JPH0557798A - Manufacture and device for fiber reinforced resin pipe - Google Patents

Abstract

(57) [Abstract] [PROBLEMS] To provide a manufacturing method and a manufacturing apparatus for a fiber-reinforced resin pipe, which enhances the adhesion between the inner core layer and the FRP layer and facilitates the peeling work of the FRP layer at the time of pipe connection. thing. [Structure] An adhesive applying step of applying an adhesive to the outer peripheral surface of the inner core layer 1, and a FRP layer manufacturing step of a thermosetting resin containing continuous strips 5 made of fiber reinforcement and glass fibers 8 and 12, A continuous series of steps of a coating layer manufacturing step using a thermosetting resin containing a continuous strip 16 for coating the FRP layer, and an automatic cutting step of cutting the FRP composite pipe manufactured through the manufacturing step to a predetermined size, Supply warm air for a certain period of time F
A method for producing a fiber-reinforced resin pipe, comprising a post-curing step of completely curing the RP layer.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a fiber-reinforced resin pipe mainly used for transporting various chemicals, fluids for chemical industry, hot water, hot spring water and the like, and an apparatus thereof.

[0002]

2. Description of the Related Art Conventionally, as a resin composite pipe, for example, one disclosed in Japanese Patent Publication No. 62-22038 is known. This resin composite pipe has a hard vinyl chloride pipe as a core material, and its surface is coated with a fiber-reinforced thermosetting resin that has strength and rigidity in both the axial direction and the circumferential direction of the pipe, and the surface is further covered. It is coated with a thermoplastic resin selected from polyolefin and polyvinyl chloride.

[0003]

However, in this conventional resin composite pipe, the FRP layer is directly formed on the outer peripheral surface of the hard vinyl chloride pipe as the core material, and both are made of the thermosetting resin in the FRP layer. The resin composite tube is integrated by the adhesive force of 1. and the adhesive force has a large variation, so that there is a problem that the impact strength and the flat strength of the resin composite pipe are lowered. Further, in this resin composite pipe, there is a problem that workability is poor because the two layers of the coating layer made of a thermoplastic resin and the FRP layer must be peeled off at the time of connecting the pipes. Further, in this resin composite pipe, glass fibers in the axial direction are attached to the outer circumference of the inner core, and further, glass fibers are attached in the circumferential direction, so that the FRP is peeled off at the time of pipe connection, There is also a problem that the glass fibers are torn and the glass fibers remain outside the inner core tube. The present invention has been made in view of such conventional problems, and an object thereof is to enhance the adhesion between the inner core layer and the FRP layer, and to facilitate the peeling work of the FRP layer at the time of pipe connection. The present invention provides a method for manufacturing the fiber-reinforced resin pipe and a manufacturing apparatus for the same.

[0004]

As means for solving the above-mentioned problems, in the method for producing a fiber-reinforced resin pipe of the present invention, an adhesive is applied to the outer peripheral surface of the inner core layer made of a thermoplastic resin pipe. Agent coating step; laminating a continuous strip of fiber reinforced material impregnated with an ultraviolet curable resin (thermosetting resin) on the surface of the adhesive layer, and applying an ultraviolet curable resin (thermosetting resin) thereon An FRP layer manufacturing process in which the impregnated glass fibers are surrounded along the axial direction, then the glass fibers are wound on the glass fibers, and then the surface is hardened in an ultraviolet curing furnace; and the surface of the FRP layer is thermosetting. A step of laminating continuous strips impregnated with a resin, winding a release film on the strip, and then curing the coating in a thermosetting oven; and an inner core layer continuously produced by the above steps. A composite consisting of a FRP layer and a coating layer An automatic cutting step of cutting the tube at a predetermined size; a series of successive steps of employing a method comprising a post-curing step to fully cure in a post-curing oven the FRP layer. Further, in the fiber-reinforced resin pipe manufacturing apparatus of the present invention, an adhesive application unit for applying an adhesive to the outer peripheral surface of the inner core layer made of a thermoplastic resin pipe that is continuously supplied; The formed inner core layer is mounted at regular intervals, and a continuous strip made of a fiber reinforced material impregnated with an ultraviolet curable resin (thermosetting resin) is passed through to form a cylindrical shape, and the above-mentioned adhesion is achieved. An inversion guide for laminating continuous strips on the surface of the agent layer, a roving guide for surrounding glass fibers impregnated with an ultraviolet curable resin (thermosetting resin) on the outer periphery in the axial direction of the inner core layer, and a glass fiber FRP layer manufacturing unit comprising a drawing die for adjusting the outer diameter of the inner core layer enclosing the glass, a winding machine for winding glass fiber, and an ultraviolet curing furnace having a high pressure mercury lamp inside;
A reversal guide for laminating the continuous strips on the surface of the FRP layer by passing through the continuous strips impregnated with a thermosetting resin to form a cylindrical shape, A film winding machine that winds a release film on the strip, and a coating layer manufacturing unit that includes a thermosetting furnace; an automatic cutting device that cuts the manufactured composite pipe to a predetermined size; The ones arranged sequentially and F
The post-curing furnace was used to completely cure the RP layer at a predetermined temperature.

[0005]

In the method and apparatus for producing a fiber-reinforced resin pipe of the present invention, the adhesion between the inner core layer and the FRP layer is strengthened, and
It is possible to efficiently manufacture a fiber-reinforced resin pipe that facilitates the peeling work of the FRP layer when connecting the pipes.

[0006]

EXAMPLES Examples of the present invention will be described below.

First, a method of manufacturing a fiber reinforced resin pipe will be described. The method for producing a fiber-reinforced resin pipe of the present invention comprises an adhesive application step of applying an adhesive to the outer peripheral surface of the inner core layer, and a FRP layer made of a thermosetting resin containing a continuous strip of fiber reinforcement and glass fibers. A continuous series of a manufacturing process, a coating layer manufacturing process using a thermosetting resin containing a continuous strip for coating the FRP layer, and an automatic cutting process for cutting the FRP composite pipe manufactured through the manufacturing process into a predetermined size. Process of
This is a post-curing step in which hot air is supplied for a certain period of time to completely cure the FRP layer.

Each step will be described in turn.
In the adhesive application step, stains and the like adhering to the outer peripheral surface of the inner core layer made of a continuously supplied thermoplastic resin tube are wiped off with a solvent such as acetone, and then a hydroxyl group-terminated polyurethane resin or polyisocyanate is used. -The step of applying an adhesive of a ternary mixed material consisting of a polyester resin and an unsaturated polyester resin to the outer peripheral surface thereof, and then blowing off the solvent with hot air to dry by touch. Here, the thermoplastic resin tube means polyvinyl chloride resin such as polyvinyl chloride resin and chlorinated polyvinyl chloride resin, polyamide resin, acrylic resin, and polycarbonate.
It is formed from a resin such as a bone resin. As the thermoplastic resin pipe, a pipe produced by connecting pipes produced in advance and connecting them, or a pipe produced continuously by extrusion molding is used. Further, as the adhesive, for example, when the inner core layer is a vinyl chloride resin, it has been experimentally confirmed that the adhesion between the inner core layer and the FRP layer is improved and the long-term heat resistance is improved. A mixed substance, that is, a mixed substance composed of a hydroxyl-terminated polyurethane resin, polyisocyanate, and unsaturated polyester resin is used.

Next, in the FRP manufacturing process, a continuous strip made of a fiber reinforced material in which the surface of the inner core layer coated with the adhesive in the adhesive coating process is impregnated with an ultraviolet curable resin (thermosetting resin) is formed. Laminated, glass fiber impregnated with ultraviolet curable resin (thermosetting resin) on it is surrounded along the axial direction,
Next, it refers to a step in which glass fibers are wound on the glass fiber and then cured in an ultraviolet curing furnace. In order to manufacture an FRP tube having excellent dimensional accuracy, it is preferable to adjust the outer diameter again with a shaping die before surface hardening with ultraviolet rays. Here, glass cloth is used as the continuous strip. As the ultraviolet curable resin with which the continuous strip is impregnated, for example, a heat-resistant unsaturated polyester resin mixed with a photosensitizer is used. As the glass fiber attached along the axial direction on the glass cloth and the glass fiber wound in the circumferential direction, for example, roving glass is used.

Next, in the coating layer manufacturing step, a continuous strip impregnated with a thermosetting resin is laminated on the FRP layer, and a release film is wound on the continuous strip to heat cure in an air-shielded environment. It refers to the process of hardening by passing through a furnace. Here, a thermosetting unsaturated polyester resin is used as the thermosetting resin. A polyester non-woven fabric is used as the continuous strip. As the release film, for example, polyethylene terephthalate is used. A far infrared curing furnace is used as the heat curing furnace.

Next, the automatic cutting step is a step of automatically cutting the composite pipe consisting of the inner core layer, the FRP layer, and the coating layer, which are continuously manufactured in the above-mentioned step, into a certain length.

Next, in the post-curing step, hot air is supplied for a certain period of time to completely cure the FRP layer. The release film is removed after this post-curing step.

Therefore, in the method for manufacturing the fiber-reinforced resin pipe of this embodiment, since the inner core layer and the FRP layer are adhered with an adhesive and the glass cloth is laminated on the lowermost layer of the FRP layer, Adhesion with the FRP layer can be improved and problems such as delamination and cracking can be prevented. Moreover, when the FRP layer is peeled off, the glass cloth does not break even if it is forcibly peeled off, and the peeling work is performed. A fiber-reinforced resin pipe that can be smoothly manufactured can be manufactured.

Next, the apparatus for manufacturing the fiber-reinforced resin pipe of the present invention will be described. An apparatus for manufacturing a fiber-reinforced resin pipe of the present invention includes an adhesive application unit for applying an adhesive to the outer peripheral surface of an inner core layer made of a thermoplastic resin pipe, an ultraviolet ray containing a continuous strip made of a fiber reinforcement and glass fibers. An FRP layer manufacturing unit for manufacturing an FRP layer of a cured resin (thermosetting resin), a coating layer manufacturing unit for manufacturing a coating layer of a continuous strip impregnated with a thermosetting resin, and an FRP manufactured by the manufacturing unit. It is composed of a series of devices arranged in sequence, which is an automatic cutting device for cutting the composite pipe into a predetermined size, and a post-curing furnace for completely curing the FRP layer by supplying hot air for a certain period of time.

The respective units will be described with reference to FIG. 1. In the adhesive application unit, the outer peripheral surface of the inner core layer 1 made of a thermoplastic resin tube which is connected by a tape and continuous is used as a solvent such as acetone. From the solvent brush 2 to be wiped with, an adhesive coating die 3 that applies an adhesive diluted with a solvent to the surface of the inner core layer 1, and an adhesive drying device 4 that dries the solvent in the adhesive to dry it by touch. It will be.

Next, in the FRP layer manufacturing unit, the glass cloth 5 is impregnated with an ultraviolet curable resin (thermosetting resin), and a resin impregnating tank 6 and an inner core layer 1 coated with an adhesive are provided at a constant interval. The glass cloth 5 impregnated with the ultraviolet curable resin (thermosetting resin) is passed through the glass cloth 5 to be formed into a cylindrical shape, which is laminated on the surface of the adhesive layer. Thermosetting resin)
A resin impregnation tank 9 for impregnating the bing glass 8, a traveling guide 10 for surrounding the traveling glass 8 along the axial direction of the inner core layer 1, and an excess resin for squeezing out the traveling glass and the traveling glass. 8. A squeezing die 11 that removes air and adjusts the outer diameter, a winding machine 13 that winds a roving glass 12, two ultraviolet curing furnaces 14 and 14 in which a high-pressure mercury lamp is placed, and a take-up machine. 15 and. If a shaping ring made of an elastic material is provided in front of the ultraviolet curing furnace, FRP pipes having excellent dimensional accuracy can be continuously produced. In addition, the resin impregnation tank 6,
A single impregnation tank may also be used for 9.

Next, the coating layer manufacturing unit is mounted with a polyester non-woven fabric 16, a resin impregnated layer 17 for impregnating the non-woven fabric 16 with a thermosetting resin, and an FRP layer at regular intervals. The inversion guide 18 which is formed into a cylindrical shape by passing the nonwoven fabric 16 impregnated with and is laminated on the surface of the FRP layer, and the polyester-based nonwoven fabric 1
6, a film winding machine 20 for winding the release film 19 from above, and a far-infrared curing furnace 21 which completes the curing reaction by passing it under an air-shielding environment. The thermal curing furnace 21 is not limited to the far infrared curing furnace.

Next, the automatic cutting device 22 is for cutting the composite pipe continuously manufactured by the unit into a predetermined size.

Next, the post-curing furnace 23 is for supplying hot air for a certain period of time to completely cure the FRP layer.

Therefore, according to the apparatus for producing a fiber-reinforced resin pipe of this embodiment, peeling or cracking does not occur even when used in piping for high-temperature chemicals and the like, and the FRP layer can be easily peeled when connecting the piping. The fiber-reinforced resin pipe can be continuously produced.

[0021]

As described above, according to the present invention, peeling or cracking does not occur even when used for piping of high temperature water, and the FRP layer is easily peeled when connecting the piping, and workability is improved. There is an effect that the fiber-reinforced resin pipe can be continuously manufactured.

Further, in the present invention, since the glass fibers in the axial direction and the circumferential direction are arranged and reinforced on the continuous strip made of the fiber reinforced material, the glass fibers in the axial direction or the circumferential direction are reinforced. There is an effect that the fiber-reinforced resin pipe can be freely designed and manufactured according to the intended use by adjusting the amount.

Further, although the resin cannot be colored when ultraviolet curing is performed, in the present invention, since the outer layer of the FRP layer is coated with a continuous strip impregnated with a thermosetting resin, this resin is used. The fiber-reinforced resin tube can be freely colored by adding a pigment to the.

Further, in the present invention, the FRP is provided on the outer layer of the FRP layer.
Since a fiber-reinforced resin pipe with high adhesion between the FRP layer and the coating layer is formed by coating a continuous strip impregnated with the same type of resin as the layer resin, the FRP layer peels once when connecting the pipes. It is possible to produce a fiber-reinforced resin tube that can be processed by

Further, in the present invention, since the coating layer is formed in an air-shielded environment, it is possible to manufacture a fiber-reinforced resin pipe having a clean appearance and excellent weather resistance and water resistance. ..

[Brief description of drawings]

FIG. 1 is a side view showing an apparatus for manufacturing a fiber-reinforced resin pipe of the present invention.

[Explanation of symbols]

 1 Inner core layer 3 Adhesive coating die 5 Glass cloth (continuous strip) 7 Inversion guide 8 Roving glass (glass fiber) 10 Roving guide 11 Drawing die 12 Roving glass (glass fiber) 14, 14 UV Curing furnace 16 Polyester nonwoven fabric (continuous strip) 18 Inversion guide 19 Release film 20 Film winding machine 21 Far infrared curing furnace (heat curing furnace) 22 Automatic cutting device 23 Post-curing furnace

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁵ Identification code Office reference number FI technical display location B29L 23:22

Claims (2)

[Claims] 1. An adhesive applying step of applying an adhesive to an outer peripheral surface of an inner core layer made of a thermoplastic resin tube; a continuous strip made of a fiber reinforced material in which an ultraviolet curable resin is impregnated on the surface of the adhesive layer. FRP layer production by stacking bodies, surrounding glass fibers impregnated with UV-curing resin along the axial direction, winding glass fibers on top of it, and then subjecting it to surface hardening in an UV-curing furnace A step of producing a coating layer in which a continuous strip impregnated with a thermosetting resin is laminated on the surface of the FRP layer, and then a release film is wound thereon and then cured in a heat curing furnace; An automatic cutting step of cutting a composite pipe consisting of an inner core layer, an FRP layer and a coating layer, which are continuously produced by the above steps, to a predetermined size; and a continuous series of steps, and the FRP layer is completely cured in a post-curing furnace A post-curing step A method for producing a fiber-reinforced resin pipe, characterized by: 2. An adhesive application unit for applying an adhesive to the outer peripheral surface of an inner core layer made of a thermoplastic resin tube that is continuously supplied; a constant interval on the inner core layer on which the adhesive layer is formed. And a reversal guide for laminating a continuous strip on the surface of the adhesive layer by forming a continuous strip made of a fiber reinforcement impregnated with an ultraviolet curable resin into a cylindrical shape, A roving guide that surrounds glass fibers impregnated with an ultraviolet curable resin on the outer circumference in the axial direction of the inner core layer, a drawing die that adjusts the outer diameter of the inner core layer that surrounds the glass fibers, and the glass fibers are wound. An FRP layer manufacturing unit including a winding machine and an ultraviolet curing furnace having a high-pressure mercury lamp arranged therein; a FRP layer-equipped unit which is mounted at regular intervals and which is passed through a continuous strip impregnated with a thermosetting resin. Cylinder The FRP
A reversal guide for laminating continuous strips on the surface of layers, a film winding machine for winding a release film on the continuous strips, and a coating layer production unit comprising a thermosetting oven; An apparatus for producing a fiber-reinforced resin pipe, comprising: an automatic cutting device for cutting into a size; and a series of devices arranged in sequence, and a post-curing furnace for completely curing the FRP layer at a predetermined temperature.