JPH0596127A - Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same - Google Patents

Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same

Info

Publication number
JPH0596127A
JPH0596127A JP3257069A JP25706991A JPH0596127A JP H0596127 A JPH0596127 A JP H0596127A JP 3257069 A JP3257069 A JP 3257069A JP 25706991 A JP25706991 A JP 25706991A JP H0596127 A JPH0596127 A JP H0596127A
Authority
JP
Japan
Prior art keywords
deodorizing
housing
malodor removing
removing agent
bed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3257069A
Other languages
Japanese (ja)
Inventor
Hirokore Nakazawa
宏是 中澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Kogyo KK
Original Assignee
Nihon Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Kogyo KK filed Critical Nihon Kogyo KK
Priority to JP3257069A priority Critical patent/JPH0596127A/en
Publication of JPH0596127A publication Critical patent/JPH0596127A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Treating Waste Gases (AREA)

Abstract

(57)【要約】 【目的】 圧力損失が小さく、かつ長期間ほぼ同一の圧
力損失を示し、立上り時間が極めて早く、その上悪臭除
去効率の極めて高い悪臭除去剤とその製法およびそれを
用いた脱臭装置の提供。 【構成】 土壌菌および/または活性汚泥菌を含有する
木質粉よりなることを特徴とする悪臭除去剤、前記悪臭
除去剤の製法において、腐触土および/または活性汚泥
から菌体を抽出し、得られた抽出液を木質粉に添加し、
木質粉の水分含有量を50〜75wt%に調整すること
を特徴とする悪臭除去剤の製法及び前記悪臭除去剤の層
およびそれを保持するため通水、通気性支持床よりなる
脱臭床、該脱臭床を収納したハウジング、該ハウジング
内の該脱臭床の下部に悪臭ガスを導入する手段、該脱臭
床を通過した排ガスをハウジングから排出するための手
段、該脱臭床を洗浄するための散水手段および該ハウジ
ングの底部に留った洗浄水を排水する手段よりなること
を特徴とする脱臭装置。
(57) [Summary] [Purpose] A malodor removing agent with a small pressure loss, almost the same pressure loss for a long period of time, an extremely fast rise time, and a very high malodor removing efficiency, its manufacturing method, and its use. Providing deodorizing equipment. [Structure] A malodor removing agent comprising a wood powder containing soil fungi and / or activated sludge fungi, and in the method for producing the malodor removing agent, fungus bodies are extracted from saprophytic soil and / or activated sludge, Add the resulting extract to wood flour,
A method for producing a malodor removing agent, characterized in that the water content of wood powder is adjusted to 50 to 75 wt%, and a layer of said malodor removing agent and a deodorizing bed comprising water-permeable and air-permeable supporting beds for holding the layer. A housing containing a deodorizing bed, a means for introducing a malodorous gas into the lower part of the deodorizing bed in the housing, a means for discharging the exhaust gas passing through the deodorizing bed from the housing, and a sprinkling means for cleaning the deodorizing bed. And a means for draining the wash water remaining at the bottom of the housing.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【技術分野】本発明は、系中の悪臭除去システムに関す
る。
TECHNICAL FIELD The present invention relates to a malodor removing system in a system.

【0002】[0002]

【従来技術】従来の生物悪臭除去システムとしては、土
壌脱臭システムが代表的なものである。この土壌脱臭シ
ステムは、適当な支持床上に一定の厚みで土壌層を設
け、この床中を悪臭含有ガスを通すことにより脱臭を行
うものであり、土壌中の菌が悪臭の分解に寄与している
とされている。土壌床の降雨と圧密による閉塞およびチ
ャンネリング、土壌層の部分嫌気と強酸性化による効果
の急低下、対象ガス中の夾雑物(タール)ならびに有機
物による土壌床下層の閉塞、土壌層の通気抵抗に基づく
床面積および層厚算定の困難性など、その他の操作因子
とともに土壌法の普及のためには解決しなければならな
い課題が存在する。一方、特開昭60−125227号
公報によれば、50〜75%含水率の木質細片とこれに
対して随意に添加される無機多孔質材料との混合物中に
各種悪臭成分を含む気体を送入し、そして前記混合物中
で前記悪臭成分を吸着および微生物反応により処理して
脱臭することを特徴とする木質細片による悪臭の微生物
処理方法が開示されており、悪臭成分の処理媒質層への
吸着に加えて悪臭の微生物活性による分解および消化等
の生化学的な処理は、外部から木質細片を含む処理媒質
層中に侵入して繁殖する微生物によって営まれるもので
ある旨説明されている。しかしながら、このシステムは
大気中の微生物が木質細片中で繁殖し、その能力を発揮
するまでの時間は少なくとも脱臭システムとして充分機
能できず、明らかにシステムの立上りが遅いという欠点
があり、また、微生物も大気中に存在するものに限られ
る。
2. Description of the Related Art A soil deodorizing system is typical of conventional biological malodor removing systems. This soil deodorization system is to deodorize by providing a soil layer with a certain thickness on a suitable support floor and passing a malodorous gas through this bed, and the bacteria in the soil contribute to the decomposition of the malodor. It is said that Closure and channeling of soil floor due to rainfall and consolidation, rapid decrease of effect due to partial anaerobic and strong acidification of soil layer, clogging of soil floor underlayer due to contaminants (tars) and organic substances in target gas, aeration resistance of soil layer There are issues that must be resolved for the spread of the soil method, along with other operational factors such as difficulty in calculating floor area and layer thickness based on On the other hand, according to Japanese Patent Application Laid-Open No. 60-125227, a gas containing various malodorous components is mixed in a mixture of wood chips having a water content of 50 to 75% and an inorganic porous material optionally added thereto. Disclosed is a method for treating a malodorous odor by wood chips, which comprises feeding and treating the malodorous component in the mixture by adsorption and microbial reaction to deodorize the malodorous component to a treatment medium layer. In addition to the adsorption of odor, biochemical treatment such as decomposition and digestion due to odorous microbial activity is explained to be performed by microorganisms that invade and propagate from the outside in the treatment medium layer containing wood chips. There is. However, this system has the drawback that the microorganisms in the atmosphere are propagated in the wood chips and at least the time it takes to exert its capacity is not sufficient to function as a deodorizing system, and that the system obviously starts up slowly. Microorganisms are also limited to those present in the atmosphere.

【0003】[0003]

【目的】本発明の目的は、圧力損失が小さく、かつ長期
間ほぼ同一の圧力損失を示し、立上り時間が極めて早
く、その上悪臭除去効率の極めて高い悪臭除去剤とその
製法およびそれを用いた脱臭装置を提供する点にある。
[Purpose] An object of the present invention is to provide a malodor removing agent having a small pressure loss, exhibiting almost the same pressure loss for a long period of time, an extremely fast rise time, and a very high malodor removing efficiency, a method for producing the malodor removing agent, and its use The point is to provide a deodorizing device.

【0004】[0004]

【構成】本発明の第一は、土壌菌および/または活性汚
泥菌を含有する木質粉よりなることを特徴とする悪臭除
去剤に関する。本発明の第二は、腐植土および/または
活性汚泥から菌体を抽出し、得られた抽出液を木質粉に
添加し、木質粉の水分含有量を50〜75wt%、好ま
しくは60〜65wt%に調整することを特徴とする悪
臭除去剤の製法に関する。本発明の第三は、土壌菌およ
び/または活性汚泥菌を含有する木質粉よりなる悪臭除
去剤の層およびそれを保持するため通水、通気性支持床
よりなる脱臭床、該脱臭床を収納したハウジング、該ハ
ウジング内の該脱臭床の下部に悪臭ガスを導入する手
段、該脱臭床を通過した排ガスをハウジングから排出す
るための手段、該脱臭床を洗浄するための散水手段およ
び該ハウジングの底部に留った洗浄水を排水する手段よ
りなることを特徴とする脱臭装置に関する。
[Structure] The first aspect of the present invention relates to a malodor removing agent comprising a wood powder containing soil bacteria and / or activated sludge bacteria. The second aspect of the present invention is to extract fungal cells from humus and / or activated sludge, add the obtained extract to wood flour, and have a water content of 50-75 wt%, preferably 60-65 wt. % Of the malodor removing agent. The third aspect of the present invention is to provide a layer of a malodor removing agent comprising wood powder containing soil fungus and / or activated sludge fungus, water passing therethrough for holding the layer, a deodorizing bed comprising an air-permeable supporting floor, and the deodorizing bed accommodated. Housing, means for introducing a malodorous gas into the lower part of the deodorizing bed in the housing, means for discharging the exhaust gas passing through the deodorizing bed from the housing, water sprinkling means for cleaning the deodorizing bed, and the housing The present invention relates to a deodorizing device comprising means for draining cleaning water remaining at the bottom.

【0005】第二の本発明における菌体の抽出には生理
的塩類溶液を使用することが好ましい。最低食塩のみを
含有する溶液でもよいが、KCl,CaCl2,MgC
2,NaHCO3,NaH2PO4,KH2PO4,グルコ
ース,MgSO4・7H2Oなどを必要に応じて含有する
生理的塩類溶液が好ましい。このような生理的塩類溶液
を使用する方が抽出菌体を長時間安定して生存させる上
で好ましいことである。菌体は、腐植土と活性汚泥を混
合し、2週間前後、またはそれ以上放置し、安定化させ
たものから抽出したものが最も好ましい。本発明の悪臭
除去剤は、菌体抽出液で処理してあるものであるから、
現場で支持床上に未処理の木質粉を置き、これに活性汚
泥をかけたものに較べてその立上り時間が早い。また、
活性汚泥の抽出液のみで処理したもの(A)に較べて活
性汚泥と腐植土の混合物から得られた抽出液で処理した
もの(B)はさらに立上りがよくなる。
It is preferable to use a physiological salt solution for the extraction of the bacterial cells in the second aspect of the present invention. A solution containing only minimum salt may be used, but KCl, CaCl 2 , MgC
A physiological salt solution containing, as required, l 2 , NaHCO 3 , NaH 2 PO 4 , KH 2 PO 4 , glucose, MgSO 4 .7H 2 O and the like is preferable. It is preferable to use such a physiological salt solution in order to allow the extracted cells to survive stably for a long time. Most preferably, the fungus body is extracted from a mixture obtained by mixing humus soil and activated sludge, leaving it for about 2 weeks or more, and stabilizing it. Since the malodor removing agent of the present invention is treated with the bacterial cell extract,
Rise time is faster than that of untreated wood flour placed on the support floor at the site and activated sludge is sprinkled on it. Also,
Compared with the one treated with only the activated sludge extract (A), the one treated with the extract obtained from the mixture of activated sludge and humus (B) has a better start-up.

【表1】 [Table 1]

【0006】本発明に用いる木質粉の木質については特
に制限はなく、間伐材や原材を利用するが、テルペン類
の含有率の高いものは余り好ましくない。木質粉は、保
水性がよく、しかも水はけがよいことや、圧力損失が少
なく、圧密化せず、微生物の付着が良好なものが好まし
い、木質粉の粒度は大体0.1〜10mm、好ましくは
0.2〜6mmである。
There is no particular limitation on the wood quality of the wood powder used in the present invention, and thinned wood or raw materials are used, but those with a high terpene content are not very preferable. It is preferable that the wood powder has good water retention, good drainage, low pressure loss, non-consolidation, and good adhesion of microorganisms. The particle size of the wood powder is about 0.1 to 10 mm, preferably It is 0.2-6 mm.

【0007】本発明の脱臭装置における散水は、たとえ
ば電磁弁またはポンプにより間欠運転(タイマーによ
る)で自動的に行ことが好ましい。また、散水に用いる
水は磁気処理された水を使用することが好ましい。その
理由は、磁気処理された水を使用する方が未処理の水を
使用した場合より菌体の増殖比が高いからである。磁場
強度と本発明における菌体の増殖比の関係は、図2に示
す。図2から明らかなように磁場強度が150Gあたり
の点で一回目の増殖比ピークを示し、300Gまではむ
しろ増殖比が低下し、その後、また上昇に転ずる。した
がって、磁気の有効利用を考えれば150G位の磁場中
に水を通すことが好ましい。また、本発明における菌体
抽出水、生理的塩類水溶液の水も前記磁気処理水である
ことが好ましい。さらに、本発明の木質粉には、必要に
応じて他の充填材、たとえば木炭、活性炭、コークス、
セラミックス、ゼオライトあるいはピートなどを混合し
て使用することもできる。
Water sprinkling in the deodorizing apparatus of the present invention is preferably performed automatically by intermittent operation (by a timer) by, for example, a solenoid valve or a pump. Further, it is preferable to use magnetically treated water as the water used for sprinkling. The reason is that the use of magnetically treated water has a higher bacterial growth rate than the case of using untreated water. The relationship between the magnetic field strength and the growth ratio of the bacterial cells in the present invention is shown in FIG. As is clear from FIG. 2, the first growth ratio peak appears at a magnetic field strength of around 150 G, and the growth ratio rather decreases up to 300 G, and then starts increasing again. Therefore, in consideration of effective use of magnetism, it is preferable to pass water through a magnetic field of about 150G. In addition, it is preferable that the cell extract water and the water of the physiological salt solution in the present invention are also the magnetically treated water. Further, the wood flour of the present invention may optionally contain other fillers such as charcoal, activated carbon, coke,
It is also possible to mix and use ceramics, zeolite, peat, or the like.

【0008】本発明装置の1例を図1を参照して説明す
る。ハウジング5内の脱臭床1は、支持体上に設けられ
たぐり石層または砕石層2、その上に形成された砂層3
およびその上に形成された本発明の悪臭除去剤層4より
構成される。処理ガスすなわち悪臭物質含有ガスはライ
ン6よりハウジング5の脱臭床1の下方に導入され、脱
臭床1を通過しながら悪臭を分解除去してハウジング上
方の排気ライン7より排気される。脱臭床1の洗浄は1
日4〜5回散水により行う。水はライン8により供給さ
れ、ポリ塩化ビニル製パイプの外側に馬蹄形永久磁石を
固定した磁化装置11を通り、スプレーノズル10によ
り散水される。散水により脱臭床1を洗浄した水は、ハ
ウジング5の底部に設けたライン9より排水される。ガ
ス流量は、通常空間速度45〜180/時の程度である
が、これに限定するものではない。
An example of the device of the present invention will be described with reference to FIG. The deodorizing bed 1 in the housing 5 is a ground stone layer or crushed stone layer 2 provided on a support, and a sand layer 3 formed thereon.
And the malodor removing agent layer 4 of the present invention formed thereon. The treatment gas, that is, the gas containing a malodorous substance, is introduced from the line 6 below the deodorizing bed 1 of the housing 5, decomposes and removes the malodor while passing through the deodorizing bed 1, and is exhausted from the exhaust line 7 above the housing. Cleaning the deodorizing floor 1 is 1
Watering is done 4-5 times a day. Water is supplied by a line 8, passes through a magnetizing device 11 having a horseshoe-shaped permanent magnet fixed to the outside of a polyvinyl chloride pipe, and is sprayed by a spray nozzle 10. The water used to wash the deodorizing floor 1 by sprinkling water is drained from the line 9 provided at the bottom of the housing 5. The gas flow rate is usually about 45 to 180 hourly space velocity, but is not limited to this.

【0009】[0009]

【実施例】木質粉は、0.3〜3mmの範囲のものを使
用した。腐植土50wt%、活性汚泥50wt%を充分
混合し、3週間放置したのち、NaCl(0.85
%)、KCl(0.2%)、CaCl2(0.2%)、
NaHCO3(0.2%)、グルコース(0.4%)よ
りなる生理的塩類水溶液を混合物に対して、10倍量加
えて混合し、得られた上澄液を抽出液として分離回収し
た。この抽出液を乾燥木質粉に散布し木質粉の水分量を
60%とすることにより、本発明の悪臭除去剤を得た。
前記図1の装置を使用し、この悪臭除去剤を40cm厚
の層となるように設け、悪臭ガスはH2S5〜7.5p
pm、CH3SH0.5ppmを含有するガスを使用し
た。実施例1は、本発明悪臭除去剤を使用したが散水系
に磁化装置を設けない場合であり、実施例2は、図1の
とおりの磁化装置を用い、150Gの磁場を与えた場合
である。対照は、従来の土壌脱臭装置によるものであ
る。これらの結果を表2に示す。
EXAMPLE Wood powder having a size in the range of 0.3 to 3 mm was used. After thoroughly mixing 50 wt% of humus and 50 wt% of activated sludge and leaving it for 3 weeks, NaCl (0.85%
%), KCl (0.2%), CaCl 2 (0.2%),
An aqueous physiological salt solution containing NaHCO 3 (0.2%) and glucose (0.4%) was added to the mixture in an amount of 10 times and mixed, and the resulting supernatant was separated and collected as an extract. This extract was sprinkled on dry wood powder to adjust the water content of the wood powder to 60% to obtain the malodor removing agent of the present invention.
Using the apparatus shown in FIG. 1, the malodor removing agent is provided in a layer having a thickness of 40 cm, and the malodorous gas is H 2 S 5 to 7.5 p.
A gas containing pm, CH 3 SH 0.5 ppm was used. Example 1 is a case where the malodor removing agent of the present invention was used but a magnetizing device was not provided in the water spray system, and Example 2 was a case where a magnetizing device as shown in FIG. 1 was used and a magnetic field of 150 G was applied. .. The control is with a conventional soil deodorizer. The results are shown in Table 2.

【表2】 本発明の悪臭除去剤は、土壌法に較べて圧力損失の少な
い点も大きなメリットである。その1例を表3に示す。
[Table 2] The malodor removing agent of the present invention is also a great merit in that it has less pressure loss than the soil method. One example is shown in Table 3.

【表3】 [Table 3]

【0010】[0010]

【効果】本発明により、圧力損失が小さく、かつ長期間
ほぼ同一の圧力損失を示し、立上り時間が極めて早く、
その上悪臭除去効率の極めて高い悪臭除去剤、その製法
およびそれを用いた脱臭装置を提供することができた。
[Effect] According to the present invention, the pressure loss is small, the pressure loss is almost the same for a long period of time, the rise time is extremely fast,
Moreover, it was possible to provide a malodor removing agent having extremely high malodor removing efficiency, a method for producing the malodor, and a deodorizing apparatus using the same.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明実施例に用いた脱臭装置の概要図であ
る。
FIG. 1 is a schematic diagram of a deodorizing device used in an example of the present invention.

【図2】いろいろの磁場強度の個々を通した処理水によ
る散布の結果、脱臭床中の菌体の増殖比を測定した結果
を示すグラフである。
FIG. 2 is a graph showing the results of spraying treated water through various magnetic field strengths, and measuring the growth ratio of bacterial cells in a deodorized bed.

【符号の説明】 1 脱臭床 2 ぐり石層または砕石層 3 砂層 4 悪臭除去剤層 5 ハウジング 6 悪臭ガス導入ライン 7 排気ライン 8 洗浄水導入ライン 9 排水ライン 10 散水ノズル 11 磁化装置[Explanation of Codes] 1 Deodorizing bed 2 Grindstone layer or crushed stone layer 3 Sand layer 4 Malodor removing agent layer 5 Housing 6 Malodorous gas introduction line 7 Exhaust line 8 Wash water introduction line 9 Drain line 10 Sprinkling nozzle 11 Magnetizing device

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 土壌菌および/または活性汚泥菌を含有
する木質粉よりなることを特徴とする悪臭除去剤。
1. A malodor removing agent comprising a wood powder containing soil bacteria and / or activated sludge bacteria.
【請求項2】 腐植土および/または活性汚泥から菌体
を抽出し、得られた抽出液を木質粉に添加し、木質粉の
水分含有量を50〜75wt%に調整することを特徴と
する悪臭除去剤の製法。
2. The method is characterized in that fungus bodies are extracted from humus soil and / or activated sludge, and the resulting extract is added to wood flour to adjust the water content of the wood flour to 50 to 75 wt%. Manufacturing method of malodor remover.
【請求項3】 土壌菌および/または活性汚泥菌を含有
する木質粉よりなる悪臭除去剤の層およびそれを保持す
るため通水、通気性支持床よりなる脱臭床、該脱臭床を
収納したハウジング、該ハウジング内の該脱臭床の下部
に悪臭ガスを導入する手段、該脱臭床を通過した排ガス
をハウジングから排出するための手段、該脱臭床を洗浄
するための散水手段および該ハウジングの底部に留った
洗浄水を排水する手段よりなることを特徴とする脱臭装
置。
3. A layer of a malodor removing agent made of wood powder containing soil fungus and / or activated sludge fungus, water passing therethrough for holding it, a deodorizing bed consisting of a breathable support floor, and a housing accommodating the deodorizing bed. A means for introducing a malodorous gas into the lower part of the deodorizing bed in the housing, a means for discharging the exhaust gas passing through the deodorizing bed from the housing, a sprinkling means for cleaning the deodorizing bed, and a bottom part of the housing. A deodorizing device comprising means for discharging the remaining cleaning water.
【請求項4】 該散水手段に供給される水を磁化する手
段を付設した請求項3記載の脱臭装置。
4. The deodorizing device according to claim 3, further comprising means for magnetizing the water supplied to the sprinkling means.
JP3257069A 1991-09-09 1991-09-09 Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same Pending JPH0596127A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3257069A JPH0596127A (en) 1991-09-09 1991-09-09 Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3257069A JPH0596127A (en) 1991-09-09 1991-09-09 Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same

Publications (1)

Publication Number Publication Date
JPH0596127A true JPH0596127A (en) 1993-04-20

Family

ID=17301316

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3257069A Pending JPH0596127A (en) 1991-09-09 1991-09-09 Offensive odor remover, manufacturing method thereof and deodorizing apparatus using the same

Country Status (1)

Country Link
JP (1) JPH0596127A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002143636A (en) * 2000-11-13 2002-05-21 Takashi Hirai Deodorizing equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002143636A (en) * 2000-11-13 2002-05-21 Takashi Hirai Deodorizing equipment

Similar Documents

Publication Publication Date Title
AU2011292103B2 (en) Mineral-releasing compost and method of using the same for soil remediation
JP2013540677A5 (en)
JPH10296288A (en) Sludge reforming method in batch type and oxidation ditch type waste water treatment method
JP3488853B2 (en) Deodorant, deodorizing method, deodorizing member and deodorizing device
KR101658156B1 (en) Adsorbent-deodorant composition comprising powdered red shale and methyl sulfonyl methane and manufacturing method thereof
JP2014237104A (en) Water purifier
JPH119674A (en) Liquid deodorizier with humic acid as effective component, its production beverage deodorizer with humic acid as effective component and its production
JP2003117341A (en) Method for treating gas containing ammonia and device therefor
JPH054019A (en) Deodorizing method and device
JP3447537B2 (en) Microorganism deodorizing device and method of operating the device
JPH0719549Y2 (en) Combined processing device for malodorous gas and sewage
JPH1142418A (en) Biological deodorization method and device therewith
JPH11169650A (en) Nitrogen-based ion treatment equipment and microorganism deodorization equipment using microorganisms
JPH0810560A (en) Biological deodorizing method using granulated loess containing composition
JPH07255825A (en) Indoor deodorizing device
JPH01317525A (en) Deodorizing method
JP2001157817A (en) Deodorizing apparatus
JP2000024448A (en) Rock wool deodorizing material, deodorizing device and deodorizing method
JP2560374B2 (en) Biological deodorizing method, biological deodorizing device, and agent for improving decomposition activity of sulfur-based odorous substances in biological deodorizing device
JPH01315317A (en) Deodorizing device for gas
JP2002113323A (en) Deodorizing equipment
JP2003019191A (en) Deodorant and deodorizing method
JP2002186829A (en) Method and apparatus for deodorizing malodorous gas
JPH06327930A (en) Biological deodorizing method
JPH09201511A (en) Soil for deodorization