JPH0478645B2 - - Google Patents

Info

Publication number: JPH0478645B2
Authority: JP; Japan
Prior art keywords: weight; latex; resin; reaction; added
Prior art date: 1987-05-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP12907587A

Other languages

English (en)

Japanese (ja)

Other versions

JPS63291913A (ja

Inventor

Hideo Goto

Koichi Matsuda

Yasuyuki Hiromoto

Hiroshi Kawasaki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ube Cycon Ltd

Original Assignee

Ube Cycon Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-05-25

Filing date

1987-05-25

Publication date

1992-12-11

1987-05-25 Application filed by Ube Cycon Ltd filed Critical Ube Cycon Ltd

1987-05-25 Priority to JP12907587A priority Critical patent/JPS63291913A/ja

1988-11-29 Publication of JPS63291913A publication Critical patent/JPS63291913A/ja

1992-12-11 Publication of JPH0478645B2 publication Critical patent/JPH0478645B2/ja

Status Granted legal-status Critical Current

Links

239000000178 monomer Substances 0.000 claims description 57
238000006243 chemical reaction Methods 0.000 claims description 52
229920000126 latex Polymers 0.000 claims description 40
239000004816 latex Substances 0.000 claims description 37
239000000203 mixture Substances 0.000 claims description 37
229920001577 copolymer Polymers 0.000 claims description 36
238000006116 polymerization reaction Methods 0.000 claims description 29
229920002554 vinyl polymer Polymers 0.000 claims description 25
239000003995 emulsifying agent Substances 0.000 claims description 19
239000012190 activator Substances 0.000 claims description 18
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 18
-1 aromatic vinyl compound Chemical class 0.000 claims description 15
229920000578 graft copolymer Polymers 0.000 claims description 15
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 14
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 9
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 9
239000008121 dextrose Substances 0.000 claims description 9
239000011790 ferrous sulphate Substances 0.000 claims description 9
235000003891 ferrous sulphate Nutrition 0.000 claims description 9
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 9
229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 9
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 9
229940048086 sodium pyrophosphate Drugs 0.000 claims description 9
235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 9
239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 7
239000012986 chain transfer agent Substances 0.000 claims description 6
239000012966 redox initiator Substances 0.000 claims description 5
229920005989 resin Polymers 0.000 description 72
239000011347 resin Substances 0.000 description 72
239000011342 resin composition Substances 0.000 description 42
229920001971 elastomer Polymers 0.000 description 25
238000000034 method Methods 0.000 description 24
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 18
230000000704 physical effect Effects 0.000 description 16
229920005992 thermoplastic resin Polymers 0.000 description 10
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 5
238000007334 copolymerization reaction Methods 0.000 description 5
238000001746 injection moulding Methods 0.000 description 5
238000005259 measurement Methods 0.000 description 5
238000002156 mixing Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 4
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 4
150000001993 dienes Chemical class 0.000 description 4
238000010528 free radical solution polymerization reaction Methods 0.000 description 4
239000005977 Ethylene Substances 0.000 description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
239000008116 calcium stearate Substances 0.000 description 3
235000013539 calcium stearate Nutrition 0.000 description 3
230000007423 decrease Effects 0.000 description 3
238000007720 emulsion polymerization reaction Methods 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
239000002932 luster Substances 0.000 description 3
239000008188 pellet Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 2
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
238000004040 coloring Methods 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
230000006698 induction Effects 0.000 description 2
238000004898 kneading Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920002959 polymer blend Polymers 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000010557 suspension polymerization reaction Methods 0.000 description 2
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 1
INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000005452 bending Methods 0.000 description 1
239000004566 building material Substances 0.000 description 1
235000015115 caffè latte Nutrition 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 1
229920006258 high performance thermoplastic Polymers 0.000 description 1
239000003999 initiator Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000012778 molding material Substances 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000000088 plastic resin Substances 0.000 description 1
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1

Landscapes

Graft Or Block Polymers (AREA)
Polymerization Catalysts (AREA)

JP12907587A 1987-05-25 1987-05-25 グラフト共重合体の製造方法 Granted JPS63291913A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP12907587A JPS63291913A (ja)	1987-05-25	1987-05-25	グラフト共重合体の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP12907587A JPS63291913A (ja)	1987-05-25	1987-05-25	グラフト共重合体の製造方法

Publications (2)

Publication Number	Publication Date
JPS63291913A JPS63291913A (ja)	1988-11-29
JPH0478645B2 true JPH0478645B2 (fr)	1992-12-11

Family

ID=15000458

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP12907587A Granted JPS63291913A (ja)	1987-05-25	1987-05-25	グラフト共重合体の製造方法

Country Status (1)

Country	Link
JP (1)	JPS63291913A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3147392B2 (ja) *	1991-03-04	2001-03-19	宇部サイコン株式会社	熱可塑性樹脂組成物
US5817707A (en) *	1996-05-06	1998-10-06	Montell North America Inc.	Process for making propylene graft copolymers using a redox initiator system

1987
- 1987-05-25 JP JP12907587A patent/JPS63291913A/ja active Granted

Also Published As

Publication number	Publication date
JPS63291913A (ja)	1988-11-29

Legal Events

Date	Code	Title	Description
2004-12-21	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2005-12-13	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2006-12-12	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
2007-05-25	EXPY	Cancellation because of completion of term
2007-08-15	FPAY	Renewal fee payment (prs date is renewal date of database)	Year of fee payment: 15 Free format text: PAYMENT UNTIL: 20071211

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