JPH0456801B2 - - Google Patents
Info
- Publication number
- JPH0456801B2 JPH0456801B2 JP27077584A JP27077584A JPH0456801B2 JP H0456801 B2 JPH0456801 B2 JP H0456801B2 JP 27077584 A JP27077584 A JP 27077584A JP 27077584 A JP27077584 A JP 27077584A JP H0456801 B2 JPH0456801 B2 JP H0456801B2
- Authority
- JP
- Japan
- Prior art keywords
- hydroxypropyl
- cellulose
- hydroxyethyl
- alcohol
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RFRMMZAKBNXNHE-UHFFFAOYSA-N 6-[4,6-dihydroxy-5-(2-hydroxyethoxy)-2-(hydroxymethyl)oxan-3-yl]oxy-2-(hydroxymethyl)-5-(2-hydroxypropoxy)oxane-3,4-diol Chemical compound CC(O)COC1C(O)C(O)C(CO)OC1OC1C(O)C(OCCO)C(O)OC1CO RFRMMZAKBNXNHE-UHFFFAOYSA-N 0.000 claims description 12
- 239000002537 cosmetic Substances 0.000 claims description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- -1 and among them Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 235000019441 ethanol Nutrition 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000008213 purified water Substances 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 239000003755 preservative agent Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000002335 preservative effect Effects 0.000 description 7
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 6
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 229940055577 oleyl alcohol Drugs 0.000 description 4
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 2
- 229940057838 polyethylene glycol 4000 Drugs 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はヒドロキシプロピルヒドロキシエチル
セルロースを含有することを特徴とする化粧料に
関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a cosmetic containing hydroxypropyl hydroxyethylcellulose.
（従来の技術）
化粧料には従来種々のものがあり、化粧水のよ
うな可溶化系、クリーム・乳液のような乳化系、
更にはフアウンデーシヨンのような油−水−粉末
の分散系まで多岐に及んでいる。(Prior art) There are various types of cosmetics in the past, including solubilized products such as lotions, emulsified products such as creams and emulsions, and
Furthermore, they range from oil-water-powder dispersion systems such as Foundation.
これらの化粧料において、水溶性高分子がコロ
イド安定化機能、使用感の調整作用、保湿作用の
役割のため使用されている。セルロース系のもの
としてカルボキシメチルセルロース、ヒドロキシ
エチルセルロース、ヒドロキシプロピルセルロー
ス、ヒドロキシプロピルメチルセルロース、メチ
ルセルロースが主として使用されており、中でも
ヒドロキシエチルセルロースが増粘剤、緩和な乳
化剤、保護コロイド剤、フイルム形成剤としてよ
く使用されている。 In these cosmetics, water-soluble polymers are used for their colloid stabilizing function, feel-adjusting effect, and moisturizing effect. Carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, and methyl cellulose are mainly used as cellulose-based materials, and among them, hydroxyethyl cellulose is often used as a thickener, mild emulsifier, protective colloid agent, and film-forming agent. ing.
（発明が解決しようとする問題点）
しかしながら、これまで使用されているヒドロ
キシエチルセルロースは、水には溶解するががエ
タノール等のアルコールを加えると沈澱しやすい
性質があり、長期の保存中に沈澱を生じやすい欠
点を有している。またその水溶液の表面張力はあ
まり低くない上、保護コロイド性が低いのが欠点
であつた。(Problem to be solved by the invention) However, the hydroxyethyl cellulose that has been used so far has the property of being soluble in water but prone to precipitate when alcohol such as ethanol is added, and does not precipitate during long-term storage. It has disadvantages that are easy to occur. Moreover, the surface tension of the aqueous solution is not very low, and its protective colloidal properties are low.
本発明の目的はこれらの欠点のない、化粧料の
増粘剤、分散剤、乳化安定剤として優れたセルロ
ース系糊料を提示することにある。 The object of the present invention is to provide a cellulose-based thickening agent that does not have these drawbacks and is excellent as a thickener, dispersant, and emulsion stabilizer for cosmetics.
（問題点を解決するための手段）
発明者は鋭意検討の結果、ヒドロキシプロピル
ヒドロキシエチルセルロースを化粧料に使用すれ
ば、ヒドロキシエチルセルロースの欠点を改良で
きることを発見し、本発明を完成させるに至つ
た。すなわち、アルコール−水系などにおける溶
解性、保存安定性が改良されるだけでなく、乳化
や懸濁分散系に使用した場合、非常になめらかな
製品を得ることができ流動性が改良できた。(Means for Solving the Problems) As a result of intensive studies, the inventors discovered that the disadvantages of hydroxyethylcellulose can be improved by using hydroxypropyl hydroxyethylcellulose in cosmetics, leading to the completion of the present invention. That is, not only the solubility and storage stability in alcohol-water systems were improved, but also when used in emulsification or suspension dispersion systems, very smooth products could be obtained and fluidity could be improved.
本発明の化粧料に使用するヒドロキシプロピル
ヒドロキシエチルセルロースは、イソプロピルア
ルコール、ｔ−ブタノールなどの炭素数３〜４の
アルコール中で、アルカリセルロースにエチレン
オキサイドとプロピレンオキサイドを同時に、あ
るいはそれぞれ別々に反応させることによつて得
られるものである。 The hydroxypropyl hydroxyethyl cellulose used in the cosmetics of the present invention can be obtained by reacting alkali cellulose with ethylene oxide and propylene oxide simultaneously or separately in an alcohol having 3 to 4 carbon atoms such as isopropyl alcohol or t-butanol. This is obtained by
本発明に用いるヒドロキシプロピルヒドロキシ
エチルセルロースは、エチレンオキサイドの平均
置換モル数（MS）が1.5〜5.0であり、プロピレ
ンオキサイドの平均置換モル数が0.05〜2.0のも
のが好ましい。 The hydroxypropyl hydroxyethylcellulose used in the present invention preferably has an average number of moles of ethylene oxide substituted (MS) of 1.5 to 5.0, and preferably has an average number of moles of propylene oxide substituted of 0.05 to 2.0.
本発明によれば各種の化粧品類が改良される
が、化粧品中に使用されるヒドロキシプロピルヒ
ドロキシエチルセルロースの含有量については、
通常0.01〜５％程度で対象とする化粧品の種類に
よりそれぞれ決められるものである。 According to the present invention, various cosmetics are improved, but regarding the content of hydroxypropyl hydroxyethylcellulose used in cosmetics,
It is usually about 0.01 to 5% and is determined depending on the type of cosmetic product.
（実施例）
以下に本発明を実施例をあげて説明する。実施
例中の％は重量基準を示す。(Example) The present invention will be described below with reference to Examples. The percentages in the examples are based on weight.
実施例 １
（化粧水） 組成（％）
ポリエチレングリコール1500 5.0
ポリエチレングリコール4000 5.0
ヒドロキシプロピルヒドロキシエチルセルロー
ス（ヒドロキシエチルMS2.1ヒドロキシプロピ
ルMS0.57） 0.1
ポリオキシエチレン（15モル）オレイルアルコ
ールエーテル 1.0
トリエタノールアミン 2.0
エチルアルコール 20.0
精製水 66.7
香 料 0.2
防腐剤 適 量
精製水にポリエチレングリコール1500、ポリエ
チレングリコール4000、ヒドロキシプロピルヒド
ロキシエチルセルロース、トリエタノールアミン
を加えて室温にて溶解し水部とする。エチルアル
コールに防腐剤、ポリオキシエチレンオレイルア
ルコールエーテル、香料を加えた室温にて溶解し
アルコール部とする。水部にアルコール部を加え
混合して可溶化を行ない、過することにより非
常に保存安定性の良い化粧水が得られた。Example 1 (lotion) Composition (%) Polyethylene glycol 1500 5.0 Polyethylene glycol 4000 5.0 Hydroxypropyl hydroxyethyl cellulose (Hydroxyethyl MS2.1 Hydroxypropyl MS0.57) 0.1 Polyoxyethylene (15 mol) Oleyl alcohol ether 1.0 Triethanolamine 2.0 Ethyl alcohol 20.0 Purified water 66.7 Fragrance 0.2 Preservative Appropriate amount Add polyethylene glycol 1500, polyethylene glycol 4000, hydroxypropyl hydroxyethyl cellulose, and triethanolamine to purified water and dissolve at room temperature to make the water part. Add a preservative, polyoxyethylene oleyl alcohol ether, and fragrance to ethyl alcohol and dissolve at room temperature to obtain the alcohol part. The alcohol part was added to the water part and mixed to solubilize it, and by filtering it, a lotion with very good storage stability was obtained.
実施例 ２
（Ｏ／Ｗ型乳液） 組成（％）
ステアリン酸 1.5
セチルアルコール 0.5
ミツロウ 2.0
ポリオキシエチレンモノオレイン酸エステル
1.0
グリセリンモノステアリン酸エステル 1.0
ヒドロキシプロピルヒドロキシエチルセルロー
ス水溶液（３％）（ヒドロキシエチルMS2.6ヒ
ドロキシプロピルMS0.21） 33.3
プロピレングリコール 5.0
エチルアルコール 10.0
精製水 42.2
香 料 0.5
染 料 適 量
防腐剤、紫外線吸収剤 〃
精製水にプロピレングリコール、染料を加熱溶
解して70℃に保ち水相をつくる。エチルアルコー
ルに香料、紫外線吸収剤を加えて溶解しアルコー
ル相をつくる。ヒドロキシプロピルヒドロキシエ
チルセルロース水溶液を除く他の成分を混合し、
加熱溶解して70℃に保ち油相をつくる。前記の水
相に前記の油相を加え、予備乳化を行い、ホモミ
キサーで均一に乳化する。これをかきまぜなが
ら、前記のアルコール相とヒドロキシプロピルヒ
ドロキシエチルセルロース水溶液を加え、かきま
ぜながら30℃まで冷却する。放置安定性が良くつ
やの良い乳液が得られた。Example 2 (O/W type emulsion) Composition (%) Stearic acid 1.5 Cetyl alcohol 0.5 Beeswax 2.0 Polyoxyethylene monooleate ester
1.0 Glycerin monostearate 1.0 Hydroxypropyl hydroxyethyl cellulose aqueous solution (3%) (Hydroxyethyl MS2.6 Hydroxypropyl MS0.21) 33.3 Propylene glycol 5.0 Ethyl alcohol 10.0 Purified water 42.2 Fragrance 0.5 Dye Appropriate amount Preservative, UV absorption Agent 〃 Heat and dissolve propylene glycol and dye in purified water and keep at 70℃ to create an aqueous phase. Add fragrance and ultraviolet absorber to ethyl alcohol and dissolve to create an alcohol phase. Mix other ingredients except hydroxypropyl hydroxyethyl cellulose aqueous solution,
Melt by heating and keep at 70℃ to create an oil phase. The above oil phase is added to the above water phase, pre-emulsified, and uniformly emulsified using a homomixer. While stirring, add the alcohol phase and the hydroxypropyl hydroxyethyl cellulose aqueous solution, and cool to 30°C while stirring. A glossy emulsion with good storage stability was obtained.
実施例 ３
（パツク） 組成（％）
ヒドロキシエチルヒドロキシプロピルセルロー
ス（ヒドロキシエチルMS1.8ヒドロキシプロピ
ルMS1.3） 3.0
カルボキシビニルポリマー 1.0
ポリオキシエチレン（15モル）オレイルアルコ
ールエーテル 1.0
トリエタノールアミン 1.0
エチルアルコール 5.0
精製水 89.0
香 料 適 量
防腐剤 〃
精製水にヒドロキシエチルヒドロキシプロピル
セルロース、カルボキシビニルポリマーを溶解
し、ポリオキシエチレン（15モル）オレイルアル
コールエーテル、香料、防腐剤を溶解したエチル
アルコールを加え、そのあとトリエタノールアミ
ンを加え増粘させる。放置安定性の良いふきとり
型パツクが得られた。Example 3 (Pack) Composition (%) Hydroxyethyl hydroxypropyl cellulose (Hydroxyethyl MS1.8 Hydroxypropyl MS1.3) 3.0 Carboxyvinyl polymer 1.0 Polyoxyethylene (15 mol) Oleyl alcohol ether 1.0 Triethanolamine 1.0 Ethyl alcohol 5.0 Purified water 89.0 Fragrance Appropriate amount Preservative Dissolve hydroxyethyl hydroxypropyl cellulose and carboxyvinyl polymer in purified water, add polyoxyethylene (15 moles) oleyl alcohol ether, fragrance, and ethyl alcohol dissolved in preservative, and dissolve. Then add triethanolamine to thicken it. A wipe-off type pack with good storage stability was obtained.
実施例 ４
（シヤンプー） 組成（％）
ラウリルポリオキシエチレン（３モル）硫酸エ
ステル トリエタノールアミン塩（40％水溶
液）ラウリルポリオキシエチレン（３モル）硫
酸エステル 32.0
ソーダ塩（30％水溶液） 21.0
ラウロイルジエタノールアミド 4.0
ポリエチレングリコール400 1.0
ヒドロキシエチルヒドロキシプロピルセルロー
ス（ヒドロキシエチルMS2.1ヒドロキシプロピ
ルMS0.6） 1.0
精製水 41.0
香 料 適 量
染 料 〃
防腐剤、紫外線吸収剤、金属イオン封鎖剤
〃
精製水を70℃に加熱し、他の成分を加え均一に
溶解したのち冷却する。均一透明なシヤンプーが
得られた。Example 4 (Shampoo) Composition (%) Lauryl polyoxyethylene (3 moles) sulfate ester Triethanolamine salt (40% aqueous solution) Lauryl polyoxyethylene (3 moles) sulfate ester 32.0 Soda salt (30% aqueous solution) 21.0 Lauroyl diethanolamine 4.0 Polyethylene glycol 400 1.0 Hydroxyethyl hydroxypropyl cellulose (Hydroxyethyl MS2.1 Hydroxypropyl MS0.6) 1.0 Purified water 41.0 Fragrance Appropriate amount Dye Preservatives, UV absorbers, sequestering agents
〃 Heat purified water to 70℃, add other ingredients, dissolve uniformly, and then cool. A uniform and transparent shampoo was obtained.
実施例 ５
（セツトローシヨン） 組成（％）
ヒドロキシエチルヒドロキシプロピルセルロー
ス（ヒドロキシエチルMS3.7ヒドロキシプロピ
ルMS1.3 2.0
プロピレングリコール 2.0
ポリオキシエチレン（20モル）ステアリルアル
コールエーテル 1.5
エチルアルコール 10.0
精製水 84.5
香 料 適 量
染 料 〃
防腐剤、紫外線吸収剤 〃
エチルアルコールにプロピレングリコール、ポ
リオキシエチレンステアリルアルコールエーテル
香料、防腐剤、紫外線吸収剤を加え溶解する。こ
れにヒドロキシエチル、ヒドロキシプロピルセル
ロースを加え混潤させ、かきまぜながら精製水を
徐々に加え染料で着色する。Example 5 (Settling) Composition (%) Hydroxyethyl hydroxypropyl cellulose (Hydroxyethyl MS3.7 Hydroxypropyl MS1.3 2.0 Propylene glycol 2.0 Polyoxyethylene (20 mol) Stearyl alcohol ether 1.5 Ethyl alcohol 10.0 Purified water 84.5 Fragrance Appropriate amount Dye Preservative, UV absorber Add propylene glycol, polyoxyethylene stearyl alcohol ether fragrance, preservative, and UV absorber to ethyl alcohol and dissolve. Add hydroxyethyl and hydroxypropyl cellulose and mix. While stirring, gradually add purified water and color with dye.
安定性良好でセツトしやすいセツトローシヨン
が得られた。 A settling lotion with good stability and easy setting was obtained.
Claims (1)
ースを含有することを特徴とする化粧料。 ２ ヒドロキシプロピルヒドロキシエチルセルロ
ースがグルコース単位当りのエチレンオキサイド
平均置換モル数が1.5〜5.0であり、プロピレンオ
キサイド平均置換モル数が0.05〜2.0である特許
請求の範囲第１項記載の化粧料。[Scope of Claims] 1. A cosmetic characterized by containing hydroxypropyl hydroxyethyl cellulose. 2. The cosmetic according to claim 1, wherein the hydroxypropyl hydroxyethyl cellulose has an average number of moles of ethylene oxide substituted per glucose unit of 1.5 to 5.0, and an average number of moles of propylene oxide substituted per glucose unit of 0.05 to 2.0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27077584A JPS61151105A (en) | 1984-12-24 | 1984-12-24 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27077584A JPS61151105A (en) | 1984-12-24 | 1984-12-24 | Cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61151105A JPS61151105A (en) | 1986-07-09 |
| JPH0456801B2 true JPH0456801B2 (en) | 1992-09-09 |
Family
ID=17490821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27077584A Granted JPS61151105A (en) | 1984-12-24 | 1984-12-24 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61151105A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5106609A (en) * | 1990-05-01 | 1992-04-21 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5100658A (en) * | 1989-08-07 | 1992-03-31 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5104646A (en) * | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| US5100657A (en) * | 1990-05-01 | 1992-03-31 | The Procter & Gamble Company | Clean conditioning compositions for hair |
| AU1664992A (en) * | 1991-03-19 | 1992-10-21 | Procter & Gamble Company, The | Cosmetic compositions containing hydrophobically modified nonionic polymer and unsaturated quaternary ammonium surfactant |
| US5807543A (en) * | 1993-08-27 | 1998-09-15 | The Procter & Gamble Co. | Cosmetic compositions containing hydrophobically modified nonionic polymer and unsaturated quaternary ammonium surfactant |
| WO1996031192A1 (en) * | 1995-04-07 | 1996-10-10 | Kuyus-Stiftung | Cosmetic composition for treating cellulite |
-
1984
- 1984-12-24 JP JP27077584A patent/JPS61151105A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61151105A (en) | 1986-07-09 |
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