JPH0481180B2 - - Google Patents
Info
- Publication number
- JPH0481180B2 JPH0481180B2 JP16902583A JP16902583A JPH0481180B2 JP H0481180 B2 JPH0481180 B2 JP H0481180B2 JP 16902583 A JP16902583 A JP 16902583A JP 16902583 A JP16902583 A JP 16902583A JP H0481180 B2 JPH0481180 B2 JP H0481180B2
- Authority
- JP
- Japan
- Prior art keywords
- general formula
- minutes
- coupler
- seconds
- add water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims 3
- 239000004332 silver Substances 0.000 claims 3
- -1 silver halide Chemical class 0.000 claims 3
- 239000000463 material Substances 0.000 claims 2
- 239000000839 emulsion Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- CLJDCQWROXMJAZ-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid Chemical compound OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 CLJDCQWROXMJAZ-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- SRFKWQSWMOPVQK-UHFFFAOYSA-K sodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(2+) Chemical compound [Na+].[Fe+2].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O SRFKWQSWMOPVQK-UHFFFAOYSA-K 0.000 description 1
- LESFYQKBUCDEQP-UHFFFAOYSA-N tetraazanium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound N.N.N.N.OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O LESFYQKBUCDEQP-UHFFFAOYSA-N 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/36—Couplers containing compounds with active methylene groups
- G03C7/38—Couplers containing compounds with active methylene groups in rings
- G03C7/384—Couplers containing compounds with active methylene groups in rings in pyrazolone rings
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
発色現像 ３分15秒
漂 白 ６分30秒
水 洗 ３分15秒
定 着 ６分30秒
水 洗 ３分15秒
安定浴 １分30秒
〔発色現像液組成〕
４−アミノ−３−メチル−Ｎ−エチル−Ｎ−
（β−ヒドロキシエチル）−アニリン硫酸塩
4.75ｇ
無水亜硫酸ナトリウム 4.25ｇ
ヒドロキシルアミン１／２硫酸塩 2.0ｇ
無水炭酸カリウム 37.5ｇ
臭化ナトリウム 1.3ｇ
ニトリロトリ酢酸・３ナトリウム塩（１水塩）
2.5ｇ
水酸化カリウム 1.0ｇ
水を加えて１とし、水酸化カリウムを用いて
PH10.0に調整する。
〔漂白液組成〕
エチレンジアミンテトラ酢酸アンモニウム塩
100.0ｇ
エチレンジアミン酢酸２アンモニウム塩 10.0ｇ
臭化アンモニウム 150.0ｇ
氷酢酸 10.0ml
水を加えて１としアンモニア水を用いてPH
6.0に調整する。
〔定着液組成〕
チオ硫酸アンモニウム（５％水溶液） 162.0ｇ
無水亜硫酸ナトリウム 12.4ｇ
水を加えて１とし、酢酸を用いてPH6.5に調整
する。
〔安定化液組成〕
ホルマリン（37％水溶液） 5.0ml
コニダツクス（小西六写真工業(株)製） 7.5ml
水を加えて１とする。
上記により得られたマゼンタ色素画像を濃度計
（PD−7R小西六写真工業(株)製）を用いて緑色光
により測定し、発色感度（試料(4)における感度を
100としたときの相対値で表示）、カブリおよび最
高濃度を算出し、その結果を下記第１表に示す。
Color development 3 minutes 15 seconds Bleach 6 minutes 30 seconds Washing with water 3 minutes 15 seconds Fixation 6 minutes 30 seconds Washing with water 3 minutes 15 seconds Stabilizing bath 1 minute 30 seconds [Color developer composition] 4-Amino-3-methyl- N-ethyl-N-
(β-hydroxyethyl)-aniline sulfate
4.75g Anhydrous sodium sulfite 4.25g Hydroxylamine 1/2 sulfate 2.0g Anhydrous potassium carbonate 37.5g Sodium bromide 1.3g Nitrilotriacetic acid trisodium salt (monohydrate)
2.5g Potassium hydroxide 1.0g Add water to make 1, and use potassium hydroxide to
Adjust to PH10.0. [Bleach solution composition] Ethylenediaminetetraacetic acid ammonium salt
100.0g Ethylenediamineacetic acid diammonium salt 10.0g Ammonium bromide 150.0g Glacial acetic acid 10.0ml Add water to 1 and pH using ammonia water
Adjust to 6.0. [Fixer composition] Ammonium thiosulfate (5% aqueous solution) 162.0g Anhydrous sodium sulfite 12.4g Add water to make 1, and adjust to PH6.5 using acetic acid. [Stabilizing liquid composition] Formalin (37% aqueous solution) 5.0ml Konidax (manufactured by Konishiroku Photo Industry Co., Ltd.) 7.5ml Add water to make 1. The magenta dye image obtained above was measured with green light using a densitometer (PD-7R manufactured by Konishiroku Photo Industry Co., Ltd.) to determine the color development sensitivity (sensitivity in sample (4)).
(expressed as a relative value when set to 100), fog and maximum density were calculated, and the results are shown in Table 1 below.
【表】【table】
発色現像 ３分30分
漂白定着 １分30分
水 洗 ３分
〔発色現像液組成〕
４−アミノ−３−メチル−Ｎ−エチル−Ｎ−
（β−メタンスルホンアミドエチル）−アニリン
硫酸塩 44ｇ
ベンジルアルコール 10.0ml
ヒドロキシルアミン硫酸塩 ２ｇ
炭酸カリウム 25.0ｇ
臭化カリウム 0.2ｇ
無水亜硫酸ナトリウム 2.0ｇ
ジエチレングリコール ３ml
水を加えて１とし、PH10.0に調整する。
〔漂白定着液組成〕
エチレンジアミンテトラ酢酸鉄ナトリウム塩
60.0ｇ
チオ硫酸アンモニウム 100.0ｇ
重亜硫酸ナトリウム 10.0ｇ
メタ重亜硫酸ナトリウム 3.0ｇ
水を加えて１とし、PH6.6に調整する。
得られたマゼンタ色素画像を実施例１と同様に
緑色光で測定し、発色感度（試料(10)を100とする
相対感度で表示）、カブリおよび最高濃度を算出
し、その結果を第２表に示す。
Color development 3 minutes 30 minutes Bleach fixing 1 minute 30 minutes Washing 3 minutes [Color developer composition] 4-amino-3-methyl-N-ethyl-N-
(β-Methanesulfonamidoethyl)-aniline sulfate 44g Benzyl alcohol 10.0ml Hydroxylamine sulfate 2g Potassium carbonate 25.0g Potassium bromide 0.2g Anhydrous sodium sulfite 2.0g Diethylene glycol 3ml Add water to 1 and adjust the pH to 10.0 do. [Bleach-fix solution composition] Ethylenediaminetetraacetic acid iron sodium salt
60.0g Ammonium thiosulfate 100.0g Sodium bisulfite 10.0g Sodium metabisulfite 3.0g Add water to 1 and adjust the pH to 6.6. The obtained magenta dye image was measured with green light in the same manner as in Example 1, and the color development sensitivity (expressed as relative sensitivity with sample (10) as 100), fog, and maximum density were calculated, and the results are shown in Table 2. Shown below.
【表】
第２表の示す結果から、本発明のマゼンタカプ
ラーを用いた試料(6)、(7)および(8)は、比較カプラ
ーを用いた試料(9)および(10)に比べて、高い発色感
度と最高濃度を有しており、カブリの増加がない
優れたカプラーであることがわかる。
比較カプラー(C)
（特公昭53−34044号記載の化合物）
比較カプラー(D)
（特開昭57−35858号記載の化合物）
実施例 ３
実施例１および実施例２で得られた試料(1)〜(10)
について耐光性、耐熱性、耐湿性の試験を行なつ
た。耐光性は得られた各画像に紫外線吸収フイル
ターを付けてキセノンフエードメーターで100時
間曝露後の残留濃度を曝露前の濃度を100として
表わした。また耐湿性は50℃、相対湿度80％の条
件で２時間保存後の残留濃度を試験前の濃度を
100として表わした。更に耐熱性は77℃の条件下
２週間保存後の残留濃度を試験前の濃度を100と
して表わした。第３表にその結果を示す。[Table] From the results shown in Table 2, samples (6), (7), and (8) using the magenta coupler of the present invention have a lower temperature than samples (9) and (10) using the comparative coupler. It can be seen that it is an excellent coupler with high color development sensitivity and maximum density, and no increase in fog. Comparative coupler (C) (compound described in Japanese Patent Publication No. 53-34044) Comparative coupler (D) (compound described in JP-A-57-35858) Example 3 Samples (1) to (10) obtained in Example 1 and Example 2
We conducted tests on light resistance, heat resistance, and moisture resistance. Light resistance was determined by measuring the residual density after 100 hours of exposure using a xenon fademeter with an ultraviolet absorption filter attached to each image, with the density before exposure being 100. In addition, the humidity resistance is the residual concentration after storage for 2 hours at 50℃ and 80% relative humidity compared to the concentration before the test.
Expressed as 100. Furthermore, heat resistance was expressed as the residual concentration after storage for 2 weeks at 77°C, with the concentration before the test being 100. Table 3 shows the results.
【表】【table】
【表】
第３表の結果から、本発明のカプラーは比較カ
プラーに比べて耐光性、耐湿性および耐熱性のす
べてにおいてすぐれており保存時における画像の
濃度低下を起し難い優れたカプラーであることが
判る。[Table] From the results in Table 3, the coupler of the present invention is superior to the comparative couplers in all aspects of light resistance, moisture resistance, and heat resistance, and is an excellent coupler that is unlikely to cause a decrease in image density during storage. I understand that.
Claims (1)
剤層が設けられたハロゲン化銀写真感光材料にお
いて、前記ハロゲン化銀乳剤層に、下記(1)、(2)、
(3)、(4)、(5)および(6)で示される化合物の少なくと
も１種を含有することを特徴とするハロゲン化銀
写真感光材料。 一般式(1) 一般式(2) 一般式(3) 一般式(4) 一般式(5) 一般式(6) [Scope of Claims] 1. In a silver halide photographic material having at least one silver halide emulsion layer provided on a support, the following (1), (2),
A silver halide photographic material containing at least one of the compounds represented by (3), (4), (5) and (6). General formula (1) General formula (2) General formula (3) General formula (4) General formula (5) General formula (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16902583A JPS6060645A (en) | 1983-09-13 | 1983-09-13 | Silver halide photosensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16902583A JPS6060645A (en) | 1983-09-13 | 1983-09-13 | Silver halide photosensitive material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6060645A JPS6060645A (en) | 1985-04-08 |
| JPH0481180B2 true JPH0481180B2 (en) | 1992-12-22 |
Family
ID=15878925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16902583A Granted JPS6060645A (en) | 1983-09-13 | 1983-09-13 | Silver halide photosensitive material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6060645A (en) |
-
1983
- 1983-09-13 JP JP16902583A patent/JPS6060645A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6060645A (en) | 1985-04-08 |
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