JPH0539552A - Powdery steel for high speed tool and its production - Google Patents
Powdery steel for high speed tool and its productionInfo
- Publication number
- JPH0539552A JPH0539552A JP3307088A JP30708891A JPH0539552A JP H0539552 A JPH0539552 A JP H0539552A JP 3307088 A JP3307088 A JP 3307088A JP 30708891 A JP30708891 A JP 30708891A JP H0539552 A JPH0539552 A JP H0539552A
- Authority
- JP
- Japan
- Prior art keywords
- ceq
- carbide
- speed tool
- high speed
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229910000831 Steel Inorganic materials 0.000 title abstract description 15
- 239000010959 steel Substances 0.000 title abstract description 15
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 17
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 10
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 21
- 229910001315 Tool steel Inorganic materials 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 abstract description 8
- 229910052720 vanadium Inorganic materials 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 150000001247 metal acetylides Chemical class 0.000 description 24
- 239000000463 material Substances 0.000 description 19
- 239000013078 crystal Substances 0.000 description 16
- 238000005520 cutting process Methods 0.000 description 14
- 238000005496 tempering Methods 0.000 description 14
- 230000001965 increasing effect Effects 0.000 description 13
- 238000010791 quenching Methods 0.000 description 12
- 230000000171 quenching effect Effects 0.000 description 12
- 239000011159 matrix material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000002791 soaking Methods 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- 238000001513 hot isostatic pressing Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000005275 alloying Methods 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000005242 forging Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- 238000010191 image analysis Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000997 High-speed steel Inorganic materials 0.000 description 1
- 238000001016 Ostwald ripening Methods 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Powder Metallurgy (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、切削工具や圧造工具に
用いられ、特に高温における硬さと耐摩耗性が要求され
る高速使用条件下において、顕著に優れた耐摩耗性と同
時に高い靭性を有する粉末高速度工具鋼およびその製造
方法に関するものである。BACKGROUND OF THE INVENTION The present invention is used for cutting tools and forging tools, and particularly under high-speed use conditions where hardness and wear resistance at high temperatures are required, it is possible to obtain not only excellent wear resistance but also high toughness. The present invention relates to a powder high speed tool steel having the same and a manufacturing method thereof.
【0002】[0002]
【従来の技術】切削工具、圧造工具に用いられる高速度
工具鋼は、高硬度で耐摩耗性が優れること、および靭性
に優れること、の2つの要求を満足することが望まれて
いる。溶製高速度工具鋼の靭性を向上させる方法として
は、Nb等の元素を微量添加し、結晶粒を微細化させて
靭性を向上する方法(例えば特開昭58-73753号、同58-11
7863号等)、Nbと希土類元素を複合添加することによ
り、Nbを主体としたMC型炭化物を均一微細化する方
法(特公昭61-896号)等種々提案されている。2. Description of the Related Art High-speed tool steels used for cutting tools and forging tools are required to satisfy the two requirements of high hardness and excellent wear resistance and toughness. As a method of improving the toughness of the molten high speed tool steel, a method of adding a trace amount of an element such as Nb and refining the crystal grains to improve the toughness (for example, JP-A-58-73753 and JP-A-58-11).
No. 7863), and a method of uniformly refining MC type carbide mainly composed of Nb by adding Nb and rare earth elements in combination (Japanese Patent Publication No. 61-896).
【0003】一方、耐摩耗性を向上させる方法として
は、炭化物を均一微細に分布させ、かつ結晶粒の微細化
が可能な粉末高速度工具鋼において、炭化物量を増大さ
せる方法が最も一般的である。例えば、特公昭57-2142
号、特開昭55-148747号は、主にW当量を高めることに
より、W,Moを主体とするM6C型炭化物量を増加さ
せ、高硬度化により耐摩耗性の向上を図ったものであ
る。また、粉末高速度工具鋼において、結晶粒の微細化
と、さらには、焼入温度を高めても結晶粒を粗大化させ
ないことを目的として、Nbを含有せしめることが検討
されている{Metall.Trans.19A(1988) P1395〜1401,特
開平1-212736号}。On the other hand, the most general method for improving wear resistance is to increase the amount of carbide in powder high speed tool steel in which carbide is uniformly and finely distributed and crystal grains can be refined. is there. For example, Japanese Examined Sho 57-2142
And JP-A-55-148747, the amount of M 6 C type carbides mainly containing W and Mo is increased by mainly increasing the W equivalent, and the wear resistance is improved by increasing the hardness. Is. Further, in the powder high speed tool steel, it is considered to contain Nb for the purpose of refining the crystal grains and further preventing the crystal grains from being coarsened even if the quenching temperature is raised {Metall. Trans. 19A (1988) P1395 to 1401, Japanese Patent Laid-Open No. 1-212736}.
【0004】[0004]
【発明が解決しようとする課題】しかし、前記特開昭58
-73753号、同58-117863号の溶製高速度工具鋼では、Nb
を過度に添加すると、Nbを主体としたNbCの粗大な炭
化物を晶出し、W,Moを主体とするM6C型炭化物も、
凝固時に粗大な炭化物を晶出させるために、結晶粒微細
化による靭性向上効果が減殺され、かえって靭性が低下
するといった問題点があった。また、上記の粉末高速度
工具鋼で、耐摩耗性を向上させる目的で、炭化物量の富
化や工具の高硬度化が行なわれてきたが、靭性が低下し
てしまい、工具の折損や欠けが問題となっていた。However, the above-mentioned Japanese Patent Laid-Open No. 58-58
-73753 and 58-117863 melted high speed tool steels have Nb
When N is excessively added, coarse NbC carbides mainly composed of Nb are crystallized, and M 6 C type carbides mainly composed of W and Mo are also
Since a coarse carbide is crystallized during solidification, there is a problem that the effect of improving the toughness by refining the crystal grains is diminished and the toughness is rather lowered. Further, in the above powder high-speed tool steel, the amount of carbide and the hardness of the tool have been increased for the purpose of improving wear resistance, but the toughness is lowered, and the tool is broken or chipped. Was a problem.
【0005】また、前記特開昭55-148747号に、Nbを添
加した粉末高速度鋼が提案されているが、この例ではN
bをVの代替として添加し、硬質の炭化物を形成するこ
とを主眼においたものである。さらに、Metall.Trans.1
9A(1988) P1395〜P1401、特開平1-212736号に開示され
る高速度工具鋼は、Nbを添加することにより、結晶粒
を粗大化せずに焼入温度を高めることを可能としている
が、本発明者の考えによると合金元素量、特にW当量が
低いために、苛酷な工具使用条件下では高温焼もどし軟
化抵抗が不十分で、また炭化物量も少ないため、耐摩耗
性も不十分である。Further, Japanese Patent Laid-Open No. 55-148747 proposes a powder high-speed steel containing Nb.
The main purpose is to add b as a substitute for V to form a hard carbide. Furthermore, Metall.Trans.1
The high speed tool steel disclosed in 9A (1988) P1395 to P1401 and Japanese Patent Laid-Open No. 1-212736 makes it possible to increase the quenching temperature without coarsening the crystal grains by adding Nb. According to the inventor's idea, the alloying element amount, particularly the W equivalent, is low, so that the high temperature temper softening resistance is insufficient under severe tool use conditions, and the carbide content is also small, so that the wear resistance is insufficient. Is.
【0006】したがって、以上説明した従来の高速度工
具鋼は、高速化が要求されている近時の工具使用条件に
対応することが困難であった。そこで、本発明は工具使
用条件の高速化に対応できる高温焼もどし軟化抵抗特性
を顕著に高めるとともに、耐摩耗性をさらに高めるため
に2〜5μmの炭化物密度を高め、かつ高靭性の粉末高速
度工具鋼の提供を課題とする。Therefore, it has been difficult for the conventional high-speed tool steel described above to meet the recent tool usage conditions in which high speed is required. Therefore, the present invention remarkably enhances the high temperature tempering softening resistance characteristics that can correspond to the speeding up of tool use conditions, and increases the carbide density of 2 to 5 μm to further enhance wear resistance, and high toughness powder high speed. The challenge is to provide tool steel.
【0007】[0007]
【課題を解決するための手段】近年、工具の使用条件が
高速化されるにつれ、工具の高硬度化が重要な要因とな
っている。本発明者も、実際にエンドミル等の工具を使
用して、工具寿命と材質要因との関係について解析した
結果、寿命向上には硬さ、特に工具使用中に、工具が高
温になるため、焼もどし軟化抵抗特性が最も重要であ
り、さらに炭化物粒径を調整することによって、耐摩耗
性が向上することを知見した。In recent years, as the use conditions of tools have become faster, increasing the hardness of the tools has become an important factor. The present inventor also actually used a tool such as an end mill and analyzed the relationship between the tool life and the material factor.As a result, the life was improved by hardness, especially since the tool became hot during use, It has been found that the reversion softening resistance property is the most important, and further the wear resistance is improved by adjusting the carbide grain size.
【0008】本発明は、この知見を考慮してなされたも
ので、下記の3点を基本的な技術思想とするものであ
る。焼もどし軟化抵抗を最大限に高めるために、化学
成分上、特に、W+2Mo、W/2MoおよびC−Ceqを
特定範囲内に規制することが有効であることを見出し
た。すなわち、W+2Mo量を増すことにより、硬い炭
化物を分散させ、マトリックス中に固溶する合金元素量
を増すことが有効である。さらに、Wの量を多くし、W
/2Mo≧1とすると、高い焼もどし硬さが得られ、高Mo
系の材料よりはより高い焼もどし軟化抵抗が得られる。
C量は他の炭化物形成元素量との兼ね合いで決める必要
があり、C−Ceqで調整される。高い焼もどし軟化抵抗
を得るためには、C−Ceqを規制し、マトリックス中に
固溶するC量を確保することが必要である。The present invention has been made in consideration of this finding, and the following three points are the basic technical ideas. In order to maximize the temper softening resistance, it has been found that it is effective to regulate W + 2Mo, W / 2Mo and C-Ceq within a specific range in terms of chemical composition. That is, it is effective to increase the amount of W + 2Mo to disperse hard carbides and increase the amount of alloying elements dissolved in the matrix. In addition, increase the amount of W
When / 2Mo ≧ 1, high tempering hardness can be obtained and high Mo
A higher temper softening resistance is obtained than the materials of the system.
The amount of C needs to be determined in consideration of the amounts of other carbide forming elements, and is adjusted by C-Ceq. In order to obtain a high tempering softening resistance, it is necessary to regulate C-Ceq and secure the amount of C that forms a solid solution in the matrix.
【0009】多くの合金元素をマトリックス中へ固溶
せしめんとして焼入温度を高くすると、結晶粒が粗大化
するが、これをNbを含有せしめ、かつそのNb/V比
を規制することにより、結晶粒の粗大化を防止し、微細
結晶粒を確保し、靭性の低下を防止する。NbはVと同
様MC炭化物を形成するが、結晶粒の粗大化を防止する
のに有効な1μm以下の微細NbCを形成するためには、
原子比でVよりも多いNbを含有しなければならない。
重量比ではNb/Vが0.5以上必要である。[0009] When many quenching temperatures are used as a solid solution of many alloying elements in the matrix, the crystal grains become coarse. However, by containing Nb and controlling the Nb / V ratio, Prevents coarsening of crystal grains, secures fine crystal grains, and prevents deterioration of toughness. Nb forms MC carbides like V, but in order to form fine NbC of 1 μm or less, which is effective for preventing coarsening of crystal grains,
It must contain more Nb than V in atomic ratio.
In weight ratio, Nb / V should be 0.5 or more.
【0010】さらに、本発明で重要な点は、耐摩耗性
の向上に2〜5μmの炭化物の密度を増加する効果がある
ことを見出した点にある。耐摩耗性を向上させるのに、
有効な炭化物は2〜5μmの中粒炭化物であって、このサ
イズの炭化物密度が最低10,000個/mm2が必要である。そ
れ未満の場合には、工具摩耗が著しく進行し低寿命とな
る。2〜5μmの中粒炭化物密度が30,000個/mm2を越えて
多くなると炭化物が連結し始め、靭性が著しく低下する
ので、2〜5μmの中粒炭化物密度を10,000〜30,000個/mm
2とした。Further, an important point in the present invention is that it has been found that it has an effect of increasing the density of carbides of 2 to 5 μm in improving wear resistance. To improve wear resistance,
Effective carbides are medium grain carbides of 2-5 μm, with a minimum carbide density of 10,000 / mm 2 for this size. If it is less than that, tool wear remarkably progresses and the life becomes short. If the medium-grain carbide density of 2-5 μm exceeds 30,000 / mm 2 , the carbides will start to be connected and the toughness will be significantly reduced.Therefore, the medium-grain carbide density of 2-5 μm will be 10,000-30,000 / mm.
2
【0011】そして、これらは以下に示すような成分バ
ランスをさらに満たして、はじめて上記の特性を満足で
きることを見い出した。すなわち本発明は、重量比でC
1.5%を越え2.2%以下、Si≦1.0%、Mn≦0.6%、Cr 3.0
〜6.0%、WまたはさらにMoをW+2Moで 20〜30%か
つ、W/2Mo≧1、V≦5.0%、Nb 2.0〜7.0%、但しNb/
V≧0.5、残部がFeおよび不可避的不純物よりなり、C
−Ceqが−0.20〜0.05(Ceq=0.24+0.033・W+0.063・Mo
+0.2V+0.1・Nb)の関係を満たし、2〜5μmの炭化物密
度が10,000〜30,000個/mm2であることを特徴とする粉末
高速度工具鋼である。It has been found that the above properties can be satisfied for the first time by satisfying the following component balance. That is, the present invention uses C by weight.
More than 1.5% and 2.2% or less, Si ≦ 1.0%, Mn ≦ 0.6%, Cr 3.0
~ 6.0%, W or 20 to 30% at W + 2Mo and W / 2Mo≥1, V≤5.0%, Nb 2.0 to 7.0%, but Nb /
V ≧ 0.5, balance of Fe and inevitable impurities, and C
-Ceq is -0.20 to 0.05 (Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo
The powder high speed tool steel is characterized by satisfying the relationship of + 0.2V + 0.1 · Nb) and having a carbide density of 2 to 5 μm of 10,000 to 30,000 pieces / mm 2 .
【0012】また、本発明は重量比でC 1.5%を越え2.2
%以下、Si≦1.0%、Mn≦0.6%、Cr3.0〜6.0%、Wまた
はさらにMoをW+2Moで 20〜30%かつ、W/2Mo≧1、
V≦5.0%、Nb 2.0〜7.0%、但しNb/V≧0.5、Co 4.0
〜15.0%、残部がFeおよび不可避的不純物よりなり、C
−Ceqが−0.20〜0.05(Ceq=0.24+0.033・W+0.063・Mo
+0.2V+0.1・Nb)の関係を満たし、2〜5μmの炭化物密
度が10,000〜30,000個/mm2であることを特徴とする粉末
高速度工具鋼である。The present invention also has a weight ratio of more than C 1.5% to 2.2.
% Or less, Si ≦ 1.0%, Mn ≦ 0.6%, Cr3.0 to 6.0%, W or 20 to 30% of Mo with W + 2Mo, and W / 2Mo ≧ 1,
V ≦ 5.0%, Nb 2.0 to 7.0%, but Nb / V ≧ 0.5, Co 4.0
~ 15.0%, the balance Fe and inevitable impurities, C
-Ceq is -0.20 to 0.05 (Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo
The powder high speed tool steel is characterized by satisfying the relationship of + 0.2V + 0.1 · Nb) and having a carbide density of 2 to 5 μm of 10,000 to 30,000 pieces / mm 2 .
【0013】本発明において、NbがVに対して多くな
りすぎると、粗大なNbCが発生しやすくなり、靭性が
低下するので、Nb/V≦2の関係を満たすことが好ま
しい。また、耐摩耗性を向上するためには、Nb+V>
6の関係を満たすことが好ましい。In the present invention, if Nb is excessively large with respect to V, coarse NbC is likely to occur and the toughness deteriorates. Therefore, it is preferable to satisfy the relationship of Nb / V ≦ 2. Further, in order to improve wear resistance, Nb + V>
It is preferable that the relationship of 6 is satisfied.
【0014】また、本発明の製造方法は重量比でC 1.5
%を越え2.2%以下、Si≦1.0%、Mn≦0.6%、Cr 3.0〜6.
0%、WまたはさらにMoをW+2Moで 20〜30%かつ、W/
2Mo≧1、V≦5.0%、Nb 2.0〜7.0%、但しNb/V≧0.
5、あるいはこれに加えてCo ≦15.0%を含み、残部がF
eおよび不可避的不純物よりなり、C−Ceqが−0.20〜
0.05(ただしCeq=0.24+0.033・W+0.063・Mo+0.2V+
0.1・Nb)の関係を満たす合金粉末を、焼結して焼結体を
得た後、熱間加工の前、あるいは熱間加工の途中で11
00℃〜1200℃の加熱処理を行うことを特徴とする
粉末高速度工具鋼の製造方法である。Further, the manufacturing method of the present invention uses C 1.5 by weight.
% To 2.2% or less, Si ≦ 1.0%, Mn ≦ 0.6%, Cr 3.0 to 6.
0%, W or 20 to 30% with Mo + W2 Mo and W /
2Mo ≧ 1, V ≦ 5.0%, Nb 2.0-7.0%, but Nb / V ≧ 0.
5, or in addition to this, contains Co ≤ 15.0%, with the balance being F
e and inevitable impurities, C-Ceq is -0.20 ~
0.05 (However, Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo + 0.2V +
After the alloy powder satisfying the relationship of 0.1 · Nb) is sintered to obtain a sintered body, before hot working or during hot working, 11
A method for producing a powder high-speed tool steel, which comprises performing a heat treatment at 00 ° C to 1200 ° C.
【0015】[0015]
【作用】本発明では、十分な硬さと焼きもどし軟化抵抗
を確保しつつ耐摩耗性を上げるために、2〜5μmの炭化
物密度を10,000〜30,000個/mm2にすることを最大の特徴
とする。このような特定サイズの炭化物密度は、成分を
特定しただけでは得ることができず、熱間加工の前、あ
るいは熱間加工の途中でソーキング等の加熱処理を行な
うことにより得ることができる。ソーキング等の加熱処
理を行なうと2μm以下の微細な炭化物は固溶し、オスト
ワルド成長により2〜5μmの炭化物の密度を上げること
ができる。2〜5μmの中粒炭化物を10,000個/mm以上とす
ることにより耐摩耗性が著しく向上するが、30,000個/m
m2を越えると炭化物が連結し始め、靭性が低下するため
好ましくない。The present invention is most characterized in that the carbide density of 2 to 5 μm is set to 10,000 to 30,000 pieces / mm 2 in order to improve wear resistance while ensuring sufficient hardness and temper softening resistance. .. Such a specific size carbide density cannot be obtained only by specifying the components, and can be obtained by performing a heat treatment such as soaking before hot working or during hot working. When heat treatment such as soaking is performed, fine carbides of 2 μm or less are solid-dissolved, and the density of carbides of 2 to 5 μm can be increased by Ostwald ripening. Wear resistance is significantly improved by making the medium-grain carbide of 2 to 5 μm 10,000 pieces / mm or more, but 30,000 pieces / m
If it exceeds m 2 , it is not preferable because carbides start to be connected and the toughness decreases.
【0016】以下に成分の限定理由を説明する。Cは同
時に添加されるCr,W,Mo,V,Nbと硬い炭化物を形成
して耐摩耗性向上に寄与する。さらに、焼入時にマトリ
ックス中に固溶して焼もどし2次硬化を向上する作用も
ある。しかし、多すぎるとマトリックス中に固溶する炭
素量が著しく増え靭性を低下させる。したがって、C量
はCr,W,Mo,V,Nb含有量との兼ね合いで決める必要
があり、本発明では1.5〜2.2%の範囲とC-Ceqの値が-
0.200.05の関係を満足するようC量を調整する。この関
係を満足させることにより、高い高温焼もどし軟化抵抗
を得るための1条件が達成される。The reasons for limiting the components will be described below. C forms a hard carbide with Cr, W, Mo, V, and Nb added at the same time, and contributes to the improvement of wear resistance. Further, it has a function of improving the secondary hardening by solid solution in the matrix during quenching. However, if the amount is too large, the amount of carbon solid-dissolved in the matrix increases remarkably and the toughness decreases. Therefore, the amount of C must be determined in consideration of the contents of Cr, W, Mo, V and Nb. In the present invention, the range of 1.5 to 2.2% and the value of C-Ceq are-.
The amount of C is adjusted so as to satisfy the relationship of 0.200.05. By satisfying this relationship, one condition for achieving high high temperature temper softening resistance is achieved.
【0017】Si,Mnは脱酸剤として添加するが、多量
に添加すると靭性を害する等の問題があるので、Si 1.
0%以下、Mn 0.6%以下に限定する。Crは焼入性を高
め、また焼もどし2次硬化性を高める目的で3〜6%添加
する。3%より少ないと上記効果が少なく、逆に6%より多
いとCrを主体とするM23C6型の炭化物が極端に増えて
全体の靭性を害し、さらに焼もどし時に炭化物の凝集を
速め軟化抵抗を減ずる。Si and Mn are added as deoxidizing agents, but if added in a large amount, there is a problem such as impairing toughness.
It is limited to 0% or less and Mn 0.6% or less. Cr is added in an amount of 3 to 6% for the purpose of enhancing the hardenability and the secondary hardening of the temper. If it is less than 3%, the above effect is small. On the contrary, if it is more than 6%, the amount of M 23 C 6 type carbides mainly composed of Cr is extremely increased and the toughness of the whole is impaired. Reduce resistance.
【0018】本発明の目的である顕著な耐摩耗性を付与
するためには、硬い炭化物を多量に分散させ、しかもマ
トリックス硬度を高める必要がある。本発明で、W,M
o量は、上記の目的で重要な元素である。Wまたはさら
にMoをW+2Moで20〜 30%とする。20%より少ないと上
記効果が少ない。しかし、W+2Moが30%を越えると、
連結した炭化物が急増し、マトリックス中に固溶する合
金元素も極端に多くなって靭性の低下が著しくなるの
で、WまたはさらにMoをW+2Moで20〜30%とする。ま
た、W/2Mo比を1以上に高めることにより、本発明の
特徴である焼もどし軟化抵抗を著しく向上するための、
他の1条件(1方はC−Ceqの条件)を満たすことがで
きる。In order to impart remarkable wear resistance, which is an object of the present invention, it is necessary to disperse a large amount of hard carbide and increase the matrix hardness. In the present invention, W, M
o Quantity is an important element for the above purposes. W or further Mo is 20 + 30% at W + 2 Mo. If it is less than 20%, the above effect is small. However, when W + 2Mo exceeds 30%,
Since the number of connected carbides increases rapidly and the amount of alloying elements that form a solid solution in the matrix is extremely increased, the toughness is significantly reduced. Therefore, W or Mo is set to 20 to 30% at W + 2Mo. Further, by increasing the W / 2Mo ratio to 1 or more, in order to remarkably improve the temper softening resistance, which is a feature of the present invention,
Other one condition (one is C-Ceq condition) can be satisfied.
【0019】Vもまた耐摩耗性を高めるのに有効な元素
である。耐摩耗性の目的からは、できるだけ多く含有さ
せたい。しかし、5%を越えると粗大なMC型炭化物が晶
出し易くなり、靭性や工具の被研削性を害するので、5%
以下とした。Nbは、本発明において最も重要な元素の
一つである。Nbを特定の成分範囲に限定すると、耐摩
耗性に有効な1〜5μmのNbを主体とした硬質の炭化物
と、1μm以下の微細な炭化物が晶出する。V is also an element effective in increasing wear resistance. For the purpose of abrasion resistance, it is desirable to contain as much as possible. However, if it exceeds 5%, coarse MC type carbides are likely to crystallize, which impairs toughness and grindability of the tool.
Below. Nb is one of the most important elements in the present invention. When Nb is limited to a specific component range, a hard carbide mainly composed of 1 to 5 μm Nb effective for wear resistance and a fine carbide of 1 μm or less are crystallized.
【0020】本発明者は、この微細なNbCが結晶粒成
長を抑制し、焼入温度を高めても結晶粒の粗大化を効果
的に抑制する成分範囲を見出した。この微細なNbCは
Nb量、Nb/V比と密接に関係しておりNb量及びNb/V
比が低いと、微細なNbCがほとんど晶出しないため、
Nb≧2%およびNb/V≧0.5となるようNb量を調整し
た。しかし、Nbが7%を越えると、極めて粗大なNbCを
晶出し、靭性や被研削性を害するので、7%以下とした。
またNbがVに対して多くなり過ぎるとNb炭化物が粗
大化する傾向となるためNb/V≦2を満たすことが望
ましい。The present inventor has found a range of components in which the fine NbC suppresses the growth of crystal grains and effectively suppresses the coarsening of crystal grains even if the quenching temperature is increased. This fine NbC is closely related to the Nb amount and the Nb / V ratio, and the Nb amount and the Nb / V ratio.
If the ratio is low, fine NbC is hardly crystallized,
The amount of Nb was adjusted so that Nb ≧ 2% and Nb / V ≧ 0.5. However, when Nb exceeds 7%, extremely coarse NbC is crystallized and impairs toughness and grindability, so it was set to 7% or less.
Further, if Nb is too much with respect to V, Nb carbide tends to be coarsened, so that it is desirable to satisfy Nb / V ≦ 2.
【0021】Coは本発明鋼の焼きもどし軟化抵抗の向
上するために極めて有効な元素である。マトリックス中
に固溶し、炭化物の析出および凝集を遅らせ、高温にお
ける硬さと強度を著しく向上させる効果があり、切削工
具、エンドミル等の工具とワークの接触部が特に高温に
なる用途にとって極めて重要な添加元素である。しか
し、Coが15.0%を越えると固溶によるCo単独相の晶出
が生ずることにより靭性が低下するので15.0%以下とし
た。また、Co添加による焼きもどし軟化抵抗を著しく
向上するためにはCoは4%以上含有することが好まし
い。Co is an extremely effective element for improving the temper softening resistance of the steel of the present invention. It forms a solid solution in the matrix, delays the precipitation and agglomeration of carbides, and has the effect of significantly improving the hardness and strength at high temperatures, which is extremely important for applications where the contact part between the tool and the work such as cutting tools and end mills is particularly hot. It is an additive element. However, if Co exceeds 15.0%, the toughness decreases due to crystallization of the Co single phase due to solid solution, so the content was made 15.0% or less. Further, in order to remarkably improve the tempering softening resistance by adding Co, Co is preferably contained at 4% or more.
【0022】[0022]
【実施例】表1に窒素ガスアトマイズ粉末をHIP(熱
間静水圧プレス処理)する方法により作製した3種類の
実験材の化学組成を示す。それぞれの材料は、HIP
後、1080℃〜1190℃の温度範囲でソーキングを行ない、
鍛伸により約16mm角とした後、該鍛伸材を860℃で焼な
まし、結晶粒が粗にならない温度範囲で可能な限り高い
温度である1250℃で15分間のオーステナイト化を行なっ
た後、550℃の熱浴焼入を行なった。なお、焼もどしは5
60℃×1時間の3回である。[Examples] Table 1 shows the chemical compositions of three kinds of experimental materials produced by the method of HIP (hot isostatic pressing) of nitrogen gas atomized powder. Each material is HIP
After that, soaking in the temperature range of 1080 ℃ ~ 1190 ℃,
After about 16 mm square by forging, the forged material was annealed at 860 ° C. and austenitized at 1250 ° C. for 15 minutes, which is the highest temperature possible in a temperature range where the crystal grains do not become coarse. , 550 ℃ hot bath quenching was performed. The tempering is 5
60 ° C x 1 hour 3 times.
【0023】試料の2〜5μmの炭化物密度の定量は、各
鍛伸材の縦断面をダイヤモンド研磨を行なった後、村上
試薬でM6C型の炭化物を腐食し、さらに10%クロム酸水
溶液で電解腐食を行ないMC型を炭化物を腐食した試料
を用意した。これらの試料を画像解析処理装置によっ
て、炭化物の定量を行なった。また、焼もどし後の硬
さ、インターセプト法による結晶粒度(焼入後)、650℃
で1時間加熱保持後、空冷した際の硬さ(焼もどし軟化抵
抗と称する)を測定した。 これらの結果を表2に示
す。Quantitative determination of the carbide density of 2 to 5 μm of the sample was carried out by diamond polishing the longitudinal section of each forged material, then corroding M 6 C type carbide with Murakami reagent, and further with 10% chromic acid aqueous solution. A sample was prepared in which electrolytic corrosion was performed and MC type was corroded by carbide. These samples were quantified for carbide by an image analysis processor. Also, hardness after tempering, grain size by intercept method (after quenching), 650 ° C
After heating and holding for 1 hour, the hardness (referred to as tempering softening resistance) when air-cooled was measured. The results are shown in Table 2.
【0024】[0024]
【表1】 [Table 1]
【0025】[0025]
【表2】 [Table 2]
【0026】表2の比較例1a,2a,3aは鋼組成は本発明の
範囲内の合金であるが、ソーキングの加熱温度が低いた
めに、2〜5μm中粒炭化物が少ない値となっているもの
である。 表2よりソーキング温度を1100℃より高める
ことにより、2〜5μmの中粒炭化物が増加することがわ
かる。また、Coを含有しない成分No.1の材料とCoを含有
する成分No.2およびNo.3を比較すると、Coを含有するこ
とによって、Coを含有しないものより成分No.2およびN
o.3の試料の焼もどし軟化抵抗が高く、切削等で高温部
が生ずる工具に対してはCoを含有することが有効である
ことがわかる。Comparative Examples 1a, 2a and 3a in Table 2 are alloys having a steel composition within the range of the present invention, but the heating temperature for soaking is low, so that there is a small amount of 2-5 μm medium-grain carbides. It is a thing. It can be seen from Table 2 that when the soaking temperature is raised above 1100 ° C, the medium-grain carbides of 2 to 5 µm increase. Also, comparing the material of component No. 1 containing no Co with the components No. 2 and No. 3 containing Co, by containing Co, the components No. 2 and N are better than those containing no Co.
It can be seen that the inclusion of Co is effective for tools in which the tempering softening resistance of the sample of o.3 is high and a high temperature part is generated by cutting or the like.
【0027】また、図1および図2に代表的な試料の炭
化物組織を示す。図1aは表2の本発明鋼である試料1c
を酸化クロムで研磨したもので、輪郭の明瞭な粒子がMC
型炭化物であり、MC型炭化物は4470個/mm2であった。ま
た、図1bは同じ材料を村上試薬でM6C型炭化物を選択
腐食したものであり、M6C型炭化物は14000個/mm2であっ
た。また、図2aは表2の比較鋼である試料1aを酸化ク
ロムで研磨、MC型炭化物を浮き出させたものであり、MC
型炭化物は690個/mm2であった。また、図2bは同じ材
料を村上試薬でM6C型炭化物を選択腐食したものであ
り、M6C型炭化物は7120個/mm2であった。1 and 2 show the carbide structures of typical samples. FIG. 1a is a sample 1c which is the steel of the present invention in Table 2.
Is polished with chrome oxide, and particles with clear contours are MC
Type carbide, MC type carbide was 4470 pieces / mm 2 . Further, FIG. 1b shows that the same material was selectively corroded with M 6 C type carbide by Murakami reagent, and the amount of M 6 C type carbide was 14000 pieces / mm 2 . In addition, FIG. 2a shows a comparison steel of Table 2, Sample 1a, which was polished with chromium oxide to emboss MC type carbides.
The number of type carbides was 690 pieces / mm 2 . In addition, FIG. 2b shows that the same material was subjected to selective corrosion of M 6 C type carbide with Murakami reagent, and the amount of M 6 C type carbide was 7120 pieces / mm 2 .
【0028】この材料の靭性を評価するため上記鍛伸材
より5φ×70 Lの試験片を採取し、上記した焼入れ、焼
もどしの熱処理を施した後、スパン50 Lで曲げ試験を
行った。また、同様の熱処理を施した真剣バイト(8-15-
6-6-20-15-0.5R)を作製し、HRC40に調質したSKD61を、
表3に示す条件で連続切削試験を行なった際の切削寿命
を測定した。また、各試料を相手リングSCM415、
摩擦距離 400m、最終荷重 6.8kg、摩擦速度 3.5m/Sで大
越式摩耗試験を行ない、比摩耗量を測定した。結果を表
4に示す。表4より、同一組成であっても、2〜5μmの
中粒炭化物密度の低い比較例1a,2a,3aの試料は、比摩耗
量が多く耐摩耗性が不十分であり、またバイト切削寿命
も短く好ましくないことがわかる。また、本発明例の中
でも、Coを含有する成分No.2およびNo.3の試料がCoのな
い成分No.1の試料よりもバイト寿命、比摩耗量ともに優
れたものであることがわかる。In order to evaluate the toughness of this material, a test piece of 5φ × 70 L was sampled from the above forged material, subjected to the above-mentioned quenching and tempering heat treatment, and then subjected to a bending test with a span of 50 L. In addition, a serious bite (8-15-
6-6-20-15-0.5R) was prepared, and SKD61 tempered to HRC40 was
The cutting life when a continuous cutting test was performed under the conditions shown in Table 3 was measured. In addition, each sample is connected to the partner ring SCM415,
The Ogoshi-type wear test was performed at a friction distance of 400 m, a final load of 6.8 kg, and a friction speed of 3.5 m / S to measure the specific wear amount. The results are shown in Table 4. Table 4 shows that even with the same composition, the samples of Comparative Examples 1a, 2a, and 3a having a low medium-grain carbide density of 2 to 5 μm have a large specific wear amount and insufficient wear resistance, and also have a cutting tool life. It turns out that it is also short and not preferable. Further, among the examples of the present invention, it can be seen that the samples of the components No. 2 and No. 3 containing Co are superior in the tool life and the specific wear amount to the samples of the component No. 1 containing no Co.
【0029】[0029]
【表3】 [Table 3]
【0030】[0030]
【表4】 [Table 4]
【0031】(実施例2)窒素ガスアトマイズ粉末をHI
P(熱間静水圧プレス処理)する方法により作製した表5
に示す組成の材料を製造した。それぞれの材料は、実施
例1と同様にHIP後、1080℃〜1170℃の温度範囲でソ
ーキングを行ない、鍛伸により約16mm角とした後、該鍛
伸材を860℃で焼なまし、結晶粒が粗にならない温度範
囲で可能な限り高い温度として試料11のみ1210℃で15分
間とし、他の試料は1250℃で15分間でそれぞれオーステ
ナイト化を行なった後、550℃の熱浴焼入を行なった。
なお、焼もどしは560℃×1時間の3回である。Example 2 Nitrogen gas atomized powder was HI
Table 5 prepared by the method of P (hot isostatic pressing)
A material having the composition shown in was produced. Each material was subjected to soaking in the temperature range of 1080 ° C to 1170 ° C after HIP in the same manner as in Example 1, and after forging to make about 16 mm square, the forged material was annealed at 860 ° C and crystallized. As much as possible within the temperature range where grains do not become coarse, only sample 11 was 1210 ° C. for 15 minutes, and other samples were austenitized at 1250 ° C. for 15 minutes, respectively, and then heat-bathed at 550 ° C. I did.
The tempering was performed three times at 560 ° C for 1 hour.
【0032】[0032]
【表5】 [Table 5]
【0033】得られた試料を実施例1と同様に試料の2〜
5μmの炭化物密度の定量は、各鍛伸材の縦断面をダイヤ
モンド研磨を行なった後、村上試薬でM6C型の炭化物
を腐食し、さらに10%クロム酸水溶液で電解腐食を行な
いMC型の炭化物を腐食した試料を用意した。これらの
試料を画像解析処理装置によって行なった。また、焼も
どし後の硬さ、インターセプト法による結晶粒度(焼入
後)、650℃で1時間加熱保持後、空冷した際の硬さ(焼も
どし軟化抵抗)を測定した。結果を表6に示す。この材
料の靭性を評価するため上記鍛伸材より5φ×70 Lの試
験片を採取し、上記した焼入れ、焼もどしの熱処理を施
した後、スパン50 Lで曲げ試験を行った。また、同様
の熱処理を施した真剣バイト(8-15-6-6-20-15-0.5R)を
作製し、HRC40に調質したSKD61を、表3に示す条件で連
続切削試験を行なった際の切削寿命を測定した。また、
各試料を相手リングSCM415、摩擦距離 400m、最
終荷重 6.8kg、摩擦速度 3.5m/Sで大越式摩耗試験を行
ない、比摩耗量を測定した。結果を表7に示す。The obtained sample was used in the same manner as in Example 1 except that
The quantification of the carbide density of 5 μm was carried out by diamond polishing the longitudinal section of each forged material, then corroding M 6 C type carbide with Murakami reagent, and electrolytic corrosion with 10% chromic acid aqueous solution. A sample in which carbide was corroded was prepared. These samples were processed by an image analysis processor. Further, the hardness after tempering, the crystal grain size by the intercept method (after quenching), the hardness after heating and holding at 650 ° C. for 1 hour, and the hardness upon cooling in air (tempering softening resistance) were measured. The results are shown in Table 6. In order to evaluate the toughness of this material, a test piece of 5φ × 70 L was sampled from the above forged material, subjected to the above-mentioned quenching and tempering heat treatment, and then subjected to a bending test with a span of 50 L. In addition, a serious cutting tool (8-15-6-6-20-15-0.5R) that had been subjected to the same heat treatment was produced, and SKD61 that had been tempered to HRC40 was subjected to a continuous cutting test under the conditions shown in Table 3. The cutting life at that time was measured. Also,
Each sample was subjected to the Ogoshi-type wear test at a mating ring SCM415, a friction distance of 400 m, a final load of 6.8 kg, and a friction speed of 3.5 m / S, and the specific wear amount was measured. The results are shown in Table 7.
【0034】[0034]
【表6】 [Table 6]
【0035】[0035]
【表7】 [Table 7]
【0036】以下、各試料について詳細に説明を行な
う。本発明鋼である試料No.4ないしNo.9はCoを含む本発
明鋼であり、2〜5μmの中粒炭化物が10000個/mm2〜2000
0個/mm2の範囲にある鋼である。本発明の試料のうち、N
o.6ないしNo.8はNb+Vが6%を越えており、硬質のMC炭化
物量が多いため、特に優れたバイト切削寿命となり、比
摩耗量も小さい値となることがわかる。このうち、No.8
はCo量が少ないため、No.6およびNo.7に比べると焼き
もどし軟化抵抗が低下したことがわかる。また、本発明
鋼の試料No.9は本実施例における比摩耗量は優れた値を
示すが、Nb/Vの値が2を越え、Nb量がV量に対し多いた
め、やや粗大なNbCが多く、抗折力が他の実施例に比べ
やや低下することがわかり、Nb/V量は2以下が好ましい
ことがわかる。Hereinafter, each sample will be described in detail. Samples No. 4 to No. 9 which are steels of the present invention are steels of the present invention containing Co, and the number of medium grain carbides of 2 to 5 μm is 10000 pieces / mm 2 to 2000.
Steel in the range of 0 pieces / mm 2 . Of the samples of the present invention, N
From No. 6 to No. 8, Nb + V exceeds 6%, and since the amount of hard MC carbide is large, it can be seen that the tool life is particularly excellent and the specific wear amount is small. Of these, No.8
It can be seen that since the Co content is small, the temper softening resistance is lower than those of No. 6 and No. 7. Further, the sample No. 9 of the present invention steel shows an excellent value of the specific wear amount in this example, but the value of Nb / V exceeds 2 and the Nb amount is large relative to the V amount, so that it is slightly coarse NbC. It is found that the transverse rupture strength is slightly lower than that of the other examples, and that the Nb / V amount is preferably 2 or less.
【0037】試料No.10はWおよびMoの添加量が少ないた
めに、焼もどし軟化抵抗が低い値となり、バイト切削寿
命が本発明の試料に比べ著しく短いものとなることわか
る。試料No.11はNbを含まないため、結晶粒が粗大化す
るのを防止するためには焼入れ温度を上げることができ
ない。そのためマトリックス中に十分な合金元素が固溶
できず、軟化抵抗が低い値となり、バイト切削寿命が本
発明の試料に比べ著しく短いものとなることがわかる。
試料No.12はC-Ceqで計算されるΔCが本発明の範囲より
も正側に外れる試料である。この試料ではマトリックス
中にCが過剰に固溶するため、抗折力が著しく、低下し
好ましくないことがわかる。試料No.13はΔCが本発明の
範囲よりも負側に外れる試料である。この試料ではΔC
が少ないために焼入れ焼もどしを行っても、本発明の試
料より、硬さが低くいためバイト切削寿命が短く、比摩
耗量も多いものとなり、好ましくないことがわかる。It can be seen that sample No. 10 has a low resistance to temper softening due to a small amount of W and Mo added, and the cutting tool life is significantly shorter than that of the sample of the present invention. Since sample No. 11 does not contain Nb, the quenching temperature cannot be increased in order to prevent the crystal grains from coarsening. Therefore, it can be seen that sufficient alloy elements cannot be solid-dissolved in the matrix, the softening resistance becomes a low value, and the cutting life of the cutting tool is remarkably shorter than that of the sample of the present invention.
Sample No. 12 is a sample in which ΔC calculated by C-Ceq is out of the range of the present invention on the positive side. It can be seen that in this sample, C is excessively solid-dissolved in the matrix, so that the transverse rupture strength is remarkably reduced, which is not preferable. Sample No. 13 is a sample in which ΔC deviates to the negative side from the range of the present invention. ΔC for this sample
Therefore, even if quenching and tempering are performed, the hardness is lower than that of the sample of the present invention, so that the tool cutting life is short and the specific wear amount is large, which is not preferable.
【0038】[0038]
【発明の効果】本発明によれば、従来不十分であった高
温での軟化抵抗特性を大幅に向上できるので高温での耐
摩耗性を顕著に改善し、かつ炭化物粒度が2〜5μmの中
程度の大きさのものが多くなるように調整することによ
り、より一層耐摩耗性を向上することができた。また結
晶粒が微細なままで、靭性も従来と同等以上に高いた
め、工具の高速使用条件下で、大幅な寿命向上が達成で
きる。EFFECTS OF THE INVENTION According to the present invention, the softening resistance property at high temperature, which has been insufficient in the past, can be significantly improved, so that the wear resistance at high temperature is remarkably improved, and the carbide grain size is 2-5 μm. It was possible to further improve the wear resistance by adjusting so that the size of the product is about the same. Further, since the crystal grains remain fine and the toughness is as high as or higher than that of the conventional one, it is possible to significantly improve the service life under the high-speed use condition of the tool.
【図1】本発明鋼の組織中の炭化物を示す図であり、図
1aはMC型炭化物を示した金属ミクロ組織写真、図1b
は同じ材料のM6C型炭化物を示した金属ミクロ組織写真
である。FIG. 1 is a diagram showing carbides in the structure of the steel of the present invention, and FIG. 1a is a metal microstructure photograph showing MC type carbides, and FIG. 1b.
Is a metal microstructure photograph showing M 6 C type carbide of the same material.
【図2】比較鋼の組織中の炭化物を示す図であり、図2
aはMC型炭化物を示した金属ミクロ組織写真、図2bは
同じ材料のM6C型炭化物を示した金属ミクロ組織写真で
ある。2 is a diagram showing carbides in the structure of a comparative steel, and FIG.
a is a metal microstructure photograph showing MC type carbide, and FIG. 2B is a metal microstructure photograph showing M 6 C type carbide of the same material.
Claims (7)
1.0%、Mn≦0.6%、Cr 3.0〜6.0%、WまたはさらにMo
をW+2Moで 20〜30%かつ、W/2Mo≧1、V≦5.0%、
Nb 2.0〜7.0%、但しNb/V≧0.5、残部がFeおよび不
可避的不純物よりなり、C−Ceqが−0.20〜0.05(ただ
しCeq=0.24+0.033・W+0.063・Mo+0.2V+0.1・Nb)の
関係を満たし、2〜5μmの炭化物密度が10,000〜30,000
個/mm2であることを特徴とする粉末高速度工具鋼。1. A weight ratio of more than C 1.5% and not more than 2.2%, Si ≦.
1.0%, Mn ≦ 0.6%, Cr 3.0-6.0%, W or even Mo
Is 20 to 30% at W + 2Mo and W / 2Mo ≧ 1, V ≦ 5.0%,
Nb 2.0 to 7.0%, but Nb / V ≧ 0.5, the balance is Fe and inevitable impurities, C-Ceq is −0.20 to 0.05 (however Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo + 0.2V + 0.1 ・Nb) is satisfied and the carbide density of 2 to 5 μm is 10,000 to 30,000.
Powder high speed tool steel characterized in that it is pieces / mm 2 .
1.0%、Mn≦0.6%、Cr 3.0〜6.0%、WまたはさらにMo
をW+2Moで 20〜30%かつ、W/2Mo≧1、V≦5.0%、
Nb 2.0〜7.0%、但しNb/V≧0.5、Co ≦15.0%、残部
がFeおよび不可避的不純物よりなり、C−Ceqが−0.2
0〜0.05(ただしCeq=0.24+0.033・W+0.063・Mo+0.2V
+0.1・Nb)の関係を満たし、2〜5μmの炭化物密度が10,
000〜30,000個/mm2であることを特徴とする粉末高速度
工具鋼。2. A weight ratio of more than C 1.5% and 2.2% or less, Si ≦
1.0%, Mn ≦ 0.6%, Cr 3.0-6.0%, W or even Mo
Is 20 to 30% at W + 2Mo and W / 2Mo ≧ 1, V ≦ 5.0%,
Nb 2.0 to 7.0%, with Nb / V ≧ 0.5, Co ≦ 15.0%, the balance Fe and inevitable impurities, and C−Ceq −0.2.
0 to 0.05 (Ceq = 0.24 + 0.033 / W + 0.063 / Mo + 0.2V
+0.1 · Nb), the carbide density of 2 ~ 5μm is 10,
Powder high-speed tool steel characterized by 000 to 30,000 pieces / mm 2 .
1.0%、Mn≦0.6%、Cr 3.0〜6.0%、WまたはさらにMo
をW+2Moで 20〜30%かつ、W/2Mo≧1、V≦5.0%、
Nb 2.0〜7.0%、但しNb/V≧0.5、Co 4.0〜15.0%、残
部がFeおよび不可避的不純物よりなり、C−Ceqが−
0.20〜0.05(ただしCeq=0.24+0.033・W+0.063・Mo+0.
2V+0.1・Nb)の関係を満たし、2〜5μmの炭化物密度が
10,000〜30,000個/mm2であることを特徴とする粉末高速
度工具鋼。3. A weight ratio of more than C 1.5% and not more than 2.2%, Si ≦.
1.0%, Mn ≦ 0.6%, Cr 3.0-6.0%, W or even Mo
Is 20 to 30% at W + 2Mo and W / 2Mo ≧ 1, V ≦ 5.0%,
Nb 2.0 to 7.0%, but Nb / V ≧ 0.5, Co 4.0 to 15.0%, balance Fe and unavoidable impurities, and C-Ceq −
0.20-0.05 (however Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo + 0.
2V + 0.1 · Nb), and a carbide density of 2-5 μm
Powder high speed tool steel characterized by 10,000 to 30,000 pieces / mm 2 .
とする請求項1ないし2に記載の粉末高速度工具鋼。4. The powder high speed tool steel according to claim 1, wherein the relationship of Nb / V ≦ 2 is satisfied.
を満たすことを特徴とする請求項1ないし2に記載の粉
末高速度工具鋼。5. The powder high speed tool steel according to claim 1, wherein the relationships of Nb / V ≦ 2 and Nb + V> 6 are satisfied.
1.0%、Mn≦0.6%、Cr 3.0〜6.0%、WまたはさらにMo
をW+2Moで 20〜30%かつ、W/2Mo≧1、V≦5.0%、
Nb 2.0〜7.0%、但しNb/V≧0.5、残部がFeおよび不
可避的不純物よりなり、C−Ceqが−0.20〜0.05(ただ
しCeq=0.24+0.033・W+0.063・Mo+0.2V+0.1・Nb)の
関係を満たす合金粉末を、焼結して焼結体を得た後、熱
間加工の前、あるいは熱間加工の途中で1100℃〜1
200℃の加熱処理を行い、2〜5μmの炭化物密度を10,
000〜30,000個/mm2に調整することを特徴とする粉末高
速度工具鋼の製造方法。6. A weight ratio of more than C 1.5% to 2.2% or less, Si ≦
1.0%, Mn ≦ 0.6%, Cr 3.0-6.0%, W or even Mo
Is 20 to 30% at W + 2Mo and W / 2Mo ≧ 1, V ≦ 5.0%,
Nb 2.0 to 7.0%, but Nb / V ≧ 0.5, the balance is Fe and inevitable impurities, C-Ceq is −0.20 to 0.05 (however Ceq = 0.24 + 0.033 ・ W + 0.063 ・ Mo + 0.2V + 0.1 ・After the alloy powder satisfying the relationship of Nb) is sintered to obtain a sintered body, before hot working or during hot working, 1100 ° C. to 1 ° C.
Heat treatment at 200 ℃, and the carbide density of 2 ~ 5μm 10,
A method for producing a powder high-speed tool steel, which is characterized by adjusting to 000 to 30,000 pieces / mm 2 .
1.0%、Mn≦0.6%、Cr 3.0〜6.0%、WまたはさらにMo
をW+2Moで 20〜30%かつ、W/2Mo≧1、V≦5.0%、
Nb 2.0〜7.0%、但しNb/V≧0.5、Co ≦15.0%、残部
がFeおよび不可避的不純物よりなり、C−Ceqが−0.2
0〜0.05(ただしCeq=0.24+0.033・W+0.063・Mo+0.2V
+0.1・Nb)の関係を満たす合金粉末を、焼結して焼結体
を得た後、熱間加工の前、あるいは熱間加工の途中で1
100℃〜1200℃の加熱処理を行い、2〜5μmの炭
化物密度を10,000〜30,000個/mm2に調整することを特徴
とする粉末高速度工具鋼の製造方法。7. A weight ratio of more than C 1.5% and not more than 2.2%, Si ≦.
1.0%, Mn ≦ 0.6%, Cr 3.0-6.0%, W or even Mo
Is 20 to 30% at W + 2Mo and W / 2Mo ≧ 1, V ≦ 5.0%,
Nb 2.0 to 7.0%, with Nb / V ≧ 0.5, Co ≦ 15.0%, the balance Fe and inevitable impurities, and C−Ceq −0.2.
0 to 0.05 (Ceq = 0.24 + 0.033 / W + 0.063 / Mo + 0.2V
+ 0.1 · Nb) alloy powder that satisfies the relationship of 1) after sintering to obtain a sintered body, before hot working or during hot working 1
A method for producing a powder high-speed tool steel, which comprises performing a heat treatment at 100 ° C to 1200 ° C to adjust a carbide density of 2 to 5 µm to 10,000 to 30,000 pieces / mm 2 .
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3-64097 | 1991-03-05 | ||
| JP6409791 | 1991-03-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0539552A true JPH0539552A (en) | 1993-02-19 |
Family
ID=13248236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3307088A Pending JPH0539552A (en) | 1991-03-05 | 1991-10-25 | Powdery steel for high speed tool and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0539552A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2662168A1 (en) * | 2012-05-08 | 2013-11-13 | WIKUS-Sägenfabrik Wilhelm H. Kullmann GmbH & Co. KG | Saw blade including a cutting element made by powder metallurgy |
| JP2015071812A (en) * | 2013-10-03 | 2015-04-16 | 山陽特殊製鋼株式会社 | Powdered high speed tool steel and manufacturing method thereof |
| CN114622122A (en) * | 2022-03-04 | 2022-06-14 | 长沙市萨普新材料有限公司 | High-niobium iron-based superhard material and preparation method thereof |
-
1991
- 1991-10-25 JP JP3307088A patent/JPH0539552A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2662168A1 (en) * | 2012-05-08 | 2013-11-13 | WIKUS-Sägenfabrik Wilhelm H. Kullmann GmbH & Co. KG | Saw blade including a cutting element made by powder metallurgy |
| JP2013233649A (en) * | 2012-05-08 | 2013-11-21 | Wikus-Saegenfabrik Wilhelm H Kullmann Gmbh & Co Kg | Saw blade including blade part made by powder metallurgy |
| JP2015071812A (en) * | 2013-10-03 | 2015-04-16 | 山陽特殊製鋼株式会社 | Powdered high speed tool steel and manufacturing method thereof |
| CN114622122A (en) * | 2022-03-04 | 2022-06-14 | 长沙市萨普新材料有限公司 | High-niobium iron-based superhard material and preparation method thereof |
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