JPH04288465A - Artificial snow dispersion method - Google Patents

Artificial snow dispersion method

Info

Publication number
JPH04288465A
JPH04288465A JP7585091A JP7585091A JPH04288465A JP H04288465 A JPH04288465 A JP H04288465A JP 7585091 A JP7585091 A JP 7585091A JP 7585091 A JP7585091 A JP 7585091A JP H04288465 A JPH04288465 A JP H04288465A
Authority
JP
Japan
Prior art keywords
water
snow
artificial snow
artificial
water absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7585091A
Other languages
Japanese (ja)
Other versions
JP3133091B2 (en
Inventor
Yuichiro Miura
雄一郎 三浦
Kazuo Hirano
和夫 平野
Taiji Kamibayashi
泰二 上林
Takayuki Nate
孝之 名手
Masanao Otsuka
政尚 大塚
Toshitake Nagai
永井 俊剛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MIURA DOLPHINS KK
Tonen Chemical Corp
Osaka Organic Chemical Industry Co Ltd
Tonen General Sekiyu KK
Sanyo Electric Co Ltd
Original Assignee
MIURA DOLPHINS KK
Tonen Sekiyu Kagaku KK
Tonen Chemical Corp
Osaka Organic Chemical Industry Co Ltd
Sanyo Electric Co Ltd
Tonen Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MIURA DOLPHINS KK, Tonen Sekiyu Kagaku KK, Tonen Chemical Corp, Osaka Organic Chemical Industry Co Ltd, Sanyo Electric Co Ltd, Tonen Corp filed Critical MIURA DOLPHINS KK
Priority to JP03075850A priority Critical patent/JP3133091B2/en
Publication of JPH04288465A publication Critical patent/JPH04288465A/en
Application granted granted Critical
Publication of JP3133091B2 publication Critical patent/JP3133091B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To get a slope having a less aging variation in snow quality by a method wherein water absorption resin absorbs water, then this resin is frozen, block-like resins are broken after freezing and powder snow are transported with gas with 0 deg.C or less and they are dispersed from above the slope at a ski site. CONSTITUTION:Artificial snow is transported from a tank 1 having artificial snow stored therein through a pipe 2 with air of 0 deg.C or less, the artificial snow 8 is dispersed from holes of a nozzle 3 from above a slope so as to make an artificial ski site. The nozzle 3 is disposed in such a way as it may be moved along a rail 4 supported from a ceiling 5 at the artificial ski site with hanger elements 6. The artificial snow absorbs water into water absorption substance, thereafter the snow is frozen and some snow of block form after freezing are further broken into powder snow. At this time, broken dry ices can be mixed with the artificial powder snow. In addition, the water absorbing resin keeps its particle form even if it absorbs water and shows a non-adhesive characteristics and a high water absorption resin particle with a water absorption power being about 30 to 500 times of that of ion exchanging water, for example, polyacrylic acid salt may be used.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は粉雪状の人工雪をスキー
場ゲレンデに散布する方法に関するものである。さらに
詳しくは、スキーに適するゲレンデを作るために、吸水
性樹脂に吸水させた後、凍結し、粉雪状人工雪としたも
のを0℃以下の気体により搬送し、スキー場ゲレンデの
上空より散布する人工雪散布方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of scattering artificial snow in the form of powder onto a ski slope. More specifically, in order to create ski slopes suitable for skiing, water is absorbed into a water-absorbing resin and then frozen to form powder-like artificial snow, which is then transported by gas at temperatures below 0°C and sprayed from above the ski resort slopes. This relates to an artificial snow spreading method.

【0002】0002

【従来の技術】最近我が国のスキー場においても、滑走
シーズンを早めたり延ばしたりするため、人工降雪装置
の導入が盛んである。人工降雪装置には大別するとガン
タイプとファンタイプの2種類がある。これらの装置で
雪を造る方法は、0℃以下の大気中で高圧の水を圧搾空
気の断熱膨張を利用して、あるいは冷たい空気を利用し
て細かい氷を造る方法である。そのようにして造られた
人工雪は水分を10%以上含み、密度が0.3〜0.4
g/cm3 、強度が1Kg/cm2以下であり、圧雪
しなければスキーに適さない。またこのような雪は天然
雪に比べ、雪質の変化が急速に進行し、数日経過すると
、外径が約1〜5mmのざらめ雪へ進む場合もある。ざ
らめ雪はスキーヤーにとって非常に滑りにくい雪であり
、そのため雪を砕く作業、すなわちグルーミングを頻繁
に行わなければならないが、それでも充分な効果がある
とはいえない。
2. Description of the Related Art Artificial snow-making devices have recently been increasingly introduced at ski resorts in Japan in order to hasten or extend the skiing season. There are two types of artificial snowmaking devices: gun type and fan type. The method for making snow using these devices is to use adiabatic expansion of compressed air with high-pressure water in the atmosphere below 0°C, or use cold air to make fine ice. The artificial snow made in this way contains more than 10% water and has a density of 0.3 to 0.4.
g/cm3, and the strength is less than 1 kg/cm2, making it unsuitable for skiing unless the snow is compacted. In addition, the quality of such snow changes more rapidly than natural snow, and after several days, it may progress to coarse snow with an outer diameter of about 1 to 5 mm. Rough snow is extremely difficult for skiers to slip on, and therefore, the work of breaking up the snow, that is, grooming, must be performed frequently, but even this cannot be said to be sufficiently effective.

【0003】また水を凍結させて氷塊とし、物理的衝撃
を与えて粉砕して氷粒や雪片とする人工造雪機も導入さ
れているが、これも厄介な雪質であるかき氷状雪または
ざらめ雪しか得られない欠点があり、前述と同様な対策
が施される。また、特公平2−36635号公報に開示
されているような、水膨潤性材料(吸水性樹脂)と水を
混合し(吸水させ)、曝気後、凍結させて造る人工雪の
場合、雪の密度や強度は、曝気条件や凍結条件によって
ばらつきやすく、密度が0.4〜0.9g/cm3 、
強度が10〜数100kg/cm2となる。そのような
雪は雪と言うよりも、ごつごつした細かい氷またはアイ
スバーンと同じ状態である。アイスバーンと同じ状態の
ものは上記のように物理的衝撃を与えて粉砕して氷粒や
雪片としなければならず、ざらめ雪状のものしか得られ
ない。従って、水膨潤性材料のみで人工雪を造る場合、
スキーに適すようにするためには凍結した粒子同志が必
要以上に結合しないように、界面活性剤を加えたり、粒
子径や吸水比率を調整したり、グルーミングを頻繁に実
施したりしなければならない。そのような雪はスキー場
にとって非常に使いにくい雪といえる。
[0003] Artificial snow-making machines have also been introduced that freeze water into ice blocks and apply physical impact to crush them into ice particles or snowflakes, but these machines also produce difficult snow types such as shaved ice or snow flakes. The drawback is that only rough snow can be obtained, so the same countermeasures as mentioned above are taken. In addition, in the case of artificial snow, which is made by mixing water-swellable material (water-absorbing resin) and water (absorbing water), aerating and freezing the snow, as disclosed in Japanese Patent Publication No. 2-36635, Density and strength tend to vary depending on aeration conditions and freezing conditions, and the density is 0.4 to 0.9 g/cm3,
The strength is 10 to several 100 kg/cm2. Such snow is more like rough, fine ice or ice burn than snow. If it is in the same state as an ice burn, it must be crushed into ice grains or snowflakes by applying a physical impact as described above, and only a rough snow-like material can be obtained. Therefore, when making artificial snow using only water-swellable materials,
To make it suitable for skiing, it is necessary to add surfactants, adjust the particle size and water absorption ratio, and perform frequent grooming to prevent frozen particles from bonding together more than necessary. . Such snow can be said to be extremely difficult to use at ski resorts.

【0004】また、屋内スキー場の人工ゲレンデに前記
水膨潤性材料(吸水性樹脂)と水を混合(重量比、約1
/80〜1/100)した糊状のものを配設し、スケー
ト場のように一旦は全面結氷させた後、その表面のみを
グルーミングして氷を削り取り人工雪とした人工ゲレン
デもある。この方法によって造られた屋内スキー場でも
上記の問題があるほか、人工雪の下にはアイスバーンの
ような氷の層があるのでストックが立たない等の問題も
ある。
[0004] Also, the water-swellable material (water-absorbing resin) and water are mixed (weight ratio: about 1) on the artificial slope of an indoor ski resort.
There are also artificial ski slopes where a glue-like material made of 1/80 to 1/100) is placed to freeze the entire surface, like a skating rink, and then only the surface is groomed to scrape off the ice to create artificial snow. In addition to the problems mentioned above, indoor ski resorts built using this method also have other problems, such as the fact that there is a layer of ice underneath the artificial snow, making it difficult for ski poles to stand.

【0005】[0005]

【発明が解決しようとする課題】従来の人工雪を用いた
スキー場ゲレンデは下記のような問題点がある。■グル
ーミングしなければならない。■スキーヤーのレベルや
好みに応じた任意の密度や強度の人工雪からなるゲレン
デが得られない。■雪質の経時変化が大きく、ゲレンデ
のコンディションを保つのが難しい。■ゲレンデの建設
費や維持費が高い。■水膨潤性材料(吸水性樹脂)と水
から凍結して造られる人工雪は、氷塊になるので、それ
を一旦粉砕しなければならない。
[Problems to be Solved by the Invention] Conventional ski slopes using artificial snow have the following problems. ■ Must be groomed. ■It is not possible to obtain slopes made of artificial snow of arbitrary density and strength depending on the skier's level and preference. ■Snow quality changes significantly over time, making it difficult to maintain the condition of the slopes. ■Slope construction and maintenance costs are high. ■Artificial snow that is made by freezing water and water-swellable materials (water-absorbing resin) turns into blocks of ice, which must first be crushed.

【0006】[0006]

【課題を解決するための手段】本発明者等は従来の問題
点を解決すべく鋭意研究を重ねた結果、本発明の目的は
、ゲレンデの建設費や維持費が安く、しかもスキーヤー
のレベルや好みに応じた任意の密度や強度を有し且つ雪
質の経時変化が少ない人工雪からなるスキー場ゲレンデ
を製造する方法を提供するものである。
[Means for Solving the Problems] As a result of intensive research by the present inventors to solve the conventional problems, the purpose of the present invention is to reduce the construction and maintenance costs of ski slopes, and to improve the level of skiers. To provide a method for manufacturing a ski resort slope made of artificial snow having arbitrary density and strength according to preference and with little change in snow quality over time.

【0007】本発明の請求項1の発明は、吸水性樹脂に
吸水させた後、凍結し、凍結後に塊状化している場合は
更に粉砕して、粉雪状人工雪としたものを0℃以下の気
体により搬送し、スキー場ゲレンデの上空より散布する
人工雪散布方法である。本発明の請求項2の発明は、粉
雪状人工雪に粉砕したドライアイスを混合したものを用
いる請求項1に記載の人工雪散布方法である。本発明の
請求項3の発明は、吸水性樹脂に添加する水量が吸水性
樹脂の最大吸水能の100%〜120%である請求項1
に記載の人工雪散布方法である。本発明の請求項4の発
明は、吸水性樹脂が下記の特性を有する高吸水性樹脂粒
状体からなる請求項1〜3のいずれかに記載の人工雪散
布方法である。■吸水しても粒状を保ち互いに非粘着性
であり、■イオン交換水に対する吸水能が約30〜50
0倍、■吸水前の粒径が約20〜500μm、■吸水後
の粒径が約0.05〜2mm。本発明の請求項5の発明
は、高吸水性樹脂粒状体が球状である請求項4に記載の
人工雪散布方法である。本発明の請求項6の発明は、高
吸水性樹脂粒状体が、ポリアクリル酸塩、ビニルアルコ
ールとアクリル酸塩共重合体またはイソブチレンと無水
マレイン酸との共重合体ケン化物である請求項4に記載
の人工雪散布方法である。本発明の請求項7の発明は、
散布ノズルが固定されたもの及び/又は移動可能なもの
からなる請求項1〜3のいずれかに記載の人工雪散布方
法である。
[0007] The invention of claim 1 of the present invention is to absorb water into a water-absorbing resin, freeze it, and if it becomes lumpy after freezing, further crush it to make powdery artificial snow, which is then heated to a temperature below 0°C. This is a method of dispersing artificial snow by transporting it with gas and dispersing it from above the ski slopes. The invention according to claim 2 of the present invention is the artificial snow spreading method according to claim 1, which uses a mixture of powdery artificial snow and crushed dry ice. The invention according to claim 3 of the present invention is characterized in that the amount of water added to the water absorbent resin is 100% to 120% of the maximum water absorption capacity of the water absorbent resin.
This is the artificial snow spreading method described in . A fourth aspect of the present invention is the artificial snow spreading method according to any one of claims 1 to 3, in which the water absorbent resin comprises super absorbent resin granules having the following characteristics. ■Even when water is absorbed, it remains granular and non-adhesive to each other; ■Water absorption capacity for ion-exchanged water is about 30 to 50.
0 times, ■ Particle size before water absorption is about 20 to 500 μm, ■ Particle size after water absorption is about 0.05 to 2 mm. The fifth aspect of the present invention is the artificial snow spreading method according to the fourth aspect, wherein the super absorbent resin particles are spherical. The invention of claim 6 of the present invention is that the super absorbent resin granules are a saponified product of polyacrylate, a copolymer of vinyl alcohol and acrylate, or a copolymer of isobutylene and maleic anhydride. This is the artificial snow spreading method described in . The invention of claim 7 of the present invention is:
4. The artificial snow spreading method according to claim 1, wherein the spreading nozzle is fixed and/or movable.

【0008】本発明に用いられる吸水性樹脂しては、デ
ンプン系、セルロース系あるいはアクリルアミド、アク
リル酸、アクリル酸塩、メタアクリル酸塩、スチレン、
ビニルエーテル等のポリマー、コポリマー、ターポリマ
ー等の合成樹脂系などがあげられるが、アクリル酸とア
クリル酸のアンモニウム塩またはアルカリ金属塩とを含
むモノマーの水溶液に、0.1〜10重量%の多価有機
金属イオン架橋剤を加えて水溶液重合し、乾燥すること
によって得られる適度に架橋された細片状高吸水性樹脂
、あるいはアクリル酸とアクリル酸のアンモニウム塩ま
たはアルカリ金属塩との共重合体に0.1〜10重量%
の多価有機金属イオン架橋剤を用いてポスト架橋するこ
とによって得られる適度に架橋された細片状高吸水性樹
脂や、とりわけ粒状を示す、有機溶剤中で逆相懸濁重合
して得られるポリアクリル酸塩、ビニルアルコールとア
クリル酸塩共重合体またはイソブチレンと無水マレイン
酸との共重合体ケン化物からなる高吸水性樹脂粒状体な
どが好適である。これらの中でも高吸水性樹脂粒状体が
特に好ましい。
The water-absorbing resin used in the present invention includes starch, cellulose, acrylamide, acrylic acid, acrylate, methacrylate, styrene,
Synthetic resin systems such as polymers such as vinyl ethers, copolymers, and terpolymers can be mentioned, but 0.1 to 10% by weight of polyhydric Appropriately crosslinked flaky superabsorbent resin obtained by adding an organometallic ion crosslinking agent, polymerizing in aqueous solution, and drying, or a copolymer of acrylic acid and an ammonium salt or alkali metal salt of acrylic acid. 0.1-10% by weight
Moderately crosslinked superabsorbent resins in the form of strips obtained by post-crosslinking using a polyvalent organometallic ion crosslinking agent, or particularly granular superabsorbent resins obtained by reverse phase suspension polymerization in an organic solvent. Suitable are superabsorbent resin particles made of polyacrylate, a copolymer of vinyl alcohol and acrylate, or a saponified copolymer of isobutylene and maleic anhydride. Among these, super absorbent resin particles are particularly preferred.

【0009】本発明に用いられる高吸水性樹脂が吸水し
た後も粒状あるいは細片状で流動性を保持し、互いに非
粘着性とするために、多価エポキシや多価アミンなどの
適当な架橋剤を用いて架橋度を高めるが、架橋し過ぎる
と吸水能が低下するので、適当な吸水能になるよう架橋
剤量を調節することが肝要である。
[0009] In order to maintain fluidity in the form of particles or strips even after the superabsorbent resin used in the present invention absorbs water and to make them non-adhesive to each other, appropriate crosslinking such as polyvalent epoxy or polyvalent amine is used. Although a crosslinking agent is used to increase the degree of crosslinking, excessive crosslinking lowers the water absorption capacity, so it is important to adjust the amount of crosslinking agent to obtain an appropriate water absorption capacity.

【0010】粒状の高吸水性樹脂が好ましい理由として
、取り扱い易いこと、スキーの滑りを悪くしないことな
どが挙げられる。従って球状の高吸水性樹脂はさらに好
ましい。更に本発明の高吸水性樹脂粒状体は、それが吸
水した後0.05mm〜2mmの粒状になるものが好ま
しく、その結果、吸水前で20〜500μm が適して
いる。20μm 以下では細か過ぎて人工雪が硬くなり
すぎ、500μm 以上では人工雪がざらめ状になり好
ましくない。
[0010] Particulate super absorbent resins are preferred because they are easy to handle and do not make skis slippery. Therefore, a spherical superabsorbent resin is more preferable. Furthermore, the superabsorbent resin particles of the present invention preferably have a particle size of 0.05 mm to 2 mm after absorbing water, and as a result, a particle size of 20 to 500 μm before absorbing water is suitable. If it is less than 20 μm, it will be too fine and the artificial snow will become too hard, and if it is more than 500 μm, the artificial snow will become rough and undesirable.

【0011】本発明に用いられる高吸水性樹脂粒状体は
イオン交換水に対する吸水能が30〜500倍、好まし
くは50〜200倍がよい。30倍より吸水能が小さい
場合は得られる人工雪の吸水能が低いため人工雪が解け
て発生する液体の水を吸収して、目的条件の雪質に維持
することが難しくなる。500倍より大きい場合は吸水
した時のゲル強度が弱く、圧力が加わると破壊され易く
好ましくない。
The superabsorbent resin particles used in the present invention have a water absorption capacity of 30 to 500 times, preferably 50 to 200 times, relative to ion-exchanged water. If the water absorption capacity is less than 30 times, the water absorption capacity of the obtained artificial snow will be low, making it difficult to maintain the desired snow quality by absorbing liquid water generated when the artificial snow melts. If it is larger than 500 times, the gel strength will be weak when water is absorbed, and it will be easily broken when pressure is applied, which is not preferable.

【0012】高吸水性樹脂粒状体の粒径、吸水倍率/吸
水能の比率および水膨潤体量等のパラメーターを任意に
動かすことにより、任意の密度や強度の雪を得ることが
できる。例えば、硬くて重い雪質を得たい場合は粒径が
小さく(20〜150μm )、吸水倍率/吸水能の比
率が大きく(30〜80%)、水膨潤体量を多くする(
30〜200重量部)。反対に軟らかくて軽い雪を得た
い場合は粒径大(150〜500μm )、吸水倍率/
吸水能の比率小(10〜50%)、水膨潤体量を少なく
(10〜80重量部)すればよい。
[0012] By arbitrarily changing parameters such as the particle diameter of the super-absorbent resin granules, the ratio of water absorption capacity/water absorption capacity, and the amount of water-swollen material, snow of arbitrary density and strength can be obtained. For example, if you want to obtain hard and heavy snow, the particle size should be small (20 to 150 μm), the ratio of water absorption capacity/water absorption capacity should be large (30 to 80%), and the amount of water-swelled material should be large (
30-200 parts by weight). On the other hand, if you want to get soft and light snow, use large particle size (150 to 500 μm) and water absorption capacity /
The ratio of water absorption capacity may be small (10 to 50%) and the amount of water-swollen material may be small (10 to 80 parts by weight).

【0013】またこれらの水膨潤体は、通常は高吸水性
樹脂粒状体の最大吸水能より低い吸水倍率とするので、
それから作られる人工雪は外気温の上昇により発生した
液体の水を吸水し、目的条件の雪質が変化しないように
維持することができる。然し、高吸水性樹脂粒状体に添
加する水量は高吸水性樹脂粒状体の最大吸水能の100
%以上であってもよい。水膨潤体を凍結させて人工雪を
作る前に余分の水を除去してもよいが、水膨潤体を凍結
させて人工雪を作る際に吸収されている水は水膨潤体か
ら排出されて高吸水性樹脂粒状体を取り囲むようにして
雪の結晶が出来るので、水膨潤体の周囲に水が存在して
いても支障はない。然し、目的条件の雪質を得るために
は高吸水性樹脂粒状体に添加する水量は高吸水性樹脂粒
状体の最大吸水能の100%〜120%が好ましい。こ
の場合、雪の結晶に取り囲まれている高吸水性樹脂粒状
体はその最大吸水能より低い吸水倍率となっているので
、この人工雪も外気温の上昇により発生した液体の水を
吸水し、目的条件の雪質が変化しないように維持するこ
とができる能力を有している。
[0013] Furthermore, since these water-swellable bodies usually have a water absorption capacity lower than the maximum water absorption capacity of the super absorbent resin granules,
The artificial snow made from it absorbs the liquid water generated by the rise in outside temperature, and can maintain the desired snow quality so that it does not change. However, the amount of water added to the super absorbent resin granules is 100% of the maximum water absorption capacity of the super absorbent resin granules.
% or more. Excess water may be removed before freezing the water-swollen material to make artificial snow, but the water absorbed when freezing the water-swollen material to make artificial snow is discharged from the water-swollen material. Since snow crystals are formed surrounding the superabsorbent resin granules, there is no problem even if water is present around the water-swollen material. However, in order to obtain the desired snow quality, the amount of water added to the superabsorbent resin granules is preferably 100% to 120% of the maximum water absorption capacity of the superabsorbent resin granules. In this case, the superabsorbent resin granules surrounded by snow crystals have a water absorption capacity lower than their maximum water absorption capacity, so this artificial snow also absorbs liquid water generated by the rise in outside temperature. It has the ability to maintain the desired snow quality so that it does not change.

【0014】高吸水性樹脂粒状体に吸水させる方法はど
んな方法でもよく、例えば攪拌した水の中に細片を投入
し、吸水倍率にもよるが数分間放置するだけでよい。水
温により吸水速度は影響を受け、低温であると吸水速度
は遅く、高温になるほど早くなる傾向があるので、例え
ば水温が10℃以下などの場合は適宜加熱して吸水させ
ることが望ましい。
[0014] Any method may be used to make the super absorbent resin granules absorb water; for example, it is sufficient to simply throw the pieces into stirred water and leave them for several minutes, depending on the water absorption capacity. The water absorption rate is affected by the water temperature, and the water absorption rate tends to be slow at low temperatures and faster at higher temperatures. For example, when the water temperature is 10° C. or lower, it is desirable to appropriately heat the water to absorb water.

【0015】吸水した高吸水性樹脂粒状体を凍結させる
方法も特に限定されるものではなく、人為的な曝気を行
うことなく簡単に経済的に人工雪が得られる。例えば、
吸水した高吸水性樹脂粒状体をドライアイス、液体窒素
、液体空気、液化炭酸等とともに公知の方法で攪拌する
などして凍結する方法、冷媒により冷却された金属製パ
イプやシート等の上に吸水した高吸水性樹脂粒状体を置
いて冷却する方法、前記の人工降雪機や人工造雪機等を
用いる方法などがあり、いずれの方法を用いてもよい。 然し、凍結方法により人工雪質が変わり、吸水した高吸
水性樹脂粒状体をドライアイス、液体窒素、液体空気、
液化炭酸等とともに攪拌するなどして凍結して得られる
人工雪は「さらさら」した粉雪状のものであるのでその
まま用いることができるが、冷媒により冷却された金属
製パイプやシート等の上に吸水した高吸水性樹脂粒状体
を置いて冷却する方法により得られる人工雪はお菓子の
「落雁」状の塊が得られるので、この場合はそれを適当
な方法で粉砕して粉雪状にして用いる。
[0015] The method of freezing the water-absorbed superabsorbent resin granules is not particularly limited, and artificial snow can be obtained easily and economically without artificial aeration. for example,
A method of freezing water-absorbing superabsorbent resin granules by stirring them with dry ice, liquid nitrogen, liquid air, liquefied carbon dioxide, etc. using a known method, or freezing the superabsorbent resin particles by placing them on a metal pipe or sheet cooled by a refrigerant. There are a method of placing and cooling super absorbent resin granules, a method of using the above-mentioned artificial snowmaking machine, artificial snowmaking machine, etc., and any method may be used. However, the quality of artificial snow changes depending on the freezing method, and the super absorbent resin granules that have absorbed water are mixed with dry ice, liquid nitrogen, liquid air,
Artificial snow obtained by freezing by stirring with liquefied carbonic acid, etc. is a "smooth" powder-like material that can be used as is, but it can be used directly on metal pipes or sheets that have been cooled with a refrigerant to absorb water. Artificial snow obtained by placing superabsorbent resin granules and cooling them yields lumps shaped like "Rakugan" of sweets, so in this case, they are crushed by an appropriate method and used as powdered snow.

【0016】液体窒素、液体空気、液化炭酸等を用いて
凍結させる方法は、これらが液体であるので、吸水させ
て膨潤した高吸水性樹脂粒状体と混合し易く、これらの
気化潜熱作用を利用して短時間に効率よく人工雪種を凍
結させることができるので好ましい方法である。液体窒
素、液体空気、液化炭酸等以外でも同効物質であれば使
用することができる。しかしこれらのなかでも液化炭酸
の使用は、冷凍効果、経済性、入手の容易さ、取り扱い
易さ等の点で好ましい。
[0016] In the freezing method using liquid nitrogen, liquid air, liquefied carbonic acid, etc., since these are liquids, they are easy to mix with the super absorbent resin particles that have been swollen by absorbing water, and take advantage of their latent heat of vaporization effect. This is a preferred method because it allows the artificial snow species to be frozen efficiently in a short period of time. Substances other than liquid nitrogen, liquid air, liquefied carbonate, etc. can be used as long as they have the same effect. However, among these, the use of liquefied carbonic acid is preferable in terms of freezing effect, economical efficiency, easy availability, ease of handling, and the like.

【0017】液化炭酸としては市販のものを用いること
ができる。液化炭酸の気化潜熱は30℃で15.1Kc
al/Kg 、10℃で48.1Kcal/Kg 、0
℃で56.1Kcal/Kgなどであり、冷却、凍結に
有効に用いることができる。液化炭酸は炭酸ガスを約4
0気圧に圧縮し冷却して製造されるものであり、炭酸ガ
スの発生源としては、天然ガスやアンモニアプラントか
らのオフガス、石油精製やエチレン分解からのオフガス
、その他化学メーカーや鉄鋼メーカーの余剰ガスや副生
ガスなどがあり、いずれでも使用することができる。
Commercially available liquefied carbonic acid can be used. The latent heat of vaporization of liquefied carbonic acid is 15.1Kc at 30℃
al/Kg, 48.1Kcal/Kg at 10℃, 0
It has a value of 56.1 Kcal/Kg at ℃, and can be effectively used for cooling and freezing. Liquefied carbonic acid has carbon dioxide gas of about 4
It is produced by compressing it to 0 atmospheres and cooling it. Sources of carbon dioxide gas include off-gas from natural gas and ammonia plants, off-gas from petroleum refining and ethylene cracking, and other surplus gas from chemical and steel manufacturers. and by-product gas, and any of them can be used.

【0018】粉雪状の人工雪をスキー場のスロープなど
に配設するためには、粉雪状の人工雪を0℃以下の気体
により搬送し、スキー場ゲレンデの上空より散布する。 ゲレンデに散布された人工雪の温度は約0〜−30℃と
なるようにするのがよいが、ゲレンデの大きさ、気温、
スキーヤーの数やスキーヤーのレベルなど各種の条件に
よって異なるで、適宜選択するのがよい。搬送に用いる
気体は特に限定されるものではなく、空気、窒素、炭酸
ガス、酸素などいずれでもよい。取り扱い易さ、安全性
、経済性などを考えて選択するのが好ましい。
In order to place powdery artificial snow on the slopes of ski resorts, the powdery artificial snow is transported by gas at a temperature of 0° C. or lower and is dispersed from above the ski resort slopes. It is best to keep the temperature of the artificial snow sprinkled on the ski slopes at about 0 to -30℃, but depending on the size of the slope, temperature,
It varies depending on various conditions such as the number of skiers and the level of skiers, so it is best to select it appropriately. The gas used for transportation is not particularly limited, and may be air, nitrogen, carbon dioxide, oxygen, or the like. It is preferable to select it considering ease of handling, safety, economic efficiency, etc.

【0019】上記のように吸水した高吸水性樹脂粒状体
を粉砕したドライアイスとともに攪拌して凍結させて人
工雪を作った後、残りのドライアイスとともに0℃以下
の気体により搬送し、スキー場ゲレンデの上空より散布
してもよい。また、一旦作った粉雪状人工雪に粉砕した
ドライアイスを混合して使用することもできる。ドライ
アイスは吸水した高吸水性樹脂粒状体を凍結させて人工
雪としたり、人工雪を冷却して適当な雪質に維持する効
果があるとともに、白煙がでるので美的効果を出す。ド
ライアイスの混合割合はこれらを考慮して適宜決めるの
が好ましい。
[0019] After the water-absorbing superabsorbent resin granules are stirred and frozen with crushed dry ice to make artificial snow as described above, they are conveyed together with the remaining dry ice using gas at a temperature of 0°C or lower, and then transported to a ski resort. It may be sprayed from above the ski slope. It is also possible to mix crushed dry ice with the powdered artificial snow that has already been made. Dry ice has the effect of freezing superabsorbent resin granules that have absorbed water to make artificial snow, cooling artificial snow to maintain appropriate snow quality, and emitting white smoke, which has an aesthetic effect. It is preferable to appropriately determine the mixing ratio of dry ice in consideration of these factors.

【0020】粉雪状の人工雪をスキー場ゲレンデの上空
より散布する方法も特に限定されるものではない。例え
ば粉雪状の人工雪を入れた容器から0℃以下の空気によ
り人工雪をパイプを通して搬送し、適当な散布ノズルか
ら人工雪をスキー場ゲレンデの上空より手動で、あるい
は機械を用いて自動的に散布する。散布ノズルの穴の数
は単数であっても、複数でもよい。散布ノズルの数、穴
の大きさ、形状、分布なども特に限定されるものではな
い。散布ノズル自体は散布手段に固定されているもので
あっても、移動可能であっても、あるいは一部が固定さ
れており一部が移動可能であってもよい。ゲレンデの大
きさ、傾斜、凹凸などを考慮して適宜選択して使用する
。人工雪の散布量、散布時期、散布時間なども特に限定
されるものではない。ゲレンデを作る際に散布すること
は勿論であるが、ゲレンデを維持するために散布しても
よい。またスキーヤーが滑走中に散布してもよいし、ゲ
レンデでのショウやデモンストレーションなどの際に散
布することもできる。
The method of scattering powdery artificial snow from above the ski slope is not particularly limited either. For example, from a container containing artificial snow in the form of powder, the artificial snow is transported through a pipe using air at temperatures below 0 degrees Celsius, and then the artificial snow is distributed from an appropriate spray nozzle over the ski slope either manually or automatically using a machine. Spread. The number of holes in the spray nozzle may be singular or plural. The number of spray nozzles, hole size, shape, distribution, etc. are also not particularly limited. The spraying nozzle itself may be fixed to the spraying means, movable, or partially fixed and partially movable. Select and use the slope appropriately, taking into account the size, slope, unevenness, etc. of the slope. The amount of artificial snow to be applied, the period of application, the time of application, etc. are not particularly limited. Of course, it can be sprayed when creating a ski slope, but it may also be sprayed to maintain the slope. It can also be sprayed by skiers while skiing, or during shows or demonstrations on the slopes.

【0021】他の散布例として次のようなものを挙げる
ことができる。 1.下部に人工雪を供給する装置の付いた容器に粉雪状
の人工雪を入れ、容器をゲレンデ整備する車両に積み、
人工雪を供給装置から散布しながらゲレンデ整備と並行
して行う方法。 2.ガンタイプあるいはファンタイプ等の人工降雪装置
に対して粉雪状の人工雪を0℃以下の圧搾空気により直
接散布する装置を付属させて散布する方法。 3.散布ノズルをゲレンデに固定して、しかもスプリン
クラーのように回転可能にして人工雪をゲレンデの上空
へ放出して散布する方法。 4.人工雪を入れた容器を人が持つか、あるいは持たず
に手に持った散布ノズルからゲレンデに散布する方法。
Other examples of dispersion include the following. 1. Powdered artificial snow is placed in a container with an artificial snow supply device at the bottom, and the container is loaded onto a vehicle that maintains the slopes.
A method of distributing artificial snow from a supply device in parallel with ski slope maintenance. 2. A method of spreading artificial snow in the form of powder by attaching a device to an artificial snow-making device such as a gun type or a fan type to directly spread artificial snow using compressed air at a temperature below 0°C. 3. A method of spraying artificial snow by fixing it on the slope and rotating it like a sprinkler to release artificial snow into the sky above the slope. 4. A method of spraying snow onto the slopes using a spray nozzle held in the hand, with or without a person holding a container filled with artificial snow.

【0022】5.図1に示すように、人工雪を入れたタ
ンク1からパイプ2を通して0℃以下の空気(図示せず
)により人工雪を搬送してノズル3の穴から人工雪8を
ゲレンデ上空から散布する方法。ノズル3は人工スキー
場の天井5から吊支具6によって支持されたレール4に
沿って矢印で示す方向に移動可能にしてある。7はパイ
プ2を支持するガイドワイヤである。この例ではノズル
3は1つであるが複数設けてもよい。またノズル3はゲ
レンデの方向に伸縮自在にしておき、人工雪を散布する
際はゲレンデ近傍へノズル3を移動させ、散布後は天井
側へ移動して収納するようにしてもよい。 6.図2に示すように、上記レール4をゲレンデ9側に
設け、パイプ2を通して0℃以下の空気(図示せず)に
より人工雪を搬送して矢印で示す方向にノズル3を移動
させながら人工雪8をゲレンデ9の上空から散布する方
法。
5. As shown in Figure 1, a method in which artificial snow is conveyed from a tank 1 containing artificial snow through a pipe 2 using air (not shown) at a temperature below 0°C, and artificial snow 8 is dispersed from above the ski slope through a hole in a nozzle 3. . The nozzle 3 is movable in the direction shown by the arrow along a rail 4 supported by a hanging support 6 from the ceiling 5 of the artificial ski resort. 7 is a guide wire that supports the pipe 2. In this example, there is one nozzle 3, but a plurality of nozzles 3 may be provided. Further, the nozzle 3 may be extendable and retractable in the direction of the slope, and when spraying artificial snow, the nozzle 3 may be moved to the vicinity of the slope, and after being sprayed, it may be moved to the ceiling side and stored. 6. As shown in FIG. 2, the rail 4 is installed on the ski slope 9 side, and the artificial snow is conveyed through the pipe 2 by air (not shown) at a temperature of 0°C or lower, and the nozzle 3 is moved in the direction shown by the arrow. How to spray 8 from above ski slope 9.

【0023】上記のように粉雪状の人工雪はそのままゲ
レンデに使用することができる。単独で直接使用するこ
とにより人工スキー場を手軽に造ることができる上、維
持も容易となる。しかし、天然雪、本発明以外の方法で
造られた人工雪や氷雪などと適宜配合して用いてもよい
。配合割合は任意でよい。ゲレンデを造るとき、例えば
、上記「落雁状の人工雪」を下に敷き、その上に「さら
さらした粉雪状の人工雪」を散布してそれぞれ適当な厚
さで構成すれば、さらに優れたスキーに適したゲレンデ
を造ることができ、ストックが立たないなどの問題もな
くなる。
[0023] As described above, the powdery artificial snow can be used as is on the slopes. By directly using it alone, it is possible to easily create an artificial ski resort, and it is also easy to maintain. However, it may be used in combination with natural snow, artificial snow made by a method other than the present invention, ice and snow, etc. as appropriate. The blending ratio may be arbitrary. When building a ski slope, for example, if you lay down the above-mentioned ``artificial snow in the shape of a falling wild goose'' and sprinkle ``artificial snow in the form of smooth powder'' on top of it, each layer having an appropriate thickness, you can create even better skis. This allows you to create a slope suitable for the ski slopes, and eliminates problems such as not being able to stock up on skis.

【0024】本発明で用いる人工雪は適当な方法により
分離回収し、乾燥するなどして再使用することができる
。本発明で用いる高吸水性樹脂粒状体はそれ自体光崩壊
性、生分解性を有するので、使用後、廃棄しても問題が
ないが、特に早期の光崩壊や生分解を望む場合は、光崩
壊、生分解用の公知促進剤、触媒、添加剤等を配合、添
加、含浸、塗布などしてもよい。
The artificial snow used in the present invention can be separated and collected by an appropriate method, dried, etc., and reused. The superabsorbent resin granules used in the present invention are themselves photodegradable and biodegradable, so there is no problem in disposing of them after use. Known accelerators, catalysts, additives, etc. for disintegration and biodegradation may be blended, added, impregnated, coated, etc.

【0025】本発明で用いる高吸水性樹脂粒状体を顔料
、染料などを用いる公知の方法で着色してもよい。また
、公知の香水、芳香剤、香料、酸化防止剤、紫外線吸収
剤、蛍光剤、核剤、増量剤、低摩擦係数を持つ物質、そ
の他添加剤などを本発明の主旨をを損なわない範囲で添
加、配合、塗布、含浸などしてもよい。
The superabsorbent resin particles used in the present invention may be colored by a known method using pigments, dyes, etc. In addition, known perfumes, fragrances, perfumes, antioxidants, ultraviolet absorbers, fluorescent agents, nucleating agents, fillers, substances with a low coefficient of friction, and other additives may be used within the scope of the invention. It may be added, blended, coated, impregnated, etc.

【0026】[0026]

【実施例】次に本発明を実施例によって具体的に説明す
るが、本発明はこの実施例に限定されるものではない。 なお、以下の実施例における吸水能、流動性、凍結後の
人工雪の密度および強度は次の操作により求められる。 (イオン交換水に対する吸水能)乾燥ポリマー0.5g
 を1リットルのイオン交換水に分散し、24時間静置
後、60メッシュの金網で濾過し得られた水膨潤体重量
(W)を測定し、この値を初めの乾燥ポリマー(W0 
)で割って得られた値である。 (吸水後の流動性)乾燥ポリマー1.0g にイオン交
換水50cc加えて吸水し切った後、動かしながら水膨
潤体を観察し、流動性を○、×、△で示した。安息角を
測定した。 (凍結後の人工雪の密度)体積のわかった雪を取りだし
、秤量し、重量を体積で割って求める。単位はg/cm
3 。雪が軟らかいときは、薄いステンレス製の内容積
のわかった箱を積雪に差し込めば、体積のわかった雪が
取れる。硬い雪の場合は、鋸で四角に雪を切りだし、寸
法を物差しで計って体積を計算する。
[Examples] Next, the present invention will be specifically explained by examples, but the present invention is not limited to these examples. In addition, the water absorption capacity, fluidity, density and strength of artificial snow after freezing in the following examples are determined by the following operations. (Water absorption capacity for ion-exchanged water) Dry polymer 0.5g
was dispersed in 1 liter of ion-exchanged water, left to stand for 24 hours, and then filtered through a 60-mesh wire mesh to measure the resulting water-swollen weight (W), and this value was compared to the initial dry polymer (W0).
) is the value obtained by dividing by (Fluidity after water absorption) After 50 cc of ion-exchanged water was added to 1.0 g of dry polymer and all water was absorbed, the water-swollen body was observed while moving, and the fluidity was indicated by ◯, ×, or △. The angle of repose was measured. (Density of artificial snow after freezing) Take the snow whose volume is known, weigh it, and divide the weight by the volume. Unit is g/cm
3. When the snow is soft, you can remove a volume of snow by inserting a thin stainless steel box with a known volume into the snow. For hard snow, cut the snow into squares with a saw, measure the dimensions with a ruler, and calculate the volume.

【0027】(凍結後の人工雪の強度)木下式硬度計で
、人工雪におもりを落下させ、落下強度を測定する。 単位はkg/cm2。円板の人工雪への沈みが7〜30
mmに入るようアダプターを交換し、換算表から強度を
求める。 さらさらした雪などの場合は感触で表した。 (粒状吸水性ポリマーの合成例)攪拌機、還流冷却器、
滴下漏斗、温度計および窒素ガス導入管を付した500
mlセパラブルフラスコに脱イオン水150gを仕込み
、分散剤として部分ケン化ポリビニルアルコール(日本
合成化学(株)製GH−23)0.2gを添加し、加熱
溶融させた後、窒素置換した。一方、あらかじめ、三角
フラスコ中でアクリル酸ラウリル、トリデシル混合エス
テル(大阪有機化学(株)製LTA)22.5g、メタ
クリル酸ヒドロキシエチル10.0g、メタクリル酸メ
チル17.5gにアゾビスジメチルバレロニトリル1.
0gを加えて溶解し、上記のセパラブルフラスコに窒素
気流バブリング下に1時間かけて滴下した。65℃で5
時間保持し、反応を終了させ、冷却後固形物を濾過し、
水洗した後、減圧乾燥してビーズ状の分散剤を得た。攪
拌機、還流冷却器、滴下漏斗、温度計および窒素ガス導
入管を付した1000mlセパラブルフラスコにn−ヘ
キサン360.7g、上記分散剤4.32gを仕込み、
50℃まで昇温し分散溶解した後、窒素置換した。
(Strength of artificial snow after freezing) A weight is dropped onto the artificial snow using a Kinoshita hardness tester to measure the falling strength. The unit is kg/cm2. The sinking of the disc into the artificial snow is 7-30
Replace the adapter so that it fits in mm, and find the strength from the conversion table. In the case of soft snow, etc., it was expressed by feel. (Example of synthesis of granular water-absorbing polymer) Stirrer, reflux condenser,
500 with dropping funnel, thermometer and nitrogen gas inlet tube
ml separable flask was charged with 150 g of deionized water, 0.2 g of partially saponified polyvinyl alcohol (GH-23, manufactured by Nippon Gosei Kagaku Co., Ltd.) was added as a dispersant, heated and melted, and then replaced with nitrogen. Meanwhile, in an Erlenmeyer flask, add 22.5 g of lauryl acrylate and tridecyl mixed ester (LTA, manufactured by Osaka Organic Chemical Co., Ltd.), 10.0 g of hydroxyethyl methacrylate, 17.5 g of methyl methacrylate, and 1 part of azobisdimethylvaleronitrile. ..
0 g was added and dissolved, and the solution was added dropwise to the above-mentioned separable flask over 1 hour under nitrogen bubbling. 5 at 65℃
Hold for a period of time to complete the reaction, filter the solid after cooling,
After washing with water, it was dried under reduced pressure to obtain a bead-like dispersant. In a 1000 ml separable flask equipped with a stirrer, reflux condenser, dropping funnel, thermometer and nitrogen gas inlet tube, 360.7 g of n-hexane and 4.32 g of the above dispersant were charged.
After the temperature was raised to 50°C to disperse and dissolve, the atmosphere was replaced with nitrogen.

【0028】一方、あらかじめ、三角フラスコ中でアク
リル酸72.0gを脱イオン水103.6gに溶解した
水酸化ナトリウム32.2gで部分中和し、さらに室温
下で過硫酸カリウム0.24gを溶解した。この単量体
水溶液を上記のセパラブルフラスコに300rpmの攪
拌速度で窒素気流バブリング下に1時間かけて滴下し、
2時間還流後、30%過酸化水素水0.1gを添加し、
さらに還流を1時間続け重合を完結させた。その後、エ
チレングリコールジグリシジルエーテル0.73gを添
加し、共沸脱水を行い濾過後、減圧乾燥して白色の高吸
水性樹脂粒状体を得た。
On the other hand, in an Erlenmeyer flask, 72.0 g of acrylic acid was partially neutralized with 32.2 g of sodium hydroxide dissolved in 103.6 g of deionized water, and then 0.24 g of potassium persulfate was further dissolved at room temperature. did. This monomer aqueous solution was added dropwise to the above separable flask at a stirring speed of 300 rpm over a period of 1 hour under nitrogen bubbling.
After refluxing for 2 hours, 0.1 g of 30% hydrogen peroxide solution was added,
Refluxing was further continued for 1 hour to complete the polymerization. Thereafter, 0.73 g of ethylene glycol diglycidyl ether was added, followed by azeotropic dehydration, filtration, and drying under reduced pressure to obtain white superabsorbent resin particles.

【0029】この高吸水性樹脂粒状体は、平均粒径が1
00μmであり優れた流動性を示す。常温の水中で攪拌
しながら19秒吸水させると50倍吸水して膨潤し、そ
の平均粒径は0.4mmとなり、これも優れた流動性を
示した。50倍吸水させ膨潤した高吸水性樹脂粒状体を
室温で60日以上放置したが、放水することなく安定に
保持することができた。脱イオン水に対する吸水能は1
00倍であった。
[0029] This super absorbent resin granule has an average particle size of 1
00 μm and exhibits excellent fluidity. When it was allowed to absorb water for 19 seconds while stirring in water at room temperature, it absorbed 50 times more water and swelled, with an average particle size of 0.4 mm, which also showed excellent fluidity. The superabsorbent resin granules that had been swollen by absorbing 50 times more water were allowed to stand at room temperature for more than 60 days, but were able to be stably maintained without being drained of water. Water absorption capacity for deionized water is 1
It was 00 times.

【0030】(人工スキー場ゲレンデの製造例)50倍
吸水させ膨潤した上記高吸水性樹脂粒状体(温度約19
℃)を木製ケース(巾20cm、長さ30cm、深さ3
cm)に一杯に入れ、−30℃の冷凍庫中で約1〜2時
間凍結させて落雁状の人工雪を作った。この落雁状の人
工雪の密度(g/cm3)は0.5、強度(Kg/cm
2) は10であった。発泡スチロール(厚さ約3cm
)を敷いた木製の人工スキー場ゲレンデ(巾約40cm
、傾斜角度約100 で長さ約4mのスロープ部とそれ
に連続している長さ約2mの水平部分からなる)の上に
ドライアイス細片を約20Kg蒔き、その上に全面に上
記の落雁状の人工雪ブロック(巾約20cm、長さ約3
0cm、厚さ約3.3cm)を配設して根雪とした。
(Example of manufacturing an artificial ski slope) The superabsorbent resin granules were swollen by absorbing 50 times more water (at a temperature of about 19
°C) in a wooden case (width 20cm, length 30cm, depth 3
cm) and frozen in a freezer at -30°C for about 1 to 2 hours to make a falling wild goose-shaped artificial snow. The density (g/cm3) of this rakugan-shaped artificial snow is 0.5, the strength (Kg/cm3)
2) was 10. Styrofoam (about 3cm thick)
) wooden artificial ski slope (width approx. 40cm)
Approximately 20 kg of dry ice chips were sown on top of the slope (consisting of a slope section with an inclination angle of about 100 degrees and a length of about 4 m and a continuous horizontal section of about 2 m in length), and on top of that, the above-mentioned rakugan shape was spread over the entire surface. Artificial snow block (width approx. 20cm, length approx. 3cm)
0 cm, thickness of approximately 3.3 cm) was placed as root snow.

【0031】別に50倍吸水させ膨潤した上記高吸水性
樹脂粒状体100重量部と粒状のドライアイス60重量
部とを、−8.3℃の室温下にミキサーを用いて約5分
間混合して凍結させ、さらさらな粉雪状人工雪を作った
。図2に示す人工雪散布装置を用いて、約−9℃に冷却
された空気によりパイプ2を通して粉雪状人工雪を搬送
して、ノズル3より上空から上記根雪の上に全面に散布
して厚さ約4cmまで敷き詰めてゲレンデ9を作った。
Separately, 100 parts by weight of the superabsorbent resin granules, which had been swollen by absorbing water 50 times, and 60 parts by weight of granular dry ice were mixed for about 5 minutes using a mixer at room temperature of -8.3°C. We froze it to create smooth, powder-like artificial snow. Using the artificial snow spreading device shown in Fig. 2, powdered artificial snow is conveyed through pipe 2 using air cooled to approximately -9°C, and is spread from above the nozzle 3 over the entire surface of the root snow to thicken it. Slope 9 was created by laying the ground to a depth of about 4 cm.

【0032】約21℃の外気温下、人工雪温度約−10
から−30℃でスキーの滑走性を調べた。その結果滑走
性が優れており、加速性は天然の粉雪と大体同じであっ
た。人工雪温度が約−10から−30℃とばらついても
、あるいは人工雪の表雪が多少融解してゲルとなっても
滑走性が優れていた。ゲレンデはストックをつかないと
登れなかった。ストックはゲレンデに容易に刺さった。 スキーのエッジはかけ易かった。またスキーで踏むとキ
ュツキュツと音がして心地がよかった。人工雪の表雪が
多少融解してゲルとなった時、粒状のドライアイスを適
当量混合すると再びさらさらした粉雪の状態とすること
ができ、これを繰り返すことによってこのゲレンデを長
時間良好な状態に維持することができた。
[0032] Outside temperature of about 21°C, artificial snow temperature of about -10
The glide properties of skis were examined at -30°C. As a result, the snow had excellent gliding properties, and its acceleration was roughly the same as that of natural powder snow. Even if the temperature of the artificial snow varied from about -10 to -30°C, or even if the surface snow of the artificial snow melted to some extent and turned into gel, the sliding properties were excellent. I couldn't climb the slopes without using ski poles. The stock stuck easily to the ski slope. It was easy to edge the skis. It also made a nice crunching sound when I stepped on it with my skis. When the surface snow of artificial snow melts to a certain extent and becomes a gel, mixing an appropriate amount of granular dry ice can make it smooth and powdery again, and by repeating this process, the ski slope can be kept in good condition for a long time. I was able to maintain it.

【0033】[0033]

【発明の効果】本発明は、高吸水性樹脂粒状体に吸水さ
せた後、凍結し、凍結後に塊状化している場合は更に粉
砕して、粉雪状人工雪としたものを0℃以下の気体によ
り搬送し、スキー場ゲレンデの上空より散布する人工雪
散布方法を提供するものであり、ゲレンデの建設費や維
持費が安く、しかもスキーヤーのレベルや好みに応じた
任意の密度や強度を有し且つ雪質の経時変化が少ない人
工雪からなるスキー場ゲレンデを製造することができる
Effects of the Invention The present invention allows super absorbent resin granules to absorb water, freeze it, and if it becomes lumpy after freezing, further crush it to make powdery artificial snow. This method provides an artificial snow dispersion method in which artificial snow is transported from above the ski resort slopes, and the construction and maintenance costs for the slopes are low, and the density and strength can be adjusted to suit the level and preference of the skier. Moreover, it is possible to manufacture a ski resort slope made of artificial snow whose snow quality changes little over time.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の人工雪散布方法の実施例を示す説明図
FIG. 1 is an explanatory diagram showing an embodiment of the artificial snow spreading method of the present invention.

【図2】本発明の人工雪散布方法の他の実施例を示す説
明図。
FIG. 2 is an explanatory diagram showing another embodiment of the artificial snow spreading method of the present invention.

【符号の説明】[Explanation of symbols]

1  タンク 2  パイプ 3  ノズル 4  レール 5  天井 6  吊支具 7  ワイヤー 8  人工雪 9  ゲレンデ 1 Tank 2 Pipe 3 Nozzle 4 Rail 5 Ceiling 6 Hanging support 7 Wire 8. Artificial snow 9 Slope

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】  吸水性樹脂に吸水させた後、凍結し、
凍結後に塊状化している場合は更に粉砕して、粉雪状人
工雪としたものを0℃以下の気体により搬送し、スキー
場ゲレンデの上空より散布する人工雪散布方法。
[Claim 1] After absorbing water into a water-absorbing resin, freezing it,
An artificial snow dispersion method in which if it has formed into clumps after freezing, it is further pulverized to form powdered artificial snow, which is transported by gas at 0°C or lower and then dispersed from above the ski slope.
【請求項2】  粉雪状人工雪に粉砕したドライアイス
を混合したものを用いる請求項1に記載の人工雪散布方
法。
2. The artificial snow spreading method according to claim 1, wherein a mixture of powdered artificial snow and crushed dry ice is used.
【請求項3】  吸水性樹脂に添加する水量が吸水性樹
脂の最大吸水能の100%〜120%である請求項1に
記載の人工雪散布方法。
3. The artificial snow spreading method according to claim 1, wherein the amount of water added to the water absorbent resin is 100% to 120% of the maximum water absorption capacity of the water absorbent resin.
【請求項4】  吸水性樹脂が下記の特性を有する高吸
水性樹脂粒状体からなる請求項1〜3のいずれかに記載
の人工雪散布方法。■吸水しても粒状を保ち互いに非粘
着性であり、■イオン交換水に対する吸水能が約30〜
500倍、■吸水前の粒径が約20〜500μm、■吸
水後の粒径が約0.05〜2mm。
4. The artificial snow spreading method according to claim 1, wherein the water-absorbing resin comprises super-absorbent resin granules having the following characteristics. ■Even when water is absorbed, it remains granular and non-adhesive to each other; ■Water absorption capacity for ion-exchanged water is approximately 30 ~
500 times, ■ Particle size before water absorption is about 20 to 500 μm, ■ Particle size after water absorption is about 0.05 to 2 mm.
【請求項5】  高吸水性樹脂粒状体が球状である請求
項4に記載の人工雪散布方法。
5. The artificial snow spreading method according to claim 4, wherein the super absorbent resin granules are spherical.
【請求項6】  高吸水性樹脂粒状体が、ポリアクリル
酸塩、ビニルアルコールとアクリル酸塩共重合体または
イソブチレンと無水マレイン酸との共重合体ケン化物で
ある請求項4に記載の人工雪散布方法。
6. The artificial snow according to claim 4, wherein the super absorbent resin granules are a saponified product of polyacrylate, a copolymer of vinyl alcohol and acrylate, or a copolymer of isobutylene and maleic anhydride. Spraying method.
【請求項7】  散布ノズルが固定されたもの及び/又
は移動可能なものからなる請求項1〜3のいずれかに記
載の人工雪散布方法。
7. The artificial snow spreading method according to claim 1, wherein the spreading nozzle is a fixed one and/or a movable one.
JP03075850A 1991-03-15 1991-03-15 Artificial snow spraying method Expired - Fee Related JP3133091B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03075850A JP3133091B2 (en) 1991-03-15 1991-03-15 Artificial snow spraying method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03075850A JP3133091B2 (en) 1991-03-15 1991-03-15 Artificial snow spraying method

Publications (2)

Publication Number Publication Date
JPH04288465A true JPH04288465A (en) 1992-10-13
JP3133091B2 JP3133091B2 (en) 2001-02-05

Family

ID=13588107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP03075850A Expired - Fee Related JP3133091B2 (en) 1991-03-15 1991-03-15 Artificial snow spraying method

Country Status (1)

Country Link
JP (1) JP3133091B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154033A (en) * 2020-01-15 2020-05-15 北京理工大学 Gel type ice and snow material with adjustable solidification temperature and transmittance and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8928552B2 (en) 2010-12-01 2015-01-06 Sony Corporation Personal digital assistant, and display control method and display control program thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154033A (en) * 2020-01-15 2020-05-15 北京理工大学 Gel type ice and snow material with adjustable solidification temperature and transmittance and preparation method thereof

Also Published As

Publication number Publication date
JP3133091B2 (en) 2001-02-05

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