JPH057987B2 - - Google Patents
Info
- Publication number
- JPH057987B2 JPH057987B2 JP58170004A JP17000483A JPH057987B2 JP H057987 B2 JPH057987 B2 JP H057987B2 JP 58170004 A JP58170004 A JP 58170004A JP 17000483 A JP17000483 A JP 17000483A JP H057987 B2 JPH057987 B2 JP H057987B2
- Authority
- JP
- Japan
- Prior art keywords
- soy sauce
- treatment
- decolorization
- flavor
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- Soy Sauces And Products Related Thereto (AREA)
Description
本発明は、醤油を原料とし、低塩、淡色かつ高
窒素で風味及び安定性に優れた液体調味料を製造
する方法に関する。
醤油は和風料理の基本的調味料として、更には
中華、洋風料理の調味料として広く利用されてい
る。従来、醤油には、その色の濃淡によりいわゆ
る濃口醤油と淡口醤油とがあり、料理の種類等に
応じて使い分けられている。また近年、高血圧そ
の他の成人病等、ナトリウムの過剰摂取に由来す
る問題点が指摘されることが多く、食塩濃度を低
減した減塩醤油も普及している。
この減塩醤油の製造は、低塩分濃度下、雑菌の
増殖を抑制しながら、醸造する、又は常法により
調製した醤油を、イオン交換膜等で電気透析し、
脱塩する等の方法により行われているが、前者の
方法は、醤油本来の芳醇な香味に欠ける傾向にあ
るため、醤油本来の香味を保持しつつ低塩化する
目的では後者の方法による必要がある。
一方、近年、食生活の多様化に伴い、醤油につ
いても多様化に対応すると共により嗜好性の高い
ものが求められる傾向にあるが、上記の電気透析
法による醤油は、色の安定性及び従来の醤油に優
る嗜好性の点で必ずしも満足できない。この色の
安定性を改善するには吸着樹脂処理、活性炭処
理、分子ふるい膜処理等により醤油中の褐変成分
を分画除去する方法が有効である。
従つて、淡色、低塩で安定性の高い醤油を得る
には、上記電気透析による脱塩処理と分子ふるい
処理による脱色とを併用して行えばよい訳である
が、この両処理を単に組合せて得られる醤油は、
その風味において、従来品と変わらないか又は若
干劣る傾向にある。
本発明者らは、上記現状を背景に、低塩、淡色
でかつ風味の著しく改善された醤油乃至は液体調
味料の取得につき鋭意検討を重ねた結果、脱塩、
脱色醤油における窒素濃度を一定値以上に高めた
場合、風味において従来品と有意に識別し得る嗜
好性の高い液体調味料が得られるとの知見に至つ
た。
本発明は、かかる知見に基づき完成されたもの
であり、即ち、生醤油又は火入れ醤油に対し、電
気透析による脱塩処理と分子ふるい膜による脱色
処理とを組合せて行い、食塩濃度12g/dl以下、
色度2.0以下好ましくは1.5以下及び総窒素1.5g/
dl以上とすることを特徴とする液体調味料の製造
法である。
なお、本発明でいう色度とは、水を対照として
10mmガラスセルを用い、波長562nm、532nmで
測定した吸光度の相加平均である。
電気透析による脱塩処理はイオン交換膜等を用
いて行い、食塩濃度12g/dl以下、好ましくは9
〜10g/dlまで脱塩する。
本発明においては、この電気透析による脱塩処
理を分子ふるい膜による脱色処理とを併用する
が、両処理を行う順序は特に限定されない。好ま
しくは最終製品の色を淡しくかつ色安定性を高め
るためには、脱塩処理後に脱色処理を施す方がよ
い。
脱色処理は、分子ふるい膜を用いて色度2.0以
下、好ましくは0.8〜1.5まで行う。分子ふるい膜
の具体例としては、帝人エンジニアリング(株)製
「TL−230」、日東電工製「NTR−1510」等が挙
げられるが、特に上記「TL−230」又はこれと同
等の機能を有する10%シヨ糖溶液の阻子率が20〜
40%であるような逆浸透膜を用い、好ましくは、
分子量500以上の成分を除去する。
本発明の液体調味料の総窒素は、1.5g/dl以
上であるが、これは、例えば、上記脱塩脱色処理
に用いる原料醤油として総窒素含量の高いもの使
用する、或いは、脱色率が高くかつ窒素成分ロス
の少ない分子ふるい膜を使用する等の方法で行
う。具体的には、脱塩・脱色処理により通例総窒
素は、原料の80〜85%程度に減少するので、原料
醤油として総窒素約1.9g/dl以上のものを使用
する。或いは、一般に脱色率が高まると、それに
比率して総窒素が減少するが、総窒素量の減少が
少なく、しかも脱色効果の高い上記「TL−230」
等の分子ふるい膜により処理する、更には、いわ
ゆるたまり醤油等の高窒素原料を「TL−230」で
膜処理する等の方法が有効である。
上記方法で得られた食塩濃度12g/dl以下
(KCl等を含めない濃度)及び色度2.0以下の醤油
は低ナトリウムでかつ保存中の色、風味等の品質
変化が少ないが、総窒素1.5g/dl以下の場合、
醤油特有のこく、風味において既存品に比べ変化
がないか劣るものしか得られない。この総窒素を
1.5g/dl以上とすることにより、こく、風味に
おいて有意に識別できる嗜好性の高い液体調味料
が得られる。
原料醤油としては、生醤油、火入れ醤油のいず
れでもよく、生醤油を用い、脱塩脱色処理後火入
れするか、或いはそのまま生醤油の液体調味料と
して提供することもできる。
尚、醤油以外の成分、例えば、HAP、「味液」
(味の素(株)製)、魚節粉、魚節類油出液、酵母エキ
ス、昆布エキス、有機酸その他の各種香味成分又
は品質安定剤・改良剤の併用は、本発明の目的を
逸脱しない限り可能なことはいうまでもない。
次に実施例により本発明を更に説明する。
実施例 1
第1表に示すような各種醤油原料を用い、第2
表のような特性を持つ醤油を調整した。
醤油の脱塩にはイオン交換膜を用いた電気透析
法により(旭硝子(株)製 Du−Ob型)食塩濃度を
8g/dlに調整した。醤油の脱色はサンプルA,
Cについては、帝人エンジニアリング(株)製ROミ
ニテスター N−型を用い同社製、逆浸透膜
TL−230を使用し、膜脱色を行い、サンプルBに
ついては、帝人エンジニアリング(株)製逆浸透膜
TL−250により脱色した。
The present invention relates to a method for producing a liquid seasoning using soy sauce as a raw material, which is low in salt, light in color, high in nitrogen, and has excellent flavor and stability. Soy sauce is widely used as a basic seasoning in Japanese cuisine, as well as in Chinese and Western cuisine. Conventionally, soy sauce is divided into so-called dark soy sauce and light soy sauce, which are classified according to their color shading, and are used depending on the type of cooking. Furthermore, in recent years, problems such as hypertension and other adult diseases caused by excessive sodium intake have often been pointed out, and low-salt soy sauce with a reduced salt concentration has also become popular. This low-salt soy sauce is produced by brewing or preparing soy sauce using a conventional method under low salt concentration while suppressing the growth of bacteria, and then electrodialyzing it using an ion exchange membrane or the like.
This is done by methods such as desalting, but the former method tends to lack the rich flavor inherent in soy sauce, so the latter method is necessary in order to maintain the original flavor of soy sauce while reducing the salt content. be. On the other hand, in recent years, with the diversification of dietary habits, there is a trend for soy sauce to respond to diversification and to be more palatable. It is not necessarily satisfactory in terms of palatability superior to soy sauce. In order to improve the stability of this color, it is effective to fractionate and remove browning components in soy sauce using adsorption resin treatment, activated carbon treatment, molecular sieve membrane treatment, etc. Therefore, in order to obtain light-colored, low-salt, and highly stable soy sauce, it is sufficient to combine the desalting treatment using electrodialysis and the decolorization treatment using molecular sieving, but it is possible to simply combine these two treatments. The soy sauce obtained by
The flavor tends to be the same or slightly inferior to conventional products. Against the background of the above-mentioned current situation, the inventors of the present invention have conducted intensive studies to obtain soy sauce or liquid seasonings that are low in salt, light in color, and have significantly improved flavor.
It was discovered that when the nitrogen concentration in decolorized soy sauce is increased above a certain value, a liquid seasoning with high palatability that can be significantly distinguished from conventional products in flavor can be obtained. The present invention has been completed based on this knowledge. Namely, raw soy sauce or pasteurized soy sauce is subjected to a combination of desalination treatment using electrodialysis and decolorization treatment using a molecular sieve membrane to achieve a salt concentration of 12 g/dl or less. ,
Chromaticity 2.0 or less preferably 1.5 or less and total nitrogen 1.5g/
This is a method for producing a liquid seasoning characterized by having a liquid seasoning of DL or more. In addition, chromaticity as used in the present invention refers to chromaticity with water as a contrast.
This is the arithmetic average of absorbance measured at wavelengths of 562 nm and 532 nm using a 10 mm glass cell. Desalination treatment by electrodialysis is performed using an ion exchange membrane, etc., and the salt concentration is 12 g/dl or less, preferably 9
Desalt to ~10g/dl. In the present invention, the desalination treatment by electrodialysis and the decolorization treatment by a molecular sieve membrane are used together, but the order in which these two treatments are performed is not particularly limited. Preferably, in order to lighten the color of the final product and improve color stability, it is better to perform a decoloring treatment after the desalting treatment. Decolorization treatment is performed using a molecular sieve membrane to a chromaticity of 2.0 or less, preferably 0.8 to 1.5. Specific examples of molecular sieve membranes include "TL-230" manufactured by Teijin Engineering Co., Ltd. and "NTR-1510" manufactured by Nitto Denko, but in particular, the above-mentioned "TL-230" or those having an equivalent function. The blockage rate of 10% sucrose solution is 20~
Preferably using a reverse osmosis membrane that is 40%
Remove components with a molecular weight of 500 or more. The total nitrogen of the liquid seasoning of the present invention is 1.5 g/dl or more, but this may be due to, for example, using a soy sauce with a high total nitrogen content as the raw material soy sauce used in the desalting and decoloring treatment, or a high decolorization rate. This is done using a method such as using a molecular sieve membrane that causes less loss of nitrogen components. Specifically, since the total nitrogen content is usually reduced to about 80 to 85% of the raw material by desalting and decolorizing treatment, a soy sauce with a total nitrogen content of about 1.9 g/dl or more is used as the raw material soy sauce. Alternatively, when the decolorization rate increases, the total nitrogen decreases in proportion to it, but the above-mentioned "TL-230" which has a small decrease in the total nitrogen amount and has a high decolorization effect.
It is also effective to treat high nitrogen raw materials such as so-called tamari soy sauce with a molecular sieve membrane such as "TL-230". The soy sauce obtained by the above method with a salt concentration of 12 g/dl or less (not including KCl, etc.) and a chromaticity of 2.0 or less is low in sodium and shows little change in quality such as color and flavor during storage, but has a total nitrogen content of 1.5 g. /dl or less,
Compared to existing products, the unique body and flavor of soy sauce is either unchanged or inferior. This total nitrogen
By adjusting the amount to 1.5 g/dl or more, a liquid seasoning with high palatability that can be significantly distinguished in body and flavor can be obtained. The raw soy sauce may be either raw soy sauce or pasteurized soy sauce, and raw soy sauce may be used and pasteurized after salting and decolorization, or it may be provided as is as a raw soy sauce liquid seasoning. Ingredients other than soy sauce, such as HAP, "flavor liquid"
(manufactured by Ajinomoto Co., Inc.), fish flakes powder, fish flakes oil extract, yeast extract, kelp extract, organic acids, and other flavor components or quality stabilizers/improvers may be used in combination without departing from the purpose of the present invention. Needless to say, this is as possible as possible. Next, the present invention will be further explained with reference to Examples. Example 1 Using various soy sauce raw materials as shown in Table 1,
We prepared soy sauce with the characteristics shown in the table. To desalt the soy sauce, the salt concentration was adjusted to 8 g/dl by electrodialysis using an ion exchange membrane (Du-Ob type manufactured by Asahi Glass Co., Ltd.). Sample A for decolorizing soy sauce.
For C, we used Teijin Engineering Co., Ltd.'s RO Mini Tester N-type and reverse osmosis membrane manufactured by Teijin Engineering Co., Ltd.
Membrane decolorization was performed using TL-230, and for sample B, reverse osmosis membrane manufactured by Teijin Engineering Co., Ltd.
Decolorization was performed using TL-250.
【表】【table】
【表】【table】
【表】
第2表に示す5サンプルについて、訓練された
味覚パネル20名を用い、豆腐のつけだけとして、
順位法による官能評価を実施した。
結果を第3表に示す。[Table] Using 20 trained taste panels, the five samples shown in Table 2 were used as just a tofu dipping sauce.
Sensory evaluation was performed using the ranking method. The results are shown in Table 3.
【表】
以上の結果から明らかなようにサンプルAは他
の4サンプルより有意差を持つて好まれる。
実施例 2
原料として溜醤油を用いて、実施例1と同様
に、電気透析による脱塩に引き続き、逆浸透膜
(TL−230)による脱色を行つた。
この場合の原料溜醤油と脱塩・脱色後の溜醤油
の特性値を第4表に示す。[Table] As is clear from the above results, sample A is preferred over the other four samples with a significant difference. Example 2 Using distilled soy sauce as a raw material, in the same manner as in Example 1, desalination by electrodialysis was followed by decolorization by a reverse osmosis membrane (TL-230). Table 4 shows the characteristic values of the raw tamed soy sauce and the tamed soy sauce after desalting and decolorization in this case.
【表】
脱塩脱色処理を行つた溜醤油は、市販濃口醤油
と比較して色度および食塩濃度は1/2以下である
にもかかわらず、T−Nは約1.5倍であり、口当
りがやわらかく、濃厚でコク味が強い。また、溜
醤油特有の味噌臭さも消失し、くせのない香りと
なつた。[Table] Tame soy sauce that has undergone desalting and decolorization has a chromaticity and salt concentration less than half that of commercially available koikuchi soy sauce, but its T-N is approximately 1.5 times higher and its mouthfeel is lower. It's soft, rich, and has a strong flavor. Additionally, the miso odor characteristic of tamed soy sauce disappeared, and the flavor became more neutral.
Claims (1)
油に対し、電気透析による脱塩処理と分子ふるい
膜による脱色処理とを組合せて行い、食塩濃度12
g/dl以下、色度2.0以下及び総窒素1.5g/dl以
上とすることを特徴とする液体調味料の製造法。1. For fresh soy sauce or pasteurized soy sauce with a total nitrogen content of 1.9 g/dl or more, a combination of desalination treatment using electrodialysis and decolorization treatment using a molecular sieve membrane is performed to reduce the salt concentration to 12
A method for producing a liquid seasoning characterized by having a chromaticity of 1.5 g/dl or less, a chromaticity of 2.0 or less, and a total nitrogen content of 1.5 g/dl or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58170004A JPS6062958A (en) | 1983-09-14 | 1983-09-14 | Making of liquid seasoning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58170004A JPS6062958A (en) | 1983-09-14 | 1983-09-14 | Making of liquid seasoning |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6062958A JPS6062958A (en) | 1985-04-11 |
| JPH057987B2 true JPH057987B2 (en) | 1993-01-29 |
Family
ID=15896803
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58170004A Granted JPS6062958A (en) | 1983-09-14 | 1983-09-14 | Making of liquid seasoning |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6062958A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004357700A (en) * | 2003-05-12 | 2004-12-24 | Kao Corp | Low salt soy sauce |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0673433B2 (en) * | 1988-03-04 | 1994-09-21 | トキタ電子株式会社 | Seasoning with soy sauce flavor |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS531360B2 (en) * | 1971-09-09 | 1978-01-18 |
-
1983
- 1983-09-14 JP JP58170004A patent/JPS6062958A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004357700A (en) * | 2003-05-12 | 2004-12-24 | Kao Corp | Low salt soy sauce |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6062958A (en) | 1985-04-11 |
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