoid compound (Japanese Patent Application No. 71622/1999).

[0007] Furthermore, various animal repellent compositions are published and described in Chemical Abstracts Volume 1 (1907) to Volume 112 (1990), but the average molecular weight of the terpenoid compound of the present invention is There is no description of a pest repellent composition based on the combined use of a low polymer of 3,000 or less and/or a low copolymer thereof. However, European Patent No. 0173410 (5.Mar
Ch. (1986) discloses that di-1-p-menthene (terpene dimer) and its high polymer (terpene polymer) are used as efficacy enhancers of defoliants such as 2,2-dichloropropionic acid. , each alone has almost no repellent effect.

[0008]

[Problems to be Solved by the Invention] The present invention is more effective than the above-mentioned conventional harmful animal repellents, has excellent long-lasting effects, has low toxicity to humans and livestock, has a mild odor, and even has a scent that can be detected. The purpose is to provide a repellent composition.

[0009]

[Means for Solving the Problems] The present invention provides specific terpenoid compound monomers and/or low polymerized or low copolymerized oligomers thereof, these terpenoid monomers, and monomers selected from phenolic, styrene, vinyl, maleic, and monomers. The basic structure is that a low copolymerized oligomer is used in combination with a compound that has been prepared.

The terpenoid compound monomers used in the present invention are a group of compounds contained in plant essential oils or resin gums obtained by steam distillation of various parts of plants. Its essence is that it contains two or more isoprenes, and substances with 10 carbon atoms (C5 x 2) are monoterpenoids, substances with 15 carbon atoms (C5 x 3) are sesquiterpenoids, and substances with 20 carbon atoms (C5 x 3) are sesquiterpenoids. Substances (C5×4) are classified as diterpenoids, and substances with 30 carbon atoms (C5×6) are classified as triterpenoids. These terpenoid compounds are aromatic and essential oil components of plants, and are substances that have no effect on the natural cycle. In addition, among biologically active natural substances, those currently recognized as having pesticide functions, such as Aspergillus spp. Lactin), acebi (acebotoxin component), etc. can also be used as so-called Chinese herbal pesticides or natural pesticidal agents that are less toxic to humans, if they are given the animal repellent function of the terpenoids of the present invention. Its insecticidal mechanism is not only direct insecticidal power, but also so-called insect growth control agents that inhibit the unique growth process such as metamorphosis of pests, thereby eradicating the pest fauna.
It is also possible to configure something useful as a growth regulator (IGR). In addition, the average molecular weight of the co-oligomer used in the present invention, that is, the co-oligomer of terpenes and terpenes and phenol-based, styrene-based, vinyl-based, and maleic monomers, is 3,000.
Below, it can be known by ice-crystal precipitation method with benzene, camphor, acetic acid, etc., high-speed gel liquid chromatography, gas chromatography, mass spectrometer, etc.

Next, terpenoid compositions that exhibit excellent effects in these repellent functions are compatible with or mixed with various natural resins and organic polymer resins, and are used in cast products, molded products, laminates, films, and adhesives. It can be used in the form of an agent or a paint. Thus, the harmful animal repellent molded product of the present invention can be used for aircraft materials, vehicles, ship materials, OA equipment, electric wires, electrical appliances, optical cable lines,
submarine communication lines, communication cables, caulking materials, sealing materials,
Building materials, toys, sports equipment, packaging materials, educational materials, medical equipment,
It can be used as a molded product for a wide variety of purposes, such as slimming devices and tableware. In addition, these terpenoid repellents are combined with various natural or synthetic resin oligomers and rubber-like resins as tackifiers, and the adhesive strength of the final repellent surface is tested using Japanese Industrial Standard Z-0237 (adhesive tape, adhesive sheet) test. When testing by tack (ball rolling method), the tactile repellency of harmful animals (tou
ch phobic) and repellent (neophobic)
By c), it is also possible to study the repellency and double the effect. This is particularly effective against birds that have wings and have the ability to fly in the air, such as harmful birds. Its adhesive strength is 10-15mm in width and 10mm in length.
cm of tape was treated with the repellent composition of the present invention, and a slope of 30 cm was applied to each tape.
30 different sizes of steel balls from 3/32 inch to 1 inch in diameter are rolled at an initial speed of 0 from a position 10 cm above the slope, and the maximum diameter that stops on the treated surface tape is Make sure that the ball size is 4 or more (measurement temperature 20°C). The present invention also includes compositions that double the effectiveness of harmful animal repellent compositions by imparting adhesive strength in this manner.

[0012] The material of the present invention will be described below.

β-Myrcene (C10H16) (Component No.
．． 1): Contained in Pei oil, hop oil, etc., boiling point 166-1
It has three double bonds at 67°C and tends to form oligomers such as dimircene over time.

Alloocymene (C10H16) (Component No.
．． 2): α-type ocimene (C1
0H16) 2,6-dimethyl-1,5,7-octatriene or β-type ocimene (C10H16) There are isomers of 2,6-dimethyl-2,5,7-octatriene, but they are stable isomers. 2,6-dimethyl-2,4,6-octatriene is called alloocimene. Boiling point 81℃ (12mm
It is easily oxidized by Hg) and tends to produce 2- to 3-polymer oligomers.

Citral (C10H16O) (Component No.
．． 3): Contained in lemongrass oil, etc., with a boiling point of 226℃
, b. Easily oxidized in air and polymerized by strong acids. Chemical name is 3,7-dimethyloctadiene-1
-It is Earl.

[0016] Linalool (C10H16O) (component No.
．． 4): Contained in orange oil and lavender oil, boiling point 1
It has optical isomers at 98-200°C and is synthesized from β-pinene. 3,7-dimethyl-1,6-octadiene-
3-ol is used.

[0017] Limonene (C10H16) (component No. 5
): Contained in large quantities in citrus fruits and widely distributed in plants together with α-pinene. There are d-, l- and dl types, and dl
-Limonene is called dipentene. Both boiling points are approximately 176℃
It is relatively stable both before and after and can be distilled under normal pressure, but it oxidizes if left permanently in the air. When treated with acid, it easily becomes dipentene, and when heated with sulfur, it changes to p-cymene. It is primarily obtained more economically than Pella oil. Also, when treated cold with mineral acids, water is added to form terpineol and hydrated turpentine.

Dipentene (C10H16) (Component No.
6): Optically inactive form of limonene. It is naturally found in many plant essential oils, such as terpine oil from various pines, citronella oil, lemongrass oil, and camphor oil, and is easily polymerized by heat at a boiling point of 178°C.

Terpinene (C10H16) (Component No.
7): There are α, β and γ types, boiling point approximately 177℃, 173
℃ and 183℃, contains cardamom oil, boiled coriander, and has a lemon-like odor. The α type quickly polymerizes in the presence of air or light and becomes resin-like. The β form can only be obtained synthetically, but the individual isomers are difficult to separate.

Terpineol (C10H16O) (component No. 8): Monocyclic monoterpene alcohol, available in α, β and γ types, with boiling points of approximately 220°C, 210°C (750mmH)
g) and has a melting point of about 69°C in cardamom oil, neroli oil and pine essential oil, and has a lilac-like aroma. Also,
Hydrated turpentine obtained by treatment with sulfuric acid also has a melting point of 116° C. and can be used as solid turpentine in the form of powder, granules, and tablets.

Anethole (C10H12O) (Component No.
．． 9): p-propenylanisole with a boiling point of approximately 81°C (2
．． 3mmHg), 230°C (760mmHg) and a melting point of about 21°C.

[0022] Pinene (C10H16) (component No. 10
): There are α and β types, and it is the most widely distributed in the plant kingdom. α-Pinene is colorless, has a unique odor, and has a boiling point of approximately 155°C.
It is found in the resins of pinaceae plants and in wood terpine oil, and is the main component of sulfate terpine, especially derived from pulp mills. There are optical isomers, but
Easily isomerized with acids or hot alkalis. In addition, using aluminum chloride or the like as a catalyst, it becomes a high polymer at -15°C with the cyclic structure remaining. In addition to dimer, α-pinene has a softening point of 65 to 97°C and a molecular weight of 6.
00 to 700 trimers, so-called oligomers, are obtained. In addition, useful terpenoid compounds such as camphor, camphor, and terpineol are derived, and are important compounds as industrial raw materials. It is also generally contained in large amounts in gum turpentine oil obtained during pine resin refining.

Nopol (C10H18O) (Component No.
11) is 6,6-dimethylbicyclo[3,1,1]hept-2-en-2-ethanol with a boiling point of about 230-24
It is a bicyclic terpene alcohol that can also be obtained by condensation of β-pinene and formaldehyde at 0°C.

Camphene (C10H16) (Component No.
12) has a weak camphor-like odor with a melting point of about 50°C, which is similar to pine needle oil. Furthermore, excess hydrogen chloride from α-pinene forms bornyl chloride, which is further treated with an alkali to be derived into camphene. It is made into various oligomers and polymers and is used in a wide variety of applications, including paints and adhesives.

Nobyl acetate (C13H21O2)
(Component No. 13) is an acetate ester of Nopol (component No. 11), which has a boiling point of about 250 to 260°C and is used as a synthetic fragrance. Furthermore, when used as a raw material for the harmful animal repellent composition of the present invention together with the following isobornyl acetate, it imparts a fragrance to humans and is effectively used as an animal repellent.

Isobornyl acetate (C12H20O
2) (Ingredient No. 14) is camphene (Ingredient No. 1
It is an aromatic liquid with a boiling point of about 224°C obtained by heating 2) with a mixture of 50% sulfuric acid and glacial acetic acid.

Phellandrene (C10H16) (component N
o. 15) has α and β types and is widely distributed in plants. The beta form, an aromatic liquid, is sometimes present at 5-7% in turpentine. Also found in fennel oil and ginger oil.
The boiling points are approximately 174°C and 171°C.

Δ3 Karen (C10H16) (Component No.
．． 16) is present in turpentine oil and is also contained in sulfate turpentine. Alias 3-Caren
Also called e, 3,7,7-trimethylbicyclo[4,1
0] Hepto-3ene with a boiling point of about 170°C.

Geraniol (C10H18O) (component N
o. 17) is naturally present in free or ester form, and is contained in rose oil and geranium oil in an amount of 40 to 50%. It has a sweet rose-like aroma, has a boiling point of about 229-230°C, and is an important ingredient in cosmetic fragrances.

Cineol (C10H18O) (Component No.
．． 13) is an aromatic liquid with a boiling point of 177°C and is used as a fragrance and medicine. Also, as a biomass, it is a terpenoid component of eucalyptus oil, which is seen as a promising plant energy source.

As mentioned above, all of these terpenoid monomers have a normal pressure boiling point of 250° C. or less, and when used alone as a harmful animal repellent, they have sufficient short-term repellent function, but long-term function cannot be expected.

[0032] Generally, when outdoors under ventilation, the material quickly evaporates and scatters, becoming ineffective, depending on the temperature, wind volume, etc. The composition of the present invention further comprises the above-mentioned terpenoid monomers and/or these terpenoid oligomers, as well as phenolic, ethylene-based,
Since it uses a low copolymer compound of vinyl and maleic acid monomers and is added as a so-called retention agent in the fragrance industry, it can volatilize and diffuse at the same effective optimum concentration for a long period of time, maintaining its repellent function. This is similar to the method of blending fragrances for cosmetics used by humans. In other words, the fastest volatile component (Top note) and the middle volatile component (Mi
ddle note) and high boiling point components (Base
This technique is exactly the same as the method used to balance the fragrance (note) and maintain a constant fragrance over a long period of time. Generally, oligomer refers to a weight average molecular weight of 10,000 or less [H. Staudinger, Die Ho
Chmolekulare Organische
Verbindungen (1932)], the repellent preferably has a molecular weight of about 3,000 or less. These are generally high viscosity liquids or low melting solids and can be isolated by conventional distillation.

The terpene oligomer is preferably dissolved and dispersed in 1 part of monomer, 1 to 10 parts of activated clay or acidic clay, and an appropriate amount of a solvent, and polymerized at about 100 to 150°C. When using a Friedelgraft type catalyst, a high molecular weight polymer having a molecular weight of 10,000 or more is likely to be formed at this reaction temperature, so it is preferable to polymerize for a short time at around 30°C. Although the high polymer may be thermally decomposed, it can also be obtained by bringing a heated solution of the monomer into contact with heated strongly acidic cation exchange resin particles. In addition, telomerization occurs in the presence of a substance with a large chain transfer constant, such as a telogen.
ation), oligomers can also be obtained.

[0034] The oligomers used in the present invention are listed below.

[0035] Pinene oligomer (component No. 19) is
Add 1% aluminum chloride of α-pinene to a 50% solution of α-pinene, stir at 30-35°C for 2 hours, filter,
Approximately 20 dimers obtained by fractional distillation removal of solvent after water washing and dehydration
%, a mixture of about 70% trimer and about 10% tetramer or higher polymer, and has an average molecular weight of about 460.

[0036] Pinene oligomer (component No. 20) is
Add 5% aluminum chloride of β-pinene to a 50% toluene solution of β-pinene, react at 40 to 45°C for 2 hours, then wash with 5% sodium hydroxide solution, then wash with water, and remove toluene and unreacted by distillation. excluding β-pinene. This composition has a softening point of about 134° C. and exhibits an average molecular weight of 1,500 when measured by the freezing point depression method using benzene as a solvent.

Dipentene oligomer (component No. 21)
is 0% dipentene in a 50% dipentene toluene solution.
．． Add 5% aluminum chloride and stir at 30 to 35°C for 2 hours to obtain about 40% of the 2-weight product and about 50% of the 3-weight product.
%, high polymer and monomer, and has an average molecular weight of about 380.

Dipentene oligomer (component No. 22)
is 50% dipentene in toluene solution.
% of aluminum chloride solution was added and kept at 40-45°C for 2 hours. Perform the same operations as in step 21 below to reach softening point 13.
The composition exhibits an average molecular weight of 1,200 at 6°C.

Camphene oligomer (component No. 23)
A camphene solution heated to 70°C was allowed to flow down at a rate of 4 ml/min into a tube with a layer length of 30 cm containing a layer of strongly acidic cation-type ion exchange resin particles kept at about 70°C, washed with cold alkali and water, and then subjected to fractional distillation. It has a composition of about 95% dimer and about 5% trimer, and has an average molecular weight of about 300.

Alloocimene oligomer (component No. 24)
) thermally decomposes an alloocimene high-molecular polymer to produce 210~
Approximately 5% monomer obtained by collecting the fraction at 315°C, 2
It is composed of about 70% mer and 25% trimer, and has an average molecular weight of about 310.

Pinene dipentene oligomer (component No.
25) is obtained by adding 1% by weight of aluminum chloride to a mixture of 1 part of α-pinene, 1.5 parts of β-pinene, and 2.5 parts of dipentene, and stirring the mixture at 30 to 35°C for 2 hours.
The cooligomer has a viscosity of about 100 cps at 0.degree. C. and an average molecular weight of about 850.

Campfennopol oligomer (component No.
．． 26) is 50% of 1 part camphene and 1 part Nopol.
Add 5% by weight of acid clay of terpene monomer to the solution,
A cooligomer obtained by stirring at 120° C. for 5 hours and rectification has a viscosity of 165 cps at 80° C. and an average molecular weight of about 1,120.

Myrsenpinene oligomer (component No. 2)
7) is 50% of 2 mol of myrcene and 1 mol of β-pinene.
This cooligomer has a viscosity of 145 cps at 80°C and an average molecular weight of about 880, obtained by adding 5% by weight of activated clay of a terpene monomer to a % toluene solution and stirring at 120°C for 2 hours.

Next, examples of copolymerized compounds of terpene monomers and monomers of other compounds (hereinafter referred to as terpine cooligomers) include the following.

[0045] The α-pinene bisphenol A cooligomer (component No. 28) includes 1 mol of α-pinene,
Dissolve 2 mol of bisphenol A in cyclohexane,
There is a cooligomer with an average molecular weight of about 1400 that is purified, dehydrated and purified by reacting at 95 to 105°C for 4 hours using activated clay as a catalyst.

For the β-pinene/styrene cooligomer (component No. 29), a solution of equal amounts of β-pinene and styrene was dropped into toluene in which aluminum chloride powder was dispersed at 30 to 40°C and reacted for 3 hours. , a cooligomer having an average molecular weight of about 1,100 is obtained by washing with water, dehydrating and distilling the obtained product.

Dipentene/phenol cooligomer (component No. 30) contains 470 g of phenol, 48%
Add 340 g of dipentene dissolved in 1 liter of toluene at 25°C to 35 ml of BF ether solution and 200 ml of toluene solution while stirring for 5 hours, react with stirring for 3 hours, and after washing and dehydrating with water, collect the fraction at 1 mmHg and 220 to 240°C. There are cooligomers with an average molecular weight of about 320-330.

For the d-limonene/vinyltoluene co-oligomer (component No. 31), 260 g of d-limonene and 8 g of aluminum chloride were stirred in 400 ml of toluene.
Add 140 vinyl toluene solution dissolved in 120 ml of toluene to the solution, polymerize at 35-40°C for 2 hours, wash with water and distill to obtain a solution with a softening point of 112° and a molecular weight of about 1.65.
There are 0 cooligomers.

As the d-limonene/styrene cooligomer (component No. 32), a solution of 400 g of d-limonene in 800 ml of toluene, 400 g of styrene in 16 g of aluminum trichloride, and 100 ml of toluene was added dropwise at 35 to 40°C for 4 hours. Softening point 1 obtained by stirring polymerization and washing with water
There is a cooligomer with a 15° average molecular weight of about 1,200.

As the d-limonene/maleic anhydride cooligomer (component No. 33), 138 g of d-limonene and 100 g of maleic anhydride were added to 800 ml of toluene and mixed together. The mixture is then gradually heated and stirred at 40-45° C. for 2 hours, resulting in a cooligomer having an average molecular weight of about 505.

[0051] As α-terpinene/maleic anhydride cooligomer (component No. 34), 800 ml of toluene
280g of α-terpinene, 16g of aluminum trichloride
There is a terpinene maleic acid cooligomer having an average molecular weight of about 475 obtained by adding 215 g of maleic anhydride to the solution and stirring at 35 to 40°C for 3 hours.

As β-pinene/acrylonitrile cooligomer (component No. 35), 16 g of aluminum chloride was added to 275 g of β-pinene in 700 ml of toluene, heated to 40° C., and 220 g of acrylonitrile was dissolved in 100 ml of toluene. A pinene acrylonitrile cooligomer having an average molecular weight of about 330 is obtained by adding the solution dropwise, stirring for 3 hours, and washing and rectifying with water.

As described above, the terpenoid compound material of the pest repellent composition of the present invention contains specific terpene monomer component No.
．． 1~No. 18 or/and their average molecular weight 3,0
Low polymerization or low copolymerization oligomer No. 00 or less. 19
~No. 27 and these specific terpenoid monomers and phenolic, styrene, and vinyl compound monomers are used as low copolymer oligomer No. 27 with an average molecular weight of 3,000 or less. 28~No. This is due to the combination with 35. In addition, sulfate terpene, gum turpentine, pera oil, or eucalyptus components are used in the wood pulp industry, respectively.
The eucalyptus oil component obtained from the rosin industry and the fruit citrus essential oil industry is mainly used as a biomass fuel (Eucalyp
tus radiata).

[0054] It has a calorific value of 10,100 kCal/kg and is a promising material in the future as an energy source. In addition, general agricultural chemicals such as other repellents such as diethylamide, naphthalene, dichlorobenzene, and benzyl ether, as well as other insecticides, sterilizers, herbicides, and nematicides, can also be used in combination. In addition, when used in combination with natural or synthetic resins, it can be molded into sheets, nets, plates, electric wires, coated tubes, etc., or it can be made into molded products having the function of repelling harmful animals in the form of paint. Furthermore, rosin, polyterpene resin, petroleum resin, coumaron, indene resin, epoxy resin, etc. are used in combination with the constituent components of the pest repellent composition of the present invention as a tackifier,
The initial adhesive strength of the repellent function is based on Japanese Industrial Standards JIS Z-
It is also possible to increase the tack (ball rolling method) of 0237 to 4.0 or more. If you do this, flies, mosquitoes, black flies, insects, etc.
Small harmful animals such as planthoppers, leafhoppers, stink bugs, cockroaches, and ants can be attracted with adhesive, and birds, snakes, and weasels can be used as tactile repellents by attaching parts of their living bodies such as their feet.
phobia) can be learned to ensure effectiveness.

[0055]

[Operation] The pest repellent of the present invention comprises a terpenoid compound monomer, this low polymer compound and/or this low copolymer compound (Oligomer or Oligo
-copolymer), it can be used in a wide range of target harmful animals, has low toxicity to humans and animals, and can also be used in combination with other agricultural chemicals.

[0056]

[Example] Example 1 84 parts of granulated natural pumice (average particle size 1.5 mm) was rolled to absorb 15 parts of the component solution shown in Table 1 below, coated with 1 part of inorganic silicic acid fine powder, and repelled. Obtain granules.

[0057]

[Table 1]

Example 2 Emulsion and Emulsified Granules 5.6 parts of polyoxyethylene (n=20) nonylphenyl ether and 2.4 parts of calcium dodecylbenzenesulfonate were mixed and dissolved in 92 parts of the component mixture shown in Table 2 below. to obtain a repellent emulsion. In addition, 75 g of zeolite particles with a diameter of 1.2 to 1.8 mm
were impregnated with 25 g of each of these repellent emulsions to obtain repellent emulsified granules.

[0059]

[Table 2]

Example 3 Aerosol A repellent aerosol is obtained by filling a pressure-resistant aerosol container with 90 ml of liquefied petroleum gas and 360 ml of a 50% water emulsion containing the ingredients shown in Table 3 below.

[0061]

[Table 3]

Example 4 Repellent tape: 50% polymethacrylic in 90 parts of the component mixture shown in Table 4 below.
Add and mix 3 parts of emulsion polymerization solution, and add 7 parts of tolylene diisocyanate (TDI) to this solution.
%, nylon fiber 50%) and repellent compatible resin content of 7.
After coating by dip coating, it is cured to obtain a repellent tape.

[0063]

[Table 4]

Example 5 Adhesive Emulsion 15 parts of polybutene (average molecular weight: about 2,350) and polyoxyethylene (n=5) were added to 50 parts of the component mixture shown in Table 5 below.
, 5 parts of lauryl ester, 15 parts of acetophenone, and 15 parts of xylene to obtain a sticky emulsion.

[0065]

[Table 5]

Example 6 Gel To 90 parts of the component mixture shown in Table 6 below, 1 part of dipendyritensorbitol, 2 parts of dimethyl formaldehyde, and 12 parts of dimethylformaldehyde were added.
- 7 parts of hydroxystearic acid is dissolved by heating to about 65-70°C, and after cooling, a repellent gel is obtained.

[0067]

[Table 6]

Example 7 Powder 10 parts of the component mixture shown in Table 7 below, 10 parts of fine pearlite powder with an average particle size of 100 mμ, and 80 parts of fine kaolin powder with an average particle size of 40 mμ are mixed to obtain a repellent powder.

[0069]

[Table 7]

Example 8 Adhesive paste 50 parts of the component mixture shown in Table 8 below was added with a sulfate terpene solution (pinene 1
5%, terpineol 14%, dipentene 11%, anethole 5%, phelandrene 4%, cedrene 2%, borneol 6%, p-cymene 3%, longifolene 4%
, other terpene hydrocarbons (36%) 15 parts, raw rubber 2 parts and polyoxyethylene (n=5) lauryl ether 5
3 parts of polyacrylic water-absorbing resin fine powder is suspended in this, and 25 parts of water is added to obtain an adhesive paste.

[0071]

[Table 8]

Example 9 Insecticidal and bactericidal animal repellent emulsion 50 parts of the ingredient mixture shown in Table 9 below, 10 parts of physiologically active ingredients, 5 parts of dimethylskilphoxide and 20 parts of kerosene were uniformly dissolved,
12 parts of polyoxyethylene (n=11) nonylphenyl ether and 3 parts of calcium dodecylbenzenesulfonate are added to obtain an insecticidal and bactericidal pest repellent composition emulsion.

[0073]

[Table 9]

[0074] Sample number 36 is a natural product control agent, No.
．． 37 and 38 are low toxicity insecticides, No. 39 can be used as a long-acting fungicide repellent.

Example 10 Harmful animal repellent paint and antifouling paint for fishing nets or underwater structures 30 parts of the component mixture shown in Table 10 below, 15 parts of vinyl propionate resin, 5 parts of bioactive agent, 1 part of methyl isobutyl ketone
0 parts, 20 parts of toluene, and 20 parts of xylene are uniformly dissolved to obtain a harmful animal repellent paint and an antifouling paint for fishing nets or underwater structures.

[0076]

[Table 10]

These are paint compositions that have insecticidal properties and strong repellency.

Example 11 Bird repellent adhesive Table 11 below
35 parts of the ingredient mixture solution, 5 parts of the insecticidal ingredient, 5 parts of the emulsifier, and 4 parts of paraffin wax are heated and made uniform, and then added to 50 parts of an aqueous solution in which 1 part of polyvinyl alcohol is dissolved while stirring, and dispersed uniformly. , obtain a bird repellent adhesive.

[0079]

[Table 11]

[0080] This test solution No. 43, 44, and 45 with a brush to a length of 10 cm on the back of a polyethylene terephthalate adhesive tape with a width of 1.5 cm, and JIS Z-
The ball was pasted on a slope with an inclination angle of 30° according to the tack (ball rolling method) of 0237, and the maximum ball diameter at which a JIS B-1501 ball bearing steel ball stopped adhering within 10 cm of the treated adhesive surface was determined. Ball tuck No. are 18, 16 and 17
showed that. These can be used as strong adhesives to repel pigeons, crows, sparrows, etc.

Example 12 Synthetic resin body containing harmful animal repellent 40 parts of the component mixture shown in Table 12 below and 60 parts of the synthetic resin were mixed and heated uniformly, and molded into a wire covering by injection molding or
Heat roll and sheet.

[0082]

[Table 12]

These wire compositions have a strong repellency against harmful animals such as rats, cockroaches, and ants.

Example 13 Pest repellent paste 20 parts of silicic anhydride fine powder and 10 parts of 50% vinyl acetate emulsion polymerization solution were added to 70 parts of the component mixture shown in Table 13 below and mixed to form a paste with a diameter of about 5 cm and a height of 7 cm. Fill a polyethylene bottle with 160 g to obtain a paste.

[0085]

[Table 13]

[0086] These are closed system telecommunication equipment (connection terminal box,
When opened and grounded to telephones, etc.), computers, food vending machines, etc., feeding damage or nesting by flies, cockroaches, ants, etc. can be prevented for a long period of time.

Example 14 Seed dressing for preventing feeding damage 17 parts of silicic anhydride was added to 33 parts of the terpene component liquid shown in Table 14 below and mixed and ground. To this, 25 parts of anhydrite and 25 parts of kaolin were added and mixed to form a powder. Get the dressing.

[0088]

[Table 14]

[0089] If 2% of soybean or corn seeds are coated with water, these powder coating agents can completely prevent plants from being damaged by feeding damage by sparrows, crows, pigeons, etc. until germination and growth.

Example 15 Pest repellent net Table 15 below
40 parts of terpene and bioactive agent solution, 30 parts of petroleum resin dissolved in 30 parts of methyl ethyl ketone, with a 4 mm opening.
, 105 g of polypropylene net per m was immersed, and after air drying,
Get a pest repellent net.

[0091]

[Table 15]

[0092] These include cockroaches, planthoppers, stink bugs,
It is a powerful repellent for pests such as insects, mosquitoes, and flies.

Example 16 Harmful animal repellent electric wire Table 1 below
15 parts of a mixed solution of the terpene solution, terbene oligomer and bioactive agent, and 85 parts of chlorinated polyethylene were impregnated with 1
mmφ, 0 on a 5kV cross-linked polyethylene insulated cable
．． It is extruded and coated to a thickness of 2 mm to obtain a harmful animal repellent wire.

[0094]

[Table 16]

[0095] This electric wire is stable without being damaged by rats or termites, and without the growth of microorganisms such as mold.

[0096] The effects of the pest repellent compositions of Examples of the present invention will be explained in the following test examples.

Test Example 1 Test method: Two dogs (1 and a half years old, Separd type mongrel) were fasted for about 1 day, and then fed commercially available cooked rice with the test sample evenly spread on it. Investigate remaining food intake.

[0098] Approximately 100 g of commercially available cooked rice is 25.2 cm in diameter.
The mixture was placed in a circular plastic container with a height of 7 cm, loosened slightly to make it uniform, and 6.5 g of each of the compositions of the present invention of sample numbers 1 to 6 of Example 1 were uniformly dispersed. For each sample material, the volumes of the empty container, rice, and sample were measured in advance, and the residual rate (corresponding to the repellency rate) of the amount of sample rice after a certain period of time was calculated. However, about 100 g of untreated cooked rice was administered every 3 days and compared with the test number group. The results are shown in Table 17 below.

0099

[Table 17]

As described above, the composition of the present invention showed a remarkable repellent effect on dogs.

Test Example 2 (Cats) Test method: Two Bermuda cat mongrels (approximately 3 years old and 1.5 years old) were kept in a metal cage of approximately 2 m3 without food for approximately one day, and commercially available cat food (tuna) was placed in a metal cage of approximately 2 m3. Meat boiled coarsely crushed product) approx. 9
5g was administered and compared with the sample number group. The results are shown in Table 18.

[0102]

[Table 18]

Test Example 3 (Dog/Cat) Polyethylene bag containing approximately 1 kg of garbage (content: approximately 1 liter)
When aerosol sample numbers 13 to 17 of Example 3 were sprayed on each bag for about 3 seconds and left together with the untreated bag in a dust collection area where stray dogs and cats were infested, the untreated area had 8.
However, the aerosol treated bags of sample numbers 13 to 17 remained unbroken for 5 days, and their repellent effect was remarkable. In addition, there was almost no garbage odor, and in fact, there was even an aromatic smell.

Test Example 4 (Boar) In a chestnut orchard where wild boars are infested, test numbers 18 to 22 of the repellent tape of Example 4 were placed at a height of about 30 cm above the ground in a test area measuring 4 x 10 m. A sample and untreated tape were attached. Approximately 2 kg of sweet potatoes were buried near the ground in the center of each area, and after a certain period of time, the remaining amount of each was weighed to measure the repellency rate.

[0105]

[Table 19]

As described above, almost all of the sweet potatoes in the treated area remained uneaten, and a remarkable repellent effect was observed over the untreated tape area.

Test Example 5 (Antelope) Tests were conducted on the effects of the adhesive emulsion of Example 5 in Test Nos. 23 to 25 in a cypress forested area in an area where Japanese serows are severely affected.

[0108] 25 times diluted with water per tree in December
Spray 0ml on the tree trunk 50-100cm above the ground, and
The extent of damage was investigated in April (211 days after spraying) and the results shown in Table 20 were obtained.

[0109]

[Table 20]

As described above, the composition of the present invention was able to minimize damage by repelling serows.

Test Example 6 (Hare) 2-year-old cypress seedlings were planted in a 4-year-old forestry area with 50 trees per area.
A damage prevention and repellent test was conducted using hares. Approximately 1 bottle of 50x solution of sample numbers 7 to 12 repellent emulsion of Example 2 was added to each bottle.
25 ml was sprayed intensively at about 50 cm above the ground, and after 3, 6 and 12 months, the number of trees damaged by feeding damage was measured, and the results shown in Table 21 were obtained by looking at the damage rate.

[0112]

[Table 21]

Test Example 7 (Rat) Test method: 70 cm long and 50 cm wide with a corrugated wire mesh lid
Ten 5-week-old mice placed in aluminum cages with a height of 10 cm were used. After fasting for about 1 day, about 6 g each of the gels of gel sample numbers 26 to 28 and 29 of Example 6 was added to about 30 g of commercially available mouse food (diameter 1 cm, length 3 cm).
was applied. Separately, it was placed in a recessed part of a corrugated wire mesh together with 30 g of an untreated hood, and the residual rate was measured at regular intervals. In addition,
Approximately 30 g of untreated feed was given every 3 days for testing. The results are shown in Table 22.

[0114]

[Table 22]

Test Example 9 (Snake) Chicken chicks weighing about 45 g are sprayed with about 3 g each of aerosol samples Nos. 13 to 15 of Example 3. This processed sample 1
0 and 2 silver halves with a body length of about 80 cm were placed in a glass circular container with a diameter of 1 m and a height of 20 cm, and after 48 hours, the feeding repellency rate was investigated. The results are shown in Table 23.

[0116]

[Table 23]

As described above, the composition of the present invention has remarkable repellency against snakes.

Test Example 10 (Pigeons) Test method: Two adult pigeons were placed in a wire mesh measuring 1 m x 3 m x 2 m, fasted for about 1 day, and fed with 40 g of corn chips. 10 g of powder of sample numbers 30 to 32 of Example 7 was mixed with each sample. The repellency rate was calculated by weighing the amount remaining in each container at regular intervals. However, about 4 ounces of untreated food every 3 days.
0g was administered and compared with the sample number group. Table 24 shows the results.
Shown below.

[0119]

[Table 24]

As described above, the composition of the present invention has the following effects on pigeons:
Shows remarkable repellent effect.

Test Example 11 (Crows) Test method: Three crows, one year old, were placed in a cage with a wire mesh measuring 1 m x 3 m x 2 m. Fast for about a day,
40 g of each bait prepared by mixing about 2 ml of fine corn grains with the repellent compositions of sample numbers 7 to 12 of the emulsified granules of Example 2 to a concentration of 4% was placed in a 6 cm x 6 cm bait container and used for testing. It was placed in a cage together with 60 g of untreated material, and the survival rate was measured at regular intervals. In addition, 40g of untreated food every 3 days.
was administered and compared with the sample number group. The results are shown in Table 25.

[0122]

[Table 25]

[0123] From the above results, the composition of the present invention had a high residual effect on crows.

Test Example 12 (Pigeons) 2 x 3 m area where pigeons constantly fly in and pollute
Apply a 20% water dispersion emulsion of sample numbers 33 to 35 of the adhesive paste of Example 8 on the balcony and its handrail,
Place 100g of fine corn grains on the balcony floor, weigh the remaining food over time, and measure the repellency rate (%).
The results shown in Table 26 were obtained.

[0125]

[Table 26]

From the above results, it was confirmed that the composition of the present invention has a high repellent effect on pigeons.

Test Example 13 (Cockroach) A circular glass container with a diameter of 1 m and a height of 20 cm has a bottom of 2 cm.
Spread cut rice leaves on top and place one female black cockroach, one adult male insect, and one larva each.
10 of the emulsions of sample numbers 7 to 12 of Example 2.
Drop 2 ml of the diluted solution into the center of a 10 x 12 cm filter paper. After air-drying, fold it into a wave shape so that there are three peaks, use it as a selter, and put it in a test glass container for 8 hours, 24 hours, and 48 hours.
After a period of time, the number of individuals gathered in each selter was measured, and the results shown in Table 27 were obtained.

[0128]

[Table 27]

[0129] From the above results, strong repellency against cockroaches was demonstrated.

Test Example 14 (Japanese termite) Red pine sapwood (with annual rings of 3 to 5 per 10 mm) was placed in a 20×20
A test piece was prepared to a size of 20 mm. Example 2
A treated test piece was obtained by immersing it in a 1% aqueous solution of emulsion sample number 9 for 10 minutes and then air drying it for 10 days.

[0131] Next, the diameter is 110 mm and the height is 150 mm (
Put 400 g of quartz sand that had been sterilized by dry heat at 105°C for 2 hours in a glass container with a capacity of 1400 ml, add 100 ml of sterilized water, set up the treated test piece and the untreated test piece, and place 50 house termites ( 48 worker ants and 2 soldier ants) were introduced. After 48 hours, the number of termites gathered on the treated and untreated specimens was counted. There were no termites on the specimen, and 42 termites were found on the untreated specimen, clearly showing a repellent effect. .

Test Example 15 (Mites) 0.125 ml (50 ml/m ) Spray. After air-drying, fold it in half and enclose it with 0.1 g of Dermatophagoides inhabited dust in between, and seal it airtight with tape. After 24 hours, the bag was opened and the total number of living insects and the number of dead insects were examined using a magnifying glass, and the results shown in Table 28 were obtained.

[0133]

[Table 28]

From the above results, it was revealed that the composition of the present invention has excellent repellent and insecticidal properties.

Test Example 16 (Slugs, Snails) Field soil is spread evenly to a thickness of about 2 cm in a glass circular container with a diameter of 20 cm, and three slugs and snails are placed therein. In addition to this, sample numbers 36-3 of the insecticidal animal repellent emulsion of Example 9 were added.
Cabbage 20 x 3 cm soaked in 38 50 times diluted with water
Insert the sections and untreated pieces. After 24 hours, the weight of each test piece was weighed and the residual rate was investigated as the repellency rate. Table 2 shows the results.
9.

[0136]

[Table 29]

From the above results, it is clear that the composition of the present invention has strong repellency against slugs and snails.

Test Example 17 (Blue mold, house fly) Example 9
0.125 ml (50 ml
/m2) Spray and air dry. This was transferred to a glass container with a diameter of 20 cm and a height of 10 cm, and 10 female adult house flies were placed there under anesthesia. After 3 hours, the number of inseminated insects that landed on the test piece and the untreated piece was investigated for 3 minutes. and 58 animals, and a repellent effect was observed. When this test piece was sprayed with 0.2 ml of blue mold spore suspension and post-incubated at 30°C saturation temperature, blue mold grew all over the untreated veneer board, but no blue mold was found on the test specimen. There were no outbreaks.

Test Example 18 (Rat) A 10 x 10 cm test piece of nylon mesh with an opening of 2 cm is immersed in the pest repellent paint samples Nos. 40 to 42 of Example 10 for 10 minutes.

[0140] After 24 hours of air drying, diameter 1.2 cm, length 3
cm of artificial bait for rats was wrapped, and the untreated netted bait was simultaneously given to one 6-month-old rat. The results are shown in Table 30.

[0141]

[Table 30]

Test Example 19 (Spodoptera japonica) Four pots of summer mandarin oranges (height 30 cm) were placed on a turntable, and samples Nos. 36 to 36 of the insecticidal repellent emulsion of Example 9 were placed on a turntable.
Spray 50 ml of a 500-fold dilution of No. 38 in water. Three air-dried treated leaves were placed in a polyethylene cup with a diameter of 10 cm and a height of 4.5 cm, and 10 3rd instar Spodoptera larvae were fed thereto, and the mortality rate was determined after 24 hours. In addition, after 15 days of being left outdoors after the spray treatment, a test was conducted again using the same method to determine the residual effect and the results shown in Table 31 were obtained. As controls, emulsions prepared using xylene instead of terpenoids in the compositions of sample numbers 36 to 38 were designated as sample numbers 36 (control) to 38 (control), respectively.

[0143]

[Table 31]

From the above results, it is clear that the insecticide repellent of the present invention is a composition with great residual effectiveness.

Test Example 20 (Crows) Four crows were placed in a 1 x 3 x 2 m wire mesh room with a diameter of 3 cm.
Set of 5 PVC perches. Apply bird repellent adhesives of sample numbers 43, 44, and 45 of Example 11 to one tree with a brush at a rate of 150 g per 1 m2, and apply 3 perches to each perch and 2 untreated perches, for a total of 5 perches. Established. As a result of observing the number of times house flies landed on perches over time, the rods treated with sample numbers 43, 44, and 45 had a sufficient repellent effect even after 5 months, and did not stop at all.

Test Example 21 (Mole) Granules of sample numbers 1 to 6 of Example 1 were applied to the soil mounds of each treatment area at a depth of 15 cm in test plots where traces of mounds of mole passage were observed in mole-infested lawn fields. Bury 30g of powdered grains,
We trampled on the embankment and measured the number of mounds that moles passed through. The test was conducted in one area of 5 m2. The results are shown in Table 32.

[0147]

[Table 32]

Test Example 22 (Marine animal fouling biological barnacles, sea squirts) A film with a thickness of 1 on a vinyl chloride board of 8 x 20 cm and a thickness of 5 mm.
The antifouling paint for fishing nets or underwater structures of Example 10 was applied so that the coating had a thickness of 0.00 μm, and was hung 30 cm below the water surface in Hakata Bay, Hakata Port, and the state of staining was periodically observed. Similarly 20x20
The paint of Example 10 was applied to a nylon fishing net having a diameter of 2 mm, a diameter of 2 mm, and an opening of 1.5 cm by dipping, and was then hung 30 cm below the water surface for a test. The results are shown in Table 33. The antifouling organisms were found to have antifouling effects, including the slime of animal organisms such as barnacles, sea squirts, and serpura, and the plant-based contaminants such as lettuce, blue seaweed, and Shiomiduro, but both vinyl chloride boards and fishing nets had long-term antifouling effects. A staining effect was observed.

[0149]

[Table 33]

[0150]

EFFECTS OF THE INVENTION The harmful animal repellent composition of the present invention suppresses and repels the ecology of animals that are relatively harmful to humans while coexisting with harmful animals that are the same living organisms as humans. In particular, as the information society continues to develop,
The installation of optical cables and electrical wiring as a means of communication has increased,
It is necessary to prevent damage from harmful animals such as rats, ants, and cockroaches, and from this point of view, the effects of the present invention are enormous.

Claims (8)

[Claims] Claim 1: A specific terpenoid compound monomer or/and a low-polymerized or low-copolymerized oligomer thereof, these terpenoid monomers, and a phenolic, styrene,
A harmful animal repellent composition comprising a low copolymer oligomer with a compound selected from vinyl, maleic, and monomers. 2. The pest repellent composition according to claim 1, wherein the low polymerization or low copolymerization compound has an average molecular weight of 3,000 or less. 3. In claim 1, the terpenoid compound monomer is myrcene, alloocimento, citral, linalool, limonene, dipentene, terpinene, terpineol, anethole, pinene, nopol,
A pest repellent composition comprising camphene, nopylacetate, isobornyl acetate, phellandrene, carene, cineole, and geraniol. 4. A specific terpenoid compound monomer or/and a low-polymerized or low-copolymerized oligomer thereof, these terpenoid monomers, and a phenol-based, styrene-based,
Low copolymerized oligomers with compounds selected from vinyl, maleic, and monomers, sulfate terpene, gum turpentine, pera oil, eucalyptus essential oil components such as cedrene, rogifolene, p-cymene, fencolterpinen-4-ol, methyl chabicol, A harmful animal repellent composition comprising one or more selected from terpine and hydrated terpine. 5. A specific terpenoid compound monomer or/and a low-polymerized or low-copolymerized oligomer thereof, and these terpenoid monomers, phenolic, styrene,
Low copolymerized oligomers with compounds selected from vinyl, maleic, and monomers, higher ketones, cinnamaldehyde, cinnamic alcohol, dialkyl toluamide, dialkyl phthalate, alkyl halides, allyl halides,
A pest repellent composition comprising a combination of one or more compounds selected from phenyl ether, benzyl ether, isobornyl acetate, isobornyl thiocyanate, and octachlordipropyl ether. 6. A pest repellent composition comprising the composition according to claims 1 to 5 in combination with one or more biologically active ingredients such as insecticidal, sterilizing, herbicidal, and plant growth regulators. 7. The composition according to claims 1 to 6 contains a synthetic surfactant, natural or synthetic rubber, recycled rubber, acrylic resin, rosin, copal, gunmaru, polyterpene resin, chlorinated polyolefin, chlorinated polyalkylene. A harmful animal repellent composition containing one or more selected from resins, polyurethane resins, petroleum resins, coumaron resins, indene resins, polyamide resins, polycarbonate resins, epoxy resins, fluororesins, carbon resins, and silicone resins. . 8. If necessary, one or more tackifiers are added to the compositions according to claims 1 to 7, so that the initial adhesive strength of the applied repellent function of the repellent composition is determined according to Japanese Industrial Standards JISZ-02.
A harmful animal repellent composition adjusted to maintain a tack of 37 (ball rolling method) of 4.0 or more.