JPH0450252B2 - - Google Patents

Info

Publication number: JPH0450252B2
Authority: JP; Japan
Prior art keywords: ferrous sulfate; acid; methyl alcohol; monohydrate; heptahydrate
Prior art date: 1985-03-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP5025585A

Other languages

English (en)

Japanese (ja)

Other versions

JPS61209920A (ja

Inventor

Shinobu Yamanaka

Keisuke Kato

Chiaki Oohama

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

MINATO SANGYO

Original Assignee

MINATO SANGYO

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-03-15

Filing date

1985-03-15

Publication date

1992-08-13

1985-03-15 Application filed by MINATO SANGYO filed Critical MINATO SANGYO

1985-03-15 Priority to JP5025585A priority Critical patent/JPS61209920A/ja

1986-09-18 Publication of JPS61209920A publication Critical patent/JPS61209920A/ja

1992-08-13 Publication of JPH0450252B2 publication Critical patent/JPH0450252B2/ja

Status Granted legal-status Critical Current

Links

OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 45
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 23
235000003891 ferrous sulphate Nutrition 0.000 claims description 14
239000011790 ferrous sulphate Substances 0.000 claims description 14
229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 14
229960005070 ascorbic acid Drugs 0.000 claims description 11
235000010323 ascorbic acid Nutrition 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 6
239000011668 ascorbic acid Substances 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
150000004682 monohydrates Chemical class 0.000 claims description 4
KFJBRJOPXNCARV-UHFFFAOYSA-L iron(2+);sulfate;dihydrate Chemical compound O.O.[Fe+2].[O-]S([O-])(=O)=O KFJBRJOPXNCARV-UHFFFAOYSA-L 0.000 claims description 2
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 22
XBDUTCVQJHJTQZ-UHFFFAOYSA-L iron(2+) sulfate monohydrate Chemical compound O.[Fe+2].[O-]S([O-])(=O)=O XBDUTCVQJHJTQZ-UHFFFAOYSA-L 0.000 description 16
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
239000002244 precipitate Substances 0.000 description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
238000002425 crystallisation Methods 0.000 description 6
230000008025 crystallization Effects 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000002211 L-ascorbic acid Substances 0.000 description 5
235000000069 L-ascorbic acid Nutrition 0.000 description 5
238000000034 method Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
239000013078 crystal Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000012452 mother liquor Substances 0.000 description 4
238000000926 separation method Methods 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
-1 heptahydrate salt Chemical class 0.000 description 3
150000004688 heptahydrates Chemical class 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000000843 powder Substances 0.000 description 3
239000002994 raw material Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
150000004677 hydrates Chemical class 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000000967 suction filtration Methods 0.000 description 2
150000004685 tetrahydrates Chemical class 0.000 description 2
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
ODBLHEXUDAPZAU-ZAFYKAAXSA-N D-threo-isocitric acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-ZAFYKAAXSA-N 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 description 1
150000000996 L-ascorbic acids Chemical class 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000004737 colorimetric analysis Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001877 deodorizing effect Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000003814 drug Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
235000010350 erythorbic acid Nutrition 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000010800 human waste Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229940026239 isoascorbic acid Drugs 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
239000010985 leather Substances 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1

Landscapes

Inorganic Compounds Of Heavy Metals (AREA)

JP5025585A 1985-03-15 1985-03-15 硫酸第一鉄一水塩の製造方法 Granted JPS61209920A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP5025585A JPS61209920A (ja)	1985-03-15	1985-03-15	硫酸第一鉄一水塩の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP5025585A JPS61209920A (ja)	1985-03-15	1985-03-15	硫酸第一鉄一水塩の製造方法

Publications (2)

Publication Number	Publication Date
JPS61209920A JPS61209920A (ja)	1986-09-18
JPH0450252B2 true JPH0450252B2 (es)	1992-08-13

Family

ID=12853868

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP5025585A Granted JPS61209920A (ja)	1985-03-15	1985-03-15	硫酸第一鉄一水塩の製造方法

Country Status (1)

Country	Link
JP (1)	JPS61209920A (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN116002769A (zh) *	2022-12-20	2023-04-25	福建中合医药股份有限公司	一种医药级一水硫酸亚铁的制作方法

1985
- 1985-03-15 JP JP5025585A patent/JPS61209920A/ja active Granted

Also Published As

Publication number	Publication date
JPS61209920A (ja)	1986-09-18

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