JPH05112406A - Preservative composition for wood - Google Patents
Preservative composition for woodInfo
- Publication number
- JPH05112406A JPH05112406A JP27403391A JP27403391A JPH05112406A JP H05112406 A JPH05112406 A JP H05112406A JP 27403391 A JP27403391 A JP 27403391A JP 27403391 A JP27403391 A JP 27403391A JP H05112406 A JPH05112406 A JP H05112406A
- Authority
- JP
- Japan
- Prior art keywords
- wood
- dmfc
- preservative composition
- composition
- preservative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000002023 wood Substances 0.000 title claims description 10
- 230000002335 preservative effect Effects 0.000 title abstract description 4
- 239000003755 preservative agent Substances 0.000 title description 4
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims abstract description 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims abstract description 3
- CEPZWWNWJNBTIM-UHFFFAOYSA-N (3-bromo-2,3-diiodoprop-2-enyl) ethyl carbonate Chemical compound CCOC(=O)OCC(I)=C(Br)I CEPZWWNWJNBTIM-UHFFFAOYSA-N 0.000 claims abstract 2
- 230000002421 anti-septic effect Effects 0.000 claims description 7
- -1 iodopropargyl Chemical group 0.000 claims description 7
- 239000003171 wood protecting agent Substances 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 3
- NMRDELHCVAOOPZ-UHFFFAOYSA-N 2,4-dimethyl-n-phenylfuran-3-carboxamide Chemical compound CC1=COC(C)=C1C(=O)NC1=CC=CC=C1 NMRDELHCVAOOPZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000002070 germicidal effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 5
- 230000002401 inhibitory effect Effects 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- GOSHEZZPLYXNIQ-UHFFFAOYSA-N (5-bromo-2,5-diiodopent-3-enyl) hydrogen carbonate Chemical compound C(C(C=CC(Br)I)I)OC(=O)O GOSHEZZPLYXNIQ-UHFFFAOYSA-N 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000222351 Pleurotus cornucopiae Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000002814 agar dilution Methods 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000007685 Pleurotus columbinus Nutrition 0.000 description 1
- 240000001462 Pleurotus ostreatus Species 0.000 description 1
- 235000001603 Pleurotus ostreatus Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000005822 Propiconazole Substances 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 1
- 229950000294 azaconazole Drugs 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- OJLOUXPPKZRTHK-UHFFFAOYSA-N dodecan-1-ol;sodium Chemical compound [Na].CCCCCCCCCCCCO OJLOUXPPKZRTHK-UHFFFAOYSA-N 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001965 potato dextrose agar Substances 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【０００２】[0002]
【産業上の利用分野】本発明は、木材用防腐組成物に関
する。TECHNICAL FIELD The present invention relates to an antiseptic composition for wood.
【０００３】更に詳しくは、２，５−ジメチルフラン−
３−カルボキシアニリド（以下、ＤＭＦＣと略す）並び
に、３−ブロモ−２，３−ジヨード−２−プロペニルエ
チルカーボネート（以下、サンプラスと略す）、３−ヨ
ード−２−プロピニルブチルカーバメート（以下、トロ
イサンと略す）及び４−クロルフェニル−３−ヨードプ
ロパルギルホルマール（以下、ＩＦ−１０００と略す）
より選ばれた１乃至３種を配合してなる、木材用防腐組
成物に関する。More specifically, 2,5-dimethylfuran-
3-carboxyanilide (hereinafter, abbreviated as DMFC), 3-bromo-2,3-diiodo-2-propenylethyl carbonate (hereinafter, abbreviated as Sampras), 3-iodo-2-propynylbutyl carbamate (hereinafter, Troysan) And 4-chlorophenyl-3-iodopropargylformal (hereinafter abbreviated as IF-1000).
The present invention relates to an antiseptic composition for wood, which comprises 1 to 3 selected from the above.
【０００４】[0004]
【従来の技術】種々の木材腐朽菌による腐朽を防ぐた
め、従来から各種の無機あるいは有機化合物が、木材防
腐剤として用いられる。しかし、従来の薬剤は毒性が高
く、人体の悪影響や環境汚染性を示したり、高濃度の使
用あるいは高価であること等の欠点を有している。2. Description of the Related Art In order to prevent decay by various wood-destroying fungi, various inorganic or organic compounds have been conventionally used as wood preservatives. However, conventional drugs have the drawbacks of being highly toxic, exhibiting adverse effects on the human body and environmental pollution, being used at high concentrations, and being expensive.
【０００５】このため、より一層効果が高く、安全で安
価な木材防腐剤の出現が望まれている。For this reason, the advent of a wood preservative that is even more effective, safe and inexpensive is desired.
【０００６】[0006]
【発明が解決しようとする課題】本発明者らは、よりす
ぐれた木材防腐剤について鋭意検討を重ねた結果、ＤＭ
ＦＣに、各単剤ともすでに殺菌効果の有ることが知られ
ているサンプラス、トロイサン、ＩＦ−１０００を配合
することにより、相剰的にすぐれた防腐効果を示すこと
を見出し、本発明を完成した。DISCLOSURE OF INVENTION Problems to be Solved by the Invention As a result of intensive investigations by the present inventors for a superior wood preservative, DM
It was found that FC has a superior antiseptic effect by adding Sampras, Troysan, and IF-1000, which are already known to have a bactericidal effect to each FC, and completed the present invention. did.
【０００７】[0007]
【０００８】[0008]
【課題を解決するための手段】本発明は、２，５−ジメ
チルフラン−３−カルボキシアニリド並びに、３−ブロ
モ−２，３−ジヨード−２−プロペニルエチルカーボネ
ート、３−ヨード−２−プロピニルブチルカーバメート
及び４−クロルフェニル−３−ヨードプロパルギルホル
マールより選ばれた１乃至３種を配合してなる、木材用
防腐組成物である。The present invention provides 2,5-dimethylfuran-3-carboxyanilide, 3-bromo-2,3-diiodo-2-propenylethyl carbonate and 3-iodo-2-propynylbutyl. A wood preservative composition comprising 1 to 3 kinds selected from carbamate and 4-chlorophenyl-3-iodopropargyl formal.
【０００９】本発明の組成物を使用する際の配合比は防
腐剤の処理対象となる樹種や木質材料の種類、あるいは
処理手段（例えば、塗布、浸漬、散布、注入、混合、接
着剤混入等）によって適宜選択しうるが、通常はＤＭＦ
Ｃと他剤との配合比は重量比で８０：１〜１：２０の範
囲が用いられ、好適には２０：１〜１：１０であり、更
に好適には４：１〜１：４である。The compounding ratio when the composition of the present invention is used is the kind of the tree species or woody material to be treated with the preservative, or the treatment means (for example, coating, dipping, spraying, pouring, mixing, admixing adhesive, etc.). ), But usually DMF
The compounding ratio of C and the other agent is 80: 1 to 1:20 by weight, preferably 20: 1 to 1:10, and more preferably 4: 1 to 1: 4. is there.
【００１０】本発明の木材用防腐組成物は、担体および
必要に応じて他の補助剤と混合して、木材防腐剤として
通常用いられる製剤形態、例えば油剤、乳剤、可溶化
剤、ペースト剤、水和剤、ドライフロアブル剤、噴霧剤
や塗料等に調製され、公知の木材防腐処理法により使用
される。The antiseptic composition for wood of the present invention is mixed with a carrier and, if necessary, other auxiliary agents, and has a formulation form usually used as an antiseptic wood, for example, oil, emulsion, solubilizer, paste, It is prepared as a wettable powder, a dry flowable agent, a spray, a paint, etc., and used by a known wood preservative treatment method.
【００１１】製剤の性状を改善し防腐効果を高めるため
適宜使用される補助剤としては、例えば陰イオン性、陽
イオン性、非イオン性の界面活性剤やメチルセルロー
ス、酢酸ビニール樹脂等の種々の高分子化合物、パラフ
ィン等の撥水剤などをあげることができる。もちろん、
アザコナゾール、プロピコナゾール、サイアベンダゾー
ル、ジクロフルアニド、アルキルアンモニウム系化合物
等の他の木材防腐・防カビ剤や、パーメスリン、サイパ
ーメスリン、エトフェンプロックス、トラロメスリン、
シラネオフェンのようなピレスロイド系化合物、クロル
ピリホス、ホキシム、フェニトロチオンのような有機リ
ン系化合物、カルバリルのようなカーバメート系化合
物、オクタクロロジプロピルエーテルのような他の木材
防虫剤とも混合し、併用することができ、それによって
一層の効果向上を図ることも可能である。Examples of the auxiliaries which are appropriately used to improve the properties of the preparation and enhance the antiseptic effect include various anionic, cationic and nonionic surfactants, methyl cellulose and vinyl acetate resin. Examples thereof include molecular compounds and water repellents such as paraffin. of course,
Azaconazole, propiconazole, siabendazole, diclofluanid, other wood preservatives and fungicides such as alkyl ammonium compounds, permethrin, cypermethrin, etofenprox, tralomesulin,
Pyrethroid compounds such as silaneofen, chlorpyrifos, phoxime, organophosphorus compounds such as fenitrothion, carbamate compounds such as carbaryl, and other wood insect repellents such as octachlorodipropyl ether can be mixed and used together. It is possible to further improve the effect.
【００１２】実際の使用に際しての本発明組成物の含量
は、製剤の形態に従い広い範囲にわたって変化させうる
が、一般には製剤中の０．１〜９５重量％、好適には
０．２〜６０重量％の範囲である。The content of the composition of the present invention in actual use can be varied over a wide range depending on the form of the preparation, but it is generally 0.1 to 95% by weight, preferably 0.2 to 60% by weight in the preparation. % Range.
【００１３】つぎに本発明の木材防腐組成物の効力を試
験例によって説明する。Next, the efficacy of the wood preservative composition of the present invention will be described with reference to test examples.
【００１４】[0014]
寒天希釈法による二元最小発育阻止濃度 寒天希釈法により、所定濃度に調製された薬剤を含む各
滅菌培地（ポテトデキストロース寒天培地：ポテト浸出
液末０．４％、グルコース２％、寒天１．５％）上に、
あらかじめ同様の培地上に生育させた木材腐朽菌カワラ
タケ、オオウズラタケおよびナミダタケの菌叢（約４ｍ
ｍ直径）を接種し、カワラタケおよびオオウズラタケで
は２５℃で５日間、ナミダタケでは２０℃で７日間培養
したのちの菌糸の生育状況から二元最小発育阻止濃度を
求めた。Binary minimum growth inhibitory concentration by agar dilution method Each sterilized medium containing the drug adjusted to a predetermined concentration by agar dilution method (potato dextrose agar medium: potato leachate 0.4%, glucose 2%, agar 1.5%) )above,
Flora of wood-rotting fungi Kawaratake, Pleurotus ostreatus and Namitake mushroom (about 4 m
m diameter) was inoculated and cultured at 25 ° C. for 5 days for Pleurotus cornucopia and Pleurotus cornucopiae for 7 days at 20 ° C. for Namitake mushroom.
【００１５】なお、相剰作用の有無は、すでにＦ．Ｃ．
ＫｕｌｌらによってＡｐｐｌｉｅｄＭｉｃｒｏｂｉｏｌ
ｏｇｙ ９ ５３８〜５４１（１９６１）に記載され、
現在一般に用いられている方法に基づいて検討した。The presence or absence of the reciprocal action has already been confirmed by F. C.
Applied Microbiol by Kull et al.
Ogy 9 538-541 (1961),
The examination was carried out based on the method generally used at present.
【００１６】まず、ＤＭＦＣにサンプラスを配合したと
きの結果を表１及び図１に、ＤＭＦＣにトロイサンを配
合したときの結果を表２及び図２に、ＤＭＦＣにＩＦ−
１０００を配合したときの結果を表３及び図３に示す。First, Table 1 and FIG. 1 show the results when DM + was mixed with Sampras, Table 2 and FIG. 2 show the results when DMOS was mixed with Troysan, and IF- was added to DMFC.
The results when 1000 is blended are shown in Table 3 and FIG.
【００１７】図１乃至図３に示した二元最小発育阻止濃
度曲線はいずれも破線で示した対角線よりも相当下方に
存在している。The binary minimum inhibitory concentration curves shown in FIGS. 1 to 3 are all located considerably below the diagonal line shown by the broken line.
【００１８】このことはサンプラス、トロイサンおよび
ＩＦ−１０００はいずれもＤＭＦＣに配合することによ
り相剰効果のあることを明白に示している。This clearly shows that Sampras, Troysan, and IF-1000 all have a summing effect by blending with DMFC.
【００１９】[0019]
【表１】 [Table 1]
【００２０】[0020]
【表２】 [Table 2]
【００２１】[0021]
【表３】 [Table 3]
【００２２】次に本発明組成物の若干の製剤例をあげる
が、配合量、補助剤の種類等は大幅に変更し得るもので
あることは云うまでもない。Next, some formulation examples of the composition of the present invention will be given, but it goes without saying that the compounding amount, the kind of auxiliary agent and the like can be changed greatly.
【００２３】[0023]
【製剤例１】 （乳剤）ＤＭＦＣを１０部およびサンプラスを３０部、
キシレン５０部に溶解させ、ポリオキシエチレンノニル
フェニルエーテル１０部を加えて十分に混合し乳剤を得
た。[Formulation Example 1] (Emulsion) 10 parts of DMFC and 30 parts of Sampras,
It was dissolved in 50 parts of xylene, 10 parts of polyoxyethylene nonyl phenyl ether was added and mixed well to obtain an emulsion.
【００２４】この乳剤は用時適量の水で希釈して、処理
すべき木質材料に塗布、浸漬、もしくはスプレー等の方
法で使用される他に、合板、パーティクルボード、ハー
ドボード等の接着剤に混入処理して使用できる。This emulsion is diluted with an appropriate amount of water at the time of use, and applied to a wood material to be treated by a method such as coating, dipping, or spraying, or as an adhesive for plywood, particle board, hard board, etc. Can be used after being mixed.
【００２５】[0025]
【製剤例２】 （油剤）ＤＭＦＣ３部およびトロイサン１部をケロシン
９６部に溶解させ油剤を得た。[Formulation Example 2] (Oil formulation) 3 parts of DMFC and 1 part of Troisan were dissolved in 96 parts of kerosene to obtain an oil formulation.
【００２６】[0026]
【製剤例３】 （水和剤）ＤＭＦＣ１５部、ＩＦ−１０００ ２５部、
クレー５６部、ラウリルアルコールスルホン酸ソーダ３
部およびポリビニルアルコール１部を混合機中で均一に
混合し、ハンマーミルで粉砕して水和剤を得た。[Formulation Example 3] (Wettable powder) DMFC 15 parts, IF-1000 25 parts,
56 parts of clay, sodium lauryl alcohol sulfonate 3
Parts and 1 part of polyvinyl alcohol were uniformly mixed in a mixer and ground with a hammer mill to obtain a wettable powder.
【００２７】[0027]
【図１】ＤＭＦＣにサンプラスを配合したときの結果を
グラフ（二元最小発育阻止濃度曲線）に表したものであ
る。FIG. 1 is a graph (binary minimum inhibitory concentration curve) showing the results when DMFC is blended with Sampras.
【図２】ＤＭＦＣにトロイサンを配合したときの結果を
グラフ（二元最小発育阻止濃度曲線）に表したものであ
る。FIG. 2 is a graph (binary minimum inhibitory concentration curve) showing the result when Troysan was mixed with DMFC.
【図３】ＤＭＦＣにＩＦ−１０００を配合したときの結
果をグラフ（二元最小発育阻止濃度曲線）に表したもの
である。FIG. 3 is a graph (binary minimum inhibitory concentration curve) showing the results when IF-1000 was added to DMFC.
─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成４年７月２４日[Submission date] July 24, 1992
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】図面[Document name to be corrected] Drawing
【補正対象項目名】図２[Name of item to be corrected] Figure 2
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【図２】 [Fig. 2]
Claims (1)
アニリド並びに、３−ブロモ−２，３−ジヨード−２−
プロペニルエチルカーボネート、３−ヨード−２−プロ
ピニルブチルカーバメート及び４−クロルフェニル−３
−ヨードプロパルギルホルマールより選ばれた１乃至３
種を配合してなる、木材用防腐組成物。1. 2,5-Dimethylfuran-3-carboxyanilide and 3-bromo-2,3-diiodo-2-
Propenyl ethyl carbonate, 3-iodo-2-propynyl butyl carbamate and 4-chlorophenyl-3
-1 to 3 selected from iodopropargyl formal
An antiseptic composition for wood, which comprises a seed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27403391A JP2951772B2 (en) | 1991-10-22 | 1991-10-22 | Wood preservative composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27403391A JP2951772B2 (en) | 1991-10-22 | 1991-10-22 | Wood preservative composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05112406A true JPH05112406A (en) | 1993-05-07 |
| JP2951772B2 JP2951772B2 (en) | 1999-09-20 |
Family
ID=17536029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27403391A Expired - Fee Related JP2951772B2 (en) | 1991-10-22 | 1991-10-22 | Wood preservative composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2951772B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0597336A1 (en) * | 1992-11-11 | 1994-05-18 | Bayer Ag | Use of furancarboxamides for the protection of materials |
| EP0755927A4 (en) * | 1994-04-15 | 1997-06-11 | Sankyo Co | Dimethylfurancarboxanilide derivative |
| US5977168A (en) * | 1994-04-15 | 1999-11-02 | Sankyo Company, Limited | Wood preservative compositions containing dimethylfurancarboxyanilide derivatives |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8785662B2 (en) | 2010-05-12 | 2014-07-22 | Sds Biotech K.K. | Anilide-based compounds for preserving wood and method of use thereof |
-
1991
- 1991-10-22 JP JP27403391A patent/JP2951772B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0597336A1 (en) * | 1992-11-11 | 1994-05-18 | Bayer Ag | Use of furancarboxamides for the protection of materials |
| EP0755927A4 (en) * | 1994-04-15 | 1997-06-11 | Sankyo Co | Dimethylfurancarboxanilide derivative |
| US5977168A (en) * | 1994-04-15 | 1999-11-02 | Sankyo Company, Limited | Wood preservative compositions containing dimethylfurancarboxyanilide derivatives |
| US6380247B2 (en) | 1994-04-15 | 2002-04-30 | Sankyo Company, Limited | Dimethylfurancarboxyanilide derivatives |
| US6506913B2 (en) | 1994-04-15 | 2003-01-14 | Sankyo Company, Limited | Dimethylfurancarboxyanilide derivatives |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2951772B2 (en) | 1999-09-20 |
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