JPH0446957A - Unsaturated polyester resin molding material - Google Patents
Unsaturated polyester resin molding materialInfo
- Publication number
- JPH0446957A JPH0446957A JP15607490A JP15607490A JPH0446957A JP H0446957 A JPH0446957 A JP H0446957A JP 15607490 A JP15607490 A JP 15607490A JP 15607490 A JP15607490 A JP 15607490A JP H0446957 A JPH0446957 A JP H0446957A
- Authority
- JP
- Japan
- Prior art keywords
- polyester resin
- unsaturated polyester
- molding material
- alkanepolyol
- resin molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 14
- 239000012778 molding material Substances 0.000 title claims description 10
- -1 alkylphenyl phosphite Chemical compound 0.000 claims abstract description 15
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- 229920005862 polyol Polymers 0.000 claims description 7
- 239000000463 material Substances 0.000 abstract description 5
- 239000003365 glass fiber Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 159000000003 magnesium salts Chemical class 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000012779 reinforcing material Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は住宅機器用、建築部材用、衛生機器用、電気機
器用等、特に光沢、透明性が要求される成形品に用いら
れる不飽和ポリエステル樹脂成形材料に関するものであ
る。[Detailed Description of the Invention] [Industrial Application Field] The present invention is directed to unsaturated resins used in molded products that particularly require gloss and transparency, such as housing equipment, building materials, sanitary equipment, electrical equipment, etc. This invention relates to polyester resin molding materials.
従来、不飽和ポリエステル樹脂成形品は高強度、耐久性
に優れ、成形時に成形材料の流動性がよい為、低圧成形
で大型成形品を成形することができるが、通常用いられ
る脂肪酸金属塩からなる離型剤では金属塩が成形品表面
にブリードアウトして光沢、透明性が低下する欠点があ
った。Conventionally, unsaturated polyester resin molded products have high strength and durability, and the fluidity of the molding material during molding is good, so large molded products can be formed by low-pressure molding. Mold release agents have the disadvantage that the metal salt bleeds out onto the surface of the molded product, reducing gloss and transparency.
従来の技術で述べたように、従来の不飽和ポリエステル
樹脂成形品は光沢、透明性が低下する問題点があった。As described in the section on the prior art, conventional unsaturated polyester resin molded products have the problem of reduced gloss and transparency.
本発明は従来の技術における上述の問題点に鑑みてなさ
れたもので、その目的とするところは、光沢、透明性に
優れた成形品が得られる不飽和ポリエステル樹脂成形材
料を提供することにある。The present invention was made in view of the above-mentioned problems in the conventional technology, and its purpose is to provide an unsaturated polyester resin molding material from which molded products with excellent gloss and transparency can be obtained. .
本発明はアルキルフェニルホスファイトと、アルカンポ
リオールリン酸エステル塩とを含有したことを特徴とす
る不飽和ポリエステル樹脂成形材料のため、離型剤が成
形品表面にブリードアウトすることがなく、光沢、透明
性を阻害しないもので、以下本発明の詳細な説明する。The present invention is an unsaturated polyester resin molding material characterized by containing an alkylphenyl phosphite and an alkane polyol phosphate ester salt, so that the mold release agent does not bleed out onto the surface of the molded product, and the gloss and shine are maintained. The present invention will be described in detail below, using materials that do not impede transparency.
本発明に用いるアルキルフェニルホスファイトは、アル
キルフェニルホスファイト全般を含むもので、添加量は
不飽和ポリエステル樹脂１００重置部（以下単に部と記
す）に対し０．１〜５部であることが好ましい、即ち０
．１部未満では離型性が低下し、５部をこえると光沢が
低下する傾向にあるからである。アルカンポリオールリ
ン酸エステル塩もアルカンポリオールリン酸エステル塩
全般を含むもので、飽和アルカンポリオールリン酸エス
テル塩でも不飽和アルカンポリオールリン酸エステル塩
でもよい、アルカンポリオールリン酸エステル塩として
はカルシウム、カリウム、ナトリウム、マグネシウム、
アルミニウム、亜鉛、錫が好ましく添加量は樹脂１００
部に対し０．０１〜０゜１部であることが望ましい、即
ち０．０１部未満ではアルキルフェニルホスファイトと
樹脂との相溶性が低下し、０．１部をこえても効果に差
がでないためである。不飽和ポリエステル樹脂は全般を
用いることができ、架橋剤としてのスチレンモノマー等
を含有させておくこともできる。充填剤としてはパルプ
、木粉、ガラスパウダー、炭酸カルシウム、クレー、シ
リカ、タルク、水酸化アルミニウム等を添加することが
できる。低収縮剤とじての熱可朔性樹脂、ガラス繊維、
ガラス繊維チップ等の補強剤、架橋剤、重合開始剤、着
色側等については特に限定するものではなく通常用いら
れるものをそのまま用いることができる。かくして得ら
れた不飽和ポリエステル樹脂成形材料を圧縮成形、押出
成形、トランスファー成形、射出型成形等により加熱加
圧成形し、光沢、透明性に優れた成形品を得ることがで
きるものである。The alkylphenyl phosphite used in the present invention includes all alkylphenyl phosphites, and the amount added is 0.1 to 5 parts per 100 parts (hereinafter simply referred to as parts) of the unsaturated polyester resin. preferred, i.e. 0
．． This is because if the amount is less than 1 part, the mold releasability tends to decrease, and if it exceeds 5 parts, the gloss tends to decrease. Alkane polyol phosphate ester salts also include all alkane polyol phosphate ester salts, and may be saturated alkane polyol phosphate ester salts or unsaturated alkane polyol phosphate ester salts. Examples of alkane polyol phosphate ester salts include calcium, potassium, sodium, magnesium,
Aluminum, zinc, and tin are preferably added in an amount of 100% resin.
It is preferable that the amount is 0.01 to 0.1 part per part.If it is less than 0.01 part, the compatibility between the alkylphenyl phosphite and the resin will decrease, and if it exceeds 0.1 part, there will be no difference in the effect. This is because it is not. Any unsaturated polyester resin can be used, and a styrene monomer or the like as a crosslinking agent can also be included. As fillers, pulp, wood flour, glass powder, calcium carbonate, clay, silica, talc, aluminum hydroxide, etc. can be added. Thermoplastic resins, glass fibers as low shrinkage agents,
Reinforcing agents such as glass fiber chips, crosslinking agents, polymerization initiators, coloring agents, etc. are not particularly limited, and commonly used ones can be used as they are. The unsaturated polyester resin molding material thus obtained can be molded under heat and pressure by compression molding, extrusion molding, transfer molding, injection molding, etc. to obtain molded products with excellent gloss and transparency.
以下本発明を実施例にもとづいて説明する。The present invention will be explained below based on examples.
実施例１及び２と比較例
第１表の配合表にもとづいて各材料をニーグーで混練し
て不飽和ポリエステル樹脂成形材料を得、該成形材料を
金型温度１５０°Ｃ１成形圧力２５０ ｋｇ／ｄで加熱
加圧成形して不飽和ポリエステル樹脂成形品を得た。Examples 1 and 2 and Comparative Examples Based on the formulation table in Table 1, each material was kneaded in a niegu to obtain an unsaturated polyester resin molding material, and the molding material was heated at a mold temperature of 150° C. and a molding pressure of 250 kg/d. A molded article of unsaturated polyester resin was obtained by heat and pressure molding.
以下余白
第
表
部
実施例１及び２と比較例の不飽和ポリエステル樹脂成形
品の性能は第２表のようである。Table 2 shows the performance of the unsaturated polyester resin molded products of Examples 1 and 2 and Comparative Example.
第 表 注水 ９０°Ｃ１ 時間処理後の減量％である。No. table water injection 90°C1 % weight loss after time treatment.
本発明は上述した如く構成されている。特許請求の範囲
に記載した構成を有する不飽和ポリエステル樹脂成形材
料においては、光沢、透明性に優れた成形品が得られる
効果を有している。The present invention is constructed as described above. The unsaturated polyester resin molding material having the structure described in the claims has the effect of providing molded products with excellent gloss and transparency.
Claims (1)
オールリン酸エステル塩とを含有したことを特徴とする
不飽和ポリエステル樹脂成形材料。(1) An unsaturated polyester resin molding material containing an alkylphenyl phosphite and an alkane polyol phosphate ester salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15607490A JPH0446957A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15607490A JPH0446957A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0446957A true JPH0446957A (en) | 1992-02-17 |
Family
ID=15619738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15607490A Pending JPH0446957A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0446957A (en) |
-
1990
- 1990-06-14 JP JP15607490A patent/JPH0446957A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69126740T2 (en) | Unsaturated polyester resin compositions and new anti-shrink agent | |
| EP0211657B1 (en) | Curable composition, method for manufacture thereof and articles made therefrom | |
| JPH0386714A (en) | Massively moldable polyester compound material which can be colored | |
| US5691409A (en) | Phenolic resin molding material | |
| US2990388A (en) | Allylic resin composition and process | |
| JPH0446957A (en) | Unsaturated polyester resin molding material | |
| JPH0446958A (en) | Unsaturated polyester resin molding material | |
| JPH0513899B2 (en) | ||
| JPH0352953A (en) | Polyamide resin composition | |
| KR910008607B1 (en) | Curable composition | |
| JPH02185560A (en) | Unsaturated polyester resin molding material | |
| JPS5993716A (en) | Thermosetting molding resin composition | |
| KR0145105B1 (en) | Manufacturing method of artificial marble sheet material having thermoforming using polyester waste fiber | |
| JPH0618984B2 (en) | Amino resin molding materials and amino resin moldings | |
| JPH0468062A (en) | Unsaturated polyester resin molding material | |
| KR970010298B1 (en) | Composition of artificial stone | |
| JPH0762214A (en) | Unsaturated polyester resin composition | |
| JPS63227660A (en) | Unsaturated polyester resin molding material | |
| JPH0468061A (en) | Manufacture of unsaturated polyester resin molding material | |
| JPH0446959A (en) | Unsaturated polyester resin molding material | |
| JPS63227653A (en) | Amino resin molding material | |
| JPS63145355A (en) | Amino resin molding material | |
| JPH0798894B2 (en) | Amino resin molding material | |
| JPH0269555A (en) | Unsaturated polyester resin molding material | |
| JPH054204B2 (en) |