JPH0482560A - Solid deodorizer and making and use thereof - Google Patents
Solid deodorizer and making and use thereofInfo
- Publication number
- JPH0482560A JPH0482560A JP2195955A JP19595590A JPH0482560A JP H0482560 A JPH0482560 A JP H0482560A JP 2195955 A JP2195955 A JP 2195955A JP 19595590 A JP19595590 A JP 19595590A JP H0482560 A JPH0482560 A JP H0482560A
- Authority
- JP
- Japan
- Prior art keywords
- solid
- wax
- solubilizer
- thermoplastic polyester
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007787 solid Substances 0.000 title claims abstract description 35
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 16
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 11
- 229920000728 polyester Polymers 0.000 claims abstract description 8
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- UYZQWKKNVBJVOF-UHFFFAOYSA-N 1-decoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCC UYZQWKKNVBJVOF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 4
- 239000002781 deodorant agent Substances 0.000 claims description 25
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 230000002485 urinary effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004898 kneading Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000001993 wax Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 9
- 235000019271 petrolatum Nutrition 0.000 abstract description 4
- 239000004264 Petrolatum Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 239000003814 drug Substances 0.000 abstract description 2
- 239000004200 microcrystalline wax Substances 0.000 abstract description 2
- 235000019808 microcrystalline wax Nutrition 0.000 abstract description 2
- 239000012188 paraffin wax Substances 0.000 abstract description 2
- 235000019809 paraffin wax Nutrition 0.000 abstract description 2
- 229940066842 petrolatum Drugs 0.000 abstract description 2
- 239000012169 petroleum derived wax Substances 0.000 abstract description 2
- 235000019381 petroleum wax Nutrition 0.000 abstract description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 abstract description 2
- 229920001225 polyester resin Polymers 0.000 abstract description 2
- 239000004645 polyester resin Substances 0.000 abstract description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 2
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 2
- 229920006395 saturated elastomer Polymers 0.000 abstract description 2
- 230000002411 adverse Effects 0.000 abstract 1
- 230000004936 stimulating effect Effects 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 208000009911 Urinary Calculi Diseases 0.000 description 7
- 210000002700 urine Anatomy 0.000 description 7
- 208000008281 urolithiasis Diseases 0.000 description 7
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 5
- 230000000873 masking effect Effects 0.000 description 5
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- 239000004155 Chlorine dioxide Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 235000019398 chlorine dioxide Nutrition 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 108090001069 Chymopapain Proteins 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 108090000526 Papain Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- ISWQCIVKKSOKNN-UHFFFAOYSA-L Tiron Chemical compound [Na+].[Na+].OC1=CC(S([O-])(=O)=O)=CC(S([O-])(=O)=O)=C1O ISWQCIVKKSOKNN-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 229960002976 chymopapain Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 239000003527 fibrinolytic agent Substances 0.000 description 1
- 230000003480 fibrinolytic effect Effects 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 230000027939 micturition Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920006230 thermoplastic polyester resin Polymers 0.000 description 1
- 210000001635 urinary tract Anatomy 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は長時間にわたって均一な消臭機能が得られる固
形消臭剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a solid deodorant that provides a uniform deodorizing function over a long period of time.
固形消臭剤は、一般に芳香剤によるマスキング作用を利
用したものがよく知られている。すなわち芳香性物質例
えば各種精油等の昇華又は揮発による芳香で、便所９台
所その他多数の人の出入する場合の悪臭をマスキングす
る目的で広く用いられてきた。Solid deodorants that utilize the masking effect of fragrances are generally well known. That is, fragrances produced by sublimation or volatilization of aromatic substances, such as various essential oils, have been widely used for the purpose of masking bad odors in toilets, kitchens, and other places where many people come and go.
そして固形消臭芳香剤には、大別して次の２種類がある
。Solid deodorant fragrances can be roughly divided into the following two types.
（ｉ）バラジクロルベンゼンを主体とする昇華性固形体
：これはバラジクロルベンゼン自体が昇華性、殺虫性を
有し、かつ成形が有利であり使用後残渣が残らない等の
特徴を有しているが、一方バラジクロルベンゼン自体が
独特の臭気を有し他の香料の有する香気やマスキング効
果を低下させる欠点もある。さらに最近では塩素化合物
であるバラジクロルベンゼンの人体に対する有害性の問
題が検討されている。(i) Sublimable solid material mainly composed of Balajichlorobenzene: Balajichlorobenzene itself has sublimation and insecticidal properties, is advantageous in molding, and leaves no residue after use. However, on the other hand, baladichlorobenzene itself has a unique odor and has the disadvantage of reducing the odor and masking effect of other fragrances. Furthermore, recently, the issue of the toxicity of baladichlorobenzene, a chlorine compound, to the human body has been studied.
（ｉｉ ）ゲル化剤を用いた固体：香料を高分子吸収の
有する芳香、マスキング効果をそのまま利用できる。し
かしこのようなゲル化剤は粘結力が十分でなくゲル化に
際して他の添加剤を要し、得られた固形剤はもろくてく
ずれ易いと同時に保水性が悪く離奨しやすいという欠点
があった。(ii) Solid using a gelling agent: The fragrance and masking effect of polymer absorption can be used as is. However, such gelling agents do not have sufficient cohesive strength and require other additives during gelation, and the resulting solid agent has the drawbacks of being brittle and easily crumbling, as well as having poor water retention and being easily separated. Ta.
なお便器（男子用）に使用される薬剤としては、古くか
ら球状のバラジクロルベンゼンが広り用いられてきたが
これは尿又は洗水によりバラジクロルベンゼンが溶解し
て殺虫効果、マスキング効果を発揮するものである。し
かしこれについても上記の問題点のため縮少される傾向
にある。As a chemical used in toilet bowls (for men), spherical baladichlorbenzene has been widely used for a long time, but the baladichlorbenzene dissolves in urine or washing water and has an insecticidal and masking effect. It is something that demonstrates the. However, this also tends to be reduced due to the problems mentioned above.
本発明は以上のバラジクロルベンゼンに代わる固形消臭
剤を提供するものであって、強い刺激臭がなく、かつ人
体に対しても有害性等のない薬剤を目的とする。The present invention provides a solid deodorant that can replace the above-mentioned balajichlorobenzene, and aims to provide a drug that does not have a strong irritating odor and is not harmful to the human body.
本発明はすなわち、固形ワックス及び／又は熱可塑性ポ
リエステルと可溶化剤と消臭成分とを含むことを特徴と
する固形消臭剤である。That is, the present invention is a solid deodorant characterized by containing a solid wax and/or a thermoplastic polyester, a solubilizer, and a deodorizing component.
本発明の固形消臭剤に使用されるワックスとしてはパラ
フィンワックス、マイクロクリスタリンワックス、ペト
ロラタム等の石油ワックスが挙げられる。また熱可塑性
ポリエステルとしてはポリエチレンテレフタレート、ポ
リブチレンテレフタレート等の飽和ポリエステル樹脂が
挙げられる。The wax used in the solid deodorant of the present invention includes petroleum waxes such as paraffin wax, microcrystalline wax, and petrolatum. Examples of the thermoplastic polyester include saturated polyester resins such as polyethylene terephthalate and polybutylene terephthalate.
また可溶化剤としてはポリエチレングリコール。Also, polyethylene glycol is used as a solubilizer.
ポリエチレンオキサイド、ポリオキシエチレン・ポリオ
キシプロピレン２・デシルテトラデシルエーテル等が挙
げられる。これらの可溶化剤は固形ワックス及び／又は
熱可塑性ポリエステル（以下ワックス等という）１００
重量部に対し０．５〜５０重量部、好ましくは１〜４０
重量部であり、上記の範囲未満では可溶化剤による本発
明消臭剤の効果が得られず上記の範囲を超えると固形物
として固化し難く、特に夏季には温度の上昇によって溶
けてしまう。Examples include polyethylene oxide, polyoxyethylene/polyoxypropylene 2/decyltetradecyl ether, and the like. These solubilizers include solid wax and/or thermoplastic polyester (hereinafter referred to as wax etc.).
0.5 to 50 parts by weight, preferably 1 to 40 parts by weight
If it is less than the above range, the effect of the solubilizer of the present deodorant will not be obtained, and if it exceeds the above range, it will be difficult to solidify as a solid, and it will melt due to the rise in temperature, especially in summer.
消臭成分としては特に限定されないが、例えばフィトン
チッド等の芳香性物質、セルラーゼ、アミラーゼ、プロ
テアーゼ等の繊維素分解酵素、パパイン、キモパパイン
等の蛋白質分解酵素、Ｌ−アスコルビン酸、第一鉄化合
物、第二鉄化合物。Deodorizing ingredients are not particularly limited, but include aromatic substances such as phytoncide, fibrinolytic enzymes such as cellulase, amylase, and protease, proteolytic enzymes such as papain and chymopapain, L-ascorbic acid, ferrous compounds, and ferrous compounds. diiron compounds.
過硫酸塩、過マンガン酸カリ、亜塩素酸アルカリ（安定
化二酸化塩素）、アクリル酸エステル、グリオキザール
等が挙げられる。この様な消臭成分の添加量は固形物（
ワックス等と可溶化剤との合計量＞ １００重量部に
対して０．１〜４０重量部、好ましくは１〜３０重量部
である。この範囲未満では消臭効果が弱く、またこの範
囲を超えると安定な固形消臭剤が得られ難い。Examples include persulfates, potassium permanganate, alkali chlorite (stabilized chlorine dioxide), acrylic esters, and glyoxal. The amount of such deodorizing ingredients added is based on solid matter (
Total amount of wax etc. and solubilizer> 0.1 to 40 parts by weight, preferably 1 to 30 parts by weight, based on 100 parts by weight. If it is less than this range, the deodorizing effect will be weak, and if it exceeds this range, it will be difficult to obtain a stable solid deodorant.
本発明固形消臭剤を製造するには、ワックス等に可溶化
剤及び消臭成分を加えて加熱溶融、混練した後、冷却し
て固化させる。ワックス等、可溶化剤、及び消臭成分は
同時に加えてもよく、またワックス等に可溶化剤を加え
て加熱溶融し、次いで消臭成分を加えて混練してもよい
。To produce the solid deodorant of the present invention, a solubilizer and a deodorizing component are added to wax or the like, heated and melted, kneaded, and then cooled to solidify. The wax, etc., solubilizer, and deodorizing component may be added at the same time, or the solubilizing agent may be added to the wax, etc., heated and melted, and then the deodorizing component is added and kneaded.
この固形消臭剤は通常の消臭剤として種々の用途に使用
し得るが、特に男子用便所における便器の排尿孔部に載
置もしくは装着すれば、尿あるいは洗水に徐々に溶解す
ることにより尿石等の付着を防ぐことができる。This solid deodorant can be used for various purposes as a regular deodorant, but especially if it is placed or attached to the urination hole of a toilet in a men's restroom, it will gradually dissolve in urine or washing water. It can prevent the adhesion of urinary stones, etc.
本発明の固形消臭剤は消臭成分と可溶化剤を固形ワック
ス等の中に均一に分散させることにより、消臭成分によ
る消臭機能とともに可溶化剤による界面活性機能を有す
る。これを上記のように便器に使用する場合は尿あるい
は洗水によりバインダーとなるワックスが徐々に溶解し
、可溶化剤や消臭成分が徐々に浸出することにより尿臭
を消すとともに尿石や水アカ等が配管内壁への付着を防
止するものである。The solid deodorant of the present invention has a deodorizing function due to the deodorant component and a surfactant function due to the solubilizer by uniformly dispersing the deodorant component and the solubilizer in solid wax or the like. When this is used in a toilet bowl as described above, the binder wax is gradually dissolved by urine or washing water, and the solubilizer and deodorizing ingredients are gradually leached out, eliminating urine odor and removing urinary stones and water. This prevents dirt etc. from adhering to the inner walls of the piping.
本発明固形消臭剤の効果を以下実施例により説明する。 The effects of the solid deodorant of the present invention will be explained below using examples.
実施例Ｉ
Ａ：熱可塑性ポリエステル樹脂（商品名プラスコートＦ
Ｒ−６００−１００，互応化学社製）
９５ｇＢ＝ポリオキシエチレン・ポリオキシ
プロピレン２・デシルテトラデシルエーテル
ｇ
Ｃ：フィトンチッド系消臭側 １０ｇ上記Ａ、
Ｂ、 Ｃを２００ｍ１ｔのビーカーに計量し、これを
８５℃に加温されたウォーターバスに入れて溶融し、十
分ブレンドした後、ビーカーを水冷して固形化した。得
られた固形消臭剤の一部分を１ｃｍ角に切断してこれを
２１容量のテドラパフク（商品名、フロンケミカル社製
）内に採集し、水１ｍｌを添加してヒートシールを行い
、この容器に濃度７５ｐｐｍのトリメチルアミン（標準
ガスＮ２基準）を充填し、３０分後のトリメチルアミン
濃度を測定したところ３．０５ ｐ ｐ ｍ以下であっ
た。Example I A: Thermoplastic polyester resin (product name Plus Coat F
R-600-100, manufactured by Gooh Kagaku Co., Ltd.)
95g B = polyoxyethylene, polyoxypropylene 2, decyltetradecyl ether g C: Phytoncide deodorizing side 10g A above,
B and C were weighed into a 200ml beaker, placed in a water bath heated to 85°C, melted, thoroughly blended, and solidified by cooling the beaker with water. A portion of the obtained solid deodorant was cut into 1 cm square pieces, collected in a 21-capacity Tedra Pafuku (trade name, manufactured by Freon Chemical Co., Ltd.), 1 ml of water was added, heat-sealed, and the pieces were placed in this container. It was filled with trimethylamine at a concentration of 75 ppm (based on standard gas N2), and the trimethylamine concentration measured 30 minutes later was 3.05 ppm or less.
残りの固形消臭剤を男子用便所の小用便器の排尿孔上に
載置し尿石等の付着状況を観察した。男子５０人が各人
１日４回として約２００回使用し２ケ月間試験を行った
が、排尿管内に尿石等の付着物質は認められなかった。The remaining solid deodorant was placed over the urinary hole of the urinal in the men's restroom, and the state of adhesion of urinary stones, etc. was observed. A test was conducted on 50 men who used the product approximately 200 times, four times a day, for two months, but no deposits such as urinary stones were found in the urinary tract.
なおこの便器は使用の都度水洗を行っている。またこの
際１０人のパネラ−により尿臭の判定を行ったところ固
形消臭剤を使用しない場合は尿臭が感知されたが、本発
明品を使用した場合は尿臭は殆んど感知されなかった。This toilet is flushed every time it is used. At this time, when 10 panelists judged urine odor, urine odor was detected when no solid deodorant was used, but when the product of the present invention was used, urine odor was hardly detected. There wasn't.
実施例２ Ａ：アルコール型ワックス（日本精蝋社製。Example 2 A: Alcohol-type wax (manufactured by Nippon Seirosha).
ＮＦＳ−９１２５） ７５ｇＢ：ポリエ
チレングリコール ２５ｇＣ：安定化二酸化塩素
水溶液（商品名オスロン。NFS-9125) 75gB: Polyethylene glycol 25gC: Stabilized chlorine dioxide aqueous solution (trade name Oslon).
ダイソー社製） １５ｇ上記Ａ、Ｂ、
Ｃを２００ｍｌのビーカーに計量し、これを６０℃に加
温されたウォーターバスに入れて溶融し、十分ブレンド
した後、ビーカーを水冷して固形化した。以下実施例と
同様な方法により濃度７０ｐｐｍの硫化水素ガス（標準
ガスＮ２基準）の試験を行ったところ、３０分後の硫化
水素濃度は０．５ ｐ ｐ ｍ以下であった。(manufactured by Daiso) 15g A, B above,
C was weighed into a 200 ml beaker, placed in a water bath heated to 60° C., melted, thoroughly blended, and then solidified by cooling the beaker with water. A test using hydrogen sulfide gas having a concentration of 70 ppm (standard gas N2 standard) was conducted in the same manner as in the example, and the hydrogen sulfide concentration after 30 minutes was 0.5 ppm or less.
また便器における尿石等の付着防止効果、防臭効果につ
いては実施例１と同様であった。Furthermore, the effect of preventing the adhesion of urinary stones and the like on the toilet bowl and the deodorizing effect were the same as in Example 1.
実施例３
実施例２の安定化二酸化塩素水溶液に代えて過マンガン
酸カリ１０ｇを使用した以外は全く同様にして固形消臭
剤を製造し同じ方法で同しく１度７０ｐｐｍの硫化水素
ガスの消臭試験を行ったところ、３０分後の硫化水素の
濃度は０．５ ｐ ｐ ｍ以下に低下した。Example 3 A solid deodorizer was produced in exactly the same manner except that 10 g of potassium permanganate was used in place of the stabilized chlorine dioxide aqueous solution in Example 2. When an odor test was conducted, the concentration of hydrogen sulfide decreased to 0.5 ppm or less after 30 minutes.
また便器における尿石等の付着防止効果、防臭効果につ
いても実施例１と同様であった。Further, the effect of preventing urinary stones from adhering to the toilet bowl and the effect of preventing deodorization were also the same as in Example 1.
本発明固形消臭剤はバラジクロルヘンゼンのような特異
な臭気を有することなくまた人体に対する有害性を考慮
する必要がないので、これに代る消臭剤として特に便器
の排尿部配管に対する尿石等の付着防止効果に優れてい
るという特徴があり、また長時間にわたって均一な消臭
効果が得られるので工業的に有用である。The solid deodorizer of the present invention does not have a unique odor like Balajichlorhenzene, and there is no need to consider its toxicity to the human body, so it can be used as an alternative deodorant especially for the urinary pipes of toilet bowls. It is industrially useful because it has an excellent effect of preventing the adhesion of urinary stones and the like, and also provides a uniform deodorizing effect over a long period of time.
Claims (5)
、可溶化剤と、消臭成分とを含むことを特徴とする固形
消臭剤。(1) A solid deodorant characterized by containing solid wax and/or thermoplastic polyester, a solubilizer, and a deodorizing component.
ンオキサイド、又はポリオキシエチレン・ポリオキシプ
ロピレン２・デシルテトラデシルエーテルである請求項
１に記載の固形消臭剤。(2) The solid deodorant according to claim 1, wherein the solubilizer is polyethylene glycol, polyethylene oxide, or polyoxyethylene/polyoxypropylene 2/decyltetradecyl ether.
可溶化剤及び消臭成分を加えて加熱溶融、混練すること
を特徴とする固形消臭剤の製法。(3) A method for producing a solid deodorant, which comprises adding a solubilizer and a deodorizing component to solid wax and/or thermoplastic polyester, heating and melting the mixture, and kneading the mixture.
臭剤。(4) The solid deodorant according to claim 1 or 2, which is shaped into a spherical shape.
器の排尿孔部に載置もしくは装着することを特徴とする
固形消臭剤の使用方法。(5) A method for using a solid deodorant, which comprises placing or attaching the solid deodorant according to claim 1, 2, or 4 to a urinary opening of a toilet bowl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2195955A JPH0640895B2 (en) | 1990-07-24 | 1990-07-24 | Solid deodorant and its manufacturing method and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2195955A JPH0640895B2 (en) | 1990-07-24 | 1990-07-24 | Solid deodorant and its manufacturing method and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0482560A true JPH0482560A (en) | 1992-03-16 |
| JPH0640895B2 JPH0640895B2 (en) | 1994-06-01 |
Family
ID=16349756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2195955A Expired - Lifetime JPH0640895B2 (en) | 1990-07-24 | 1990-07-24 | Solid deodorant and its manufacturing method and use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0640895B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040018669A (en) * | 2002-08-26 | 2004-03-04 | 제일모직주식회사 | Automobile Gel Type Air Freshener Composition |
-
1990
- 1990-07-24 JP JP2195955A patent/JPH0640895B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040018669A (en) * | 2002-08-26 | 2004-03-04 | 제일모직주식회사 | Automobile Gel Type Air Freshener Composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0640895B2 (en) | 1994-06-01 |
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