JPH0513259A - Formation of mark of articles - Google Patents

Formation of mark of articles

Info

Publication number
JPH0513259A
JPH0513259A JP3162921A JP16292191A JPH0513259A JP H0513259 A JPH0513259 A JP H0513259A JP 3162921 A JP3162921 A JP 3162921A JP 16292191 A JP16292191 A JP 16292191A JP H0513259 A JPH0513259 A JP H0513259A
Authority
JP
Japan
Prior art keywords
mark
black
formation
capacitor
article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3162921A
Other languages
Japanese (ja)
Inventor
Koji Amano
弘司 天野
Seiichi Katsumata
誠一 勝俣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm Co Ltd
Original Assignee
Rohm Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm Co Ltd filed Critical Rohm Co Ltd
Priority to JP3162921A priority Critical patent/JPH0513259A/en
Publication of JPH0513259A publication Critical patent/JPH0513259A/en
Pending legal-status Critical Current

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  • Laser Beam Processing (AREA)
  • Details Of Resistors (AREA)

Abstract

PURPOSE:To provide a mark formation method which marks an article quickly and obtains a darkened mark without producing such defects as blur, stain, thinner, thicker and loss which are observed in the formation methods, such as mark formation by the application of ink, color mark formation by laser irradiation and surface roughened mark formation by laser irradiation. CONSTITUTION:A laminated ceramic capacitor 10 which a lead wire 20 is soldered with, is preheated and submerged in fine particle paint powder 40 which includess a coloring agent which is colored in black by laser irradiation and then it is coated with a paing film 50 with specified thickness and shape. After the coating, the paint film 50 is dried at a high temperature gaseous body and laser light L is applied to the coated side which forms a mark side of the capacitor 10 by way of a mask 60 having a specified mark pattern. As a result, the color agent in the paint film 50 is colored in black by the irradiation with the laser light L, thereby forming a black mark 70.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、プラスチック成形品、
注形品等の物品、特に積層セラミックコンデンサ、抵抗
器、ハイブリッドIC等の電子部品を対象とする標印形
成方法に関する。
The present invention relates to a plastic molded article,
The present invention relates to a marking forming method for an object such as a cast product, particularly for an electronic component such as a laminated ceramic capacitor, a resistor and a hybrid IC.

【0002】[0002]

【従来の技術】積層セラミックコンデンサ等の電子部品
には、個別識別として記号、マーク、数字等を標印して
あるが、この標印は、例えば積層セラミックコンデンサ
では次のように行う。まず、既知の方法で作製した積層
セラミックコンデンサの外部電極にリード線をはんだ接
合したものを余熱した後、フェノール樹脂又はエポキシ
樹脂、酸無水物、顔料、難燃剤からなる粉体塗料粉末中
に浸漬する。その後、コンデンサに付着した塗膜を高温
気体中で硬化させる。
2. Description of the Related Art Symbols, marks, numbers, etc. are marked as individual identifications on electronic parts such as monolithic ceramic capacitors. This marking is performed as follows, for example, in monolithic ceramic capacitors. First, after the lead wires are soldered to the external electrodes of the monolithic ceramic capacitor manufactured by a known method, after preheating, it is dipped in a powder coating powder consisting of a phenol resin or epoxy resin, an acid anhydride, a pigment, and a flame retardant. To do. Then, the coating film attached to the capacitor is cured in a high temperature gas.

【0003】次いで、黒色顔料、樹脂、溶媒からなるイ
ンクを硬化した塗装面に転写、スクリーン印刷又はロッ
ドプリンタで塗布して、黒色の標印を形成する(方法
A)。或いは、黄色酸化鉄系顔料を配合した粉体塗料粉
末中に、リード線付コンデンサを同様に余熱してから浸
漬した後、乾燥・硬化させた塗装面にレーザ光を照射し
て、前記酸化鉄系顔料の酸化により茶色の標印を施す
(方法B)。或いは、粉体塗料粉末中への余熱・浸漬に
よって得られる塗装面をレーザ光の照射で粗くし、表面
粗度の違いで標印を設ける(方法C)。
Then, an ink composed of a black pigment, a resin, and a solvent is transferred to the hardened coated surface, screen-printed or applied by a rod printer to form a black mark (method A). Alternatively, after preheating the capacitor with lead wire in a powder coating powder containing a yellow iron oxide pigment in the same manner and immersing it in the powder coating powder, irradiate the dried and hardened coated surface with laser light to produce the iron oxide. A brown marking is applied by oxidation of the system pigment (method B). Alternatively, the coated surface obtained by residual heat / immersion in the powder coating powder is roughened by laser light irradiation, and a mark is provided according to the difference in surface roughness (method C).

【0004】[0004]

【発明が解決しようとする課題】しかしながら、上記従
来のような標印方法A、Cによれば、インク量の変化、
レオロジーの変化、被印刷物の形状変化等により、標印
の掠れ、滲み、細り、太り、欠如等が発生する。或い
は、電子部品を基板に装着した後の溶剤洗浄により、標
印の剥離、標印中の成分(有機結合剤、顔料等)溶出に
よる標印の消失等が生ずることもある。更に、方法Aで
は標印形成に時間が掛かるという欠点もある。又、前記
方法Bのようにレーザ光の照射によって標印を発色させ
る方法では、これらの欠点は殆どみられないが、発色は
茶色や白色等であり、黒発色は得られない。
However, according to the conventional marking methods A and C, the change in ink amount,
Blurring, bleeding, thinning, thickening, lacking, etc. of the mark occur due to changes in rheology, changes in the shape of the material to be printed, and the like. Alternatively, the solvent may be washed after mounting the electronic component on the substrate, whereby the mark may be peeled off, or the mark may disappear due to elution of components (organic binder, pigment, etc.) in the mark. Further, the method A has a drawback that it takes time to form the mark. Further, in the method of coloring the mark by irradiating the laser beam like the method B, these defects are hardly seen, but the coloring is brown or white, and black coloring is not obtained.

【0005】従って、本発明の目的は、上記方法A、C
で起こる問題点や、方法Bでの黒色化できない現状に鑑
み、そのような問題点を生起させずに黒色標印が得られ
ると共に、標印スピードが早い標印形成方法を提供する
ことにある。
Therefore, the object of the present invention is to provide the above methods A and C.
In view of the problems that occur in No. 1 and the current situation where the method B cannot be blackened, a black mark can be obtained without causing such problems, and a mark forming method having a high marking speed is provided. .

【0006】[0006]

【課題を解決するための手段】前記目的を達成するため
に、本発明の物品の標印形成方法は、レーザ照射により
黒色に発色する発色剤を含有する粉体塗料粉末中に物品
を余熱してから浸漬し、得られた物品の塗膜を乾燥させ
た後、物品の標印形成面となる塗装面に対して、所定の
標印パターンを持つマスクを介してレーザ光を照射する
ことを特徴とするものである。
In order to achieve the above object, the method for forming a mark of an article of the present invention is to preheat an article in a powder coating powder containing a color former which develops black by laser irradiation. After soaking it, and drying the coating film of the obtained article, irradiate the laser beam through the mask with the predetermined marking pattern on the coating surface that becomes the marking forming surface of the article. It is a feature.

【0007】本発明の標印形成方法によれば、粉体塗料
粉末中に黒色発色剤を含有させてあるため、この塗料粉
末から得られる塗膜にマスクを介してレーザ光を照射す
ると、レーザ光による黒色発色剤の酸化又は還元作用に
よって塗装面の被照射部分のみが黒色に発色し、結果的
に所定パターンの標印が形成される。この黒色発色剤と
しては、レーザ光照射によって黒色化すれば特定され
ず、Pb、Cu等の塩が例示される。
According to the mark forming method of the present invention, since the black color former is contained in the powder coating powder, when a coating film obtained from this coating powder is irradiated with laser light through a mask, the laser light is emitted. Due to the oxidation or reduction action of the black color former by light, only the irradiated portion of the coated surface is colored black, and as a result, a mark having a predetermined pattern is formed. The black color-developing agent is not specified as long as it is blackened by laser light irradiation, and examples thereof include salts such as Pb and Cu.

【0008】[0008]

【実施例】以下、本発明の物品の標印形成方法を実施例
に基づいて説明する。図1〜図7にその工程を順に示
す。この実施例では、標印形成対象物品として積層セラ
ミックコンデンサを例にしてある。まず、図1におい
て、既知の方法で作製した積層セラミックコンデンサを
用意する。このコンデンサ10は、誘電体セラミック層
と内部電極層を交互に積層した積層体11の一対の端面
に外部電極12を設けたものである。このコンデンサ1
0の両外部電極12に、それぞれリード線20をはんだ
接合して、リード付積層セラミックコンデンサを得る
(図2参照)。
EXAMPLES The method for forming a mark of an article according to the present invention will be described below based on examples. 1 to 7 show the steps in order. In this embodiment, a monolithic ceramic capacitor is used as an example of the article for which the mark is to be formed. First, in FIG. 1, a monolithic ceramic capacitor manufactured by a known method is prepared. In this capacitor 10, external electrodes 12 are provided on a pair of end faces of a laminated body 11 in which dielectric ceramic layers and internal electrode layers are alternately laminated. This capacitor 1
Lead wires 20 are soldered to both outer electrodes 12 of 0 to obtain a laminated ceramic capacitor with leads (see FIG. 2).

【0009】次に、着色顔料及び体質顔としてのTiO
2 、シアニンブルー、SiO2 、難燃性樹脂としての臭
素化エポキシ樹脂、及びSb、前記黒色発色剤を5〜2
0%、更に硬化剤としての酸無水物等からなる粉体塗料
粉末を調製する。この粉体塗料粉末の軟化点以上(本例
では80〜150℃)にコンデンサ10を適当なヒータ
30によって余熱する(図3参照)。その後、粉体塗料
粉末40中に余熱したコンデンサ10を浸漬する(図4
参照)。この浸漬時に、コンデンサ10周辺の塗料粉末
40がコンデンサの余熱によって軟化して粘着性を有す
るようになり、コンデンサ10の表面に付着する。この
余熱・浸漬は、塗膜が所要の厚さ(例えば1000μm
程度)と形状になるまで繰り返す。
Next, a coloring pigment and TiO as a constitutional face.
2 , cyanine blue, SiO 2 , brominated epoxy resin as a flame-retardant resin, and Sb, the black color former 5 to 2
A powder coating powder consisting of 0% and an acid anhydride as a curing agent is prepared. The capacitor 10 is preheated by an appropriate heater 30 to a temperature above the softening point of the powder coating powder (80 to 150 ° C. in this example) (see FIG. 3). Then, the preheated capacitor 10 is immersed in the powder coating powder 40 (FIG. 4).
reference). During this immersion, the paint powder 40 around the capacitor 10 is softened by the residual heat of the capacitor and becomes sticky, and adheres to the surface of the capacitor 10. This residual heat / immersion causes the coating film to have a required thickness (for example, 1000 μm).
Repeat) until the shape is reached.

【0010】そして、塗膜を形成したコンデンサ10を
120〜250℃で3分間以上加熱する。加熱により、
塗膜中の臭素化エポキシ樹脂のエポキシ基と酸無水物と
が反応し、臭素化エポキシ樹脂が高分子化し、不溶・不
融の外装塗膜50が積層体11、外部電極12及びリー
ド線20の一部分に形成される(図5参照)。なお、本
実施例において、粉体塗料粉末に含まれる顔料は既知の
顔料を使用してもよく、樹脂についてもビスフェノール
型エポキシ樹脂又はフェノール樹脂でもよく、これらの
樹脂を用いる場合は難燃性を付与するために難燃剤を別
途添加する。
Then, the coated capacitor 10 is heated at 120 to 250 ° C. for 3 minutes or more. By heating
The epoxy group of the brominated epoxy resin in the coating film reacts with the acid anhydride, the brominated epoxy resin polymerizes, and the insoluble / non-melting exterior coating film 50 forms the laminate 11, the external electrode 12, and the lead wire 20. Is formed on a part of the (see FIG. 5). In this example, the pigment contained in the powder coating powder may be a known pigment, and the resin may be a bisphenol type epoxy resin or a phenol resin. A flame retardant is added separately to impart.

【0011】その後、図6に示すように、記号、マー
ク、数字等の所定の標印パターンを有するマスク60
を、コンデンサ10の標印形成面の前方に一定間隔を置
いて配し、出力3J以上のCO2 レーザLをマスク60
に向かって照射する。この結果、マスク60は標印パタ
ーンが切抜き部分になっているので、パターン通りにレ
ーザLが塗装面に当たり、この塗装面に所定の標印70
が形成される(図7参照)。この時、塗膜50中の黒色
発色剤がレーザ光によって黒色に発色するため、黒色の
標印が得られる。又、レーザ照射による触刻の深さは精
精1〜10μmであり、塗膜50の厚さ1000μmに
比べ僅少であり、コンデンサ10自体には全く影響しな
い。更に、コンデンサの性能、例えば耐溶剤性(アセト
ン、1・1・1トリクロールエタンへの5分間浸漬によ
る溶剤洗浄)、静電容量、誘電正接、絶縁抵抗等には全
く問題は発生しない。
Thereafter, as shown in FIG. 6, a mask 60 having a predetermined marking pattern such as symbols, marks and numbers.
Are arranged in front of the mark forming surface of the condenser 10 at a constant interval, and a CO 2 laser L having an output of 3 J or more is masked by the mask 60.
Irradiate toward. As a result, the marking pattern of the mask 60 is the cutout portion, so the laser L hits the coating surface according to the pattern, and the predetermined marking 70 is applied to this coating surface.
Are formed (see FIG. 7). At this time, the black color-developing agent in the coating film 50 is colored black by the laser light, so that a black mark is obtained. Further, the depth of touching by laser irradiation is 1 to 10 μm, which is smaller than the thickness of the coating film 50 of 1000 μm, and does not affect the capacitor 10 at all. Further, there is no problem at all with respect to the performance of the capacitor, such as solvent resistance (solvent cleaning by immersion in acetone, 1.1.1 / 1 trichloroethane for 5 minutes), capacitance, dielectric loss tangent, insulation resistance and the like.

【0012】上記実施例は、積層セラミックコンデンサ
に関するものであるが、本発明の形成方法はこれに限定
されないことは言うまでもなく、コンデンサ以外の電子
部品、例えば抵抗器、ハイブリッドIC等に対しても同
様に行うことができるだけでなく、プラスチック成形
品、注形品等の物品にも適用可能である。
Although the above embodiments relate to a monolithic ceramic capacitor, it goes without saying that the forming method of the present invention is not limited to this, and the same applies to electronic parts other than capacitors, such as resistors and hybrid ICs. In addition to the above, it can be applied to articles such as plastic molded products and cast products.

【0013】[0013]

【発明の効果】本発明の物品の標印形成方法は、以上説
明したように構成されるので、下記の効果を有する。 (1)前記従来の方法Aのように有機物のインクを塗布
するのではなく、粉体塗料粉末中への余熱・浸漬によっ
て塗膜を施し、この塗膜に標印を形成するので、標印形
成後に行う溶剤洗浄に対する耐溶剤性が向上する。 (2)掠れ、滲み、細り、太り、欠損等の不都合が生じ
ない、寸法精度の良い標印が得られる。 (3)標印スピードが、例えば従来の転写方法による6
00個/分に比べて、1000個/分以上と格段に早
い。 (4)粉体塗料粉末中に有機溶剤を使用しないため、火
災の心配がない。 (5)標印がその方法上安定して形成されるため、標印
形成工程を他の工程の加工機に併合できる等、標印形成
工程での監視要員を削減できる。
The method for forming a mark of an article according to the present invention is configured as described above and therefore has the following effects. (1) Instead of applying an organic ink as in the conventional method A, a coating film is formed by residual heat / immersion in powder coating powder, and a mark is formed on this coating film. The solvent resistance to solvent cleaning performed after formation is improved. (2) It is possible to obtain a mark with good dimensional accuracy without causing inconveniences such as blurring, bleeding, thinning, thickening, and loss. (3) The marking speed is, for example, 6 according to the conventional transfer method.
Remarkably faster than 1000 pieces / minute compared to 00 pieces / minute. (4) Since no organic solvent is used in the powder coating powder, there is no risk of fire. (5) Since the mark is stably formed in terms of its method, it is possible to reduce the number of monitoring personnel in the mark forming process, such as the mark forming process can be combined with the processing machine of another process.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の標印形成方法の一例に係る第一段階の
工程図である。
FIG. 1 is a process drawing of a first stage according to an example of a mark forming method of the present invention.

【図2】本発明の標印形成方法の一例に係る第二段階の
工程図である。
FIG. 2 is a process drawing of the second stage according to an example of the mark forming method of the present invention.

【図3】本発明の標印形成方法の一例に係る第三段階の
工程図である。
FIG. 3 is a process drawing of a third step according to an example of the mark forming method of the present invention.

【図4】本発明の標印形成方法の一例に係る第四段階の
工程図である。
FIG. 4 is a process drawing of the fourth step according to an example of the mark forming method of the present invention.

【図5】図4に示す浸漬工程で得られたコンデンサの外
観図である。
5 is an external view of a capacitor obtained in the dipping process shown in FIG.

【図6】本発明の標印形成方法の一例に係る第五段階の
工程図である。
FIG. 6 is a process drawing of the fifth step according to an example of the mark forming method of the present invention.

【図7】図6に示すレーザ光照射工程で得られたコンデ
ンサの外観図である。
7 is an external view of a capacitor obtained in the laser light irradiation step shown in FIG.

【符号の説明】[Explanation of symbols]

10 積層セラミックコンデンサ 11 積層体 12 外部電極 20 リード線 30 ヒータ 40 粉体塗料粉末 50 塗膜 60 マスク 70 標印 L レーザ光 10 Multilayer ceramic capacitors 11 laminate 12 external electrodes 20 lead wires 30 heater 40 powder coating powder 50 coatings 60 mask 70 Mark L laser light

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】レーザ照射により黒色に発色する発色剤を
含有する粉体塗料粉末中に物品を余熱してから浸漬し、
得られた物品の塗膜を乾燥させた後、物品の標印形成面
となる塗装面に対して、所定の標印パターンを持つマス
クを介してレーザ光を照射することを特徴とする物品の
標印形成方法。
1. An article is preheated and immersed in a powder coating powder containing a color-developing agent that develops black color by laser irradiation,
After drying the coating film of the obtained article, the coated surface to be the mark forming surface of the article is irradiated with laser light through a mask having a predetermined mark pattern. Mark formation method.
【請求項2】前記物品が電子部品であることを特徴とす
る請求項1記載の物品の標印形成方法。
2. The method for forming a mark on an article according to claim 1, wherein the article is an electronic component.
JP3162921A 1991-07-03 1991-07-03 Formation of mark of articles Pending JPH0513259A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3162921A JPH0513259A (en) 1991-07-03 1991-07-03 Formation of mark of articles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3162921A JPH0513259A (en) 1991-07-03 1991-07-03 Formation of mark of articles

Publications (1)

Publication Number Publication Date
JPH0513259A true JPH0513259A (en) 1993-01-22

Family

ID=15763769

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3162921A Pending JPH0513259A (en) 1991-07-03 1991-07-03 Formation of mark of articles

Country Status (1)

Country Link
JP (1) JPH0513259A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001358414A (en) * 2000-06-16 2001-12-26 Ibiden Co Ltd Printed wiring board and method of manufacturing the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55110001A (en) * 1979-02-16 1980-08-25 Hitachi Ltd Method of marking electronic part
JPS61283101A (en) * 1985-06-07 1986-12-13 株式会社村田製作所 Impartment of display to electronic component
JPS6489508A (en) * 1987-09-30 1989-04-04 Murata Manufacturing Co Method of imparting display to electronic component

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55110001A (en) * 1979-02-16 1980-08-25 Hitachi Ltd Method of marking electronic part
JPS61283101A (en) * 1985-06-07 1986-12-13 株式会社村田製作所 Impartment of display to electronic component
JPS6489508A (en) * 1987-09-30 1989-04-04 Murata Manufacturing Co Method of imparting display to electronic component

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001358414A (en) * 2000-06-16 2001-12-26 Ibiden Co Ltd Printed wiring board and method of manufacturing the same

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