JPH04316466A - Treatment of raw laver - Google Patents
Treatment of raw laverInfo
- Publication number
- JPH04316466A JPH04316466A JP3079410A JP7941091A JPH04316466A JP H04316466 A JPH04316466 A JP H04316466A JP 3079410 A JP3079410 A JP 3079410A JP 7941091 A JP7941091 A JP 7941091A JP H04316466 A JPH04316466 A JP H04316466A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- raw
- seaweed
- salts
- quality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000206607 Porphyra umbilicalis Species 0.000 title abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 8
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract description 7
- 150000007524 organic acids Chemical class 0.000 claims abstract description 6
- 235000015165 citric acid Nutrition 0.000 claims abstract description 5
- 239000004310 lactic acid Substances 0.000 claims abstract description 5
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001630 malic acid Substances 0.000 claims abstract description 4
- 235000011090 malic acid Nutrition 0.000 claims abstract description 4
- 235000005985 organic acids Nutrition 0.000 claims abstract description 4
- 241001474374 Blennius Species 0.000 claims description 51
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 159000000001 potassium salts Chemical class 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 238000012545 processing Methods 0.000 abstract description 21
- 238000003306 harvesting Methods 0.000 abstract description 7
- 230000006866 deterioration Effects 0.000 abstract description 6
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 abstract 1
- 241000195493 Cryptophyta Species 0.000 description 16
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 10
- 239000001540 sodium lactate Substances 0.000 description 10
- 235000011088 sodium lactate Nutrition 0.000 description 10
- 229940005581 sodium lactate Drugs 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 239000012535 impurity Substances 0.000 description 6
- 239000013535 sea water Substances 0.000 description 6
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000206761 Bacillariophyta Species 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000001472 potassium tartrate Substances 0.000 description 2
- 235000019265 sodium DL-malate Nutrition 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- 235000019263 trisodium citrate Nutrition 0.000 description 2
- 239000004251 Ammonium lactate Substances 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 241000665112 Zonitoides nitidus Species 0.000 description 1
- 235000019286 ammonium lactate Nutrition 0.000 description 1
- 229940059265 ammonium lactate Drugs 0.000 description 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000016693 dipotassium tartrate Nutrition 0.000 description 1
- UZLGHNUASUZUOR-UHFFFAOYSA-L dipotassium;3-carboxy-3-hydroxypentanedioate Chemical compound [K+].[K+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O UZLGHNUASUZUOR-UHFFFAOYSA-L 0.000 description 1
- CQAIPTBBCVQRMD-UHFFFAOYSA-L dipotassium;phosphono phosphate Chemical compound [K+].[K+].OP(O)(=O)OP([O-])([O-])=O CQAIPTBBCVQRMD-UHFFFAOYSA-L 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000002526 disodium citrate Substances 0.000 description 1
- 235000019262 disodium citrate Nutrition 0.000 description 1
- 235000019820 disodium diphosphate Nutrition 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
- 229940038485 disodium pyrophosphate Drugs 0.000 description 1
- 235000019524 disodium tartrate Nutrition 0.000 description 1
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- -1 inorganic acid salts Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002444 monopotassium citrate Substances 0.000 description 1
- 235000015861 monopotassium citrate Nutrition 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 235000016337 monopotassium tartrate Nutrition 0.000 description 1
- HWPKGOGLCKPRLZ-UHFFFAOYSA-M monosodium citrate Chemical compound [Na+].OC(=O)CC(O)(C([O-])=O)CC(O)=O HWPKGOGLCKPRLZ-UHFFFAOYSA-M 0.000 description 1
- 239000002524 monosodium citrate Substances 0.000 description 1
- 235000018342 monosodium citrate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000007686 potassium Nutrition 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- KYKNRZGSIGMXFH-ZVGUSBNCSA-M potassium bitartrate Chemical compound [K+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O KYKNRZGSIGMXFH-ZVGUSBNCSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 229940086065 potassium hydrogentartrate Drugs 0.000 description 1
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 description 1
- 239000001521 potassium lactate Substances 0.000 description 1
- 235000011085 potassium lactate Nutrition 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
- SVICABYXKQIXBM-UHFFFAOYSA-L potassium malate Chemical compound [K+].[K+].[O-]C(=O)C(O)CC([O-])=O SVICABYXKQIXBM-UHFFFAOYSA-L 0.000 description 1
- 235000011033 potassium malate Nutrition 0.000 description 1
- 229940111695 potassium tartrate Drugs 0.000 description 1
- 235000011005 potassium tartrates Nutrition 0.000 description 1
- JZRVQGVITBCZDB-UHFFFAOYSA-M potassium;3,4-dihydroxy-4-oxobutanoate Chemical compound [K+].[O-]C(=O)C(O)CC(O)=O JZRVQGVITBCZDB-UHFFFAOYSA-M 0.000 description 1
- WKZJASQVARUVAW-UHFFFAOYSA-M potassium;hydron;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [K+].OC(=O)CC(O)(C(O)=O)CC([O-])=O WKZJASQVARUVAW-UHFFFAOYSA-M 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- WPUMTJGUQUYPIV-UHFFFAOYSA-L sodium malate Chemical compound [Na+].[Na+].[O-]C(=O)C(O)CC([O-])=O WPUMTJGUQUYPIV-UHFFFAOYSA-L 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- NKAAEMMYHLFEFN-ZVGUSBNCSA-M sodium;(2r,3r)-2,3,4-trihydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O NKAAEMMYHLFEFN-ZVGUSBNCSA-M 0.000 description 1
- DOJOZCIMYABYPO-UHFFFAOYSA-M sodium;3,4-dihydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)C(O)CC([O-])=O DOJOZCIMYABYPO-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/60—Edible seaweed
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Edible Seaweed (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、新規な生ノリの処理法
に関するものである。詳しく述べると、生ノリの摘採か
ら干し海苔製造の加工処理工程に入るまでの間に、ノリ
が品質劣化するのを防ぐための新規な収穫した生ノリの
処理法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel method for treating raw seaweed. More specifically, the present invention relates to a new method for processing harvested raw seaweed to prevent the quality of seaweed from deteriorating during the period from harvesting the raw seaweed to entering the processing process for producing dried seaweed.
【0002】0002
【従来の技術】干し海苔は、従来、次ぎのような作業工
程を経て製造されている。BACKGROUND OF THE INVENTION Dried seaweed has conventionally been produced through the following process.
【0003】収穫(摘採)した原藻(生ノリ)は、船上
で夾雑物を除去し、珪藻等を取り除くために海水等での
水洗いを行った後、加工場に運ぶ。[0003] Harvested raw algae (raw seaweed) are removed from impurities on board a ship, washed with seawater to remove diatoms, etc., and then transported to a processing plant.
【0004】加工場では、作業量に応じて原藻を真水で
洗い、水切りし、チョッパーで細断した後、水さらしを
行い、抄き機でノリみすの上に抄き込み、脱水、乾燥を
行って干し海苔とする。[0004] At the processing plant, depending on the amount of work, the raw algae is washed with fresh water, drained, shredded with a chopper, soaked in water, poured onto a laver with a paper machine, dehydrated, and dried. Dried seaweed.
【0005】この工程では、水洗い、水さらしなどの作
業に留意して作業しても、微小な夾雑物を取り切ること
は困難であり、上級の干し海苔を作る上での障害となっ
ている。[0005] In this process, even if you are careful about washing, soaking, etc., it is difficult to remove minute impurities, which is an obstacle to producing high-quality dried seaweed. .
【0006】また、通常は、1回の収穫で得られた生ノ
リは数回に分けて加工することになる。ところで、生ノ
リは、赤変する等、徐々に劣化するために、収穫後時間
を経てから加工処理した場合干し海苔の品質の低下を招
くことにもなっている。[0006] Normally, raw nori obtained from one harvest is divided into several parts and processed. By the way, raw seaweed gradually deteriorates, such as turning red, so if it is processed long after it has been harvested, the quality of dried seaweed will deteriorate.
【0007】この問題を解決する方法として、特開平1
−269473号では、塩酸、リン酸等の無機酸、酢酸
、クエン酸等の有機酸を使用する方法が提案されている
。しかし、その効果は酸を使用しない場合と比較して、
食感などでやや向上が認められているにすぎない。[0007] As a method to solve this problem,
No. 269473 proposes a method using inorganic acids such as hydrochloric acid and phosphoric acid, and organic acids such as acetic acid and citric acid. However, the effect is compared to when no acid is used.
Only a slight improvement in texture was observed.
【0008】[0008]
【発明が解決しようとする課題】したがって、本発明の
目的は、干し海苔製造において、収穫後時間を経てから
加工処理した場合でも、干し海苔の品質の低下を招くこ
とのないように生ノリが品質劣化するのを防ぎ、安定し
た高品質の干し海苔を製造できるようにすると共に、作
業性も向上する利点を有する新規な収穫した生ノリの処
理法を提供することである。[Problems to be Solved by the Invention] Therefore, an object of the present invention is to provide a method for producing dried seaweed so that the quality of the dried seaweed does not deteriorate even when the dried seaweed is processed long after harvest. To provide a novel method for processing harvested raw seaweed, which has the advantage of preventing quality deterioration, producing stable and high-quality dried seaweed, and improving workability.
【0009】[0009]
【課題を解決するための手段】本発明者等は、上記のよ
うな干し海苔製造上での問題点を解決すべく、永年品質
および作業性の向上に関する研究、検討を行ってきた結
果、水溶性の有機酸または無機酸の塩類の水溶液を用い
て、収穫した原藻(生ノリ)を洗浄することにより作業
性が著しく向上すると共に、品質にも格段の向上が認め
られるのを見出し、本発明に至った。[Means for Solving the Problems] In order to solve the above-mentioned problems in producing dried seaweed, the inventors of the present invention have conducted research and studies on improving long-term quality and workability, and have developed a water-soluble We discovered that by washing harvested raw algae (raw seaweed) with an aqueous solution of organic or inorganic acid salts, the workability was significantly improved, and the quality was also significantly improved. This led to the invention.
【0010】すなわち、上記目的は、生ノリを有機酸、
リン酸および重合リン酸よりなる群から選ばれた少なく
とも1種の酸の水溶性の塩類の水溶液で洗浄することを
特徴とする生ノリの処理法によって達成される。[0010] That is, the above purpose is to treat raw seaweed with an organic acid,
This is achieved by a method for treating raw seaweed, which is characterized by washing with an aqueous solution of a water-soluble salt of at least one acid selected from the group consisting of phosphoric acid and polymerized phosphoric acid.
【0011】本発明は、塩類を形成する酸がクエン酸、
酒石酸、乳酸、リンゴ酸、リン酸または重合リン酸であ
り、塩類がナトリウム塩またはカリウム塩である。また
本発明は、該塩類の0.005〜0.5重量%の水溶液
を使用する生ノリの処理法である。この水溶液で処理す
る生ノリ(原藻)の量も変動するが、一般的には、原藻
に対し、0.001〜0.15重量%の塩類で処理する
ことになる。[0011] In the present invention, the acid forming the salts is citric acid,
Tartaric acid, lactic acid, malic acid, phosphoric acid or polymerized phosphoric acid, and the salts are sodium salt or potassium salt. Further, the present invention is a method for treating raw seaweed using an aqueous solution of 0.005 to 0.5% by weight of the salts. Although the amount of raw seaweed (original algae) to be treated with this aqueous solution varies, it is generally treated with 0.001 to 0.15% by weight of salts based on the raw algae.
【0012】0012
【作用】収穫直後の原藻を塩類の希薄水溶液で洗浄する
と、原藻に付着した夾雑物や珪藻類が剥離し易くなり、
その後の水洗により重厚で光沢の良い清浄な原藻が得ら
れる。このために、干し海苔とした場合には、穴空きや
破れのない重厚で光沢の良い上級の製品を得ることがで
きる。[Effect] When raw algae is washed with a dilute aqueous solution of salts immediately after harvesting, impurities and diatoms attached to the raw algae can be easily peeled off.
After washing with water, a thick, shiny and clean raw algae can be obtained. For this reason, when dried seaweed is used, it is possible to obtain a high-quality product that is thick and glossy without holes or tears.
【0013】また、該塩類の水溶液による処理を施した
原藻は、加工場での待ち時間が長時間にわたっても赤変
を起こすこと無く、良質の品質を保つことができる。こ
のために、従来は加工処理の順番によって漸次低下の認
められた干し海苔の品質が、本発明により安定し、低下
することなく上質の干し海苔を提供することが可能とな
る。 本発明に使用される塩類としては、クエン酸一
ナトリウム、クエン酸二ナトリウム、クエン酸三ナトリ
ウム、酢酸ナトリウム、酒石酸水素ナトリウム、酒石酸
二ナトリウム、乳酸ナトリウム、リンゴ酸一ナトリウム
、リンゴ酸二ナトリウム、クエン酸一カリウム、クエン
酸二カリウム、クエン酸三カリウム、酢酸カリウム、酒
石酸水素カリウム、酒石酸二カリウム、乳酸カリウム、
リンゴ酸一カリウム、リンゴ酸二カリウム、クエン酸ア
ンモニウム、乳酸アンモニウム等の有機酸のナトリウム
塩、カリウム塩およびアンモニウム塩類、リン酸一ナト
リウム、リン酸二ナトリウム、リン酸三ナトリウム、ピ
ロリン酸二ナトリウム、ピロリン酸四ナトリウム、リン
酸一カリウム、リン酸二カリウム、リン酸三カリウム、
ピロリン酸二カリウム、ピロリン酸四カリウム、リン酸
二アンモニウム等の無機酸のナトリウム塩、カリウム塩
およびアンモニウム塩類があり、好ましくは、クエン酸
、乳酸、リンゴ酸の中性または弱酸性あるいは弱アルカ
リ性のナトリウム塩類またはカリウム塩類である。なお
、塩化ナトリウム、塩化カリウムは、海水の主要成分で
もあり効果は認められない。[0013] In addition, raw algae treated with the aqueous solution of salts can maintain good quality without causing red discoloration even after a long waiting time at a processing plant. For this reason, the quality of dried seaweed, which conventionally was recognized to gradually deteriorate depending on the order of processing, is stabilized by the present invention, and it becomes possible to provide high-quality dried seaweed without deterioration. Salts used in the present invention include monosodium citrate, disodium citrate, trisodium citrate, sodium acetate, sodium hydrogen tartrate, disodium tartrate, sodium lactate, monosodium malate, disodium malate, Monopotassium acid, dipotassium citrate, tripotassium citrate, potassium acetate, potassium hydrogen tartrate, dipotassium tartrate, potassium lactate,
Sodium, potassium and ammonium salts of organic acids such as monopotassium malate, dipotassium malate, ammonium citrate, ammonium lactate, monosodium phosphate, disodium phosphate, trisodium phosphate, disodium pyrophosphate, Tetrasodium pyrophosphate, monopotassium phosphate, dipotassium phosphate, tripotassium phosphate,
Examples include sodium salts, potassium salts, and ammonium salts of inorganic acids such as dipotassium pyrophosphate, tetrapotassium pyrophosphate, and diammonium phosphate, and preferably neutral, weakly acidic, or weakly alkaline salts of citric acid, lactic acid, and malic acid. Sodium salts or potassium salts. Note that sodium chloride and potassium chloride are also major components of seawater and have no effect.
【0014】これらの塩類は水道水、井戸水等に溶かし
て使用することができるが、簡便には海水に溶かしたも
ので充分な効果が認められる。[0014] These salts can be used by being dissolved in tap water, well water, etc., but it is convenient to dissolve them in seawater and sufficient effects are observed.
【0015】塩類の使用量は、ノリの収穫の時期(回数
)や使用する塩類の種類によって加減する必要がある、
例えば乳酸ナトリウムの50%溶液の場合では、200
リットルの洗浄用の水に対して50〜1000ml、好
ましくは100〜700mlを添加混合して使用する。
50ml未満の場合は、乳酸ナトリウム水溶液を加えず
に水洗した場合と同様の効果しか得られず、一方、10
00mlを越え、多量に塩類を使用すると、原藻の水切
れが悪くなり、乾燥に長時間を要することになり、また
、持ち重みがするために作業性が低下することになる。[0015] The amount of salt used must be adjusted depending on the time (number of times) of nori harvesting and the type of salt used.
For example, in the case of a 50% solution of sodium lactate, 200
It is used by adding and mixing 50 to 1000 ml, preferably 100 to 700 ml, per liter of water for washing. If the volume is less than 50 ml, the same effect as washing with water without adding sodium lactate aqueous solution can be obtained;
If a large amount of salt is used, exceeding 0.00 ml, the raw algae will have difficulty draining water, requiring a long time to dry, and will be heavy to hold, resulting in reduced workability.
【0016】この方法では、使用する塩類をほぼ中性の
ものとしているため、特開平1−269473号に開示
されているごとく、洗浄用の水の液性(pH)の調整に
気を使う必要はほとんどなく、海上での作業では大きな
利点となる。また、排水等により海水の液性に影響を与
えることがないことも利点としてあげられる。[0016] In this method, since the salts used are almost neutral, it is necessary to take care to adjust the pH of the washing water, as disclosed in JP-A-1-269473. This is a major advantage when working at sea. Another advantage is that the liquid properties of seawater are not affected by drainage, etc.
【0017】[0017]
【実施例】以下に、実施例を示して本発明の効果を説明
するが、本発明は、示された実施例に限定されるもので
はない。なお、実施例および比較例中で用いた干し海苔
の規格等級は九州有明海沿岸での評価基準(実績)によ
る、この規格を表2および表3に示す。EXAMPLES The effects of the present invention will be explained below with reference to examples, but the present invention is not limited to the examples shown. Note that the standard grades of dried seaweed used in the Examples and Comparative Examples are shown in Tables 2 and 3 based on evaluation standards (actual results) along the coast of the Ariake Sea in Kyushu.
【0018】実施例1
5番摘みの原藻約400kgを、船上で大きな夾雑物を
除去した後、海水100リットルに対して乳酸ナトリウ
ム300mlを加え混和させた処理水(pHはほぼ中性
)で洗浄したところ、珪藻および微小な夾雑物が除去さ
れ軟らかい光沢の良い生ノリとなった。これを4回に別
けて常法にしたがって加工処理し、干し海苔にしたとこ
ろ、ノリ特有の黒い光沢のある製品が得られた。しかも
製品には、穴空き(マル)や破れがなく、通常は2割り
程度見込まれるロスもなく、98%が3等の良質の干し
海苔となった。さらに、加工処理の順番が遅くなっても
、原藻の保管中に生ノリが赤変することなく、4回目の
加工処理品の場合、加工処理まで約6時間経過していた
が、干し海苔の等級4等の良質の干し海苔が96%得ら
れた。結果を表1に示す。Example 1 Approximately 400 kg of raw algae picked at No. 5 was removed on board to remove large impurities, and then treated with treated water (pH is approximately neutral) made by adding and mixing 300 ml of sodium lactate to 100 liters of seawater. When washed, the diatoms and minute impurities were removed, resulting in a soft and glossy raw nori. When this was divided into four parts and processed according to conventional methods to make dried seaweed, a product with the black gloss characteristic of seaweed was obtained. Furthermore, there were no holes or tears in the product, and there was no loss that would normally be expected to be around 20%, and 98% of the dried seaweed was of 3rd grade quality. Furthermore, even if the order of processing was delayed, the fresh seaweed did not turn red during storage of the raw seaweed, and in the case of the fourth processed product, about 6 hours had passed before processing, but the dried seaweed did not turn red during storage. 96% of high quality dried seaweed of grade 4 was obtained. The results are shown in Table 1.
【0019】比較例1
実施例1と同一の原藻を、乳酸ナトリウムに代えて実施
例1と同量の乳酸を使用した水(pH約2.5)で洗浄
したところ、生ノリは実施例1と比較してやや硬いもの
の、夾雑物は除去され、光沢も比較的良好であった。こ
の生ノリを加工して得られた干し海苔は、1回目の処理
では4等に該当したが、2回目、3回目と加工処理の順
番が下がるにしたがって品質も落ち、4回目の処理では
保管中に生ノリが赤変したこともあり、品質は6〜7等
にまで落ち、実施例1に比べ品質的に劣る干し海苔とな
った。しかも、いずれの加工処理でも穴空きや破れが生
じており、全体では2割を越えるロスがあり、品質の低
下を加味した場合の差は大きなものであった。結果を表
1に示す。Comparative Example 1 When the same raw algae as in Example 1 was washed with water (pH approximately 2.5) using the same amount of lactic acid as in Example 1 instead of sodium lactate, raw seaweed was washed with water (pH approximately 2.5). Although it was slightly harder than No. 1, impurities were removed and the gloss was relatively good. The dried seaweed obtained by processing this raw seaweed was ranked 4th grade in the first treatment, but the quality deteriorated as the order of processing decreased in the second and third times, and in the fourth treatment, it was stored. Due to the fact that the raw seaweed inside turned red, the quality dropped to grade 6-7, resulting in dried seaweed inferior in quality compared to Example 1. In addition, holes and tears occurred in all processing processes, resulting in a total loss of more than 20%, which was a large difference when taking into account the deterioration in quality. The results are shown in Table 1.
【0020】比較例2
実施例1と同一の原藻を、乳酸ナトリウムを含まない海
水のみで洗浄したところ、生ノリは硬く光沢が劣り、加
工処理で得られた干し海苔は、1回目の処理では破れや
原藻の混入がみられるものの、上5等の比較的良質の製
品が得られたが、2回目、3回目と加工処理の順番が下
がるにしたがって品質も落ち、4回目の処理では保管中
に生ノリが赤変したこともあり、7〜8等の品質の著し
く劣る干し海苔となった。なお4回目の加工処理までの
経過時間は約6時間であった。しかも、いずれの加工処
理でも穴空きや破れが生じており、全体では3割に近い
ロスがあり、品質の低下分と合わせると4割を越える製
品が番外となった。結果を表1に示す。Comparative Example 2 When the same raw seaweed as in Example 1 was washed only with seawater not containing sodium lactate, the raw seaweed was hard and had poor gloss, and the dried seaweed obtained by processing was inferior to the first treatment. Although there were some cracks and contamination with raw algae, a relatively high-quality product with a grade of 5 was obtained. However, as the order of processing goes down in the second and third processing, the quality deteriorates, and in the fourth processing, Due to the fact that the raw nori turned red during storage, the quality of the dried nori was extremely poor, ranking 7-8. Note that the elapsed time until the fourth processing was about 6 hours. Moreover, holes and tears occurred in all the processing processes, resulting in a loss of nearly 30% of the total, and when combined with the reduction in quality, more than 40% of the products were rejected. The results are shown in Table 1.
【0021】実施例2
実施例1と同一の原藻を使用し、乳酸ナトリウムに代え
てリンゴ酸ナトリウムを使用した以外は実施例1と同様
の処理を行った結果、実施例1と同様に良質の干し海苔
(第1回目の処理で上4等、第4回目で上5等)を得る
ことができた。結果を表1に示す。Example 2 The same raw algae as in Example 1 were used, and the same treatment as in Example 1 was carried out except that sodium malate was used instead of sodium lactate. As a result, the same quality as in Example 1 was obtained. We were able to obtain dried seaweed (Top 4 in the first treatment, Top 5 in the fourth). The results are shown in Table 1.
【0022】実施例3
実施例1と同一の原藻を使用し、乳酸ナトリウムに代え
てクエン酸三ナトリウムとクエン酸一カリウムの等量混
合物を使用した以外は実施例1と同様の処理を行った結
果、実施例1と同様に良質の干し海苔(第1回目の処理
で3等、第4回目で上5等)を得ることができた。結果
を表1に示す。Example 3 The same raw algae as in Example 1 were used, and the same treatment as in Example 1 was carried out except that a mixture of equal amounts of trisodium citrate and monopotassium citrate was used instead of sodium lactate. As a result, as in Example 1, good quality dried seaweed (3rd grade in the first treatment, top 5 in the fourth treatment) could be obtained. The results are shown in Table 1.
【0023】実施例4
実施例1と同一の原藻を使用し、乳酸ナトリウムに代え
て酒石酸カリウムを使用した以外は実施例1と同様の処
理を行った結果、生ノリでは乳酸ナトリウムを使用した
場合と比較して光沢がやや劣るものの、加工処理は順調
であり、良質の干し海苔(第1回目の処理で上4等、第
4回目で上5等)が得られた。結果を表1に示す。Example 4 The same raw algae as in Example 1 were used, and the same treatment as in Example 1 was carried out except that potassium tartrate was used instead of sodium lactate. As a result, sodium lactate was used in raw nori. Although the gloss was slightly inferior compared to the case, the processing went well and good quality dried seaweed was obtained (Top 4 in the first treatment, Top 5 in the fourth). The results are shown in Table 1.
【0024】[0024]
【表1】[Table 1]
【0025】[0025]
【表2】[Table 2]
【0026】[0026]
【表3】[Table 3]
【0027】[0027]
【発明の効果】生ノリを水溶性の塩類で処理することに
より、収穫後時間を経ても赤変することなく、製造時の
作業性を向上させると共に、従来は加工処理の順番によ
って漸次低下の認められた干し海苔の品質が、本発明に
より安定し、低下することなく均質で上質な干し海苔を
得ることができる。[Effect of the invention] By treating raw seaweed with water-soluble salts, it does not turn red even after harvesting, improving workability during production, and reducing the gradual deterioration that was previously possible depending on the order of processing. The recognized quality of dried seaweed is stabilized by the present invention, and homogeneous and high-quality dried seaweed can be obtained without deterioration.
Claims (4)
群から選ばれた少なくとも1種の酸の水溶性の塩類の水
溶液で洗浄することを特徴とする生ノリの処理法。1. A method for treating raw seaweed, which comprises washing raw seaweed with an aqueous solution of a water-soluble salt of at least one acid selected from the group consisting of organic acids and phosphoric acid.
酸、乳酸、リンゴ酸、リン酸または重合リン酸である請
求項1に記載の生ノリの処理法。2. The method for treating raw nori according to claim 1, wherein the acid forming the salts is citric acid, tartaric acid, lactic acid, malic acid, phosphoric acid or polymerized phosphoric acid.
塩である請求項1または請求項2に記載の生ノリの処理
法。3. The method for treating raw seaweed according to claim 1 or 2, wherein the salts are sodium salts or potassium salts.
水溶液を使用する請求項1〜3のいずれか一つに記載の
生ノリの処理法。4. The method for treating raw seaweed according to any one of claims 1 to 3, wherein an aqueous solution of 0.005 to 0.5% by weight of the salts is used.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3079410A JPH04316466A (en) | 1991-04-12 | 1991-04-12 | Treatment of raw laver |
| KR1019910017817A KR920019277A (en) | 1991-04-12 | 1991-10-10 | Treatment of appearance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3079410A JPH04316466A (en) | 1991-04-12 | 1991-04-12 | Treatment of raw laver |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04316466A true JPH04316466A (en) | 1992-11-06 |
Family
ID=13689096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3079410A Pending JPH04316466A (en) | 1991-04-12 | 1991-04-12 | Treatment of raw laver |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH04316466A (en) |
| KR (1) | KR920019277A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104366599A (en) * | 2014-11-20 | 2015-02-25 | 洞头县水产科学技术研究所 | Processing method of seasoned laver |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446350B1 (en) * | 2000-03-07 | 2004-09-01 | 조재형 | Laver seasoned with the powder of curry, bean sauce, cinnamon, licorice or mustard, etc. |
| KR100448595B1 (en) * | 2001-10-26 | 2004-09-13 | 김효성 | The apple fermented liquid and the preparation method of laver with the liquid |
| KR100448596B1 (en) * | 2002-01-23 | 2004-09-13 | 김효성 | The plum fermented liquid and the preparation method of laver with the liquid |
| KR100448597B1 (en) * | 2002-01-23 | 2004-09-13 | 김효성 | The grape fermented liquid and the preparation method of laver with the liquid |
| KR20040037517A (en) * | 2002-10-29 | 2004-05-07 | 김효성 | The complex fremented liquid of the apple grapes plum and the manufacturing method of laver using the liquid |
-
1991
- 1991-04-12 JP JP3079410A patent/JPH04316466A/en active Pending
- 1991-10-10 KR KR1019910017817A patent/KR920019277A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104366599A (en) * | 2014-11-20 | 2015-02-25 | 洞头县水产科学技术研究所 | Processing method of seasoned laver |
Also Published As
| Publication number | Publication date |
|---|---|
| KR920019277A (en) | 1992-11-19 |
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