JPH0457971A - Washing-resistant non-slip treatment of fabric - Google Patents

Washing-resistant non-slip treatment of fabric

Info

Publication number
JPH0457971A
JPH0457971A JP16760190A JP16760190A JPH0457971A JP H0457971 A JPH0457971 A JP H0457971A JP 16760190 A JP16760190 A JP 16760190A JP 16760190 A JP16760190 A JP 16760190A JP H0457971 A JPH0457971 A JP H0457971A
Authority
JP
Japan
Prior art keywords
agent
fabric
washing
slip
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16760190A
Other languages
Japanese (ja)
Inventor
Toyoo Kobayashi
小林 豊夫
Shoji Tsuji
辻 照二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP16760190A priority Critical patent/JPH0457971A/en
Publication of JPH0457971A publication Critical patent/JPH0457971A/en
Pending legal-status Critical Current

Links

Landscapes

  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

PURPOSE:To carry out the subject washing-resistant non-slip treatment by scatteringly applying a sizing agent composition composed of an acrylic resin containing a heat-expanding agent in combination with a crosslinking agent and a water repelling agent to one side of a fabric and drying the treated fabric. CONSTITUTION:To one side of a woven fabric composed of a natural fiber, a synthetic fiber, etc., a sizing agent composition composed of an acrylic polymer resin blended with a heat-expanding agent in combination with a crosslinking agent, e.g. a water soluble heat-reactive urethane in which isocyanate groups are blocked and a water repelling agent, preferably a fluoro- based water repelling agent is made to adhere scatteringly using the roller printing method, etc. The above-treated woven fabric is subsequently dried, thus enabling the objective non-slip treatment excellent in washing resistance and free from falling off of the non-slip agent due to washing.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、布帛の耐洗濯性滑り止め加工方法に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to a washing-resistant and anti-slip processing method for fabric.

(従来の技術) カーペット等が定位置からずれて乱雑になるのを防止す
る滑り止め加工は、例えば実公昭58−51072号公
報に提案されているように、カーペットの裏面に塩化ビ
ニルペーストレジンを塗工し、エンボスして凹凸を形成
する方法、あるいは実開昭81−23884号公報に提
案されているように、カーペットの二次基布に発泡剤を
配合した塩化ビニルペーストレジン組成物を付与し、加
熱発泡させて凹凸を形成させる方法等が知られている。
(Prior art) Anti-slip processing to prevent carpets from shifting from their regular positions and becoming untidy is proposed in Japanese Utility Model Publication No. 58-51072, for example, by applying vinyl chloride paste resin to the back side of carpets. A method of coating and embossing to form irregularities, or applying a vinyl chloride paste resin composition containing a foaming agent to the secondary base fabric of the carpet, as proposed in Japanese Utility Model Application Publication No. 81-23884. However, a method of forming irregularities by heating and foaming is known.

(発明が解決しようとする課題) ところが、これ等従来の滑り止め加工方法はカーペット
を対象に検討されてきたため耐洗濯性はなく、数回の洗
濯で処理薬剤が脱落するという欠点を有する。本発明は
上述の問題点に鑑みてなされたものであって、簡単な処
方で耐洗濯性のある滑り止め加工を行ない得る方法の提
供を目的とするものである。
(Problems to be Solved by the Invention) However, since these conventional anti-slip processing methods have been studied for carpets, they are not wash resistant and have the disadvantage that the treatment chemicals fall off after several washes. The present invention has been made in view of the above-mentioned problems, and an object of the present invention is to provide a method that can provide a wash-resistant anti-slip finish with a simple formulation.

(課題を解決するための手段) 上述の目的は、加熱発泡剤を配合したアクリル系樹脂、
架橋剤及び撥水剤を含む糊組成物を布帛の一側に散点状
Eこ付着せしめ、次いで乾燥することを特徴とする布帛
の耐洗濯性滑り止め加工方法により達成される。
(Means for solving the problem) The above purpose is to produce an acrylic resin containing a heat foaming agent,
This is achieved by a method for making a fabric wash-resistant and non-slip, which is characterized by applying a glue composition containing a crosslinking agent and a water repellent to one side of the fabric in a dotted manner, and then drying it.

以下本発明の詳細な説明する。The present invention will be explained in detail below.

本発明で云う布帛とは、織物、li物、不織布などが挙
げられ、その構成繊維としては、綿、麻、羊毛、絹等の
天然!I#、ナイロン、ポリエステル、アクリル等の合
成繊維、またそれらの混用であってもよい。
The fabric referred to in the present invention includes woven fabrics, li materials, non-woven fabrics, etc., and its constituent fibers include natural fibers such as cotton, linen, wool, and silk. Synthetic fibers such as I#, nylon, polyester, acrylic, or a mixture thereof may be used.

本発明に使用する糊組成物は、加熱発泡剤を配合したア
クリル系樹脂、架橋剤及び撥水剤からなる。
The glue composition used in the present invention consists of an acrylic resin blended with a heat-foaming agent, a crosslinking agent, and a water repellent.

本発明で云うアクリル系樹脂とは、1個以上のビニル基
を含有するモノマーを単独又は2者以上乳化重合して得
られるアクリル又はメタクリル化合物、例えばアクリル
酸、メタクリル酸、メチルアクリレート、メチルメタア
クリレート、エチルアクリレート、エチルメタクリレー
ト、ブチルアクリレート、ブチルメタクリレート、アク
リロニトリル、アクリルアミド、メチロールアクリルア
ミド、2−ヒドロキシエチルアクリレート、クーヒドロ
キシブチルアクリレート等の乳化重合物のエマルジョン
が挙げられ、その使用量は糖組成物中固型分換算で20
〜50重量%が好ましい。
The acrylic resin referred to in the present invention is an acrylic or methacrylic compound obtained by emulsion polymerization of one or more monomers containing one or more vinyl groups, such as acrylic acid, methacrylic acid, methyl acrylate, and methyl methacrylate. , ethyl acrylate, ethyl methacrylate, butyl acrylate, butyl methacrylate, acrylonitrile, acrylamide, methylol acrylamide, 2-hydroxyethyl acrylate, and co-hydroxybutyl acrylate. 20 in terms of type
~50% by weight is preferred.

本発明で云う発泡剤とは、上記アクリル系樹脂中にアゾ
ジカルボンアミドのような有機発泡剤や重炭酸ソーダの
ような無機発泡剤や低沸点炭化水素を内包する熱膨張性
のマイクロカプセルを混合したもの等が挙げられ、その
使用量は糖組成物中固型分換算で3〜15重量%が好ま
しい。
The blowing agent referred to in the present invention is a mixture of the above-mentioned acrylic resin with an organic blowing agent such as azodicarbonamide, an inorganic blowing agent such as sodium bicarbonate, or thermally expandable microcapsules containing a low-boiling hydrocarbon. The amount used is preferably 3 to 15% by weight in terms of solid content in the sugar composition.

本発明で云う架橋剤としては、イソシアネート基をブロ
ックした水溶性熱反応型ウレタン、市販商品名として第
一工業製薬(株)のエラストロンMF−9、エラストロ
ンW−11及びバイ二ノに株)のシンターブレットBA
P等や、アルキレングリコールジクリシジルエーテル及
びポリアルキレンゲリコールジクリシジルエーテル等の
水溶性ジクリシジルエーテル訊導体、市販商品名として
は共栄社油脂化学工業(株)のエポライト200E、エ
ポライト400E、エポライト400Pや、アミノブラ
スト樹脂例えばトリメチロールメラミン、ヘキサメチロ
ールメラミンなどのメラミン系樹脂、ジメチロールジヒ
ドロキシ尿素、ジメチロールエチレン尿素、ジメチロー
ルジメトキシエチレン尿素、ジメチロールブチレン尿素
、ジメチロールプロピレン尿素、ジメチロール5ヒドロ
キシプロピレン尿素などの尿素系樹脂、ジメチロールウ
ロンなどのウロン系樹脂などが挙げられる。かかる架橋
剤の使用量は糖組成物中固型分換算で0.6〜6重量%
が好ましい。
The crosslinking agent referred to in the present invention includes water-soluble heat-reactive urethane with blocked isocyanate groups, and commercially available product names such as Elastron MF-9, Elastron W-11 manufactured by Daiichi Kogyo Seiyaku Co., Ltd., and Sinter manufactured by Bainino Ni Co., Ltd. Bullet BA
P, etc., water-soluble dicrycidyl ether conductors such as alkylene glycol dicrycidyl ether and polyalkylene gelylcol dicrycidyl ether, commercially available product names include Epolite 200E, Epolite 400E, Epolite 400P of Kyoeisha Yushi Kagaku Kogyo Co., Ltd. Amino blast resins such as melamine resins such as trimethylol melamine and hexamethylol melamine, dimethylol dihydroxy urea, dimethylol ethylene urea, dimethylol dimethoxy ethylene urea, dimethylol butylene urea, dimethylol propylene urea, dimethylol 5 hydroxypropylene urea, etc. Examples include urea-based resins and uron-based resins such as dimethyloluron. The amount of such crosslinking agent used is 0.6 to 6% by weight in terms of solid content in the sugar composition.
is preferred.

本発明において用いる撥水剤は特に限定されず、フッ素
系撥水剤、シリコン系撥水剤、ジルコニウム系撥水剤が
いずれも使用できるが、耐久性の点からフッ素系撥水剤
を用いるのが好ましい。かかる撥水剤の使用量は糖組成
物中固型分換算で0.3〜5重量%が好ましい。
The water repellent used in the present invention is not particularly limited, and any of fluorine-based water repellents, silicone-based water repellents, and zirconium-based water repellents can be used; however, from the viewpoint of durability, it is preferable to use fluorine-based water repellents. is preferred. The amount of such water repellent used is preferably 0.3 to 5% by weight in terms of solid content in the sugar composition.

かかる糊組成物を布帛の一側に散点状に付着する方法は
、ローラ捺染法、スクリーン捺染法、ロータリースクリ
ーン捺染法等により実施することが出来る。そして、布
帛の片面に付着せしめ130℃〜160℃で60〜70
秒乾燥を行なう。印捺量は印捺方法、糊組成、布帛の種
類により異なるが、糊組成物の固型分が布帛の重量に対
して50〜100重量%付与されることが好ましい。尚
、乾燥後の熱処理は加熱発泡剤が完全に発泡しクレータ
状になり見映が悪くなるので好ましくない。
The method of applying such a paste composition in the form of dots on one side of the fabric can be carried out by a roller printing method, a screen printing method, a rotary screen printing method, or the like. Then, it was attached to one side of the fabric and heated to 60-70℃ at 130℃-160℃.
Dry for seconds. Although the amount of printing varies depending on the printing method, glue composition, and type of fabric, it is preferable that the solid content of the glue composition is 50 to 100% by weight based on the weight of the fabric. Note that heat treatment after drying is not preferable because the heated foaming agent completely foams and forms a crater shape, resulting in poor appearance.

(作用) 本発明は、発泡剤を配曾したアクリル系樹脂を使用し、
且つ散点状に付着せしめているので摩擦力が増大し滑り
止め効果を発揮するようになる。
(Function) The present invention uses an acrylic resin containing a blowing agent,
Moreover, since it is attached in a scattered manner, the frictional force increases and the anti-slip effect is exhibited.

また、アクリル系樹脂、架橋剤及び撥水剤の組合わせで
繊維に強固に固着するようになり耐洗濯性を有するよう
になる。
In addition, the combination of acrylic resin, crosslinking agent, and water repellent allows it to firmly adhere to fibers and has washing resistance.

(実施例) 以下、実施例により本発明を具体的に説明する。(Example) Hereinafter, the present invention will be specifically explained with reference to Examples.

実施例1 経糸に20番手単糸、緯糸に16番手単糸を用いた経糸
密度112本/インチ、緯糸密度38本/インチのタッ
サー織物を常法により毛焼、糊抜、精練、漂白、シルケ
ット、プリントを施した。
Example 1 A tussah fabric with a warp density of 112 yarns/inch and a weft yarn density of 38 yarns/inch using a No. 20 single yarn for the warp and a No. 16 single yarn for the weft was subjected to hair burning, desizing, scouring, bleaching, and mercerization by conventional methods. , printed.

次に、このプリント処理布の裏面に、加熱発泡剤を配合
したアクリル系樹脂としてEXPバインダーN8R−8
(日本フィシ(株)社製、固型分57.5電量%)73
重量部、アクリル系樹脂としてEXPバインダーCTR
−128(日本フィラ(株)社製、固型分50重量%)
22重量部、フッ素系撥水剤としてFGX−KM(三木
理研工業(株)製、固型分30重量%)3重量部、アミ
ノブラスト樹脂としてスミテックスレジンM−6(住人
化学(株)社製、固型分50重量%)2重量部からなる
糊組成物をロータリースクリーン捺染機を用いて散点状
に付着せしめ、150°CX60秒乾燥し、本発明実施
例1の製品を得た。
Next, EXP binder N8R-8 was applied as an acrylic resin containing a heat foaming agent to the back side of the printed fabric.
(manufactured by Nippon Fisi Co., Ltd., solid content 57.5% electric power) 73
Weight part, EXP binder CTR as acrylic resin
-128 (manufactured by Nippon Fila Co., Ltd., solid content 50% by weight)
22 parts by weight, 3 parts by weight of FGX-KM (manufactured by Miki Riken Kogyo Co., Ltd., solid content 30% by weight) as a fluorine-based water repellent, Sumitex Resin M-6 (manufactured by Sumima Kagaku Co., Ltd.) as an aminoblast resin. A glue composition consisting of 2 parts by weight of 50% by weight (solid content: 50% by weight) was applied in a dotted manner using a rotary screen printing machine, and dried at 150° C. for 60 seconds to obtain a product of Example 1 of the present invention.

比較例1 実施例1と同様のプリント処理布に、加熱発泡剤を配合
したアクリル系樹脂としてEXPバインダーN5R−8
(日本フィシ(株)社製)77重量部、アクリル系樹脂
としてEXPバインダー0TR−128(日本フィシ(
株)社製)23重量部からなる糊組成物をロータリース
クリーン捺染機を用いて散点状に付着せしめ、150°
CX60秒乾燥し比較例1の製品を得た。
Comparative Example 1 EXP binder N5R-8 was added to the same printed fabric as in Example 1 as an acrylic resin containing a heat foaming agent.
(manufactured by Nippon Fishi Co., Ltd.) 77 parts by weight, EXP binder 0TR-128 (Nippon Fisi Co., Ltd.) as an acrylic resin.
A glue composition consisting of 23 parts by weight (manufactured by Co., Ltd.) was applied in scattered dots using a rotary screen printing machine, and
CX was dried for 60 seconds to obtain a product of Comparative Example 1.

次tこ実施例1及び比較例1で得られた製品の滑り止め
性を測定した。その結果を第1表に示す。
Next, the anti-slip properties of the products obtained in Example 1 and Comparative Example 1 were measured. The results are shown in Table 1.

尚、滑り止め性は第1図に示すようにヨコ11cmxタ
テ14 amの試験片(1)をデコラ貼りテーブル(2
)に置き、その上に2009の荷重(3)をかけ、タテ
方向に重り(4)を増していき試験片(1)が動き出し
た時の重り(4)の重量を測定する事により評価した。
As shown in Figure 1, the anti-slip property was measured by using a test piece (1) measuring 11 cm wide x 14 am long on a table (2) pasted with Decora.
), applied a load (3) of 2009 on it, increased the weight (4) in the vertical direction, and measured the weight of the weight (4) when the test piece (1) started to move. .

また洗濯はJISL−0217105法に準じて50回
実施した。
Further, washing was carried out 50 times according to JISL-0217105 method.

第1表 第1表から明らかな様に本発明実施例により得られた製
品は洗濯50回後も滑り止め性を有していることがわか
る。
As is clear from Table 1, the products obtained according to the examples of the present invention have anti-slip properties even after being washed 50 times.

(発明の効果) 以上詳述したように、本発明によればテーブルクロスな
どの布帛の滑り止めが効果的に発揮され、また優れた布
帛への付着性によりこの滑り止めが洗濯により脱落する
ことも回避されインテリア用品等に頗る有用である。
(Effects of the Invention) As described in detail above, according to the present invention, the anti-slip properties of fabrics such as tablecloths are effectively exhibited, and the excellent adhesion to fabrics prevents the anti-slip properties from falling off when washed. It is also useful for interior goods and the like.

しかも特別な装置を必要とせず、安価に提供できるとい
う効果を奏する。
Moreover, it does not require any special equipment and can be provided at low cost.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は滑り止め注を評価するための試験装置を示す側
面図である。 符号の説明 (1)・・・試料片、    (2)・・・デコラ貼り
テーブル、(3)・・・荷重、     (4)・・・
重り。 第1図
FIG. 1 is a side view showing a testing device for evaluating anti-slip notes. Explanation of symbols (1)... Sample piece, (2)... Decora pasted table, (3)... Load, (4)...
weight. Figure 1

Claims (1)

【特許請求の範囲】[Claims] 1)加熱発泡剤を配合したアクリル系樹脂、架橋剤及び
撥水剤を含む糊組成物を布帛の一側に散点状に付着せし
め、次いで乾燥することを特徴とする布帛の耐洗濯性滑
り止め加工方法。
1) Washing resistance slippage of fabric characterized by applying a glue composition containing an acrylic resin containing a heat-foaming agent, a crosslinking agent, and a water repellent to one side of the fabric in a dotted manner and then drying it. Stopping method.
JP16760190A 1990-06-26 1990-06-26 Washing-resistant non-slip treatment of fabric Pending JPH0457971A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16760190A JPH0457971A (en) 1990-06-26 1990-06-26 Washing-resistant non-slip treatment of fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16760190A JPH0457971A (en) 1990-06-26 1990-06-26 Washing-resistant non-slip treatment of fabric

Publications (1)

Publication Number Publication Date
JPH0457971A true JPH0457971A (en) 1992-02-25

Family

ID=15852796

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16760190A Pending JPH0457971A (en) 1990-06-26 1990-06-26 Washing-resistant non-slip treatment of fabric

Country Status (1)

Country Link
JP (1) JPH0457971A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002013080A (en) * 2000-06-27 2002-01-18 Ks Senshoku Kk Nonslip fabric
US6723253B2 (en) * 2000-10-27 2004-04-20 The Procter & Gamble Company Domestic treatment of fabrics with film-forming materials and blowing agents
CN105780540A (en) * 2016-05-11 2016-07-20 游晟印染(深圳)有限公司 Textile foaming limited slip stamp and manufacturing process thereof
JP2018080428A (en) * 2016-11-18 2018-05-24 シードプランニング株式会社 Antislip processing method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002013080A (en) * 2000-06-27 2002-01-18 Ks Senshoku Kk Nonslip fabric
US6723253B2 (en) * 2000-10-27 2004-04-20 The Procter & Gamble Company Domestic treatment of fabrics with film-forming materials and blowing agents
CN105780540A (en) * 2016-05-11 2016-07-20 游晟印染(深圳)有限公司 Textile foaming limited slip stamp and manufacturing process thereof
JP2018080428A (en) * 2016-11-18 2018-05-24 シードプランニング株式会社 Antislip processing method

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