JPH0533157B2 - - Google Patents
Info
- Publication number
- JPH0533157B2 JPH0533157B2 JP59234402A JP23440284A JPH0533157B2 JP H0533157 B2 JPH0533157 B2 JP H0533157B2 JP 59234402 A JP59234402 A JP 59234402A JP 23440284 A JP23440284 A JP 23440284A JP H0533157 B2 JPH0533157 B2 JP H0533157B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- synthetic paper
- image receptor
- resin layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5209—Coatings prepared by radiation-curing, e.g. using photopolymerisable compositions
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、熱転写による記録に用いられる熱転
写記録用受像体に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a thermal transfer recording image receptor used for thermal transfer recording.
従来の技術
熱転写による記録方法の中で特に昇華性染料を
用いた昇華転写方式は、階調の優れた印刷並の画
質を与える。この画質は転写体のみならず受像体
の品質にも大きく影響され、アート紙等のセルロ
ース原料の紙より合成紙がよい画質を与える。中
でも、我々の検討の結果では、フイルムの内部に
空孔（ボイド）を形成して擬紙化したポリプロピ
レン系合成紙〔例えば、商品名：ユポ、王子油化
合成紙(株)〕が優れた特性を示すことが解つた。BACKGROUND OF THE INVENTION Among thermal transfer recording methods, a sublimation transfer method using a sublimable dye provides image quality with excellent gradation comparable to that of printing. This image quality is greatly influenced not only by the quality of the transfer body but also by the quality of the image receptor, and synthetic paper provides better image quality than paper made from cellulose such as art paper. Among these, our results show that polypropylene-based synthetic paper (for example, product name: Yupo, manufactured by Oji Yuka Synthetic Paper Co., Ltd.), which is made of pseudopaper by forming voids inside the film, is superior. It was found that these characteristics were exhibited.
発明が解決しようとする問題点
しかし、このポリプロピレン系合成紙は、空孔
を作製するために延伸していること、又、ポリプ
ロピレンの耐熱性が低いため、昇華転写方式や高
エネルギー記録に用いると熱により収縮してカー
ルを発生するため取扱いが困難になる。Problems to be Solved by the Invention However, this polypropylene-based synthetic paper is stretched to create pores, and polypropylene has low heat resistance, so it cannot be used for sublimation transfer methods or high-energy recording. It shrinks and curls due to heat, making it difficult to handle.
本発明は、カールがなく取扱いの容易な受像体
を得ることを目的とする。 An object of the present invention is to obtain an image receptor that does not curl and is easy to handle.
問題点を解決するための手段
基材としてポリプロピレン系合成紙を用い、前
記基材の少なくとも片面に硬化性樹脂の硬化樹脂
層を設け、前記硬化樹脂層上に染着層を設けた熱
転写記録用受像体を構成する。Means for Solving the Problems A thermal transfer recording device using polypropylene synthetic paper as a base material, providing a cured resin layer of a curable resin on at least one side of the base material, and providing a dyeing layer on the cured resin layer. Constitutes an image receptor.
作 用
硬化樹脂層を設けることによつて合成紙に耐熱
性が付与され、合成紙のカールが防止される。Effect By providing the cured resin layer, heat resistance is imparted to the synthetic paper and curling of the synthetic paper is prevented.
又、硬化性樹脂は硬化時に収縮するためこの効
果もカール防止に有効と考えられる。 Furthermore, since the curable resin contracts during curing, this effect is also considered to be effective in preventing curling.
実施例
第１図に本発明の一実施例である受像体の断面
模式図を示す。ポリプロピレン系合成紙である基
材４上に硬化樹脂層５と染着層６とが順次積層に
構成されている。染着層６は染料に対し染着性を
示す組成物であれば特に限定されるものでなく、
例えば、シリカのような顕色性粒子を含む高分子
組成物、あるいは分散染料に対して染着性を示す
ポリエステル樹脂、エポキシ樹脂等を含む高分子
組成物等がある。Embodiment FIG. 1 shows a schematic cross-sectional view of an image receptor that is an embodiment of the present invention. A cured resin layer 5 and a dyeing layer 6 are sequentially laminated on a base material 4 which is polypropylene synthetic paper. The dyeing layer 6 is not particularly limited as long as it is made of a composition that exhibits dyeability.
For example, there are polymer compositions containing color developer particles such as silica, or polymer compositions containing polyester resins, epoxy resins, etc. that exhibit dyeability to disperse dyes.
硬化樹脂層５の表面を粗面５ａとして、染着層
６との密着性を高めることも有効である。 It is also effective to make the surface of the cured resin layer 5 a rough surface 5a to improve its adhesion to the dyeing layer 6.
基材のポリプロピレン系合成紙は、合成紙の製
法として知られるフイルム法合成紙とフアイバー
法合成紙から区分すると前者の分類に入り、ポリ
プロピレン樹脂を主成分とする組成物をダイ・ス
リツトから押し出し、さらに、冷延伸あるいは熱
延伸して作製されるものである。この合成紙は内
部紙化方式といわれ、フイルムの内部に空孔（ボ
イド）が形成されている。 Polypropylene-based synthetic paper as a base material falls into the former category when divided into film-process synthetic paper and fiber-process synthetic paper, both of which are known synthetic paper manufacturing methods. Furthermore, it is produced by cold stretching or hot stretching. This synthetic paper is called an internal paper type, and voids are formed inside the film.
硬化性樹脂とは、熱、波動エネルギーあるい
は、粒子線硬化性樹脂である。 The curable resin is a heat, wave energy, or particle beam curable resin.
例えば、各種エポキシ樹脂、シリコーン樹脂、
フエノール樹脂、キシレン樹脂、ユリア樹脂、メ
ラミン樹脂、不飽和ポリエステル樹脂、アルキド
樹脂、フラン樹脂、オリゴアクリレート、アクリ
レートモノマー等を用いることができる。 For example, various epoxy resins, silicone resins,
Phenol resins, xylene resins, urea resins, melamine resins, unsaturated polyester resins, alkyd resins, furan resins, oligoacrylates, acrylate monomers, and the like can be used.
特に、オリゴアクリレートとして、例えば、ポ
リオールアクリレート、ポリエステルアクリレー
ト、エポキシアクリレート、ウレタンアクリレー
ト、シリコーンアクリレート、ポリアセタールの
アクリレート等がある。 In particular, oligoacrylates include, for example, polyol acrylates, polyester acrylates, epoxy acrylates, urethane acrylates, silicone acrylates, polyacetal acrylates, and the like.
オリゴアクリレートには、テトラヒドロフルフ
リルアクリレート、ラウリルメタクリレート等の
アクリレートモノマーを添加して用いることもで
きる。オリゴアクリレートは放射線、あるいはベ
ンゾイルパーオキサイド等の硬化触媒、ベンゾフ
エノン等の増感剤を用いて加熱あるいは紫外線に
より硬化させて用いることができる。 Acrylate monomers such as tetrahydrofurfuryl acrylate and lauryl methacrylate can also be added to the oligoacrylate. Oligoacrylates can be cured by radiation, heating using a curing catalyst such as benzoyl peroxide, a sensitizer such as benzophenone, or ultraviolet rays.
エポキシ樹脂の中でも環状脂肪族エポキシ樹脂
は、テトラエチレンペンタミン等の硬化剤を用い
て熱硬化あるいは芳香族ジアゾニウム塩、芳香族
ヨードニウム塩、芳香族スルホニウム塩等の重合
開始剤を用いて紫外線硬化させて使用することが
でき、耐熱性に優れているため有用である。例え
ば、ビニルシクロヘキセンジオキシド、３，４−
エポキシ−６−メチルシクロヘキシルメチル−
３，４−エポキシ−６−メチルシクロヘキサンカ
ルボキシレイト、３，４−エポキシシクロヘキシ
ルメチル−３，４−エポキシシクロヘキサンカル
ボキシレイト等がある。 Among epoxy resins, cycloaliphatic epoxy resins are cured by heat using a curing agent such as tetraethylenepentamine or by ultraviolet curing using a polymerization initiator such as aromatic diazonium salt, aromatic iodonium salt, or aromatic sulfonium salt. It is useful because it can be used in various applications and has excellent heat resistance. For example, vinylcyclohexene dioxide, 3,4-
Epoxy-6-methylcyclohexylmethyl-
Examples include 3,4-epoxy-6-methylcyclohexanecarboxylate and 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate.
硬化樹脂層中には、界面活性剤等を添加して染
着層が均一に塗工できるようにしてもよい。硬化
樹脂層はその耐熱性を向上させるため、あるいは
第１図のようにその表面を粗面化させて染着層と
の密着性をよくするために、粒子を内部や表面に
含有してもよい。添加する粒子は白色顔料が望ま
しいが、特に限定されるものでなく、金属、無機
系、有機系の各種粒子、例えば、各種金属、金属
酸化物、金属硫化物、金属炭化物、金属窒化物、
金属フツ化物等の各種金属化合物、四フツ化エチ
レン、ポリイミド等の高分子、黒鉛、フツ化カー
ボン、カーボンブラツク、鉱物、無機塩、有機
塩、有機顔料等を用いることができる。 A surfactant or the like may be added to the cured resin layer so that the dyed layer can be applied uniformly. The cured resin layer may contain particles inside or on the surface to improve its heat resistance or to roughen its surface to improve adhesion with the dyeing layer as shown in Figure 1. good. The particles to be added are preferably white pigments, but are not particularly limited, and various metal, inorganic, and organic particles, such as various metals, metal oxides, metal sulfides, metal carbides, metal nitrides,
Various metal compounds such as metal fluorides, polymers such as tetrafluoroethylene and polyimide, graphite, carbon fluoride, carbon black, minerals, inorganic salts, organic salts, and organic pigments can be used.
特に、カリオン、クレー、炭酸カルシウム、酸
化亜鉛、硫酸バリウム、アルミナ、水酸化アルミ
ニウム、酸化チタン、合成非晶質シリカ、炭酸マ
グネシウム、炭酸カルシウム、珪酸カルシウム、
珪酸アルミニウム、珪酸マグネシウム、カーボン
ブラツク、酸化鉄等が有力である。 In particular, carrion, clay, calcium carbonate, zinc oxide, barium sulfate, alumina, aluminum hydroxide, titanium oxide, synthetic amorphous silica, magnesium carbonate, calcium carbonate, calcium silicate,
Potential examples include aluminum silicate, magnesium silicate, carbon black, and iron oxide.
合成非晶質シリカには無水シリカ及び含水シリ
カがある。無水シリカとしては気相法で作製され
た超微粒子が有用である。例えば、西独デグサ社
で開発された高純度の超微粒子上シリカ（商品
名：アエロジル、日本アエロジル株式会社）があ
る。 Synthetic amorphous silica includes anhydrous silica and hydrated silica. As the anhydrous silica, ultrafine particles produced by a gas phase method are useful. For example, there is high-purity ultrafine particle supersilica (trade name: Aerosil, Nippon Aerosil Co., Ltd.) developed by Degussa AG, West Germany.
含水シリカあるいはホワイトカーボンとして
は、例えば、塩野裁製薬株式会社の「カープレツ
クス」、日本シリカ工業株式会社の「ニツプシー
ル」、水澤化学工業株式会社の「シルトン」、徳山
曹達株式会社の「フアインシール、トクシール」
等の名称で市販されているものがある。 Hydrous silica or white carbon includes, for example, "Carplex" by Shiono Seiyaku Co., Ltd., "Nipseal" by Nippon Silica Industries Co., Ltd., "Silton" by Mizusawa Chemical Industry Co., Ltd., and "Fine Seal, Tokusil" by Tokuyama Soda Co., Ltd.
There are products available on the market under the names of
粒子径を、0.1μｍ以下とした場合は、染着層と
の接着性向上の効果が非常に大きい。 When the particle size is 0.1 μm or less, the effect of improving adhesion to the dyed layer is very large.
粒子の結着剤に対する添加比率は、１〜400重
量部の範囲で用いることができる。特に添加比率
が10〜300重量部の範囲で安定した特性を示す。 The addition ratio of the particles to the binder can range from 1 to 400 parts by weight. Particularly stable properties are exhibited when the addition ratio is in the range of 10 to 300 parts by weight.
以下、具体例実施例を示す。 Specific examples will be shown below.
実施例 １
厚さが150μｍのポリプロピレン系合成紙〔商
品名：ユポ、王子油化合成紙(株)〕の片面に、エポ
キシアクリレート樹脂10重量部、オリゴエステル
アクリレート樹脂20重量部、増感剤として２−ヒ
ドロキシ−２−メチルプロピオフエノン1.5重量
部、無水シリカ〔AEROSIL 300、日本アエロジ
ル(株)〕24重量部、酢酸エチル60重量部からなる塗
工液をワイヤーバーで塗工し、60℃の熱風で乾燥
後、1kwの高圧水銀灯により照射して厚さ5μｍの
硬化樹脂層を形成し、さらにこの硬化樹脂層上に
活性白土７重量部、スチレン・ブタジエン・ラバ
ーラテツクス（固形分：20重量％）100重量部か
らなる塗工液を塗工して厚さ3μｍの染着層を形
成し、受像体を作製した。Example 1 10 parts by weight of epoxy acrylate resin, 20 parts by weight of oligoester acrylate resin, and as a sensitizer were applied to one side of polypropylene synthetic paper with a thickness of 150 μm [trade name: Yupo, Oji Yuka Synthetic Paper Co., Ltd.]. A coating solution consisting of 1.5 parts by weight of 2-hydroxy-2-methylpropiophenone, 24 parts by weight of anhydrous silica [AEROSIL 300, Nippon Aerosil Co., Ltd.], and 60 parts by weight of ethyl acetate was applied with a wire bar, and heated at 60°C. After drying with hot air of A coating solution containing 100 parts by weight (% by weight) was applied to form a dyed layer with a thickness of 3 μm, thereby producing an image receptor.
次に、厚さが10μｍのポリイミドフイルム上に
下記の構造式で表わされる昇華性染料3.5重量部、
ポリカーボネート3.5重量部、平均粒径1μｍの
Al2O34重量部、塩化メチレン100重量部を混合し
たインキをワイヤーバーで塗工して転写体を作製
した。 Next, 3.5 parts by weight of a sublimable dye represented by the following structural formula was placed on a polyimide film with a thickness of 10 μm.
3.5 parts by weight of polycarbonate, average particle size 1μm
A transfer body was prepared by applying an ink containing 4 parts by weight of Al 2 O 3 and 100 parts by weight of methylene chloride using a wire bar.
この転写体を用いて、以下のサーマルヘツド記
録条件で上記の受像体（Ａ−５版）の染着層に記
録した。 Using this transfer member, recording was carried out on the dyed layer of the above image receptor (A-5 plate) under the following thermal head recording conditions.
主および副走査の線密度；４ドツト／mm
記録電力：0.7W／ドツト
ヘツドの加熱時間：２〜８ｍｓ
記録面積：各加熱時間とも20×100mm
カールの大きさは、記録後の受像体を平板上に
おいてＡ−５版の横方向の両端部が平板上から浮
く高さを測定して評価した。 Main and sub-scan linear density: 4 dots/mm Recording power: 0.7 W/dot Head heating time: 2 to 8 ms Recording area: 20 x 100 mm for each heating time Evaluation was made by measuring the height at which both lateral ends of the A-5 plate were lifted above the flat plate.
その結果、上記で記録された受像体の端部の浮
く高さは平均８mmであつた。 As a result, the floating height of the edge of the image receptor recorded above was 8 mm on average.
実施例 ２
厚さが150μｍの合成紙（ユポ）の一方の面に、
３，４−エポキシシクロヘキシルメチル−３，４
−エポキシシクロヘキサンカルボキシレイト30重
量部、重合開始剤（pp−33、旭電化工業株式会
社）２ｇ、ポリエーテル変性シリコーンオイル
0.4重量部、酢酸エチル100重量部からなる塗工液
をワイヤーバーで塗工し、60℃の熱風で乾燥後、
1kwの高圧水銀灯により照射して硬化させ、厚さ
3μｍの硬化樹脂層を形成させた。次に他方の面
にも上記の塗工液を塗工して、3μｍの硬化樹脂
層を形成した。Example 2 On one side of synthetic paper (YUPO) with a thickness of 150 μm,
3,4-epoxycyclohexylmethyl-3,4
- 30 parts by weight of epoxycyclohexane carboxylate, 2 g of polymerization initiator (pp-33, Asahi Denka Kogyo Co., Ltd.), polyether-modified silicone oil
A coating solution consisting of 0.4 parts by weight and 100 parts by weight of ethyl acetate was applied with a wire bar, and after drying with hot air at 60℃,
Irradiate with a 1kw high-pressure mercury lamp to harden the thickness.
A cured resin layer of 3 μm was formed. Next, the above coating liquid was applied to the other side to form a 3 μm thick cured resin layer.
次に両面に硬化樹脂層を有する合成紙の片面
に、無水シリカ〔AEROSIL 300〕４重量部、オ
リゴエステルアクリレート樹脂15重量部、２−ヒ
ドロキシ−２−メチルプロピオフエノン0.75重量
部、ポリエーテル変性シリコーンオイル0.2重量
部、酢酸エチル90重量部からなる塗工液を塗工
し、上記水銀灯にて硬化させ染着層を形成し受像
体を作製した。 Next, on one side of synthetic paper having a cured resin layer on both sides, 4 parts by weight of anhydrous silica [AEROSIL 300], 15 parts by weight of oligoester acrylate resin, 0.75 parts by weight of 2-hydroxy-2-methylpropiophenone, and modified polyether were added. A coating solution consisting of 0.2 parts by weight of silicone oil and 90 parts by weight of ethyl acetate was applied and cured using the mercury lamp described above to form a dyed layer, thereby producing an image receptor.
次に実施例１と同様の転写体を用い、又同様の
記録条件にて上記の受像体（Ａ−５版）の染着層
に記録してカールの大きさを測定した。 Next, using the same transfer body as in Example 1 and under the same recording conditions, recording was performed on the dyed layer of the above image receptor (A-5 plate) to measure the size of curl.
その結果、端部の浮く高さは平均６mmであつ
た。 As a result, the floating height of the end was 6 mm on average.
（比較例）
厚さが150μｍの合成紙（ユポ）の片面に活性
白土７重量部、スチレン・ブタジエン・ラバーラ
テツクス（固形分：20重量％）100重量部からな
る塗工液を塗工して、厚さ8μｍの染着層を形成
し、受像体を作製した。(Comparative example) A coating solution consisting of 7 parts by weight of activated clay and 100 parts by weight of styrene-butadiene rubber latex (solid content: 20% by weight) was applied to one side of synthetic paper (YUPO) with a thickness of 150 μm. Then, a dyed layer with a thickness of 8 μm was formed to produce an image receptor.
実施例１と同様にしてこの受像体（Ａ−５版）
に記録し、カールの大きさを測定した結果、端部
の浮く高さは平均28mmであつた。 This image receptor (A-5 version) was prepared in the same manner as in Example 1.
As a result of recording the curl size and measuring the size of the curl, the average floating height of the end was 28 mm.
本発明の受像体はワツクス等の溶融しやすい結
着剤を用いた転写体の受像体としても、特に高速
（高エネルギー）記録に対して有効に使用するこ
とができる。 The image receptor of the present invention can also be effectively used as an image receptor for a transfer body using a binder that easily melts such as wax, especially for high-speed (high energy) recording.
発明の効果
本発明は、ポリプロピレン系合成紙を基材に用
いた受像体に発生するカール発生の問題を、基材
に耐熱性硬化樹脂層を付加することによつて解決
したものであり、カールがなく取扱いの容易な受
像体が得られる。Effects of the Invention The present invention solves the problem of curling that occurs in image receptors using polypropylene synthetic paper as a base material by adding a heat-resistant hardened resin layer to the base material. An easy-to-handle image receptor is obtained.
第１図は本発明の一実施例である受像体の断面
模式図である。
４……基材、５……硬化樹脂層、６……染着
層。
FIG. 1 is a schematic cross-sectional view of an image receptor according to an embodiment of the present invention. 4... Base material, 5... Cured resin layer, 6... Dyeing layer.
Claims (1)
前記基材の少なくとも片面に硬化性樹脂の硬化樹
脂層を設け、前記硬化樹脂層上に染着層を設けた
熱転写記録用受像体。1 Using polypropylene synthetic paper as the base material,
An image receptor for thermal transfer recording, wherein a cured resin layer of a curable resin is provided on at least one side of the base material, and a dyeing layer is provided on the cured resin layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59234402A JPS61112693A (en) | 1984-11-07 | 1984-11-07 | Image receiving body for thermal transfer recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59234402A JPS61112693A (en) | 1984-11-07 | 1984-11-07 | Image receiving body for thermal transfer recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61112693A JPS61112693A (en) | 1986-05-30 |
| JPH0533157B2 true JPH0533157B2 (en) | 1993-05-18 |
Family
ID=16970438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59234402A Granted JPS61112693A (en) | 1984-11-07 | 1984-11-07 | Image receiving body for thermal transfer recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61112693A (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0655549B2 (en) * | 1985-10-15 | 1994-07-27 | 王子油化合成紙株式会社 | Image receiving sheet for thermal transfer recording |
| JP2627739B2 (en) * | 1985-12-26 | 1997-07-09 | 大日本印刷株式会社 | Heat transfer sheet and manufacturing method thereof |
| JP2565866B2 (en) * | 1986-02-25 | 1996-12-18 | 大日本印刷株式会社 | Heat transfer sheet |
| JP2787981B2 (en) * | 1986-08-27 | 1998-08-20 | 大日本印刷株式会社 | Heat transfer sheet |
| JPS6391286A (en) * | 1986-10-06 | 1988-04-21 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JP2855191B2 (en) * | 1987-03-20 | 1999-02-10 | 大日本印刷株式会社 | Heat transfer sheet |
| JP2772792B2 (en) * | 1987-02-25 | 1998-07-09 | 日東電工株式会社 | Image receptor for thermal transfer |
| JP2852419B2 (en) * | 1987-03-04 | 1999-02-03 | 大日本印刷株式会社 | Manufacturing method of heat transfer sheet |
| JP2555342B2 (en) * | 1987-03-12 | 1996-11-20 | 王子油化合成紙株式会社 | Image receiving sheet for thermal transfer recording |
| JP2852924B2 (en) * | 1987-03-20 | 1999-02-03 | 大日本印刷株式会社 | Heat transfer sheet |
| JPS63290790A (en) * | 1987-05-22 | 1988-11-28 | Oji Yuka Gouseishi Kk | Image-receiving sheet for thermal transfer recording |
| JPS6424794A (en) * | 1987-07-20 | 1989-01-26 | Kanzaki Paper Mfg Co Ltd | Image-receiving sheet for thermal transfer recording |
| JPS6478886A (en) * | 1987-09-21 | 1989-03-24 | Sony Chemicals | Sheet to be transferred for overhead projector |
| JPH01125291A (en) * | 1987-11-11 | 1989-05-17 | Sony Chem Corp | Sheet for sublimation transfer |
| EP0386262B1 (en) * | 1988-08-31 | 1995-08-09 | Dai Nippon Insatsu Kabushiki Kaisha | Image reception sheet |
| JP3042531B2 (en) * | 1988-08-31 | 2000-05-15 | 大日本印刷株式会社 | Heat transfer sheet |
| JP2686467B2 (en) * | 1992-12-01 | 1997-12-08 | 大日本印刷株式会社 | Heat transfer sheet |
| US5462911A (en) * | 1993-09-24 | 1995-10-31 | Dai Nippon Printing Co., Ltd. | Thermal transfer image-receiving sheet |
| JP4517277B2 (en) * | 2003-12-02 | 2010-08-04 | 東洋紡績株式会社 | Slide fastener parts and slide fasteners suitable for dyeing |
| US7479470B2 (en) | 2004-08-04 | 2009-01-20 | Ricoh Company, Ltd. | Thermal transfer receiver, method for producing the same, method for recording image, and recorded image |
| JP2007022065A (en) | 2005-06-16 | 2007-02-01 | Chisso Corp | Sublimation type thermal transfer image receptor |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60143993A (en) * | 1983-12-29 | 1985-07-30 | Mitsubishi Rayon Co Ltd | Coating agent for cationic dye dry transfer color development |
| JPS616649A (en) * | 1984-06-20 | 1986-01-13 | Konishiroku Photo Ind Co Ltd | Image receiving element |
| JPS6034898A (en) * | 1984-07-17 | 1985-02-22 | Dainippon Printing Co Ltd | Thermal transfer recording sheet |
-
1984
- 1984-11-07 JP JP59234402A patent/JPS61112693A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61112693A (en) | 1986-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |