JPH04324A - Production of grain-oriented silicon steel sheet having large sheet thickness and excellent in magnetic property - Google Patents

Production of grain-oriented silicon steel sheet having large sheet thickness and excellent in magnetic property

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Publication number
JPH04324A
JPH04324A JP2100633A JP10063390A JPH04324A JP H04324 A JPH04324 A JP H04324A JP 2100633 A JP2100633 A JP 2100633A JP 10063390 A JP10063390 A JP 10063390A JP H04324 A JPH04324 A JP H04324A
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Japan
Prior art keywords
rolling
hot
final
annealing
hot rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2100633A
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Japanese (ja)
Other versions
JPH0742506B2 (en
Inventor
Yasunari Yoshitomi
吉冨 康成
Katsuro Kuroki
黒木 克郎
Kiyoshi Ueno
植野 清
Nobuyuki Takahashi
延幸 高橋
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Nippon Steel Corp
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Nippon Steel Corp
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Publication of JPH04324A publication Critical patent/JPH04324A/en
Publication of JPH0742506B2 publication Critical patent/JPH0742506B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Soft Magnetic Materials (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、トランス等の鉄心として使用される磁気特性
の優れた一方向性電磁鋼板の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for manufacturing a unidirectional electrical steel sheet with excellent magnetic properties used as an iron core of a transformer or the like.

〔従来の技術〕[Conventional technology]

一方向性電磁鋼板は、主にトランスその他の電気機器の
鉄心材料として使用されており、励磁特性、鉄損特性等
の磁気特性に優れていることが要求される。励磁特性を
表す数値としては、磁場の強さ800A/mにおける磁
束密度B,が通常使用される。また、鉄損特性を表す数
値としては、周波数50七で1.7テスラー(T)まで
磁化したときのlkg当りの鉄FjlW,,/5.を使
用いている。
Unidirectional electrical steel sheets are mainly used as core materials for transformers and other electrical equipment, and are required to have excellent magnetic properties such as excitation properties and iron loss properties. As a numerical value representing the excitation characteristic, a magnetic flux density B at a magnetic field strength of 800 A/m is usually used. In addition, the numerical value representing the iron loss characteristic is iron FjlW,,/5. are using.

磁束密度は、鉄損特性の最大支配因子であり、船釣にい
って磁束密度が高いはど鉄損特性が良好ニナる。なお、
一般的に磁束密度を高くすると二次再結晶粒が大きくな
り、鉄損特性が不良となる場合がある。これに対しては
、磁区制御により、二次再結晶粒の粒径に拘らず、鉄損
特性を改善することができる。
Magnetic flux density is the most dominant factor in iron loss characteristics, and when fishing on a boat, the higher the magnetic flux density, the better the iron loss characteristics. In addition,
Generally, when the magnetic flux density is increased, secondary recrystallized grains become larger, which may result in poor iron loss characteristics. On the other hand, by magnetic domain control, the iron loss characteristics can be improved regardless of the grain size of the secondary recrystallized grains.

この一方向性型M!鋼板は、最終仕上焼鈍工程で二次再
結晶を起こさせ、鋼板面に(1101,圧延方向に<0
01>軸をもったいわゆるゴス組織を発達させることに
より、製造されている。良好な磁気特性を得るためには
、磁化容易軸である<001>を圧延方向に高度に揃え
ることが必要である。二次再結晶粒の方向性は、MnS
、 At N等をインヒビターとして利用し、最終強圧
下圧延を施す方法によって大幅に改善され、それに伴っ
て鉄損特性も著しく向上する。
This unidirectional type M! The steel plate undergoes secondary recrystallization in the final finish annealing process, and the steel plate surface has (1101, <0 in the rolling direction).
01> It is manufactured by developing a so-called Goss structure with an axis. In order to obtain good magnetic properties, it is necessary to highly align <001>, which is the axis of easy magnetization, in the rolling direction. The orientation of secondary recrystallized grains is MnS
, At 2 N, etc. as an inhibitor, and a final strong reduction rolling is performed, which significantly improves the iron loss characteristics.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

ところで、近年タービン発電機用鉄心材料等の用途に、
現用の高級無方向性電磁鋼板にかわって、方向性電磁鋼
板を用いたいというニーズが高まってきた。上記用途に
関していえば、他の無方向性電磁鋼板の用途と比較して
、一方向の磁気特性が重要とされるため、方向性電磁調
板を用いたいというニーズが高まってきたわけである。
By the way, in recent years, it has been used as iron core material for turbine generators, etc.
There has been a growing need to use grain-oriented electrical steel sheets in place of the currently used high-grade non-oriented electrical steel sheets. Regarding the above-mentioned uses, compared to other uses of non-oriented electromagnetic steel sheets, unidirectional magnetic properties are considered to be more important, so there has been an increasing need to use directional electromagnetic control plates.

一方、方向性電磁鋼板の熱延後の製造の土工、程は、熱
延板焼鈍−冷延一説炭焼鈍一仕上焼鈍となっており、無
方向性電磁鋼板の熱延後の主工程である冷延−焼鈍と比
較して、複雑となっている。そのため、製造コストから
して、方向性!磁鋼板の方が無方向性電磁鋼板よりかな
り高いものとなる。更に、主として0.5 m厚等の厚
手を必要とする上記用途においては、例えば0.08w
t%程度のCを含有する通常の方向性電磁鋼用スラブを
素材として用いると、脱炭焼鈍工程で磁気時効の生じな
いCレヘル(例えば0.003wt%以下)まで脱炭す
るのに要する時間がかかりすぎるため、当然製造コスト
が高くなってしまう。
On the other hand, the manufacturing process after hot rolling of grain-oriented electrical steel sheets consists of hot rolling annealing, cold rolling, charcoal annealing, and finishing annealing, which are the main processes after hot rolling of non-oriented electrical steel sheets. It is more complicated than cold rolling-annealing. Therefore, from the manufacturing cost, direction! Magnetic steel sheets are considerably more expensive than non-oriented electrical steel sheets. Furthermore, in the above-mentioned applications that mainly require a thickness of 0.5 m, for example, 0.08 w.
When a normal grain-oriented electrical steel slab containing approximately t% of C is used as a material, the time required to decarburize it to a C level (for example, 0.003 wt% or less) where magnetic aging does not occur in the decarburization annealing process. Since it takes too much, the manufacturing cost naturally increases.

また、方向性を磁鋼板の製造においては通常熱延後組織
の不均一化、析出処理等を目的として熱延板焼鈍が行わ
れている。例えばAINを主インヒビターとする製造方
法においては、特公昭4623820号公報に示すよう
に熱延板焼鈍においてAINの析出処理を行ってインヒ
ビターを制御する方法がとられている。
In addition, in the production of oriented magnetic steel sheets, hot-rolled sheets are usually annealed for the purpose of making the structure non-uniform, precipitation treatment, etc. after hot rolling. For example, in a manufacturing method using AIN as the main inhibitor, as shown in Japanese Patent Publication No. 4,623,820, a method is used in which a precipitation treatment of AIN is performed during hot-rolled sheet annealing to control the inhibitor.

近年多量のエネルギー消費をするこのような方向性電磁
鋼板の製造工程に対する見直しが進められ、工程、エネ
ルギーの簡省略化の要請が強まってきた。このような要
請に応えるべく、AINを主インヒビターとする製造方
法において、熱延板焼鈍でのAINの析出処理を、熱延
後の高温巻取で代替する方法(特公昭59−45730
号公報)が提案された。確かにこの方法によって熱延板
焼鈍を省略しても、磁気特性をある程度確保することは
できるが、5〜20トンのコイル状で巻取られる通常の
方法においては、冷却過程でコイル内での場所的な熱履
歴の差が生じ、必然的にAINの析出が不均一となり、
最終的な磁気特性はコイル内の場所によって変動し、歩
留が低下する結果となる。
In recent years, the manufacturing process of grain-oriented electrical steel sheets, which consumes a large amount of energy, has been reviewed, and there has been a growing demand for simplification of the process and energy. In order to meet these demands, in a manufacturing method in which AIN is the main inhibitor, a method (Japanese Patent Publication No. 59-45730
Publication No.) was proposed. It is true that magnetic properties can be maintained to a certain extent even if hot-rolled sheet annealing is omitted using this method, but in the normal method of winding into a 5-20 ton coil, Differences in thermal history occur locally, which inevitably results in uneven precipitation of AIN.
The final magnetic properties vary depending on location within the coil, resulting in lower yields.

そこで本発明者らは、従来はとんど注目されていなかっ
た仕上熱延最終バス後の再結晶現象に着目し、この現象
を利用して80%以上の強圧下1回冷延による製造法に
おいて熱延板焼鈍を省略することを検討した。
Therefore, the present inventors focused on the recrystallization phenomenon after the final bath of finish hot rolling, which had not received much attention in the past, and utilized this phenomenon to develop a manufacturing method using one cold rolling under a strong reduction of 80% or more. We considered omitting hot-rolled sheet annealing.

一方向性電磁鋼板の熱延に関しては、高温スラブ加熱(
例えば1300℃以上)時のスラブ結晶粒の粗大成長に
起因する二次再結晶不良(圧延方向に連なった線状細粒
発生)を防止するために、熱延時の960〜1190℃
での温度で1バス当り30%以上の圧下率で再結晶化高
圧下圧延を施し、粗大結晶粒を分断する方法が提案され
ている(特公昭60−37172号公報)。確かにこの
方法によって線状細粒発生が減少するが、熱延板焼鈍を
施す製造プロセスを前提としている。
For hot rolling of unidirectional electrical steel sheets, high-temperature slab heating (
For example, in order to prevent secondary recrystallization failure (occurrence of linear fine grains connected in the rolling direction) caused by coarse growth of slab crystal grains at temperatures of 960 to 1190°C during hot rolling,
A method has been proposed in which coarse crystal grains are divided by performing recrystallization high reduction rolling at a temperature of 30% or more per bath (Japanese Patent Publication No. 37172/1983). This method certainly reduces the generation of linear fine grains, but it is based on the manufacturing process of hot-rolled sheet annealing.

また、MnS、  MnSe、 Sbをインヒビターと
する製造方法において、熱延時の950〜1200’C
の温度で圧下率10%以上で連続して熱延し、引き続き
3°(/sec以上の冷却速度で冷却することによって
MnS、  MnSeを均一微細に析出させ、磁気特性
を向上させる方法が提案されている(特開昭51−20
716号公報)。また熱延を低温で行い再結晶の進行を
抑制し、剪断変形で形成される(110)<001>方
位粒が引き続く再結晶で減少するのを防止することによ
って磁気特性を向上させる方法が提案されている(特公
昭59−32526号公報、特公昭59−35415号
公報)。これらの方法においても、熱延板焼鈍無しの1
回冷延法での製造は検討さえされていない。また超低炭
素を含有する珪素鋼スラブの熱延において、熱延板で歪
を蓄積させる低温大圧下熱延を行い、引き続く熱延板焼
鈍での再結晶により超低炭素材特有の粗大結晶粒を分断
する方法が提案されている(特公昭59−34212号
公報)。しかしこの方法においても、熱延板焼鈍無しの
1回冷延法での製造は検討さえされていない。
In addition, in a manufacturing method using MnS, MnSe, or Sb as an inhibitor,
A method has been proposed in which MnS and MnSe are precipitated uniformly and finely by continuously hot rolling at a temperature of 10% or more with a reduction rate of 10% or more, followed by cooling at a cooling rate of 3°/sec or more, thereby improving the magnetic properties. (Unexamined Japanese Patent Publication No. 51-20
Publication No. 716). In addition, a method has been proposed to improve magnetic properties by performing hot rolling at a low temperature to suppress the progress of recrystallization and to prevent the (110) <001> oriented grains formed by shear deformation from being reduced by subsequent recrystallization. (Japanese Patent Publication No. 59-32526, Japanese Patent Publication No. 59-35415). In these methods as well, 1 without annealing the hot rolled sheet.
Production by the re-cold rolling method has not even been considered. In addition, when hot-rolling silicon steel slabs containing ultra-low carbon, we conduct low-temperature, large-reduction hot rolling that accumulates strain in the hot-rolled plate, and then recrystallize in the subsequent hot-rolled plate annealing to create the coarse crystal grains characteristic of ultra-low carbon materials. A method has been proposed (Japanese Patent Publication No. 59-34212). However, even in this method, production by a one-time cold rolling method without hot-rolled sheet annealing has not even been considered.

そこで本発明者らは、従来はとんど注目されていなかっ
た仕上熱延の最終パス後の再結晶現象に着目し、この現
象を利用して80%以上の強圧下1回冷延による製造法
において熱延板焼鈍を省略して優れた磁気特性をもつ一
方向性電磁鋼板を得ることを目的として研究を行った。
Therefore, the present inventors focused on the recrystallization phenomenon after the final pass of finishing hot rolling, which had not received much attention in the past, and utilized this phenomenon to develop a method for manufacturing by cold rolling in one pass under a strong reduction of 80% or more. Research was conducted with the aim of obtaining unidirectional electrical steel sheets with excellent magnetic properties by omitting the hot-rolled sheet annealing process.

〔課題を解決するための手段〕[Means to solve the problem]

本発明は、かかる目的を達成するために重量でC:  
0.010〜0.060%、Si:2.5〜4.5%な
らびに通常のインヒビター成分を含み、残余はFeおよ
び不可避的不純物よりなる珪素鋼スラブに対し、熱延終
了温度を750〜1150℃とし、最終3パスの累積圧
下率を50%以上とする熱延を行い、引き続き熱延板焼
鈍をすることなく圧下率80%以上の冷延、脱炭焼鈍、
最終仕上焼鈍を施すことを特徴とする0、 4〜1.0
 m厚の厚手一方向性電mm板の製造法を提供するもの
である。
In order to achieve such an objective, the present invention provides C:
For silicon steel slabs containing 0.010 to 0.060%, Si: 2.5 to 4.5%, and normal inhibitor components, with the remainder consisting of Fe and unavoidable impurities, the hot rolling end temperature was set to 750 to 1150. ℃, perform hot rolling with a cumulative reduction rate of 50% or more in the final three passes, followed by cold rolling with a reduction rate of 80% or more without hot-rolled sheet annealing, decarburization annealing,
0, 4 to 1.0 characterized by final annealing
The present invention provides a method for manufacturing a thick unidirectional electric plate having a thickness of m.

更に、この特徴に加えて、仕上熱延の最終パスの圧下率
を20%以上とすることによって、−層磁気特性の優れ
た一方向性電磁鋼板が得られる。
Furthermore, in addition to this feature, by setting the rolling reduction ratio in the final pass of finish hot rolling to 20% or more, a unidirectional electrical steel sheet with excellent -layer magnetic properties can be obtained.

〔作 用] 本発明が対象としている一方向性電磁鋼板は、従来用い
られている製鋼法で得られた溶鋼を連続鋳造法或いは造
塊法で鋳造し、必要に応じて分塊工程を挟んでスラブと
し、引き続き熱間圧延して熱延板とし、次いで熱延板焼
鈍を施すことなく圧下率80%以上の冷延、脱炭焼鈍、
最終仕上焼鈍を順次行うことによって製造される。
[Function] The unidirectional electrical steel sheet targeted by the present invention is produced by casting molten steel obtained by a conventional steel manufacturing method using a continuous casting method or an ingot forming method, and inserting a blooming process as necessary. The slab is made into a slab, followed by hot rolling to make a hot rolled plate, and then cold rolled with a rolling reduction of 80% or more without annealing the hot rolled plate, decarburized annealing,
Manufactured by sequential final annealing.

本発明者らは、仕上熱延の最終パス後の再結晶現象に注
目して、種々の観点から広範囲にわたって研究したとこ
ろ、この現象と磁気特性が密接に関係していることを確
かめた。以下、実験結果を基に詳細に説明する。
The present inventors focused on the recrystallization phenomenon after the final pass of finish hot rolling and conducted extensive research from various viewpoints, and as a result, confirmed that this phenomenon and magnetic properties are closely related. A detailed explanation will be given below based on experimental results.

第1図は熱延終了温度及び熱延の最終3パスの累積圧下
率が製品の磁束密度に与える影響を表したグラフである
。ここでは、C: 0.036重量%、Si:3.20
重量%、酸可溶性At : 0.027重量%、N :
 0.0081重量%、S : 0.007重量%、M
n : 0.15重量%を含有し、残部Fe及び不可避
的不純物からなる20〜80閣厚のスラブを1150〜
1400℃に加熱し、6パスで3,4閣厚の熱延板に熱
延し、約1秒後に水冷し、550℃まで冷却した後、5
50℃に1時間保持して炉冷する巻取りシミュレートを
施し、熱延板焼鈍を施すことなく約85%の強圧下圧延
を行って最終板厚0.5 amの冷延板とし、830〜
1000℃の温度で脱炭焼鈍を行い、引き続きMgOを
主成分とする焼鈍分離剤を塗布して最終仕上焼鈍を行っ
た。
FIG. 1 is a graph showing the influence of the hot rolling end temperature and the cumulative reduction rate of the final three passes of hot rolling on the magnetic flux density of the product. Here, C: 0.036% by weight, Si: 3.20
Weight %, acid soluble At: 0.027 weight %, N:
0.0081% by weight, S: 0.007% by weight, M
n: 0.15% by weight, and the balance is Fe and unavoidable impurities.
Heated to 1400℃, hot-rolled into a hot-rolled sheet of 3 or 4 thickness in 6 passes, cooled with water after about 1 second, cooled to 550℃,
A winding simulation was performed in which the sheet was kept at 50°C for 1 hour and cooled in a furnace, and then a cold rolled sheet with a final thickness of 0.5 am was obtained by performing heavy reduction rolling of about 85% without performing hot rolled sheet annealing. ~
Decarburization annealing was performed at a temperature of 1000°C, followed by applying an annealing separator containing MgO as a main component, and final finish annealing was performed.

第1図から明らかなように熱延終了温度750〜115
0℃で、かつ最終3パスの累積圧下率50%以上の場合
にB、≧1.8 B Tの高い磁束密度が得られている
。また本発明者らはこの新知見をさらに詳細に検討した
As is clear from Figure 1, the hot rolling finish temperature is 750 to 115.
A high magnetic flux density of B≧1.8 B T was obtained at 0° C. and when the cumulative reduction rate of the final three passes was 50% or more. The present inventors also investigated this new finding in more detail.

第2図は、第1図で磁束密度が良好であった熱延終了温
度750〜1150℃で、かつ熱延の最終3パス累積圧
下率50%以上の場合における熱延の最終パスの圧下率
と磁束密度との関係を表したグラフである。
Figure 2 shows the rolling reduction in the final pass of hot rolling when the magnetic flux density was good in Figure 1, at a hot rolling end temperature of 750 to 1150°C, and when the cumulative rolling reduction in the final three passes of hot rolling was 50% or more. It is a graph showing the relationship between magnetic flux density and magnetic flux density.

第2図から明らかなように最終パスの圧下率が20%以
上の場合に88≧1.907の高い磁束密度が得られて
いる。
As is clear from FIG. 2, a high magnetic flux density of 88≧1.907 is obtained when the rolling reduction ratio in the final pass is 20% or more.

熱延終了温度、最終3パスの累積圧下率、最終パスの圧
下率と製品の磁束密度との間に第1図及び第2図に示し
た関係が成立する理由については、必ずしも明らかでは
ないが、本発明者らは次のように推察している。
Although it is not necessarily clear why the relationships shown in Figures 1 and 2 hold between the hot rolling end temperature, the cumulative rolling reduction rate of the final three passes, the rolling reduction rate of the final pass, and the magnetic flux density of the product. , the present inventors speculate as follows.

従来から(110)<001>二次再結晶粒の母体は熱
延時表面層での剪断変形で形成されると考えられており
、熱延板での(110)<ool>方位粒を冷延再結晶
後に富化するためには、熱延板での(110)<001
>方位粒を粗粒で、かつ歪の少ない状態にすることが有
効と考えられている。他方、通常行われる熱延板焼鈍の
役割は、AIN等の析出処理、冷却時の変態相の形成、
冷却時の固溶C1固溶N、微細炭窒化物の生成等が考え
られるが、これらの役割に加えて、再結晶による歪の低
下も熱延板焼鈍の重要な役割と考えられる。
It has been conventionally believed that the matrix of (110) <001> secondary recrystallized grains is formed by shear deformation in the surface layer during hot rolling. In order to enrich after recrystallization, (110)<001 in hot rolled sheet
> It is considered effective to make the oriented grains coarse and have little strain. On the other hand, the roles of commonly performed hot-rolled sheet annealing are precipitation treatment of AIN, etc., formation of transformed phases during cooling,
The formation of solid solution C1, solid solution N, and fine carbonitrides during cooling may be considered, but in addition to these roles, reduction in strain due to recrystallization is also considered to be an important role of hot-rolled sheet annealing.

そこで本発明者らは、熱間加工シミュレーターを用いて
、熱間加工再結晶挙動を詳細に検討した。
Therefore, the present inventors investigated the hot working recrystallization behavior in detail using a hot working simulator.

第3図は、熱間加工後の再結晶挙動を示すグラフである
。この場合、重量でC: 0.040%、Si:3.2
7%、Mn : 0.14%、S : 0.007%、
酸可溶性At : 0.027%、N : 0.007
6%を含有する粗圧延材より試料を切り出し、1150
℃×10分の加熱後、各温度で75%の1パス圧下を加
え、加工した温度で所定の時間保持した後水焼入れした
。しかる後、本発明者らが開発したE CP (Ele
ctronchannelling pattern)
を画像解析して結晶歪を測定する方法(日本金属学会秋
期講演大会概要集(1988、11) P2S5)を用
いて再結晶率を測定した。ここでは、標準試料の焼鈍板
に1.5%冷延した場合のECPの鮮明度より高い値を
示す粒の面積率(低歪粒の面積率)を再結晶率と呼んで
いる。この方法は従来の金属組織を目視判定して再結晶
率を測定する方法と比較して格段に精度がよい。第3図
かられかるように、1000〜1050”Cの温度範囲
で最も再結晶の進行が速いことがわかる。
FIG. 3 is a graph showing recrystallization behavior after hot working. In this case, C: 0.040%, Si: 3.2 by weight
7%, Mn: 0.14%, S: 0.007%,
Acid soluble At: 0.027%, N: 0.007
A sample was cut out from a rough rolled material containing 6%.
After heating for 10 minutes at ℃, a one-pass reduction of 75% was applied at each temperature, and after holding at the processing temperature for a predetermined time, water quenching was performed. After that, E CP (Ele
ctron channeling pattern)
The recrystallization rate was measured using a method of measuring crystal strain by image analysis (Japan Institute of Metals Autumn Conference Abstracts (1988, November) P2S5). Here, the area ratio of grains (area ratio of low strain grains) that exhibits a value higher than the ECP sharpness when a standard sample annealed plate is cold rolled by 1.5% is called recrystallization ratio. This method is much more accurate than the conventional method of visually determining the metal structure and measuring the recrystallization rate. As can be seen from FIG. 3, it can be seen that recrystallization progresses fastest in the temperature range of 1000 to 1050''C.

また、同一素材の試料を用いて、同一条件の加熱を行い
、10〜90%の圧下率で1000℃で圧下し、100
0℃の温度に1秒間保持した後水焼入れした。
In addition, samples of the same material were heated under the same conditions, rolled down at 1000°C with a rolling reduction rate of 10 to 90%, and
After being held at a temperature of 0° C. for 1 second, water quenching was performed.

しかる後上記と同一の方法で再結晶粒を判定し、その再
結粒の粒径(円相当直径)と再結晶率(低歪粒の面積率
)を画像解析機を用いて測定した。
Thereafter, recrystallized grains were determined in the same manner as above, and the grain size (circular equivalent diameter) and recrystallization rate (area ratio of low strain grains) of the recrystallized grains were measured using an image analyzer.

圧下率と粒径および再結晶率の関係を第4図に示す。第
4図かられかるように、圧下率が大きいほど再結晶率は
高く、再結晶粒の粒径は小さくなる。
FIG. 4 shows the relationship between rolling reduction, grain size, and recrystallization rate. As can be seen from FIG. 4, the larger the rolling reduction, the higher the recrystallization rate and the smaller the recrystallized grain size.

本発明の条件である、熱延終了温度を750〜1150
℃とし、最終3バスの累積圧下率を50%以上とするこ
と、さらに加えて、最終パスの圧下率を20%以上とす
ることは、第3図、第4図から明らかなように、いずれ
も仕上熱延の最終パス後に、再結晶を容易ならしめ、再
結晶粒径を微細とする要件となっていると考えられる。
The hot rolling finish temperature, which is the condition of the present invention, is 750 to 1150.
As is clear from Figures 3 and 4, it is clear from Figures 3 and 4 that the cumulative rolling reduction rate of the final three passes should be 50% or more, and in addition, the rolling reduction rate of the final pass should be 20% or more. This is considered to be a requirement for facilitating recrystallization and making the recrystallized grain size fine after the final pass of finish hot rolling.

従って、本発明の場合、熱延板の結晶粒径は小さいが歪
が少ない状態となり、(110) <001>方位粒を
冷延再結晶後に富化する点では、粒径の点で不利である
が、歪の点で有利であり、結果的には、脱炭焼鈍後の状
態で(110)<001>方位粒に大きな影響を与えな
いと考えられる。
Therefore, in the case of the present invention, the grain size of the hot-rolled sheet is small, but the strain is small, and enriching the (110) <001> oriented grains after cold-rolling recrystallization is disadvantageous in terms of grain size. However, it is advantageous in terms of strain, and as a result, it is considered that it does not have a large effect on the (110) <001> oriented grains in the state after decarburization annealing.

他方脱炭板の主方位である(111 ) <112>。On the other hand, the main orientation of the decarburization plate is (111) <112>.

(1001<025>は(110)<001>二次再結
晶粒の粒成長に影響を与える方位として知られており、
(111)<112>が多いはど(100)<025>
が少ないほど(110)<001>二次再結晶粒の粒成
長が容易となると考えられる。本発明においては、最終
パス後に引き続く再結晶において、再結晶が進みやすく
、結晶粒も微細化されやすくなる。この本発明の熱延板
を引き続き冷延再結晶させると冷延前の粒径が小さいが
ために粒界近傍から(111) <112 >が多く植
生じ、粒内から植生ずる(100)<025>が相対的
に減少する。
(1001<025> is known as an orientation that affects grain growth of (110)<001> secondary recrystallized grains,
(111) <112> is common (100) <025>
It is considered that the smaller the (110)<001> secondary recrystallized grains, the easier the grain growth. In the present invention, in the recrystallization that follows after the final pass, recrystallization tends to progress and crystal grains also tend to become finer. When this hot-rolled sheet of the present invention is subsequently cold-rolled and recrystallized, many (111) <112> grains grow near the grain boundaries because the grain size before cold rolling is small, and (100) <025> is relatively reduced.

従って本発明においては、熱延最終パス後に弓き続く再
結晶によって熱延板が低歪で、かつ結晶粒径が小さい状
態となったがために、脱炭板の状態で(1101<00
1>方位粒に影響を与えることなく、(110)<00
1>方位粒の粒成長に有利な(111] <112>方
位粒を増加させ、(1101<001>方位粒の粒成長
を妨げる(100) <025>方位粒を減少させるこ
とに成功した。これにより熱延板焼鈍を省略しても良好
な磁気特性を得ることが可能となるものと考えられる。
Therefore, in the present invention, since the recrystallization that continues after the final hot rolling pass brings the hot rolled sheet into a state of low strain and small grain size, the decarburized sheet (1101<00
1>(110)<00 without affecting the oriented grains
We succeeded in increasing (111) <112> oriented grains, which are advantageous for grain growth of 1> oriented grains, and decreasing (100) <025> oriented grains, which hinder the grain growth of (1101<001> oriented grains). It is thought that this makes it possible to obtain good magnetic properties even if hot-rolled sheet annealing is omitted.

次いで、本発明の各要件について説明する。Next, each requirement of the present invention will be explained.

本発明で使用されるスラブは重量でC: 0.010〜
0.060%、Si:2.5〜4.5%ならびに通常の
インヒビター成分を含み残余はFeおよび不可避的不純
物よりなる。
The slab used in the present invention has a weight C: 0.010~
0.060%, Si: 2.5-4.5% and normal inhibitor components, with the remainder consisting of Fe and unavoidable impurities.

次に上記成分の限定理由について述べる。Cは0.01
0%未満になると二次再結晶が不安定となり、二次再結
晶した場合でもBIl≧1.80(T)が得がたいので
、0.010%以上とした。また、0.060%を超え
ると板厚が0.4〜1.0と厚いために脱炭不良が発生
して好ましくない。また、Siについては4.5%を超
えると冷延が困難となり好ましくなく、2゜5%未満で
は良好な磁気特性を得ることが困難となり好ましくない
。また、インヒビター構成元素として、必要に応じてA
j、 N、 Mn、  S、 Se。
Next, the reason for limiting the above components will be described. C is 0.01
If it is less than 0%, secondary recrystallization will become unstable, and even if secondary recrystallization is performed, it will be difficult to obtain BIl≧1.80 (T), so it is set to 0.010% or more. Moreover, if it exceeds 0.060%, the plate thickness will be as thick as 0.4 to 1.0%, resulting in poor decarburization, which is not preferable. Furthermore, if Si exceeds 4.5%, cold rolling becomes difficult, which is undesirable, and if it is less than 2.5%, it becomes difficult to obtain good magnetic properties, which is undesirable. In addition, as an inhibitor constituent element, A
j, N, Mn, S, Se.

Sb、 B、 Cu、旧、 Nb、 Cr、 Sn、 
Ti等を添加することもできる。
Sb, B, Cu, old, Nb, Cr, Sn,
Ti and the like can also be added.

このスラブの加熱温度は、特に限定されるものではない
が、コストの面から1300℃以下とすることが好まし
い。
The heating temperature of this slab is not particularly limited, but from the viewpoint of cost, it is preferably 1300° C. or lower.

加熱されたスラブは、引き続き熱延されて熱延板となる
。本発明の特徴はこの熱延工程にある。
The heated slab is subsequently hot-rolled into a hot-rolled sheet. The feature of the present invention lies in this hot rolling process.

つまり、熱延終了温度を750〜1150℃とし、仕上
熱延の最終3パスの累積圧下率を50%以上とすること
が良好な磁気特性を得る上で好ましい。
In other words, in order to obtain good magnetic properties, it is preferable that the hot rolling end temperature be 750 to 1150° C. and the cumulative reduction rate of the final three passes of finish hot rolling be 50% or more.

また、さらに加えて、仕上熱延の最終バスの圧下率を2
0%以上にすることは、良好な磁気特性を得る上で一層
好ましい。
In addition, the rolling reduction ratio of the final bath for finish hot rolling was increased by 2.
It is more preferable to make it 0% or more in order to obtain good magnetic properties.

熱延工程は通常100〜400mm厚のスラブを加熱し
た後、いづれも複数回のバスで行う粗圧延と仕上圧延よ
り成る。粗圧延の方法については特に限定するものでは
なく通常の方法で行われる。
The hot rolling process usually consists of heating a slab with a thickness of 100 to 400 mm, and then rough rolling and finish rolling, both of which are performed in multiple baths. The rough rolling method is not particularly limited and may be carried out by a conventional method.

本発明の特徴は粗圧延に引き続く仕上圧延にある。The feature of the present invention is the finish rolling that follows the rough rolling.

仕上圧延は通常4〜10パスの高速連続圧延で行われる
。通常仕上圧延の圧下配分は前段が圧下率が高く、後段
に行くほど圧下率を下げて形状を良好なものとしている
。圧延速度は通常100〜3000+w/winとなっ
ており、バス間の時間は0.01〜100秒となってい
る。本発明で限定しているのは、熱延終了温度と最終3
パスの累積圧下率とさらに加えて最終パスの圧下率だけ
であり、その他ノ条件は特に限定するものではないが、
最終3パスのバス間時間を1000秒以上と異常に長く
とるとバス間の回復、再結晶で歪が開放され、蓄積歪の
効果が得られにくくなるので好ましくない。その信任上
熱延前段の数パスでの圧下率については、最終パスまで
加えた歪が残っていることが期待しにくいので特に限定
せず、最終3パスだけを重視すれば十分である。
Finish rolling is usually performed by high-speed continuous rolling of 4 to 10 passes. Normally, the reduction ratio in finish rolling is such that the reduction rate is high in the earlier stage, and the reduction rate is lowered toward the later stage to obtain a good shape. The rolling speed is usually 100 to 3000+w/win, and the time between baths is 0.01 to 100 seconds. What is limited in the present invention is the hot rolling end temperature and the final 3
Only the cumulative rolling reduction rate of the passes and the rolling reduction rate of the final pass are included, and other conditions are not particularly limited.
If the inter-bus time of the final three passes is abnormally long, such as 1000 seconds or more, the strain will be released by recovery and recrystallization between the buses, making it difficult to obtain the effect of accumulated strain, which is not preferable. For reliability, it is difficult to expect that the strain applied in the first pass of hot rolling will remain until the final pass, so it is not particularly limited, and it is sufficient to focus only on the final three passes.

次いで上記熱延条件の限定理由について述べる。Next, the reason for limiting the above hot rolling conditions will be described.

熱延終了温度を750−1150℃1最終3バスの累積
圧下率を50%以上としたのは、第1図から明らかなよ
うにこの範囲でB8≧1.88(T)の良好な磁束密度
B6をもつ製品が得られるためである。なお最終3パス
の累積圧下率の上限については特に限定するものではな
いが工業的には99,9%以上の累積圧下を加えること
は困難である。またさらに好ましくは最終パスの圧下率
を20%以上としたのは第2図から明らかなようにこの
範囲において、B8≧1.90(T)の−層良好な磁束
密度B、をもつ製品が得られるためである。なお最終パ
スの圧下率の上限は特に限定するものではないが、工業
的には90%以上の圧下を加えることは困難である。
The reason why the hot rolling end temperature was set at 750-1150°C and the cumulative reduction ratio of the final three baths was set to 50% or more is that, as is clear from Figure 1, a good magnetic flux density of B8 ≥ 1.88 (T) is achieved in this range. This is because a product with B6 can be obtained. The upper limit of the cumulative reduction rate of the final three passes is not particularly limited, but industrially it is difficult to apply a cumulative reduction of 99.9% or more. More preferably, the rolling reduction ratio in the final pass is set to 20% or more, as is clear from FIG. This is because it can be obtained. Although the upper limit of the rolling reduction rate in the final pass is not particularly limited, it is industrially difficult to apply a rolling reduction of 90% or more.

熱延の最終バス後、通常0.1〜100秒程度空冷され
た後水冷され300〜700 ’Cの温度で巻取られ、
徐冷される。この冷却プロセスについては特に限定され
るものではないが、熱延後1秒以上空冷することは、再
結晶を進ませる上で好ましい。
After the final bath of hot rolling, it is usually air cooled for about 0.1 to 100 seconds, then water cooled and wound up at a temperature of 300 to 700'C.
It is slowly cooled. Although this cooling process is not particularly limited, air cooling for 1 second or more after hot rolling is preferable in order to advance recrystallization.

この熱延板は熱延板焼鈍を施すことなく80%以上の圧
下率で冷延される。圧下率を80%以上としたのは、圧
下率を上記範囲とすることによって、脱炭仮において尖
鋭な(110)<OOi>方位粒と、これに蚕食され易
い対応方位粒((111)<112>方位粒等)を適正
量得ることができ、磁束密度を高める上で好ましいため
である。
This hot-rolled sheet is cold-rolled at a rolling reduction of 80% or more without performing hot-rolled sheet annealing. The reason why the rolling reduction rate is set to 80% or more is that by setting the rolling reduction rate in the above range, sharp (110) <OOi> oriented grains and corresponding oriented grains ((111) <112> orientation grains, etc.), which is preferable for increasing magnetic flux density.

冷延板の板厚を0.4〜1.0 ymと規定したのは、
厚手一方向性電vLiil板を得る本発明の目的のため
である。また、1.0 ym超では、脱炭焼鈍に時間が
かかりすぎて好ましくない。
The thickness of the cold-rolled sheet was defined as 0.4 to 1.0 ym because
It is for the purpose of the present invention to obtain thick unidirectional electrical vLiil plates. Moreover, if it exceeds 1.0 ym, decarburization annealing takes too much time, which is not preferable.

冷延後鋼板は通常の方法で脱炭焼鈍、焼鈍分離剤塗布、
仕上焼鈍を施されて最終製品となる。なお脱炭焼鈍後の
状態で二次再結晶に必要なインヒビター強度が不足して
いる場合には、仕上焼鈍等においてインヒビターを強化
する処理が必要となる。インヒビター強化法の一例とし
ては、A!を含有する鋼において仕上焼鈍雰囲気ガスの
窒素分圧を高めに設定する方法が知られている。
After cold rolling, the steel plate is decarburized and annealed in the usual way, coated with an annealing separator,
Finish annealing is applied to the final product. Note that if the inhibitor strength required for secondary recrystallization is insufficient in the state after decarburization annealing, a treatment to strengthen the inhibitor in finish annealing or the like is required. An example of an inhibitor strengthening method is A! A method is known in which the nitrogen partial pressure of the final annealing atmosphere gas is set to be high for steel containing .

〔実施例〕〔Example〕

以下実施例を説明する。 Examples will be described below.

一実施例1− C: 0.034重量%、Si:3.21重量%、Mn
二〇、16重量%、S : 0.007重量%、酸可溶
性へ!:0.026重量%、N : 0.0078重量
%を含有し、残部Fe及び不可避的不純物からなる60
■厚のスラブを1150″Cの温度で加熱した後、10
50℃で熱延を開始し6パスで熱延して3.4 mの熱
延板とした。この時圧下配分を■60→28→13→6
.5→5.0→3.8→3.4(m)、■60→40→
26→14→7.3→4.1→3.4(m)、■60→
40→26→14→7.3→4.4→3.4(M)の3
条件とした。熱延終了後は1秒間空冷後550℃まで水
冷し、550℃に1時間保持した後、炉冷する巻取シミ
ュレーションを行った。この熱延板を酸洗して圧下率的
85%で0.5閣の冷延板とし、830℃で250秒保
持する脱炭焼鈍を施した。得られた脱炭焼鈍板に、Mg
Oを主成分とする焼鈍分離剤を塗布し、N225%、N
275%の雰囲気ガス中で15℃/時の速度で1200
″Cまで昇温し、引き続きHz100%雰囲気ガス中で
1200℃で20時間保持する最終仕上焼鈍を行った。
Example 1 - C: 0.034% by weight, Si: 3.21% by weight, Mn
20.16% by weight, S: 0.007% by weight, acid soluble! : 0.026% by weight, N: 0.0078% by weight, and the remainder consists of Fe and inevitable impurities.
■ After heating a thick slab at a temperature of 1150″C, 10
Hot rolling was started at 50° C. and hot rolled in 6 passes to obtain a 3.4 m hot rolled sheet. At this time, the pressure distribution is ■60 → 28 → 13 → 6
.. 5 → 5.0 → 3.8 → 3.4 (m), ■60 → 40 →
26 → 14 → 7.3 → 4.1 → 3.4 (m), ■60 →
40 → 26 → 14 → 7.3 → 4.4 → 3.4 (M) 3
It was made a condition. After hot rolling, a winding simulation was performed in which the material was air cooled for 1 second, then water cooled to 550° C., held at 550° C. for 1 hour, and then cooled in a furnace. This hot-rolled sheet was pickled to obtain a cold-rolled sheet with a rolling reduction of 85% and a thickness of 0.5 mm, and was subjected to decarburization annealing at 830° C. for 250 seconds. Mg was applied to the obtained decarburized annealed plate.
Apply an annealing separator mainly composed of O, N225%, N
1200 at a rate of 15°C/hour in 275% atmospheric gas
Final annealing was carried out by raising the temperature to "C" and then holding it at 1200C for 20 hours in a 100% Hz atmosphere gas.

熱延条件、熱延終了温度と製品の磁気特性を第1表に示
す。
Table 1 shows the hot rolling conditions, hot rolling end temperature, and magnetic properties of the product.

一実施例2− C: 0.035重量%、Si:3.28重量%、Mn
=0.16重量%、S : 0.007重量%、酸可溶
性へ!:0.027重量%、N : 0.0080重量
%を含有し、残部Fe及び不可避的不純物からなる40
■厚のスラブを1150℃の温度で加熱した後、6パス
で熱延して3、4 mの熱延板とした。この時圧下配分
を4o→21→14→10−7.0−4.0→3.4 
(m)とし、熱延開始温度を01000℃、■900 
’C1■800℃1■700℃の4条件とした。熱延終
了後の冷却条件、引き続く最終仕上焼鈍までの工程条件
は実施例1と同じ条件で行った。
Example 2 - C: 0.035% by weight, Si: 3.28% by weight, Mn
=0.16% by weight, S: 0.007% by weight, acid soluble! : 0.027% by weight, N: 0.0080% by weight, and the balance consists of Fe and inevitable impurities.
A thick slab was heated at a temperature of 1150°C and then hot-rolled in 6 passes to form a 3-4 m hot-rolled plate. At this time, the pressure distribution is 4o → 21 → 14 → 10-7.0-4.0 → 3.4
(m), hot rolling start temperature is 01000℃, ■900℃
There were four conditions: 'C1, 800°C, 1 and 700°C. The cooling conditions after hot rolling and the process conditions up to the final final annealing were the same as in Example 1.

熱延条件、熱延終了温度と製品の磁気特性を第2表に示
す。
Table 2 shows the hot rolling conditions, hot rolling end temperature, and magnetic properties of the product.

一実施例3− C: 0.048重量%、Si:3.30重量%、Mn
二0.15重量%、S : 0.006重量%、酸可溶
性Af: 0.031重量%、N : 0.0080重
量%を含有し、残部Fe及び不可避的不純物からなる7
0m厚のスラブを1250℃の温度で加熱した後、6パ
スで熱延して3.0閣の熱延板とした。この時圧下配分
を70→45→30−15−7.5→4.5→3.0 
(m)とし、熱延開始温度を■1250℃1■1100
℃1■1000℃の3条件とした。熱延終了後は実施例
1と同じ条件で冷却した。この熱延板を酸洗して圧下率
的83%で0.5 wmの冷延板とし、830℃で15
0秒保持し引き続き850℃に20秒保持する脱炭焼鈍
を施した。得られた脱炭焼鈍板にMgOを主成分とする
焼鈍分離剤を塗布し、N225%、Hz75%の雰囲気
ガス中で10℃/時の速度で880℃まで昇温し、引き
続きN275%、H225%雰囲気ガス中で15℃/時
の速度で1200℃まで昇温し、引き続きH!100%
の雰囲気ガス中で1200℃で20時間保持する最終仕
上焼鈍を行った。
Example 3 - C: 0.048% by weight, Si: 3.30% by weight, Mn
20.15% by weight, S: 0.006% by weight, acid-soluble Af: 0.031% by weight, N: 0.0080% by weight, and the balance consists of Fe and inevitable impurities.
A slab with a thickness of 0 m was heated at a temperature of 1250° C. and then hot-rolled in 6 passes to obtain a hot-rolled sheet with a thickness of 3.0 mm. At this time, the reduction distribution is 70 → 45 → 30-15-7.5 → 4.5 → 3.0
(m), and the hot rolling start temperature is ■1250℃1■1100℃
Three conditions were used: 1°C and 1000°C. After the hot rolling was completed, cooling was performed under the same conditions as in Example 1. This hot-rolled sheet was pickled to obtain a cold-rolled sheet with a rolling reduction of 83% and a thickness of 0.5 wm.
Decarburization annealing was performed by holding at 850° C. for 0 seconds and then holding at 850° C. for 20 seconds. The resulting decarburized annealed plate was coated with an annealing separator mainly composed of MgO, heated to 880°C at a rate of 10°C/hour in an atmospheric gas of 225% N2 and 75% Hz, and then heated to 880°C at a rate of 10°C/hour. % atmosphere gas at a rate of 15°C/hour to 1200°C, and then H! 100%
Final annealing was performed at 1200° C. for 20 hours in an atmospheric gas.

た。Ta.

熱延条件、熱延終了温度と製品の磁気特性を第3表に示
す。
Table 3 shows the hot rolling conditions, hot rolling end temperature, and magnetic properties of the product.

一実施例4 C: 0.019重量%、Si:3.lQ重量%、Mn
:0.16重量%、S : 0.007重量%、酸可溶
性A!: 0.031重量%、N : 0.0078重
量%を含有し、残部Fe及び不可避的不純物からなる4
0閣厚のスラブを1150℃の温度で加熱した後、10
50℃で熱延を開始し、5パスで熱延して3.8 mm
の熱延板とした。
Example 4 C: 0.019% by weight, Si: 3. lQ weight%, Mn
: 0.16% by weight, S: 0.007% by weight, acid soluble A! : 0.031% by weight, N: 0.0078% by weight, and the remainder consists of Fe and inevitable impurities.
After heating a slab of 0 cabinet thickness at a temperature of 1150℃, 10
Start hot rolling at 50°C and hot roll in 5 passes to 3.8 mm.
It was made into a hot rolled sheet.

この時圧下配分を下記の3条件とした。At this time, the reduction distribution was set to the following three conditions.

■40→16→7.4→5.8→4.3→3.8(m+
)■40→30→22.7→13.6→6.8→3.8
(mm)■40→30→23→14→7.6→3.8(
mm)熱延後の冷却を実施例1と同じ条件で行った。
■40 → 16 → 7.4 → 5.8 → 4.3 → 3.8 (m+
)■40→30→22.7→13.6→6.8→3.8
(mm)■40→30→23→14→7.6→3.8(
mm) Cooling after hot rolling was performed under the same conditions as in Example 1.

この熱延板を酸洗して圧下率約87%で0.5Mの冷延
板とし、引き続き最終仕上焼鈍までの工程条件を実施例
1と同じ条件で行った。
This hot-rolled sheet was pickled to obtain a cold-rolled sheet of 0.5M with a rolling reduction of about 87%, and the process conditions up to final annealing were the same as in Example 1.

熱延条件、熱延終了温度、製品の磁気特性を第4表に示
す。
Table 4 shows the hot rolling conditions, hot rolling end temperature, and magnetic properties of the product.

−実施例5− C: 0.033重量%、Si:3.20重量%、Mn
=0.14重量%、S : 0.007重量%、酸可溶
性へ!二0.027重量%、N : 0.0079重量
%を含有し、残部Fe及び不可避的不純物からなる40
mm厚のスラブを1150℃の温度で加熱した後、10
50℃で熱延を開始し、6パスで熱延して3.4閣の熱
延板とした。
-Example 5- C: 0.033% by weight, Si: 3.20% by weight, Mn
=0.14% by weight, S: 0.007% by weight, acid soluble! 40 containing 20.027% by weight, N: 0.0079% by weight, and the balance consisting of Fe and inevitable impurities.
After heating a mm thick slab at a temperature of 1150°C, 10
Hot rolling was started at 50° C. and hot rolled in 6 passes to obtain a hot rolled sheet of 3.4 mm.

この時圧下配分を■40→15→7.3→5.1→4.
4→3.8−=3.4 (m) 、■40−25−15
→10→8→5.7→3.4(閣)の2条件とした。熱
延終了後の冷却条件、引き続く脱炭焼鈍までの工程条件
は実施例1と同じ条件で行った。次いで、この脱炭板に
750℃×30秒の熱処理を施し、この時Nlhガスを
雰囲気ガスに混合させ、鋼板に窒素吸収を生ぜしめた。
At this time, the pressure distribution is ■40 → 15 → 7.3 → 5.1 → 4.
4→3.8-=3.4 (m), ■40-25-15
→ Two conditions were set: 10 → 8 → 5.7 → 3.4 (Kaku). The cooling conditions after hot rolling and the process conditions up to the subsequent decarburization annealing were the same as in Example 1. Next, this decarburized plate was subjected to heat treatment at 750° C. for 30 seconds, and at this time, Nlh gas was mixed with the atmospheric gas to cause nitrogen absorption in the steel plate.

しかる後、MgOを主成分とする焼鈍分離剤を塗布し、
1200℃までN275%、8225%の雰囲気ガス中
で10℃/時の速度で昇温し、次いでHz100%の雰
囲気ガス中で1200℃で20時間保持する最終仕上焼
鈍を行った。
After that, an annealing separator mainly composed of MgO is applied,
Final annealing was carried out by increasing the temperature to 1200° C. at a rate of 10° C./hour in an atmospheric gas containing 275% N and 8225%, and then holding the temperature at 1200° C. for 20 hours in an atmospheric gas containing 100% Hz.

熱延条件、熱延終了温度と製品の磁気特性を第5表に示
す。
Table 5 shows the hot rolling conditions, hot rolling end temperature, and magnetic properties of the product.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、本発明においては、熱延終了温度
と熱延最終3パスの累積圧下率とさらに好ましくば熱延
の最終バスの圧下率を制御することにより、熱延板焼鈍
を施すことなく、1回冷延法で良好な磁気特性を有する
厚手一方向性電磁鋼板を製造することができるので、そ
の工業的効果は極めて大である。
As explained above, in the present invention, hot-rolled sheet annealing is performed by controlling the hot-rolling end temperature, the cumulative rolling reduction rate of the final three passes of hot rolling, and more preferably the rolling reduction rate of the final bath of hot rolling. Since a thick unidirectional electrical steel sheet having good magnetic properties can be produced by a single cold rolling process without any process, the industrial effect is extremely large.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は熱延終了温度及び熱延の最終3パスの累積圧下
率が製品の磁束密度に与える影響を表したグラフであり
、第2図は熱延の最終バスの圧下率が製品の磁束密度に
与える影響を表したグラフであり、第3図は、熱間加工
再結晶挙動を示すグラフであり、第4図は再結晶率、再
結晶粒径に対する圧下率の影響を示すグラフである。 20   4θ     6θ θO 整数最終パスの、圧下率(%) 第1図 O1lθθ≦Bl(T) e  +  t19o≦B11(r)<1.りe・ ;
δ# (T) < 180 θ 2θ    40〃6θ    〃 んν 麩延i科3パスの累積圧下雫(幻 加工完了後l′うの時間(δec)
Figure 1 is a graph showing the influence of the end temperature of hot rolling and the cumulative reduction rate of the final three passes of hot rolling on the magnetic flux density of the product. FIG. 3 is a graph showing the effect on density; FIG. 3 is a graph showing hot working recrystallization behavior; FIG. 4 is a graph showing the effect of rolling reduction on recrystallization rate and recrystallized grain size. . 20 4θ 6θ θO Integer Final pass rolling reduction rate (%) Figure 1 O1lθθ≦Bl(T) e + t19o≦B11(r)<1. ri e・;
δ# (T) < 180 θ 2θ 40〃6θ 〃 ν Cumulative reduction drop of 3 passes of Funobe (l' time after completion of phantom machining (δec)

Claims (2)

【特許請求の範囲】[Claims] (1)重量でC:0.010〜0.060%、Si:2
.5〜4.5%ならびに通常のインヒビター成分を含み
、残余はFeおよび不可避的不純物よりなる珪素鋼スラ
ブを熱延し、熱延板焼鈍をすることなく、引き続き圧下
率80%以上の冷延、脱炭焼鈍、最終仕上焼鈍を施して
0.4〜1.0mm厚の厚手一方向性電磁鋼板を製造す
る方法において、熱延終了温度を750〜1150℃と
し、最終3パスの累積圧下率を50%以上とすることを
特徴とする磁気特性の優れた厚い板厚の一方向性電磁鋼
板の製造方法。
(1) C: 0.010-0.060%, Si: 2 by weight
.. Hot-rolling a silicon steel slab containing 5 to 4.5% and normal inhibitor components, with the remainder consisting of Fe and unavoidable impurities, followed by cold rolling at a rolling reduction of 80% or more without hot-rolled plate annealing, In a method of producing thick unidirectional electrical steel sheets with a thickness of 0.4 to 1.0 mm by performing decarburization annealing and final finish annealing, the hot rolling end temperature is 750 to 1150 ° C., and the cumulative reduction rate of the final three passes is 50% or more, a method for producing a thick unidirectional electrical steel sheet with excellent magnetic properties.
(2)仕上熱延の最終パスの圧下率が20%以上である
ことを特徴とする請求項1記載の磁気特性の優れた厚い
板厚の一方向性電磁鋼板の製造方法。
(2) The method for manufacturing a thick unidirectional electrical steel sheet with excellent magnetic properties according to claim 1, characterized in that the rolling reduction in the final pass of finish hot rolling is 20% or more.
JP2100633A 1990-04-17 1990-04-17 Method for manufacturing thick unidirectional electrical steel sheet with excellent magnetic properties Expired - Lifetime JPH0742506B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2100633A JPH0742506B2 (en) 1990-04-17 1990-04-17 Method for manufacturing thick unidirectional electrical steel sheet with excellent magnetic properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2100633A JPH0742506B2 (en) 1990-04-17 1990-04-17 Method for manufacturing thick unidirectional electrical steel sheet with excellent magnetic properties

Publications (2)

Publication Number Publication Date
JPH04324A true JPH04324A (en) 1992-01-06
JPH0742506B2 JPH0742506B2 (en) 1995-05-10

Family

ID=14279241

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JPH0742506B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011219793A (en) * 2010-04-06 2011-11-04 Nippon Steel Corp Hot-rolled plate for oriented electromagnetic steel sheet excellent in magnetic characteristic, and method of producing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011219793A (en) * 2010-04-06 2011-11-04 Nippon Steel Corp Hot-rolled plate for oriented electromagnetic steel sheet excellent in magnetic characteristic, and method of producing the same

Also Published As

Publication number Publication date
JPH0742506B2 (en) 1995-05-10

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