JPH05339600A - Aerosol type cleaner - Google Patents

Aerosol type cleaner

Info

Publication number
JPH05339600A
JPH05339600A JP17888092A JP17888092A JPH05339600A JP H05339600 A JPH05339600 A JP H05339600A JP 17888092 A JP17888092 A JP 17888092A JP 17888092 A JP17888092 A JP 17888092A JP H05339600 A JPH05339600 A JP H05339600A
Authority
JP
Japan
Prior art keywords
aerosol
cleaning agent
type cleaning
liquid
hlb
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17888092A
Other languages
Japanese (ja)
Other versions
JP3155071B2 (en
Inventor
Toshinaga Okubo
利長 大久保
Nobuyuki Takada
信幸 高田
Mari Tanomura
真里 田能村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to JP17888092A priority Critical patent/JP3155071B2/en
Publication of JPH05339600A publication Critical patent/JPH05339600A/en
Application granted granted Critical
Publication of JP3155071B2 publication Critical patent/JP3155071B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

(57)【要約】 【構成】 炭素数が８〜２６の二級アルコールおよび／
または分岐アルコールのアルキレンオキサイド付加体で
ＨＬＢが１０以下の特性非イオン界面活性剤、他の界面
活性剤および水を含む洗浄液を含有することを特徴とす
るエアゾール型洗浄剤。 【効果】 本発明のエアゾール型洗浄剤は、泡状で噴射
できる時間が長く、噴射回数を多くして使用しても安定
な泡が得られ、噴射液がガラスなどの噴射面で垂れるこ
とはない。(57) [Summary] [Structure] Secondary alcohols having 8 to 26 carbon atoms and /
Alternatively, an aerosol type cleaning agent comprising a alkylene oxide adduct of a branched alcohol and having a HLB of 10 or less, a characteristic nonionic surfactant, another surfactant and a cleaning liquid containing water. [Effect] The aerosol-type cleaning agent of the present invention has a long period of time in which it can be sprayed in the form of foam, and a stable foam can be obtained even when the spray is used many times, and the spray liquid does not drip on the spray surface such as glass. Absent.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【産業上の利用分野】本発明は良好な泡状の噴射液が得
られるエアゾール型洗浄剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an aerosol type cleaning agent capable of obtaining a good foamy jet liquid.

【０００２】[0002]

【従来の技術】エアゾール型洗浄剤は、耐圧缶に洗浄剤
水溶液と液化石油ガス（以下、ＬＰＧという）などの噴
射剤とを混入して得られ、自動車、電車などのフロント
ガラス、リヤウィンドウなどの表面に付着しているホコ
リ、汚染物をガラス面より浮き上がらせ、溶解あるいは
分散させて布や紙による拭き取りを容易にする。たとえ
ば、特開昭６０−２６０７００号公報には、ドデシルベ
ンゼンスルホン酸ナトリウム、ポリオキシエチレンノニ
ルフェノールエーテル（ＨＬＢ＝１３）、トリエタノー
ルアミン、ケイ酸ナトリウム、ＮａＯＨ、水からなるガ
ラス表面の水系撥水解除剤のエアゾール化したものが開
示されているが、表面にケイ酸ナトリウム、ＮａＯＨな
ど固形分が残り好ましくない。2. Description of the Related Art Aerosol type cleaning agents are obtained by mixing a cleaning agent aqueous solution and a propellant such as liquefied petroleum gas (hereinafter referred to as LPG) in a pressure can, and are used for windshields of automobiles, trains, rear windows, etc. Dust and contaminants adhering to the surface of the glass are floated above the glass surface and dissolved or dispersed to facilitate wiping with a cloth or paper. For example, in Japanese Patent Laid-Open No. 60-260700, release of water-based water repellent on a glass surface consisting of sodium dodecylbenzenesulfonate, polyoxyethylene nonylphenol ether (HLB = 13), triethanolamine, sodium silicate, NaOH, and water. Although an aerosolized agent has been disclosed, solid contents such as sodium silicate and NaOH remain on the surface, which is not preferable.

【０００３】また、特開昭６２−２５７９９４号公報に
は、１，３‐ジメチル‐２‐イミダゾリジノン（１，３
‐ジエチル‐２‐イミダゾリジノン）、ポリオキシエチ
レンラウリルエーテル、ラウリルベンゼンスルフォン酸
ナトリウム、モノエタノールアミンからなるガラスクリ
ーナーが開示され、特開昭５８−５３９６号公報、特開
昭５８−２１４９５号公報には、ポリオキシエチレン型
非イオン界面活性剤を用いたガラスクリーナーが開示さ
れ、拭き取り易さ、シミ残りの少さの利点を示してい
る。Further, JP-A-62-257994 discloses that 1,3-dimethyl-2-imidazolidinone (1,3
-Diethyl-2-imidazolidinone), polyoxyethylene lauryl ether, sodium laurylbenzene sulfonate, and monoethanolamine are disclosed in Japanese Patent Laid-Open Nos. 58-5396 and 58-21495. Discloses a glass cleaner using a polyoxyethylene type nonionic surfactant, and shows the advantages of easy wiping and less stain residue.

【０００４】しかし、これらのガラスクリーナーのエア
ゾール化製品には、つぎのような問題点がある。エアゾ
ール缶の内部では、噴射剤のＬＰＧと洗浄剤水溶液とは
混和せず層状となっている。そのため、使用時に缶を振
ってＬＰＧと洗浄剤水溶液を混合して、噴射する。混合
後すぐ噴射するとＬＰＧ乳化滴が均一に水溶液に分散し
ているため噴射液は良好な泡状となる。しかし、缶を振
ってしばらくして噴射すると、洗浄剤水溶液中に分散し
たＬＰＧ乳化滴が徐々に分離して、再び、水溶液層上に
層を形成するので、噴射液は十分な泡状とならない。However, the aerosolized products of these glass cleaners have the following problems. Inside the aerosol can, the propellant LPG and the aqueous detergent solution are immiscible and form a layer. Therefore, at the time of use, the can is shaken to mix the LPG and the cleaning agent aqueous solution and then sprayed. When jetted immediately after mixing, the LPG emulsified droplets are uniformly dispersed in the aqueous solution, so that the jetted liquid becomes a good foam. However, when the can is shaken and jetted after a while, the LPG emulsion droplets dispersed in the detergent aqueous solution gradually separate and form a layer again on the aqueous solution layer, so the jetted liquid does not become a sufficient foamy state. ..

【０００５】したがって、エアゾール型洗浄剤では、缶
を振った後に洗浄剤水溶液中にＬＰＧができるだけ長い
間乳化滴状態のものが望まれ、噴射液が良好な泡状とな
って噴射できる時間が長いものが望まれている。Therefore, in the aerosol type cleaning agent, it is desired that the LPG is in an emulsified droplet state in the cleaning agent aqueous solution for as long as possible after shaking the can, and it takes a long time for the ejection liquid to be in the form of a good foam. Things are desired.

【０００６】[0006]

【発明が解決しようとする課題】本発明の目的は、上記
のエアゾール型洗浄剤の問題点を解決することであり、
良好な泡状となって噴射できる時間が長いエアゾール型
洗浄剤、すなわち安定な泡が得られる噴射回数が多い、
噴射液がガラスなどの噴射面で垂れないようなエアゾー
ル型洗浄剤を提供することである。SUMMARY OF THE INVENTION An object of the present invention is to solve the above problems of the aerosol type cleaning agent,
Aerosol type cleaner with good foaming time and long spraying time, that is, stable foaming is obtained many times,
It is an object of the present invention to provide an aerosol-type cleaning agent in which a spray liquid does not drip on a spray surface such as glass.

【０００７】[0007]

【課題を解決するための手段】本発明者らは、上記問題
を解決すべく種々の検討の結果、特定アルコールのアル
キレンオキサイド付加体からなり、かつ、ＨＬＢが１０
以下の非イオン界面剤を用いることにより本発明の目的
を達成することを見出し、本発明のエアゾール型洗浄剤
を完成するに至った。As a result of various investigations to solve the above problems, the present inventors have found that they consist of an alkylene oxide adduct of a specific alcohol and have an HLB of 10 or less.
It has been found that the object of the present invention can be achieved by using the following nonionic surfactants, and the aerosol type cleaning agent of the present invention has been completed.

【０００８】すなわち、本発明のエアゾール型洗浄剤
は、炭素数が８〜２６の二級アルコールおよび／または
分岐アルコールのアルキレンオキサイド付加体からなる
ＨＬＢが１０以下の特性非イオン界面活性剤、他の界面
活性剤および水を含む洗浄液を含有することを特徴とす
る。好ましくは、水と実質的に混和しない液化ガスを噴
射剤として含むエアゾール型洗浄剤である。That is, the aerosol-type cleaning agent of the present invention comprises a characteristic nonionic surfactant having an HLB of 10 or less, which is composed of an alkylene oxide adduct of a secondary alcohol having 8 to 26 carbon atoms and / or a branched alcohol, and other It is characterized by containing a cleaning liquid containing a surfactant and water. Preferably, it is an aerosol type cleaning agent containing a liquefied gas which is substantially immiscible with water as a propellant.

【０００９】本発明のエアゾール型洗浄剤に用いる上記
の特性非イオン活性剤は、炭素数が８〜２６の二級アル
コールのアルキレンオキサイド付加体および／または炭
素数が８〜２６の分岐アルコールのアルキレンオキサイ
ド付加体からなり、かつ、ＨＬＢが１０以下のものであ
る。ここで、炭素数が８〜２６の二級アルコールのアル
キレンオキサイド付加体とは、一般式The above-mentioned characteristic nonionic activator used in the aerosol type detergent of the present invention is an alkylene oxide adduct of a secondary alcohol having 8 to 26 carbon atoms and / or an alkylene of a branched alcohol having 8 to 26 carbon atoms. It is an oxide adduct and has an HLB of 10 or less. Here, the alkylene oxide adduct of a secondary alcohol having 8 to 26 carbon atoms is represented by the general formula

【００１０】[0010]

【化１】 （式中、Ｒ1 とＲ2 はアルキル基、両者の炭素数の合計
は７〜２５、ｍ＝１〜１５、ｎ＝０〜１５を示す。（Ｃ
2 Ｈ4 Ｏ）単位と（Ｃ3 Ｈ6 Ｏ）単位がブロックもしく
はランダムに結合してもよい。）[Chemical 1] (In the formula, R 1 and R 2 are alkyl groups, and the total number of carbon atoms of both is 7 to 25, m = 1 to 15, and n = 0 to 15 are shown.
The 2 H 4 O) unit and the (C 3 H 6 O) unit may be bonded in a block or random manner. )

【００１１】具体的な化合物名としては、ポリオキシエ
チレン第２級デシルエーテル、ポリオキシエチレン第２
級ドデシルエーテル、ポリオキシエチレン第２級テトラ
デシルエーテルなどをあげることができる。Specific compound names include polyoxyethylene secondary decyl ether and polyoxyethylene secondary
Examples thereof include secondary dodecyl ether and polyoxyethylene secondary tetradecyl ether.

【００１２】また、炭素数が８〜２６の分岐アルコール
のアルキレンオキサイド付加体とは、一般式The alkylene oxide adduct of a branched alcohol having 8 to 26 carbon atoms has the general formula

【化２】 （式中、Ｒ1 とＲ2 はアルキル基、両者の炭素数の合計
は６〜２４、ｍ＝１〜１５、ｎ＝０〜１５を示す。また
（Ｃ2 Ｈ4 Ｏ）単位と（Ｃ3 Ｈ6 Ｏ）単位がブロックも
しくはランダムに結合してもよい。）[Chemical 2] (In the formula, R 1 and R 2 are alkyl groups, and the total number of carbon atoms of both is 6 to 24, m = 1 to 15, and n = 0 to 15. In addition, a (C 2 H 4 O) unit and a (C 2 H 4 O) unit are used. 3 H 6 O) units may be bonded in blocks or randomly.)

【００１３】具体的な化合物名としては、ポリオキシエ
チレンヘキシルデシルエーテル、ポリオキシエチレンイ
ソステアリルエーテル、ポリオキシエチレンオクチルド
デシルエーテルなどをあげることがてきる。本発明の洗
浄剤に用いるアルキレンオキシドは、上記のような化合
物であり、さらに、分子中の親水性基と親油性基とのバ
ランスを示す値ＨＬＢが水分散性もしくは親油性を示す
１０以下であることが必須である。たとえば、ＨＬＢ＝
７のポリオキシエチレン（ｐ＝５）イソステアリルエー
テルは好ましく使用できる（実施例３〜５参照）に対し
て、ＨＬＢ＝１２のポリオキシエチレン（ｐ＝１５）イ
ソステアリルエーテル（比較例５）は好ましくない。Specific compound names include polyoxyethylene hexyl decyl ether, polyoxyethylene isostearyl ether, polyoxyethylene octyl dodecyl ether and the like. The alkylene oxide used in the detergent of the present invention is a compound as described above, and further, when the value HLB indicating the balance between the hydrophilic group and the lipophilic group in the molecule is 10 or less indicating water dispersibility or lipophilicity. It is essential to have. For example, HLB =
Polyoxyethylene (p = 5) isostearyl ether of 7 can be preferably used (see Examples 3 to 5), whereas polyoxyethylene (p = 15) isostearyl ether of HLB = 12 (Comparative Example 5) can be used. Not preferable.

【００１４】本発明の洗浄剤に用いる特性非イオン界面
活性剤の使用量は、洗浄液に対して０．００５〜０．５
重量％、好ましくは０．０１〜０．２重量％である。
０．００５重量％未満の場合は効果がなく、また、０．
５重量％をこえる場合は活性剤が拭き面に多く残るので
好ましくない。Characteristic nonionic surfactant used in the cleaning agent of the present invention is used in an amount of 0.005 to 0.5 with respect to the cleaning liquid.
%, Preferably 0.01 to 0.2% by weight.
If it is less than 0.005% by weight, no effect is obtained, and if it is 0.
If it exceeds 5% by weight, a large amount of the activator remains on the wiping surface, which is not preferable.

【００１５】本発明の洗浄剤には、上記の特性非イオン
界面活性剤以外に他の界面活性剤を使用する。その界面
活性剤としては、カルボキシベタイン、スルホベタイ
ン、アミノカルボン酸塩、イミダゾリン誘導体などの両
性界面活性剤、アルキルベンゼンスルホン酸塩（以下、
ＡＢＳと略す）、高級アルコールおよび高級アルコール
の酸化エチレン付加物の硫酸エステル塩などの陰イオン
界面活性剤などを使用する。In the detergent of the present invention, other surfactants are used in addition to the above characteristic nonionic surfactant. Examples of the surfactant include carboxybetaine, sulfobetaine, aminocarboxylic acid salts, amphoteric surfactants such as imidazoline derivatives, alkylbenzene sulfonates (hereinafter,
Abbreviated as ABS), higher alcohols, and anionic surfactants such as sulfuric acid ester salts of ethylene oxide adducts of higher alcohols.

【００１６】具体的なものとしては、両性活性剤として
カルボキシベタイン型が好ましく、ラウリルジメチルア
ミノ酢酸ベタインなどをあげることができる。その使用
量は特に限定されるものではなく、また種類によって異
なるが、通常洗浄液に対して０．００２〜０．５重量
％、好ましくは０．００５〜０．１重量％である。Specifically, a carboxybetaine type is preferable as the amphoteric activator, and lauryldimethylaminoacetic acid betaine and the like can be mentioned. The amount used is not particularly limited and varies depending on the type, but is usually 0.002 to 0.5% by weight, preferably 0.005 to 0.1% by weight with respect to the cleaning liquid.

【００１７】陰イオン界面活性剤としては、アルキルベ
ンゼンスルホン酸塩、アルキル硫酸エステル塩、アルキ
ルエトキシ硫酸エステル塩、オレフインスルホン酸塩、
脂肪酸塩、アルキルエトキシカルボン酸塩、α‐スルホ
脂肪酸エステル塩、α‐スルホ脂肪酸塩、モノアルキル
リン酸エステル塩などを挙げることができる。陰イオン
界面活性剤の量は、特に限定されるものではなく、また
種類によっても異なるが、洗浄液に対して通常０．００
２〜０．５重量％、好ましくは０．００５〜０．１重量
％である。As the anionic surfactant, alkylbenzene sulfonate, alkyl sulfate ester salt, alkyl ethoxy sulfate ester salt, olefin sulfonate,
Examples thereof include fatty acid salts, alkyl ethoxycarboxylic acid salts, α-sulfo fatty acid ester salts, α-sulfo fatty acid salts, monoalkyl phosphate ester salts and the like. The amount of the anionic surfactant is not particularly limited and varies depending on the type, but is usually 0.00 with respect to the cleaning liquid.
2 to 0.5% by weight, preferably 0.005 to 0.1% by weight.

【００１８】本発明の洗浄剤は、上記成分のほかにアル
カリ剤を添加して液のｐＨを９〜１２に保つのが好まし
い。アルカリ剤として好適なものは、モルホリン、トリ
エタノールアミン、ジエタノールアミン、モノエタノー
ルアミンなどのアルカノールアミン類などである。さら
に水、香料、色素などを添加することができる。また、
界面活性剤、香料などを混合する場合の溶剤として、エ
タノール、イソプロピルアルコールなどのアルコール
類、またはこれらのアルコール類とエチレングリコー
ル、プロピレングリコールなどのグリコール類、もしく
はアルキルエーテルが使用される。その使用量は特に限
定されるものではなく、洗浄液に対して、通常０．１〜
１５重量％である。The detergent of the present invention preferably contains an alkaline agent in addition to the above components to maintain the pH of the liquid at 9 to 12. Suitable as the alkaline agent are alkanolamines such as morpholine, triethanolamine, diethanolamine and monoethanolamine. Further, water, a fragrance, a pigment, etc. can be added. Also,
Alcohols such as ethanol and isopropyl alcohol, or these alcohols and glycols such as ethylene glycol and propylene glycol, or alkyl ethers are used as a solvent when mixing a surfactant, a fragrance, and the like. The amount used is not particularly limited, and is usually 0.1 to the cleaning liquid.
It is 15% by weight.

【００１９】本発明の洗浄剤は、液体のまま使用するこ
とができるが、通常水と実質的に混合しない液化ガス、
たとえばＬＰＧなどを噴射剤として、上記の組成の洗浄
液に２〜１０重量％混合してエアゾール製品として好適
に使用する。The cleaning agent of the present invention can be used as a liquid, but is usually a liquefied gas that is not substantially mixed with water,
For example, LPG or the like is mixed as a propellant with the cleaning liquid having the above composition in an amount of 2 to 10% by weight, and is suitably used as an aerosol product.

【００２０】[0020]

【実施例】つぎに実施例、比較例にて本発明のエアゾー
ル型洗浄剤について説明する。実施例、比較例における
％は、洗浄液に対する重量百分率を示す。 実施例１ １リットルビーカーに水７２７ｇを入れ、アルカリ剤と
してモノエタノールアミン８ｇ（１％）、非イオン界面
活性剤としてポリオキシエチレン（ｐ＝３）ラウリル・
ミリスチルエーテル（ＨＬＢ＝７．９）０．４ｇ（０．
０５％）を添加し、ジェット式アジター（ＴＹＰＥ Ｓ
Ｊ）を用いて１５００ｒ．ｐ．ｍで５分間撹拌後、他の
界面活性剤としてポリオキシエチレンアルキルエーテル
硫酸エステルＮａ塩（ＡＥＳ‐Ｎａ）０．０８ｇ（０．
０１％）、ラウリルジメチルアミノ酢酸ベタイン０．０
８ｇ（０．０１％）、香料０．３２ｇ（０．０４％）、
エタノール６４ｇ（８％）に溶解した溶液を加え、更に
１５分撹拌して洗浄液を得た。この洗浄液２６０ｇとＬ
ＰＧ１０．８ｇをエアゾール缶に充填し、エアゾール型
洗浄剤を得た。EXAMPLES Next, the aerosol type cleaning agent of the present invention will be described with reference to Examples and Comparative Examples. % In the examples and comparative examples indicates the weight percentage with respect to the cleaning liquid. Example 1 727 g of water was placed in a 1 liter beaker, monoethanolamine 8 g (1%) was used as an alkaline agent, and polyoxyethylene (p = 3) lauryl was used as a nonionic surfactant.
0.4 g of myristyl ether (HLB = 7.9) (0.
(05%) is added to the jet agitator (TYPE S
J.) and 1500 r. p. After stirring for 5 minutes at m.m., 0.08 g (0. 0%) of polyoxyethylene alkyl ether sulfate ester Na salt (AES-Na) as another surfactant.
01%), lauryl dimethylaminoacetic acid betaine 0.0
8g (0.01%), fragrance 0.32g (0.04%),
A solution dissolved in 64 g (8%) of ethanol was added and further stirred for 15 minutes to obtain a cleaning liquid. 260g of this cleaning liquid and L
An aerosol can was filled with 10.8 g of PG to obtain an aerosol type cleaning agent.

【００２１】エアゾール型洗浄剤を充填したエアゾール
缶を１０分間振とう（振幅：４５cm、振動数：６回／
秒）後、一昼夜以上静置し噴射液の泡状態を評価した。
評価はエアゾール缶を約２０cmの振り巾で１０回振って
約１秒噴射し、以後１０秒後ごとに１５cm離れて垂直ガ
ラス面に約１秒噴射して噴射液がガラス面で安定な泡状
態が持続する噴射回数を測定した。（安定な泡状態にな
らない場合は、噴射液がガラス面にとどまらずに垂れ
る）評価結果を表１に示す。Shake the aerosol can filled with the aerosol type cleaning agent for 10 minutes (amplitude: 45 cm, frequency: 6 times /
Second), and allowed to stand still for one day or more to evaluate the foam state of the injection liquid.
For evaluation, the aerosol can was shaken 10 times with a shaking width of about 20 cm and sprayed for about 1 second, and then every 10 seconds, sprayed for about 1 second on the vertical glass surface at a distance of 15 cm, and the sprayed liquid was a stable bubble state on the glass surface. The number of injections that lasted was measured. (In the case where a stable bubble state is not obtained, the jetted liquid drips without staying on the glass surface). The evaluation results are shown in Table 1.

【００２２】実施例２〜４、６、７ 非イオン活性剤とその配合量をかえる以外は、実施例１
と同様に行なった。結果を表１に示す。Examples 2 to 4, 6 and 7 Example 1 was repeated except that the amount of the nonionic activator and its blending amount were changed.
It carried out similarly to. The results are shown in Table 1.

【００２３】実施例５ ポリオキシエチレン（ｐ＝５）イソステアリルエーテル
（ＨＬＢ＝７）を０．１５％、ＡＥＳ‐Ｎａを０．０５
％、ラウリルジメチルアミノ酢酸ベインを０．０５％と
する以外は、実施例１と同様に行った。結果を表１に示
す。Example 5 Polyoxyethylene (p = 5) isostearyl ether (HLB = 7) 0.15%, AES-Na 0.05.
%, And lauryldimethylaminoacetic acid bain in 0.05%, and the same procedure as in Example 1. The results are shown in Table 1.

【００２４】比較例１〜５ 非イオン活性剤の種類とその配合量をかえる以外は実施
例１と同様に行った。結果は表１に示す。Comparative Examples 1 to 5 The same procedure as in Example 1 was carried out except that the kind of nonionic activator and the blending amount thereof were changed. The results are shown in Table 1.

【００２５】[0025]

【表１】 [Table 1]

【００２６】[0026]

【発明の効果】本発明のエアゾール型洗浄剤は、泡状で
噴射できる時間が長く、噴射回数を多くして使用しても
安定な泡が得られ、噴射液がガラスなどの噴射面で垂れ
ることはない。EFFECT OF THE INVENTION The aerosol-type cleaning agent of the present invention has a long foaming time, and stable foam can be obtained even if it is used by increasing the number of times of spraying, and the sprayed liquid drips on the spraying surface such as glass. There is no such thing.

Claims (2)

【特許請求の範囲】[Claims] 【請求項１】 炭素数が８〜２６の二級アルコールおよ
び／または分岐アルコールのアルキレンオキサイド付加
体でＨＬＢが１０以下の特性非イオン界面活性剤、他の
界面活性剤および水を含む洗浄液を含有することを特徴
とするエアゾール型洗浄剤。1. A washing liquid containing a characteristic nonionic surfactant having an HLB of 10 or less and an alkylene oxide adduct of a secondary alcohol and / or a branched alcohol having 8 to 26 carbon atoms, other surfactant and water. An aerosol type cleaning agent characterized by: 【請求項２】 水と実質的に混和しない液化ガスを噴射
剤として含む請求項１記載のエアゾール型洗浄剤。2. The aerosol-type cleaning agent according to claim 1, which contains a liquefied gas which is substantially immiscible with water as a propellant.
JP17888092A 1992-06-15 1992-06-15 Aerosol cleaning agent Expired - Fee Related JP3155071B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17888092A JP3155071B2 (en) 1992-06-15 1992-06-15 Aerosol cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17888092A JP3155071B2 (en) 1992-06-15 1992-06-15 Aerosol cleaning agent

Publications (2)

Publication Number Publication Date
JPH05339600A true JPH05339600A (en) 1993-12-21
JP3155071B2 JP3155071B2 (en) 2001-04-09

Family

ID=16056317

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Link
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Publication number Priority date Publication date Assignee Title
JP2014074125A (en) * 2012-10-05 2014-04-24 Dainippon Jochugiku Co Ltd Expandable detergent composition
JP2016060862A (en) * 2014-09-19 2016-04-25 横浜油脂工業株式会社 Glass cleaner

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