JPH0480286A - Fluorescent high-pressure mercury lamp - Google Patents
Fluorescent high-pressure mercury lampInfo
- Publication number
- JPH0480286A JPH0480286A JP19529390A JP19529390A JPH0480286A JP H0480286 A JPH0480286 A JP H0480286A JP 19529390 A JP19529390 A JP 19529390A JP 19529390 A JP19529390 A JP 19529390A JP H0480286 A JPH0480286 A JP H0480286A
- Authority
- JP
- Japan
- Prior art keywords
- phosphor
- pressure mercury
- activated
- mercury lamp
- trivalent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052753 mercury Inorganic materials 0.000 title claims abstract description 36
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 11
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 11
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- OTCUBYPHLVALCK-UHFFFAOYSA-N magnesium yttrium(3+) borate Chemical compound B([O-])([O-])[O-].[Mg+2].[Y+3] OTCUBYPHLVALCK-UHFFFAOYSA-N 0.000 claims abstract description 6
- QWVYNEUUYROOSZ-UHFFFAOYSA-N trioxido(oxo)vanadium;yttrium(3+) Chemical compound [Y+3].[O-][V]([O-])([O-])=O QWVYNEUUYROOSZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 5
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims abstract description 5
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 claims abstract description 4
- DXNVUKXMTZHOTP-UHFFFAOYSA-N dialuminum;dimagnesium;barium(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mg+2].[Mg+2].[Al+3].[Al+3].[Ba+2].[Ba+2] DXNVUKXMTZHOTP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 3
- 239000010452 phosphate Substances 0.000 claims abstract description 3
- 230000005855 radiation Effects 0.000 claims abstract 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- 238000009877 rendering Methods 0.000 abstract description 18
- 230000004907 flux Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 229910019990 cerium-doped yttrium aluminum garnet Inorganic materials 0.000 description 3
- 238000000295 emission spectrum Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- BQPIGGFYSBELGY-UHFFFAOYSA-N mercury(2+) Chemical compound [Hg+2] BQPIGGFYSBELGY-UHFFFAOYSA-N 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 229910019655 synthetic inorganic crystalline material Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は演色性を改善した蛍光高圧水銀灯に関するもの
である。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a fluorescent high-pressure mercury lamp with improved color rendering.
従来の技術
蛍光高圧水銀灯の演色性を改善するために、その発光管
から放出される短波長青色域の水銀輝線出力を吸収する
作用がある蛍光体を使用することが試みられており、３
価のセリウム付活したイツトリウムアルミネート（Ｙ３
Ａｅ５０１２ ： Ｃｅ”）を用い、赤色蛍光体く例え
ば、３価のユーロピウムで付活したイットリウムバナデ
ート）と組み合わせる方法が米国特許第４０３４２５７
号明細書に開示されている。Conventional Technology In order to improve the color rendering properties of fluorescent high-pressure mercury lamps, attempts have been made to use phosphors that have the effect of absorbing the mercury emission line output in the short wavelength blue region emitted from the arc tubes.
Yttrium aluminate activated with valent cerium (Y3
U.S. Pat. No. 4,034,257 discloses a method using Ae5012: Ce") and combining it with a red phosphor (for example, yttrium vanadate activated with trivalent europium).
It is disclosed in the specification of No.
発明が解決しようとする課題
蛍光高圧水銀灯は、その優れた寿命特性により屋外照明
を中心にして広く一般照明に使用されている代表的な高
圧放電灯である。このランプの欠点は演色性が低いこと
にあり、Ｃ，１，Ｅ、の平均演色評価数Ｒａは４３程度
である。近年蛍光高圧水銀灯の演色性改善が試みられ、
従来の赤色蛍光体に加えて青緑色蛍光体を付加すること
により、そのＲａは５２程度にまで改善された。しかし
なから、この改善された演色性を有する蛍光高圧水銀灯
においても色の見え方を重視する屋内照明に用いるには
なお不充分であり、広く普及するには至っていない。Problems to be Solved by the Invention Fluorescent high-pressure mercury lamps are typical high-pressure discharge lamps that are widely used for general lighting, mainly outdoor lighting, due to their excellent longevity characteristics. The disadvantage of this lamp is that its color rendering properties are low, and the average color rendering index Ra of C, 1, and E is about 43. In recent years, attempts have been made to improve the color rendering properties of fluorescent high-pressure mercury lamps.
By adding a blue-green phosphor in addition to the conventional red phosphor, its Ra was improved to about 52. However, even this fluorescent high-pressure mercury lamp with improved color rendering properties is still insufficient for use in indoor lighting where color appearance is important, and it has not become widely used.
このように、従来方法において演色性改善か充分になさ
れない理由の一つは、発光管から放出されている４０５
ｎｍおよび４３６ｎｍの水銀輝線出力か強すぎるためで
あることが知られている。As described above, one of the reasons why the color rendering properties cannot be improved sufficiently in the conventional method is that the 405 emitted from the arc tube
It is known that this is because the mercury emission line output at wavelengths of 436 nm and 436 nm is too strong.
これらのうち、４０５ｎｍの水銀ＩＩ出力については酸
化チタン被膜を利用するなどして抑制することか可能で
あるが、このように単に水銀輝線出力を抑制することは
ランプ効果の低下を伴うため不適当とされている。すな
わち、従来の演色性改善形高圧水銀灯では前記短波長青
色域の水銀輝線出力を抑制することなく演色性の改善を
はかっているため、その改善も充分ではなく屋内照明に
広く普及させていくためには、なお−層の改善が望まれ
ている。Among these, it is possible to suppress the mercury II output at 405 nm by using a titanium oxide film, but simply suppressing the mercury bright line output in this way is inappropriate because it involves a decrease in the lamp effect. It is said that In other words, in conventional high-pressure mercury lamps with improved color rendering properties, the color rendering properties are improved without suppressing the output of mercury bright lines in the short wavelength blue region, so the improvement is not sufficient, and it is necessary to spread the lamps widely for indoor lighting. However, it is still desired to improve the layer.
このような事情に基づいて、近年短波長青色域に吸収を
有する蛍光体が開発され、上記短波長青色域の水銀輝線
出力を抑制することによって生じるランプ効率の低下を
防止する検討かなされでいる。例えば、上記短波長青色
域に吸収を有する蛍光体としてＹ３．ＡＱｓ○１２ Ｃ
ｅ＋３（以下、−数式としてＹＡＧ：Ｃｅと略記する）
を用い、従来の赤色蛍光体とともに高圧水銀灯に適用し
て演色性の改善を試みた例が前記米国特許第４０３４−
２５７号明細書に示されているが、それらのランプのＲ
ａは５１程度であり満足できるものではなかった。Based on these circumstances, phosphors that absorb in the short wavelength blue region have been developed in recent years, and studies are being conducted to prevent the reduction in lamp efficiency caused by suppressing the mercury emission line output in the short wavelength blue region. . For example, Y3. AQs○12 C
e+3 (hereinafter abbreviated as YAG:Ce as a - formula)
An example of an attempt to improve color rendering by applying this to a high-pressure mercury lamp together with a conventional red phosphor is disclosed in the above-mentioned US Pat. No. 4,034-
No. 257, the R of those lamps is
a was about 51, which was not satisfactory.
課題を解決するための手段
以上のように、高圧水銀灯の演色性を改善するためには
、その発光管から放出される短波長青色域の水銀輝線出
力を抑制すると七もに従来の方法にみられるような赤色
域への発光の付加を行うだけては満足できる結果が得ら
れない。発明者らはさらに肯−黄緑色域にわたる広い波
長域に蛍光体による発光を付加する検討を行い、種々の
ランプを試作して高圧水銀灯の演色性を大幅に改善でき
ることを見いだした。すなわち、ＹＡＧ：Ｃｅと赤色蛍
光体を組み合わせた場合はすでに述べたようにＲａは５
１程度であるが、ＹＡＧ・Ｃｅと赤色蛍光体に加えて青
緑色蛍光体くここでは、二価のユーロピウムおよび２価
のマンカンで共付活されたバリウムマグ不シウムアルミ
不一ト〉を追加した組合わせにおいてはＲａは大幅に改
善され５８程度になった。Means for Solving the Problems As mentioned above, in order to improve the color rendering properties of high-pressure mercury lamps, it is necessary to suppress the output of mercury bright lines in the short wavelength blue region emitted from the arc tubes, which is different from conventional methods. It is not possible to obtain satisfactory results by simply adding light emission to the red region. The inventors further investigated adding light emission by a phosphor in a wide wavelength range covering the positive to yellow-green region, and found that the color rendering properties of high-pressure mercury lamps could be significantly improved by making various lamps. In other words, when YAG:Ce and red phosphor are combined, Ra is 5 as already mentioned.
1, but in addition to YAG/Ce and the red phosphor, a blue-green phosphor is added. In the combination, Ra was significantly improved to about 58.
また、ＹＡＧ：Ｃｅと赤色蛍光体および青緑色蛍光体に
加えてさらに緑色蛍光体（ここでは、３価のセリウムお
よび３価のテルビウムで共付活したイツトリウムマグネ
シウムボレート）を追加した組合せにおいて、そのＲａ
は６０程度となることが見いだされた。ここで、青緑色
蛍光体として２価のユーロピウムおよび２価のマンガン
で共付活したバリウムマグネシウムアルミネートに限定
したのはランプ効率の低下を伴わないという条件を課し
たためである。また、緑色蛍光体として３価のセリウム
および３価のテルヒウムで共付活じたイツトリウムマグ
ネシウムボレートに限定したのは他の緑色蛍光体を用い
た場合と比較して寿命中の光速維持率の低下が少ないこ
とがわかったからである。In addition, in addition to YAG:Ce, a red phosphor and a blue-green phosphor, a green phosphor (here, yttrium magnesium borate co-activated with trivalent cerium and trivalent terbium) is added, That Ra
was found to be about 60. Here, the blue-green phosphor was limited to barium magnesium aluminate co-activated with divalent europium and divalent manganese because the condition was imposed that the lamp efficiency would not be reduced. In addition, the fact that we limited the green phosphor to yttrium magnesium borate co-activated with trivalent cerium and trivalent terhium has a lower light speed maintenance rate during its lifetime than when using other green phosphors. This is because it was found that the decrease was small.
作用
かかる構成による七、高圧水銀灯の発光管か放出する４
０５ｎｍおよび４３６ｎｍの水銀輝線出力を吸収する作
用と、紫外線によって励起され黄緑色域に発光を生じる
作用を併せ持つＹＡＧ Ｃｅを用いることによる演色性
改善の効果と、高圧水銀灯の発光スペクトルにおいて欠
如している４４０ｎｍ〜５４０ｎｍおよび５９０ｎｍ〜
７００ｎｍ付近の波長域の光出力を蛍光体を用いて補う
ことによる演色性改善の効果が相乗的に作用するこ七に
よって、演色性を大幅に向上させることができる。7. High-pressure mercury lamp arc tube emits 4.
The effect of improving color rendering by using YAG Ce, which has both the ability to absorb mercury emission line output at 05 nm and 436 nm and the ability to generate light in the yellow-green region when excited by ultraviolet rays, is lacking in the emission spectrum of high-pressure mercury lamps. 440nm~540nm and 590nm~
The effect of improving the color rendering properties by supplementing the light output in the wavelength range around 700 nm using a phosphor works synergistically, thereby making it possible to significantly improve the color rendering properties.
実施例
以下、本発明の一実施例について図面を用いて説明する
。EXAMPLE Hereinafter, an example of the present invention will be described with reference to the drawings.
実施例１
Ｙｏ、５ｓＶＯ４：Ｅｕｏ、ｏｓ
７０ｗｔ％′Ｂａｏ、ｓＭｇ＋、５３Ａｆ’
１４０２４：ＥｕＯ，２，Ｍｎ０ｏ７ １５ｗ
ｔ％Ｙｏ、ｓＭｇｏ ７ＢｓＯ＋ｏ：Ｃｅｏ、＋、Ｔ
ｂｏ、：＋ １０ｗｔ％Ｙ２．ｓＡ＆
ｓＯ＋２：Ｃｅｏ、＋ ５
ｗｔ％上記混合物を用い、それに５ｉｖｔ％の５ｉ０２
粉末を加えて充分に混合した後、１０ｏＷ高圧水銀灯の
外管の内面に３．０■／ ａｎｔの塗布量となるように
塗布した。得られたランプの１００時間光束値ハ４６２
０ ルー メ”ｙ、色温度！−１４２００Ｋ 。Example 1 Yo, 5sVO4: Euo, os
70wt%'Bao, sMg+, 53Af'
14024:EuO,2,Mn0o7 15w
t%Yo,sMgo 7BsO+o:Ceo,+,T
bo, :+10wt%Y2. sA&
sO+2: CEO, +5
wt% using the above mixture and adding 5ivt% of 5i02
After adding the powder and thoroughly mixing it, it was applied to the inner surface of the outer bulb of a 10oW high-pressure mercury lamp at a coating amount of 3.0 μ/ant. The 100 hour luminous flux value of the obtained lamp was 462
0 lume"y, color temperature!-14200K.
Ｒａは６０であり、従来の蛍光高圧水銀灯のＲａ（５０
−５５程度）に比べて明らかな改善がみられた。Ra is 60, which is higher than that of conventional fluorescent high-pressure mercury lamp (50
-55), a clear improvement was seen.
第１図は本実施例による１００Ｗ蛍光高圧水銀灯の分光
分布を示す。第２図は各蛍光体の発光スペクトルを示す
。第２図の曲線１はＢａｏ、ａＭｇ＋、５３Ａｅ１４０
２４ ： Ｅｕｏ、２．Ｍｎｏ、ｏ７）曲線２はＹｏ、
ｓＭ ｇｏ、７ＢｓＯ＋ｏ ： ＣｅＯ，Ｉ 、 Ｔ
ｂｏ３Ｘ曲線３はＹｏ、５ｓＶＯ４： Ｅ ｕＯｏ５の
ものである。FIG. 1 shows the spectral distribution of the 100W fluorescent high-pressure mercury lamp according to this example. FIG. 2 shows the emission spectra of each phosphor. Curve 1 in Figure 2 is Bao, aMg+, 53Ae140
24: Euo, 2. Mno, o7) Curve 2 is Yo,
sM go, 7BsO+o: CeO, I, T
bo3X curve 3 is of Yo, 5sVO4: E uOo5.
第３図の曲線ｌは本実施例による１００Ｗ蛍光高圧水銀
灯の寿命中の光束維持率の推移を示すもので、比較とし
てＹｏ ９Ｍｇｏ７Ｂｓｏ１ｏ： Ｃｅ。Curve 1 in FIG. 3 shows the change in luminous flux maintenance rate during the life of the 100W fluorescent high-pressure mercury lamp according to this example, and for comparison, Yo9Mgo7Bso1o:Ce.
Ｔｂｏ、：＋の代わりにＹ＋、ｓＳ ｉ Ｏｓ ： Ｃ
ｅ。Tbo, :+ instead of Y+, sS i Os : C
e.
Ｔｂｏ３を緑色蛍光体として用いた場合のデータを曲線
２に示す。Curve 2 shows data when Tbo3 is used as a green phosphor.
第３図から明らかなように、３価のセリウムおよび３価
のテルビウムで共付活したイツトリウムマグネシウムボ
レートが寿命中を通して安定な特性を示すことがわかる
。As is clear from FIG. 3, it can be seen that yttrium magnesium borate co-activated with trivalent cerium and trivalent terbium exhibits stable characteristics throughout its life.
実施例２
実施例１と同じ蛍光体混合物を同様にして４００Ｗ用外
管の内面に塗布し、４００Ｗ蛍光高圧水銀灯を作製した
。得られたランプの１００時間光束は２４５００ルーメ
ン、色温度は４０５０Ｋ。Example 2 The same phosphor mixture as in Example 1 was similarly applied to the inner surface of a 400W outer bulb to produce a 400W fluorescent high-pressure mercury lamp. The resulting lamp has a 100 hour luminous flux of 24,500 lumens and a color temperature of 4,050K.
Ｒａは５８であり従来の蛍光高圧水銀灯のＲａ（５０〜
５５程度）に比べて明らかな改善がみられた。Ra is 58, which is higher than that of conventional fluorescent high-pressure mercury lamps (50~
A clear improvement was seen compared to the previous version (approximately 55).
実施例３
Ｙｏ、５ｓＶｏ、５ｓＰｏ４ｓ０４：Ｅｕｏ、ｏｓ
８０ｗｔ ９゜Ｂａｏ、ｓＭｇ＋、５ｓＡｅ
＋＋０２４：Ｅｕｏ、＋、Ｍｎｏ、ｏｓ ５ｉ
ｖｔ％Ｙｏ、ｓＭｇｏ、５ＢｓＯ＋ｏ：Ｃｅｏ、 ＋
、Ｔｂｏ４１０ｗｔ ’。Example 3 Yo, 5sVo, 5sPo4s04:Euo, os
80wt 9゜Bao, sMg+, 5sAe
++024: Euo, +, Mno, os 5i
vt%Yo, sMgo, 5BsO+o:Ceo, +
, Tbo410wt'.
Ｙ２．ｓＡ＆ ｓＯ＋２：Ｃｅｏ、＋
５ｗｔ％上記混合物を用い、それに３ｗｔ％
の５ｉ０２粉末を加えて充分に混合した後、１００Ｗ高
圧水銀灯の外管の内面に４■／ ｃＪの割合になるよう
塗布し、通常の方法により１００Ｗ蛍光高圧水銀灯を作
製した。得られたランプの１００時間光束は４４００ル
ーメン、色温度は３９００に、Ｒａ１ｉ６２てあり、明
らかに改善された演色性を示した。Y2. sA & sO+2: CEO, +
5 wt% using the above mixture, and 3 wt%
After adding the 5i02 powder and mixing thoroughly, it was coated on the inner surface of the outer bulb of a 100W high-pressure mercury lamp at a ratio of 4 cm/cJ, and a 100W fluorescent high-pressure mercury lamp was produced by the usual method. The resulting lamp had a 100-hour luminous flux of 4,400 lumens, a color temperature of 3,900, and Ra1i62, showing clearly improved color rendering properties.
発明の詳細
な説明したように、本発明の蛍光高圧水銀灯は、その蛍
光体被膜を３価のセリウムで付活したイツトリウムアル
ミネートである第１の蛍光体と、２価のユーロピウムお
よび２価のマンガンで共付活されたバリウムマグネシウ
ムアルミネートである第２の蛍光体と、３価のセリウム
および３価のテルビウムで共付活されたイツトリウムマ
グネシウムボレートである第３の蛍光体と、３価のユー
ロピウムで付活されたイットリウムハナデートおよび３
価のユーロピウムで付活されたイットリウムバナデート
フォスフェートの少な（とも−種である第４の蛍光体と
からなるように構成することにより、その演色性を従来
の蛍光高圧水銀灯に比べて大幅に改善することができ、
その用途を屋内照明の分野にも拡大できるものである。As described in detail, the fluorescent high-pressure mercury lamp of the present invention comprises a first phosphor which is yttrium aluminate whose phosphor coating is activated with trivalent cerium, divalent europium and divalent cerium. a second phosphor which is barium magnesium aluminate co-activated with manganese; a third phosphor which is yttrium magnesium borate co-activated with trivalent cerium and trivalent terbium; Yttrium hanadate activated with valent europium and 3
By configuring the structure to consist of a fourth phosphor containing a small amount of yttrium vanadate phosphate activated with valent europium, its color rendering properties are significantly improved compared to conventional fluorescent high-pressure mercury lamps. can be improved,
Its application can also be extended to the field of indoor lighting.
第１図は本発明の実施例１の蛍光高圧水銀灯の分光分布
を示す図、第２図は本発明にかがる蛍光体の発光スペク
トルを示す図、第３図は本発明の実施例１の１００Ｗ蛍
光高圧水銀灯の寿命中における光束維持率の維持を示す
図である。
代理人の氏名 弁理士 粟野重孝 はが１名区
知＝
ＩＩＯｆ：ｏ−
→（・区 ＼
い
口 廿 ｒ ｃ
＋＋トFIG. 1 is a diagram showing the spectral distribution of a fluorescent high-pressure mercury lamp according to Example 1 of the present invention, FIG. 2 is a diagram showing the emission spectrum of the phosphor according to the present invention, and FIG. 3 is a diagram showing Example 1 of the present invention. FIG. 2 is a diagram showing the maintenance of the luminous flux maintenance rate during the life of a 100W fluorescent high-pressure mercury lamp. Name of agent: Patent attorney Shigetaka Awano
Claims (1)
光管を囲む外管と、この外管内面に被着形成された蛍光
体被膜とを備えた蛍光高圧水銀灯において、前記蛍光体
皮膜が３価のセリウムで付活されたイットリウムアルミ
ネートである第１の蛍光体と、２価のユーロピウムおよ
び２価のマンガンで共付活されたバリウムマグネシウム
アルミネートである第２の蛍光体と、３価のセリウムお
よび３価のテルビウムで共付活されたイットリウムマグ
ネシウムボレートである第３の蛍光体と、３価のユーロ
ピウムで付活されたイットリウムバナデートおよび３価
のユーロピウムで付活されたイットリウムバナデートフ
ォスフェートの少なくとも１種である第４の蛍光体とか
らなることを特徴とする蛍光高圧水銀灯。A fluorescent high-pressure mercury lamp comprising an arc tube that emits visible radiation and ultraviolet radiation, an outer tube surrounding the arc tube, and a phosphor coating formed on the inner surface of the outer tube, wherein the phosphor coating is a first phosphor that is yttrium aluminate activated with divalent cerium; a second phosphor that is barium magnesium aluminate coactivated with divalent europium and divalent manganese; a third phosphor that is yttrium magnesium borate coactivated with cerium and trivalent terbium; yttrium vanadate activated with trivalent europium; and yttrium vanadate activated with trivalent europium. A fluorescent high-pressure mercury lamp comprising a fourth phosphor that is at least one type of phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19529390A JPH0480286A (en) | 1990-07-23 | 1990-07-23 | Fluorescent high-pressure mercury lamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19529390A JPH0480286A (en) | 1990-07-23 | 1990-07-23 | Fluorescent high-pressure mercury lamp |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0480286A true JPH0480286A (en) | 1992-03-13 |
Family
ID=16338749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19529390A Pending JPH0480286A (en) | 1990-07-23 | 1990-07-23 | Fluorescent high-pressure mercury lamp |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0480286A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006072919A3 (en) * | 2005-01-10 | 2006-09-21 | Philips Intellectual Property | Illumination system comprising barium magnesium aluminate phosphor |
| US7329988B2 (en) | 1996-07-29 | 2008-02-12 | Nichia Corporation | Light emitting device with blue light LED and phosphor components |
-
1990
- 1990-07-23 JP JP19529390A patent/JPH0480286A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7329988B2 (en) | 1996-07-29 | 2008-02-12 | Nichia Corporation | Light emitting device with blue light LED and phosphor components |
| US7362048B2 (en) | 1996-07-29 | 2008-04-22 | Nichia Kagaku Kogyo Kabushiki Kaisha | Light emitting device with blue light led and phosphor components |
| JP2008160140A (en) * | 1996-07-29 | 2008-07-10 | Nichia Chem Ind Ltd | Light emitting device and display device |
| US7531960B2 (en) | 1996-07-29 | 2009-05-12 | Nichia Corporation | Light emitting device with blue light LED and phosphor components |
| US7682848B2 (en) | 1996-07-29 | 2010-03-23 | Nichia Corporation | Light emitting device with blue light LED and phosphor components |
| JP2011009793A (en) * | 1996-07-29 | 2011-01-13 | Nichia Corp | Light emitting device and display device |
| JP2013102196A (en) * | 1996-07-29 | 2013-05-23 | Nichia Chem Ind Ltd | Light-emitting device and display unit |
| US9130130B2 (en) | 1996-07-29 | 2015-09-08 | Nichia Corporation | Light emitting device and display comprising a plurality of light emitting components on mount |
| WO2006072919A3 (en) * | 2005-01-10 | 2006-09-21 | Philips Intellectual Property | Illumination system comprising barium magnesium aluminate phosphor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH06248265A (en) | Blue light emitting phosphor for fluorescent lamp and fluorescent lamp using the same | |
| JPS6142851A (en) | Fluorescent lamp | |
| JP2003282026A (en) | Fluorescent lamp having a single phosphor layer | |
| JP4315664B2 (en) | Phosphor composition for low pressure discharge lamp and low pressure discharge lamp | |
| JPS5842590B2 (en) | fluorescent lamp | |
| JPH05334999A (en) | Low-pressure mercury discharge lamp | |
| JPH0480286A (en) | Fluorescent high-pressure mercury lamp | |
| JP4199530B2 (en) | Fluorescent substance for mercury vapor discharge lamp and mercury vapor discharge lamp | |
| JPH0625358B2 (en) | Fluorescent high pressure mercury lamp | |
| JPH04234481A (en) | Fluorescent high-pressure mercury-vapor lamp | |
| JPS6024151B2 (en) | fluorescent light | |
| JPH0480285A (en) | Fluorescent high-pressure mercury lamp | |
| JPH0625357B2 (en) | Fluorescent high pressure mercury lamp | |
| JPH04234482A (en) | Fluorescent high-pressure mercury-vapor lamp | |
| JPS6228539B2 (en) | ||
| JPS6049553A (en) | Fluorescent lamp | |
| JPH04188556A (en) | High-pressure fluorescent mercury lamp | |
| JPH04188557A (en) | High-pressure fluorescent mercury lamp | |
| JPH09213276A (en) | Metal halide lamp | |
| JP3245885B2 (en) | Fluorescent lamp | |
| JPH01156391A (en) | Luminescent composition for fluorescent lamp and fluorescent lamp using said composition | |
| JPS62208539A (en) | Fluorescent high pressure mercury lamp | |
| JP4205487B2 (en) | Luminescent composition, fluorescent lamp, and phosphor coating solution for fluorescent lamp | |
| JPS6313254A (en) | Fluorescent high-pressure mercury lamp | |
| JPH06124689A (en) | Fluorescent high pressure mercury lamp |