JPH0578232A - Bathing agent - Google Patents
Bathing agentInfo
- Publication number
- JPH0578232A JPH0578232A JP23824891A JP23824891A JPH0578232A JP H0578232 A JPH0578232 A JP H0578232A JP 23824891 A JP23824891 A JP 23824891A JP 23824891 A JP23824891 A JP 23824891A JP H0578232 A JPH0578232 A JP H0578232A
- Authority
- JP
- Japan
- Prior art keywords
- water
- silk fibroin
- bathing
- soluble
- bath agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000003287 bathing Methods 0.000 title abstract description 10
- 108010022355 Fibroins Proteins 0.000 claims abstract description 19
- 239000013040 bath agent Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000007062 hydrolysis Effects 0.000 abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 4
- 108010038807 Oligopeptides Proteins 0.000 abstract description 3
- 102000015636 Oligopeptides Human genes 0.000 abstract description 3
- 150000001413 amino acids Chemical class 0.000 abstract description 3
- 229910017053 inorganic salt Inorganic materials 0.000 abstract description 3
- 239000002562 thickening agent Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 241000255789 Bombyx mori Species 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 description 1
- 239000003788 bath preparation Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- OUHCLAKJJGMPSW-UHFFFAOYSA-L magnesium;hydrogen carbonate;hydroxide Chemical compound O.[Mg+2].[O-]C([O-])=O OUHCLAKJJGMPSW-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は湯上がり感に優れた浴用
剤に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a bath agent having an excellent feeling of boiling water.
【０００２】[0002]
【従来の技術】一般に、浴湯中に溶解して使用される浴
用剤は、無水硫酸ナトリウム、炭酸カルシウム、炭酸水
素ナトリウム等の無機塩類を主成分として、これに香
料、着色料を配合したものが多いが、湯上がり感は必ず
しも満足すべきものではない。また、アミノ酸やオリゴ
ペプチドを含有し湯上がり感に優れた浴用剤も知られて
いない。2. Description of the Related Art Generally, a bath agent which is used by dissolving it in hot water is composed mainly of an inorganic salt such as anhydrous sodium sulfate, calcium carbonate, sodium hydrogen carbonate, and a fragrance and a coloring agent. However, the feeling of bathing is not always satisfactory. Further, a bath agent containing an amino acid or an oligopeptide and having an excellent feeling after bathing is not known.
【０００３】一方、絹フィブロインは、蚕の体内で生合
成される天然タンパク質である。蚕の体内では液状を保
っているが、蚕の口より吐出されると繊維状の個体とな
り、水に不溶性となる。絹は古来よりその優美な光沢と
滑らかな肌触りより衣料素材として珍重されている。ま
た、絹のイメ−ジを活用して化粧品原料としての利用が
考えられ物理的または化学的方法により微細な粒子とな
し、これらを添加した石鹸、クリ−ム等が開発されてい
る。しかし、これらの絹フィブロインは水不溶性のため
利用方法が限られており、近年加水分解により絹を水溶
化し食品に用いられている（蚕糸科学と技術、vol30, 4
2 (1991)）。しかし水溶性絹フィブロインを浴用剤に用
いた例はない。On the other hand, silk fibroin is a natural protein biosynthesized in the silkworm body. Although it remains liquid within the body of the silkworm, it becomes fibrous when discharged from the mouth of the silkworm and becomes insoluble in water. Since ancient times, silk has been prized as a material for clothing due to its elegant luster and smooth texture. Further, it is considered that the silk image is used as a raw material for cosmetics, and fine particles are formed by physical or chemical methods, and soaps, creams, etc. to which these are added have been developed. However, since these silk fibroins are insoluble in water, their use is limited, and in recent years, silk has been solubilized by hydrolysis to be used in foods (silk thread science and technology, vol 30, 4
2 (1991)). However, there is no example of using water-soluble silk fibroin as a bath agent.
【０００４】[0004]
【発明が解決しようとする課題】本発明の課題は、肌を
しっとりかつすべすべさせ湯上がり感に優れた浴用剤を
提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a bath preparation which makes the skin moist and smooth and has an excellent feeling after bathing.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、水溶性の
絹フィブロインからなる浴用剤が上記の問題点を解決で
きることを見いだし本発明を完成した。すなわち本発明
は、絹フィブロインを含有することを特徴とする浴用剤
に関するものである。The present inventors have found that a bath agent made of water-soluble silk fibroin can solve the above problems and completed the present invention. That is, the present invention relates to a bath agent containing silk fibroin.
【０００６】水溶性の絹フィブロインは以下の方法で調
製される。絹糸、くず絹、紡績くず、くず繭等をアルカ
リまたは酸で加水分解して水溶化し、中和後透析等によ
り塩類を除去する。得られた脱塩液を濃縮し、凍結乾燥
または噴霧乾燥し必要により摩砕して、水溶性の絹フィ
ブロイン粉末を得る。加水分解の度合いは、絹が水溶化
すれば目的を達するが、絹フィブロインペプチドとして
の平均分子量が５００程度にすると収率が高い。浴用剤
に無機塩類を添加して用いる場合は、脱塩工程を省略す
ることもできる。Water-soluble silk fibroin is prepared by the following method. A silk thread, waste silk, spun waste, waste cocoon, etc. are hydrolyzed with an alkali or an acid to make them water-soluble, and after neutralization, salts are removed by dialysis or the like. The resulting desalted solution is concentrated, freeze-dried or spray-dried, and optionally ground, to obtain a water-soluble silk fibroin powder. The degree of hydrolysis reaches the purpose when the silk is water-solubilized, but the yield is high when the average molecular weight of the silk fibroin peptide is about 500. When inorganic salts are added to the bath agent, the desalting step can be omitted.
【０００７】浴用剤は下記の方法で調製される。水溶性
絹フィブロインの配合量は５〜９０％の範囲で選択する
ことができる。好ましくは１０〜５０％で用いられる。
本浴用剤に配合する他の配合剤としては無機塩、油性成
分、水に不溶の微粉糖類、増粘剤、各種界面活性剤、香
料、色素、分散剤等があり通常の浴用剤に用いられる配
合剤を添加することができる。The bath agent is prepared by the following method. The amount of water-soluble silk fibroin can be selected in the range of 5 to 90%. It is preferably used at 10 to 50%.
Other compounding agents to be added to the present bath agent include inorganic salts, oily ingredients, water-insoluble fine powder saccharides, thickeners, various surfactants, fragrances, pigments, dispersants, etc., which are used in ordinary bath agents. Compounding agents can be added.
【０００８】無機塩としては、塩化ナトリウム、炭酸ナ
トリウム、塩化カリウム、硫化カリウム、リン酸ナトリ
ウム、無水硫酸ナトリウム、炭酸水素ナトリウム、炭酸
カルシウム、無水硫酸マグネシウム、炭酸マグネシウム
等通常用いられる無機塩類も一種または二種以上を配合
して用いる。As the inorganic salt, one or more commonly used inorganic salts such as sodium chloride, sodium carbonate, potassium chloride, potassium sulfide, sodium phosphate, anhydrous sodium sulfate, sodium hydrogencarbonate, calcium carbonate, anhydrous magnesium sulfate, magnesium carbonate or the like can be used. Used in combination of two or more kinds.
【０００９】油性成分としては、サフラワ−油、ゴマ
油、ホホバ油、カカオ油、オリ−ブ油、スクワラン等が
用いられる。増粘剤としては、メチルセルロ−ス等の水
溶性高分子が用いられる。界面活性剤としては、Ｎ，Ｎ
−ジアルキルアミノアルキレンアンモニウムベタイン等
の両性イオン界面活性剤が用いられる。As the oily component, safflower oil, sesame oil, jojoba oil, cocoa oil, olive oil, squalane and the like are used. A water-soluble polymer such as methyl cellulose is used as the thickener. As the surfactant, N, N
-Zwitterionic surfactants such as dialkylaminoalkylene ammonium betaines are used.
【００１０】本発明の浴用剤の形状は、適宜選択でき例
えば顆粒状、タブレット状等が用いられる。The shape of the bath agent of the present invention can be appropriately selected and, for example, granules, tablets and the like are used.
【００１１】[0011]
【作用】本発明の浴用剤は、水溶性の絹フィブロインを
配合したことにより絹フィブロインの加水分解したアミ
ノ酸またはオリゴペプチドが肌に吸着もしくは吸収され
優れた湯上がり感を得ることができ、健康増進にも効果
的である。[Function] The bath agent of the present invention contains water-soluble silk fibroin, so that the hydrolyzed amino acid or oligopeptide of silk fibroin can be adsorbed or absorbed on the skin to obtain an excellent feeling of bathing, which improves health. Is also effective.
【００１２】[0012]
実施例１ 水溶性絹フィブロインの調製 ２Ｎ塩酸８ｌに、くず絹１００ｇを加え１００℃で４８
時間処理し完全に溶解させた。２Ｎの水酸化ナトリウム
で中和後、室温で限外濾過膜を用いて透析を８時間行っ
た。終了後、２００ｍｌまで減圧濃縮し、凍結乾燥を行
った。水溶性絹フィブロイン９０ｇが得られた（収率９
０％）。平均分子量は４５０であった。Example 1 Preparation of Water-Soluble Silk Fibroin To 8 l of 2N hydrochloric acid, 100 g of waste silk was added and the mixture was heated at 100 ° C. for 48 hours.
It was treated for a time and completely dissolved. After neutralizing with 2N sodium hydroxide, dialysis was performed at room temperature for 8 hours using an ultrafiltration membrane. After completion, the solution was concentrated under reduced pressure to 200 ml and freeze-dried. 90 g of water-soluble silk fibroin was obtained (yield 9
0%). The average molecular weight was 450.
【００１３】実施例２ 実施例１で調製した水溶性絹フィブロイン粉末 ８０
ｇ、無水硫酸ナトリウム１００ｇ、炭酸水素ナトリウム
１００ｇ、香料（α−アミルシンナミックアルデヒ
ド）１ｇを混合し、ロ−リングパンにより顆粒状の浴用
剤Ａを調製した。Example 2 Water-soluble silk fibroin powder prepared in Example 1 80
g, 100 g of anhydrous sodium sulfate, 100 g of sodium hydrogen carbonate, and 1 g of a fragrance (α-amylcinnamic aldehyde) were mixed, and a granular bath agent A was prepared by a rolling pan.
【００１４】比較例１ 水溶性絹フィブロイン粉末を除いた以外は、実施例１と
同じ配合と製法により顆粒状の浴用剤Ｂを調製した。Comparative Example 1 A granular bath agent B was prepared by the same formulation and production method as in Example 1 except that the water-soluble silk fibroin powder was removed.
【００１５】評価例 パネラ−２０人に実施例２と比較例１で調製した各浴用
剤を１０日間づつ使用させ、湯上がり後の肌のしっとり
感とすべすべ感を官能評価した。使用方法は浴用剤５０
ｇを浴湯２００〜２５０ｌに溶解して使用した。結果を
表１に示した。Evaluation Example 20 panelists were made to use each of the bath agents prepared in Example 2 and Comparative Example 1 for 10 days, and the skin moisturizing feeling and smoothness after bathing were sensory evaluated. Usage is bath agent 50
g was dissolved in 200 to 250 l of hot water and used. The results are shown in Table 1.
【００１６】[0016]
【表１】 [Table 1]
Claims (2)
る浴用剤1. A bath agent containing silk fibroin.
とする請求項１記載の浴用剤2. The bath agent according to claim 1, wherein the silk fibroin is water-soluble.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23824891A JPH0578232A (en) | 1991-09-18 | 1991-09-18 | Bathing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23824891A JPH0578232A (en) | 1991-09-18 | 1991-09-18 | Bathing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0578232A true JPH0578232A (en) | 1993-03-30 |
Family
ID=17027355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23824891A Pending JPH0578232A (en) | 1991-09-18 | 1991-09-18 | Bathing agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0578232A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07247211A (en) * | 1994-03-08 | 1995-09-26 | Kanebo Ltd | Bathing agent composition |
| JPH11139986A (en) * | 1997-11-04 | 1999-05-25 | Ichimaru Pharcos Co Ltd | Bioactive composition derived from silk protein hydrolyzate |
| JP2005002063A (en) * | 2003-06-13 | 2005-01-06 | Shiseido Co Ltd | Agent for promoting recovery of barrier function of skin |
| JP2008088185A (en) * | 2007-11-29 | 2008-04-17 | Ichimaru Pharcos Co Ltd | Immunostimulant derived from silk protein hydrolyzate |
| US7901668B2 (en) | 2001-11-29 | 2011-03-08 | Eaudelman Co., Ltd. | Silk fibroin emulsifier and process for the production thereof |
-
1991
- 1991-09-18 JP JP23824891A patent/JPH0578232A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07247211A (en) * | 1994-03-08 | 1995-09-26 | Kanebo Ltd | Bathing agent composition |
| JPH11139986A (en) * | 1997-11-04 | 1999-05-25 | Ichimaru Pharcos Co Ltd | Bioactive composition derived from silk protein hydrolyzate |
| US7901668B2 (en) | 2001-11-29 | 2011-03-08 | Eaudelman Co., Ltd. | Silk fibroin emulsifier and process for the production thereof |
| JP2005002063A (en) * | 2003-06-13 | 2005-01-06 | Shiseido Co Ltd | Agent for promoting recovery of barrier function of skin |
| JP2008088185A (en) * | 2007-11-29 | 2008-04-17 | Ichimaru Pharcos Co Ltd | Immunostimulant derived from silk protein hydrolyzate |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20010403 |