JPH05209078A - ウレタン基あるいはウレタン基およびイソシアヌレート基を含有する硬質発泡体の製造方法および発泡剤を含有するこのための乳濁液 - Google Patents

ウレタン基あるいはウレタン基およびイソシアヌレート基を含有する硬質発泡体の製造方法および発泡剤を含有するこのための乳濁液

Info

Publication number
JPH05209078A
JPH05209078A JP4171340A JP17134092A JPH05209078A JP H05209078 A JPH05209078 A JP H05209078A JP 4171340 A JP4171340 A JP 4171340A JP 17134092 A JP17134092 A JP 17134092A JP H05209078 A JPH05209078 A JP H05209078A
Authority
JP
Japan
Prior art keywords
weight
parts
vinyl
agent
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP4171340A
Other languages
English (en)
Japanese (ja)
Inventor
Otto Volkert
オットー、フォルケルト
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JPH05209078A publication Critical patent/JPH05209078A/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C08J2203/144—Perhalogenated saturated hydrocarbons, e.g. F3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/146—Saturated hydrocarbons containing oxygen and halogen atoms, e.g. F3C-O-CH2-CH3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/91—Plural blowing agents for producing nonpolyurethane cellular products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Cosmetics (AREA)
JP4171340A 1991-06-27 1992-06-29 ウレタン基あるいはウレタン基およびイソシアヌレート基を含有する硬質発泡体の製造方法および発泡剤を含有するこのための乳濁液 Withdrawn JPH05209078A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4121161.8 1991-06-27
DE4121161A DE4121161A1 (de) 1991-06-27 1991-06-27 Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen und treibmittel enthaltende emulsionen hierfuer

Publications (1)

Publication Number Publication Date
JPH05209078A true JPH05209078A (ja) 1993-08-20

Family

ID=6434819

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4171340A Withdrawn JPH05209078A (ja) 1991-06-27 1992-06-29 ウレタン基あるいはウレタン基およびイソシアヌレート基を含有する硬質発泡体の製造方法および発泡剤を含有するこのための乳濁液

Country Status (9)

Country Link
US (3) US5205956A (fr)
EP (1) EP0523398B1 (fr)
JP (1) JPH05209078A (fr)
KR (1) KR930000561A (fr)
AT (1) ATE146204T1 (fr)
CA (1) CA2070209C (fr)
DE (2) DE4121161A1 (fr)
DK (1) DK0523398T3 (fr)
ES (1) ES2095354T3 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
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JPH05279653A (ja) * 1991-06-27 1993-10-26 Elf Atochem Sa ポリマーフォーム用の発泡剤及び/または断熱ガスとしての(ペルフルオロアルキル)エチレンの適用
JPH09124760A (ja) * 1995-11-02 1997-05-13 Sanyo Chem Ind Ltd 硬質ポリイソシアヌレートフォームの製造法
JP2015212387A (ja) * 2006-03-21 2015-11-26 ハネウェル・インターナショナル・インコーポレーテッド 発泡剤並びにフッ素置換されたオレフィンおよびエーテルを含む組成物、および発泡方法
JP2016500584A (ja) * 2012-09-28 2016-01-14 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 複合プロフィールを製造するための方法

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BE1005181A3 (fr) * 1991-08-19 1993-05-18 Solvay Compositions comprenant un ether fluore et utilisation de ces compositions.
WO1994020587A1 (fr) * 1993-03-02 1994-09-15 E.I. Du Pont De Nemours And Company Compositions comprenant un hexafluoropropane
US5611210A (en) * 1993-03-05 1997-03-18 Ikon Corporation Fluoroiodocarbon blends as CFC and halon replacements
US5278196A (en) * 1993-03-25 1994-01-11 Great Lakes Chemical Corp. Hydrofluorocarbon compositions as blowing agents for cellular plastics
US5494601A (en) * 1993-04-01 1996-02-27 Minnesota Mining And Manufacturing Company Azeotropic compositions
EP0638607B1 (fr) * 1993-08-10 1999-07-14 Matsushita Electric Industrial Co., Ltd. Isolant thermique et son procédé de préparation
US5539006A (en) * 1993-12-15 1996-07-23 Bayer Corporation Rigid foams with improved insulation and physical properties
US5539008A (en) * 1993-12-29 1996-07-23 Minnesota Mining And Manufacturing Company Foamable composition containing unsaturated perfluorochemical blowing agent
US5530035A (en) * 1994-06-15 1996-06-25 General Electric Company Method of preparing polyurethane foam of low thermal conductivity
KR0180613B1 (en) * 1994-09-07 1999-05-15 Matsushita Electric Industrial Co Ltd Thermal insulating foamed material and method for manufacturing the same
WO1996012759A2 (fr) * 1994-10-20 1996-05-02 The Dow Chemical Company Procede de preparation de mousse de polyurethane en presence d'un hydrocarbure servant d'agent gonflant
US5762822A (en) * 1994-12-29 1998-06-09 Basf Corporation Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture
US5786398A (en) * 1995-03-24 1998-07-28 Owens-Corning Fiberglas Technology Inc. Manufacture of insulating foams containing film forming additives
US20030158277A1 (en) * 1995-07-03 2003-08-21 Blanpied Robert H. Method of producing rigid foams and products produced therefrom
US6306919B1 (en) 1995-07-03 2001-10-23 Exxonmobil Chemical Patents, Inc. Thermosetting plastic foam
US6117917A (en) * 1999-04-12 2000-09-12 Elf Atochem North America, Inc. Blowing agent blends and use thereof
US6586487B1 (en) * 2000-07-12 2003-07-01 Bayer Corporation Low-density, water blown polyurethane foams for energy-absorbing applications
US20040126564A1 (en) * 2000-11-15 2004-07-01 Atlas Roofing Corporation Thermosetting plastic foams and methods of production thereof using adhesion additives
US6866923B2 (en) * 2000-11-15 2005-03-15 Atlas Roofing Corporation Thermosetting plastic foams and methods of production thereof using adhesion additives
US20040224141A1 (en) * 2001-11-02 2004-11-11 Seiling Kevin A. Composite decking
DE10218696A1 (de) * 2002-04-26 2003-11-27 Moellertech Gmbh Verfahren zur Herstellung eines schäumbaren Kunststoffes
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
PT2277972T (pt) * 2002-10-25 2019-06-11 Honeywell Int Inc Composições contendo olefinas substituídas por flúor
US20050269549A1 (en) * 2004-06-02 2005-12-08 Jinhuang Wu Polyol premixes incorporating trans-1, 2-dichloroethylene
WO2006030946A1 (fr) * 2004-09-13 2006-03-23 Kureha Corporation Microsphere a moussage thermique, procede pour la produire, utilisation de celle-ci, composition la contenant et article correspondant
TWI482748B (zh) * 2005-06-24 2015-05-01 Honeywell Int Inc 含有經氟取代之烯烴之組合物
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ATE440894T1 (de) * 2006-01-06 2009-09-15 Supresta Llc Nicht halogene, flammhemmende zusätze zur verwendung in festem polyurethanschaum
FR2899234B1 (fr) * 2006-03-31 2017-02-17 Arkema Composition d'agent d'expansion
US8580864B2 (en) 2006-05-04 2013-11-12 Air Products And Chemicals, Inc. Trimer catalysts with improved processability and surface cure
JP5763338B2 (ja) 2007-03-29 2015-08-12 アーケマ・インコーポレイテッド ヒドロフルオロオレフィンとヒドロクロロフルオロオレフィンの発泡剤組成物
US8053485B2 (en) 2007-11-08 2011-11-08 Sika Technology Ag Polyurethane foam
JP4691683B2 (ja) * 2009-06-02 2011-06-01 モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 ポリウレタン発泡組成物およびポリウレタンフォームの製造方法
US9481759B2 (en) 2009-08-14 2016-11-01 Boral Ip Holdings Llc Polyurethanes derived from highly reactive reactants and coal ash
US8846776B2 (en) 2009-08-14 2014-09-30 Boral Ip Holdings Llc Filled polyurethane composites and methods of making same
CN103717656B (zh) 2011-08-01 2016-03-23 巴斯夫欧洲公司 Hfo/水发泡的硬质泡沫体系
WO2013026813A1 (fr) 2011-08-23 2013-02-28 Basf Se Microémulsions
CA2851349C (fr) 2011-10-07 2020-01-21 Russell L. Hill Composites de polymere inorganique/polymere organique et procedes pour les preparer
WO2014168633A1 (fr) 2013-04-12 2014-10-16 Boral Ip Holdings (Australia) Pty Limited Composites formés à partir d'une charge absorbante et d'un polyuréthane
WO2015042300A1 (fr) 2013-09-19 2015-03-26 Dow Global Technologies Llc Procédé assisté par dépression pour fabriquer des mousses de polyuréthane rigides à cellules fermées à l'aide d'un mélange d'agents d'expansion
EP2886591A1 (fr) 2013-12-19 2015-06-24 Evonik Industries AG Composition, appropriée à la fabrication de mousses polyuréthane, contenant au moins un agent de nucléation
US10138341B2 (en) 2014-07-28 2018-11-27 Boral Ip Holdings (Australia) Pty Limited Use of evaporative coolants to manufacture filled polyurethane composites
US9752015B2 (en) 2014-08-05 2017-09-05 Boral Ip Holdings (Australia) Pty Limited Filled polymeric composites including short length fibers
US9988512B2 (en) 2015-01-22 2018-06-05 Boral Ip Holdings (Australia) Pty Limited Highly filled polyurethane composites
US10030126B2 (en) 2015-06-05 2018-07-24 Boral Ip Holdings (Australia) Pty Limited Filled polyurethane composites with lightweight fillers
US20170267585A1 (en) 2015-11-12 2017-09-21 Amitabha Kumar Filled polyurethane composites with size-graded fillers
CA3168221C (fr) 2015-12-08 2026-05-19 Amrize Technology Switzerland Llc Procede de fabrication de panneaux de construction en mousse a base d'isocyanate
CA3034242C (fr) 2016-08-19 2021-04-06 Firestone Building Products Company, Llc Procede de production de panneaux de construction en mousse a base d'isocyanate
EP3583161B1 (fr) * 2017-02-17 2021-09-01 Zephyros Inc. Composition polymère activable comprenant au moins deux acides carboxyliques comme agents de soufflage
CN109679130B (zh) * 2017-10-19 2021-09-07 山东理工大学 包含六氟丁烯和有机醇胺盐化合物的复合发泡剂
US12291620B2 (en) 2017-12-04 2025-05-06 Holcim Technology Ltd Isocyanate-based foam construction boards
US10870987B1 (en) 2017-12-04 2020-12-22 Firestone Building Products Company, Llc Isocyanate-based foam construction boards
US12509566B2 (en) * 2020-02-04 2025-12-30 The Chemours Company Fc, Llc Nucleating agents for PIR foams
CN115814325B (zh) * 2022-11-23 2024-04-19 浙江工业大学 一种含氟灭火剂组合物

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FR2678279B1 (fr) * 1991-06-27 1993-09-03 Atochem Application de (perfluoroalkyl)-ethylenes comme agents d'expansion et/ou gaz d'isolation pour mousses de polymeres.
US5166182A (en) * 1992-03-23 1992-11-24 Atlas Roofing Corporation Thermosetting plastic foams and methods of production thereof using novel blowing agents

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05279653A (ja) * 1991-06-27 1993-10-26 Elf Atochem Sa ポリマーフォーム用の発泡剤及び/または断熱ガスとしての(ペルフルオロアルキル)エチレンの適用
JPH09124760A (ja) * 1995-11-02 1997-05-13 Sanyo Chem Ind Ltd 硬質ポリイソシアヌレートフォームの製造法
JP2015212387A (ja) * 2006-03-21 2015-11-26 ハネウェル・インターナショナル・インコーポレーテッド 発泡剤並びにフッ素置換されたオレフィンおよびエーテルを含む組成物、および発泡方法
JP2017078176A (ja) * 2006-03-21 2017-04-27 ハネウェル・インターナショナル・インコーポレーテッド 発泡剤並びにフッ素置換されたオレフィンおよびエーテルを含む組成物、および発泡方法
JP2018159074A (ja) * 2006-03-21 2018-10-11 ハネウェル・インターナショナル・インコーポレーテッドHoneywell International Inc. 発泡剤並びにフッ素置換されたオレフィンおよびエーテルを含む組成物、および発泡方法
JP2016500584A (ja) * 2012-09-28 2016-01-14 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 複合プロフィールを製造するための方法

Also Published As

Publication number Publication date
ATE146204T1 (de) 1996-12-15
DE59207652D1 (de) 1997-01-23
CA2070209A1 (fr) 1992-12-28
ES2095354T3 (es) 1997-02-16
EP0523398B1 (fr) 1996-12-11
DE4121161A1 (de) 1993-01-07
US5205956A (en) 1993-04-27
CA2070209C (fr) 1997-05-13
DK0523398T3 (da) 1996-12-30
US5278195A (en) 1994-01-11
KR930000561A (ko) 1993-01-15
EP0523398A1 (fr) 1993-01-20
US5300534A (en) 1994-04-05

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