JPH06145562A - Aerosol foaming paint - Google Patents
Aerosol foaming paintInfo
- Publication number
- JPH06145562A JPH06145562A JP33652092A JP33652092A JPH06145562A JP H06145562 A JPH06145562 A JP H06145562A JP 33652092 A JP33652092 A JP 33652092A JP 33652092 A JP33652092 A JP 33652092A JP H06145562 A JPH06145562 A JP H06145562A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- aerosol
- liquefied gas
- hfc
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 28
- 239000003973 paint Substances 0.000 title claims abstract description 18
- 238000005187 foaming Methods 0.000 title abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000003380 propellant Substances 0.000 claims abstract description 6
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 claims abstract description 5
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000009835 boiling Methods 0.000 claims abstract description 4
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 claims abstract description 3
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000002576 ketones Chemical class 0.000 claims abstract description 3
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000006260 foam Substances 0.000 claims description 19
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 claims description 2
- RFCAUADVODFSLZ-UHFFFAOYSA-N 1-Chloro-1,1,2,2,2-pentafluoroethane Chemical compound FC(F)(F)C(F)(F)Cl RFCAUADVODFSLZ-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 235000019406 chloropentafluoroethane Nutrition 0.000 claims description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims description 2
- 235000019404 dichlorodifluoromethane Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 238000005507 spraying Methods 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 3
- 239000003002 pH adjusting agent Substances 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 11
- 239000005357 flat glass Substances 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 239000001273 butane Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000001054 red pigment Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920006328 Styrofoam Polymers 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000008261 styrofoam Substances 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- AHFMSNDOYCFEPH-UHFFFAOYSA-N 1,2-difluoroethane Chemical compound FCCF AHFMSNDOYCFEPH-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- -1 HCFC -225 Chemical compound 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
- C08J2207/04—Aerosol, e.g. polyurethane foam spray
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、ガラス、木、プラステ
ィックや金属、例えば店舗のショウウインドーや家の窓
ガラスのディスプレーとして、膨らんだ絵や文字を描く
ためのエアゾール型発泡ペイントに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an aerosol type foam paint for drawing inflated pictures and characters as a display for glass, wood, plastic and metal such as shop window and window glass of a house.
【０００２】[0002]
【従来の技術】近年、自らの手で店舗のショウウインド
ーや家の窓ガラスの装飾を行う人が増え、絵や文字を簡
単に描けるものの要望が高まっている。現在、自らの手
で装飾に使用するものとしては、雪がついているように
見せるエアゾール型のスノースプレーと称するものがあ
る。これは、ガラスに塗布し雪がついているように粉っ
ぽい塗膜を形成するもので、絵や文字を描こうとした場
合、抜き型のような型紙を使用する必要があり、立体感
を出すことは出来ない。もう一つは、膨らんだ絵や文字
を描くことを目的とした発泡する特殊インクがある。こ
れは、紙や布などを被塗対象とし、塗布後ドライヤーや
アイロンなどで熱をかけて発泡させるものである。2. Description of the Related Art In recent years, an increasing number of people are decorating shop windows and window glasses of homes by themselves, and there is an increasing demand for those who can easily draw pictures and characters. At present, what is called an aerosol-type snow spray that is used to decorate with one's own hands is made to look like snow. This is applied to glass to form a powdery coating that looks like snow.If you want to draw pictures or letters, it is necessary to use a paper pattern such as a punch, giving a three-dimensional effect. I can't. The other is special ink that expands for the purpose of drawing inflated pictures and letters. In this method, paper or cloth is applied, and after application, heat is applied with a dryer or iron to foam.
【０００３】[0003]
【発明が解決しようとする課題】エアゾール型スノース
プレーと称するものには次のような欠点がある。即ち、
これだけでは立体感を出すことが出来ず、立体的な絵や
文字を飾ろうとするときは、あらかじめ発泡スチロール
などの厚みのある板状のものを絵や文字の形を切り抜い
て貼るという工程をとらなければならず、かなりの労力
と経験を必要とする。また、除去する場合はアルコール
や、ガラスクリーナーなどでかなり力をいれて拭き取る
など、かなりの労力を必要とする。発泡する特殊インク
には次のような欠点がある。これは、塗布後熱をかけて
発泡させるという後工程が必要であり、かつ除去を考え
ていないものであり、除去が非常に困難である。本発明
は、立体的な絵や文字を、手軽にガラス面や壁などに描
けることの出来るものを提供することを目的として鋭意
検討した結果、スプレーするだけで立体的な絵や文字が
描け、除去も手で剥離するだけで簡単に出来るエアゾー
ル型発泡ペイントを完成した。What is called an aerosol type snow spray has the following drawbacks. That is,
This alone does not give a three-dimensional effect, and when decorating a three-dimensional picture or character, the step of cutting out the shape of the picture or character and attaching it with a thick plate-like object such as Styrofoam must be taken in advance. It requires considerable effort and experience. In addition, when removing it, a considerable amount of labor is required, such as wiping with alcohol or glass cleaner with a great deal of force. The foaming special ink has the following drawbacks. This requires a post-process of applying heat to cause foaming after application, and does not consider removal, and thus is very difficult to remove. The present invention, three-dimensional pictures and characters, as a result of earnestly studying for the purpose of providing what can be easily drawn on the glass surface or wall, the three-dimensional pictures and characters can be drawn just by spraying, We have completed an aerosol-type foam paint that can be removed simply by peeling by hand.
【０００４】[0004]
【課題を解決するための手段】上記目的を達成するため
に、鋭意研究を重ねた結果、描いた後すぐに発泡する発
泡ペイントを、携帯および使用に際し、安全で取扱いが
簡便な条件としてエアゾールとすることが効果的である
ことを知見し、本発明を完成するに至った。本発明は、
エアゾール噴射剤である液化ガスに樹脂を溶解させ、
水、界面活性剤、可塑剤および易揮発性溶剤を任意に適
量配合し、噴射後速やかに発泡するエアゾール型発泡ペ
イントを提供する。[Means for Solving the Problems] In order to achieve the above object, as a result of intensive studies, a foamed paint that foams immediately after being drawn is used as an aerosol under conditions that are safe and easy to handle when carrying and using. The inventors have found that it is effective to complete the present invention. The present invention is
Dissolve the resin in liquefied gas that is an aerosol propellant,
Provided is an aerosol-type foam paint in which water, a surfactant, a plasticizer, and an easily volatile solvent are arbitrarily mixed in appropriate amounts and foamed immediately after jetting.
【０００５】本発明における液化ガスは、エアゾール噴
射剤として使用可能であり、さらにエアゾール缶内にお
いて液体であるものが望ましく、ＨＦＣ−１３４ａ、Ｈ
ＣＦＣ−２２、ＨＣＦＣ−１４２ｂ、ＨＦＣ−１５２
ａ、ＣＦＣ−１２、ＣＦＣ−１１４、ＣＦＣ−１１５、
ジメチルエーテルおよびＬ．Ｐ．Ｇ（プロパン、ブタ
ン）のような液化ガスが一種または二種以上の混合物で
使用される。The liquefied gas used in the present invention can be used as an aerosol propellant, and is preferably a liquid in an aerosol can, such as HFC-134a and HFC-134a.
CFC-22, HCFC-142b, HFC-152
a, CFC-12, CFC-114, CFC-115,
Dimethyl ether and L.I. P. Liquefied gases such as G (propane, butane) are used in one or a mixture of two or more.
【０００６】発泡物の主体となる樹脂は、アクリル系樹
脂、ケトン系樹脂、アルデヒド系樹脂、フタル酸系樹
脂、ＰＶＡ系樹脂およびスチレン／マレイン酸系樹脂の
ような樹脂が一種または二種以上の混合物で使用される
が、好ましくは、溶剤のはいっていない固形樹脂か、易
揮発性溶剤に溶解させた樹脂が使用される。The resin that is the main constituent of the foam is one or more of resins such as acrylic resins, ketone resins, aldehyde resins, phthalic acid resins, PVA resins and styrene / maleic acid resins. It is used as a mixture, but preferably a solvent-free solid resin or a resin dissolved in an easily volatile solvent is used.
【０００７】樹脂の発泡を助け、除去を一層容易にし、
かつエアゾール容器から噴射させる際にノズルのつまり
を防止する目的で、水、界面活性剤、可塑剤を任意に選
び適量配合することが出来る。界面活性剤としては、カ
チオン、アニオン、ノニオンおよび両性などの界面活性
剤が挙げられ、可塑剤としては、Ｄ．Ｏ．ＰやＤ．Ｂ．
Ｐなどが挙げられる。いずれも一定の効果があるが、好
ましくは、発泡物の主体となる樹脂に相溶する界面活性
剤や可塑剤が使用される。Aids in resin foaming and makes removal easier,
In addition, water, a surfactant, and a plasticizer can be arbitrarily selected and mixed in appropriate amounts for the purpose of preventing clogging of the nozzle when sprayed from an aerosol container. Surfactants include cation, anion, nonionic and amphoteric surfactants, and plasticizers include D.I. O. P and D. B.
P and the like. Both have a certain effect, but it is preferable to use a surfactant or a plasticizer that is compatible with the resin that is the main component of the foam.
【０００８】樹脂の発泡の程度や発泡する速さ、乾燥速
度、そしてエアゾール容器内の圧力を調節するために沸
点６０℃以下の易揮発性溶剤を入れることが出来る。沸
点６０℃程度以下の易揮発性溶剤としては、ＣＦＣ−１
１、ＨＣＦＣ−１２３、ＨＣＦＣ−１４１ｂ、ＨＣＦＣ
−２２５、塩化メチレン、ペンタン、ヘキサン、アセト
ンおよび酢酸メチルなどの、一種または二種以上の混合
物で使用される。尚、上記のようにして得られたエアゾ
ール型発泡ペイントに意匠性や好感度を増すために、染
料、顔料、金属粉、マイカ粉、香料などを添加すること
が出来る。また、その他の補助剤としてＰＨ調整剤、増
粘剤、シリコーンオイルなどを添加することも出来る。A volatile solvent having a boiling point of 60 ° C. or less can be added in order to control the degree of foaming of the resin, the speed of foaming, the drying speed, and the pressure in the aerosol container. As the volatile solvent having a boiling point of about 60 ° C. or less, CFC-1
1, HCFC-123, HCFC-141b, HCFC
-225, methylene chloride, pentane, hexane, acetone and methyl acetate, and the like, or a mixture of two or more thereof. In addition, a dye, a pigment, a metal powder, a mica powder, a fragrance, or the like can be added to the aerosol type foam paint obtained as described above in order to enhance the design and the favorable impression. Further, as other auxiliary agents, a pH adjusting agent, a thickening agent, silicone oil and the like can be added.
【０００９】[0009]
【作用】本発明は、エアゾール噴射剤である液化ガスに
樹脂を溶解させ、水、界面活性剤、可塑剤および易揮発
性溶剤を任意に適量配合し、噴射後速やかに発泡し、立
体的な絵や文字を手軽に描くことの出来るエアゾール型
発泡ペイントである。According to the present invention, a resin is dissolved in a liquefied gas which is an aerosol propellant, and water, a surfactant, a plasticizer and an easily volatile solvent are arbitrarily mixed in an appropriate amount, and immediately after injection, foaming is performed to form a three-dimensional structure. An aerosol-type foam paint that allows you to easily draw pictures and letters.
【００１０】得られる噴射物は、液化ガスや易揮発性溶
剤の蒸発により膨れ上がり、さらに水と界面活性剤を添
加したものは、その起泡力により、より膨れ上がった発
泡物となる。また、樹脂と相溶する可塑剤を添加するこ
とによっても樹脂が軟らかくなるため発泡程度を増すこ
とが出来る。発泡の程度は、塗布スピードや被塗物との
距離を変えることによっても調節出来る。塗布スピード
をゆっくりにし、距離を近づける程、より膨れ上がった
発泡物が得られる。The resulting jetted product swells due to the evaporation of the liquefied gas or the easily volatile solvent, and the one to which water and the surfactant are added becomes a further swollen foam due to the foaming force. Further, the addition of a plasticizer compatible with the resin also softens the resin, so that the degree of foaming can be increased. The degree of foaming can also be adjusted by changing the coating speed and the distance to the object to be coated. The slower the coating speed and the closer the distance, the more expanded the foam is obtained.
【００１１】本発明は、スプレーするだけで立体的な絵
や文字を描ける物であり、除去する場合も手で剥離する
だけと簡単なものである。そして、これに水、界面活性
剤、可塑剤を任意に添加したものは、さらに剥離が容易
になりガラスなどの被塗物に残りにくくなる。この界面
活性剤や可塑剤は、いかなるものでもかまわないが、好
ましくは発泡物の主体となる樹脂に相溶するものであ
る。According to the present invention, a three-dimensional picture or a character can be drawn only by spraying, and the removal is as simple as peeling by hand. And what added water, a surfactant, and a plasticizer arbitrarily to this becomes easy to peel, and becomes hard to remain on a to-be-coated article, such as glass. Any of these surfactants and plasticizers may be used, but preferably they are compatible with the resin that is the main constituent of the foam.
【００１２】[0012]
【実施例】本発明の実施例を説明するが、本発明はこれ
によって限定されるものではない。 実施例１ アルデヒド系樹脂（ＢＡＳＦ社製 ラロパールＡ−８
１）６０ｇ、界面活性剤１．５ｇ、Ｄ．Ｏ．Ｐ１．５ｇ
および赤色顔料１ｇを、適当な大きさのエアゾール容器
に入れエアゾールバルブをクリンチする。それに、液化
ガスであるブタン３０ｇと同じく液化ガスであるジメチ
ルエーテル１５ｇを充填し、アルデヒド系樹脂を溶解し
た。得られたエアゾール型発泡ペイントを窓ガラスに噴
射すると、窓ガラスに付着後速やかにふくれあがり、立
体的な絵や文字を描くことが出来た。EXAMPLES Examples of the present invention will be described, but the present invention is not limited thereto. Example 1 Aldehyde-based resin (LASF Pearl A-8 manufactured by BASF)
1) 60 g, surfactant 1.5 g, D.I. O. P1.5g
Then, 1 g of the red pigment is put in an aerosol container of an appropriate size, and the aerosol valve is clinched. Then, 30 g of butane, which is a liquefied gas, and 15 g of dimethyl ether, which is a liquefied gas, were charged to dissolve the aldehyde resin. When the obtained aerosol type foamed paint was sprayed on the window glass, it quickly bulged after adhering to the window glass, and a three-dimensional picture or character could be drawn.
【００１３】実施例２ アクリル系樹脂（三菱レイヨン社製 ダイヤナールＢＲ
−１０１）４５ｇ、アルデヒド系樹脂（ＢＡＳＦ社製
ラロパールＡ−８１）４５ｇ、界面活性剤７ｇ、Ｄ．
Ｏ．Ｐ６ｇおよび赤色染料０．１ｇを適当な大きさのエ
アゾール容器に入れエアゾールバルブをクリンチする。
それに、液化ガスであるブタン４３ｇおよびジメチルエ
ーテル８１ｇを充填し、アクリル系樹脂およびアルデヒ
ド系樹脂をを溶解した。得られたエアゾール型発泡ペイ
ントを窓ガラスに噴射すると、窓ガラスに付着後速やか
にふくれあがり、立体的な絵や文字を描くことが出来
た。Example 2 Acrylic resin (Dianal BR manufactured by Mitsubishi Rayon Co., Ltd.
-101) 45 g, aldehyde resin (manufactured by BASF)
Laropearl A-81) 45 g, surfactant 7 g, D.I.
O. P6g and 0.1g of red dye are put into an appropriately sized aerosol container and the aerosol valve is clinched.
Then, 43 g of butane as a liquefied gas and 81 g of dimethyl ether were charged to dissolve the acrylic resin and the aldehyde resin. When the obtained aerosol type foamed paint was sprayed on the window glass, it quickly bulged after adhering to the window glass, and a three-dimensional picture or character could be drawn.
【００１４】実施例３ アクリル系樹脂（三菱レイヨン社製 ダイヤナールＢＲ
−１０１）６０ｇ、Ｄ．Ｏ．Ｐ２０ｇおよび赤色顔料１
ｇを適当な大きさのエアゾール容器に入れエアゾールバ
ルブをクリンチする。それに、液化ガスであるブタン２
０ｇおよびジメチルエーテル９０ｇを充填し、アクリル
系樹脂を溶解した。得られたエアゾール型発泡ペイント
を窓ガラスに噴射すると、実施例１および２に比べると
細いが立体的な絵や文字を描くことが出来た。Example 3 Acrylic resin (Dianal BR manufactured by Mitsubishi Rayon Co., Ltd.
-101) 60 g, D.I. O. P20g and red pigment 1
Place g in an appropriately sized aerosol container and clinch the aerosol valve. In addition, butane 2 which is a liquefied gas
0 g and 90 g of dimethyl ether were filled and the acrylic resin was dissolved. When the obtained aerosol type foamed paint was sprayed on the window glass, it was possible to draw a three-dimensional picture or character although it was thinner than in Examples 1 and 2.
【００１５】実施例４ アクリル系樹脂（三菱レイヨン社製 ダイヤナールＢＲ
−１０１）５０部を精製水４０部、ジポリオキシエチレ
ン（２）アルキルエーテルリン酸２部、Ｄ．Ｏ．Ｐ１０
部の溶液にディスパー撹拌機にて撹拌分散させ、さらに
赤色顔料２部を添加し分散させた。前記の分散液６０ｇ
を適当な大きさのエアゾール容器に入れエアゾールバル
ブをクリンチし、液化ガスであるブタン４０ｇおよびジ
メチルエーテル４０ｇを充填し、アクリル系樹脂を溶解
した。得られたエアゾール型発泡ペイントを窓ガラスに
噴射すると、水と界面活性剤の起泡力と、液化ガスの蒸
発により実施例１および２に比べると太い立体的な絵や
文字を描くことが出来た。更に界面活性剤と水を添加し
ているため、乾燥後ガラスからの除去は、手で剥離する
だけでガラスにほとんど残りなく除去することが出来
た。Example 4 Acrylic resin (Dianal BR manufactured by Mitsubishi Rayon Co., Ltd.
50 parts of purified water, 2 parts of dipolyoxyethylene (2) alkyl ether phosphoric acid, D.I. O. P10
Part of the solution was stirred and dispersed by a disper stirrer, and 2 parts of red pigment was further added and dispersed. 60 g of the above dispersion
Was placed in an aerosol container of an appropriate size, the aerosol valve was clinched, and 40 g of liquefied gas butane and 40 g of dimethyl ether were charged to dissolve the acrylic resin. When the obtained aerosol type foam paint is sprayed on the window glass, a thick three-dimensional picture or letters can be drawn as compared with Examples 1 and 2 due to the foaming power of water and the surfactant and the evaporation of the liquefied gas. It was Furthermore, since a surfactant and water are added, the glass can be removed from the glass after drying with almost no residue on the glass by peeling by hand.
【００１６】[0016]
【発明の効果】本発明によるエアゾール型発泡ペイント
は、前もって型紙を用意したり、発泡スチロール板を切
り抜いたりせずに、そして塗布後熱をかけるという工程
もなしに、スプレーするだけで、手軽に立体的な絵や文
字を描くことが出来る。そして除去についても、手で剥
離するだけの簡単なものである。EFFECT OF THE INVENTION The aerosol type foam paint according to the present invention can be easily sprayed by spraying without preparing a pattern paper in advance or cutting out the Styrofoam plate and without applying a heat after coating. You can draw realistic pictures and letters. Also, the removal is as simple as peeling by hand.
Claims (4)
を溶解させ、噴射後、速やかに発泡するエアゾール型発
泡ペイント。1. An aerosol type foam paint in which a resin is dissolved in a liquefied gas which is an aerosol propellant, and foams quickly after being sprayed.
ＦＣ−２２、ＨＣＦＣ−１４２ｂ、ＨＦＣ−１５２ａ、
ＣＦＣ−１２、ＣＦＣ−１１４、ＣＦＣ−１１５、ジメ
チルエーテルおよびＬ．Ｐ．Ｇの一種または二種以上の
混合物である請求項１記載のエアゾール型発泡ペイン
ト。2. The liquefied gas is HFC-134a, HC
FC-22, HCFC-142b, HFC-152a,
CFC-12, CFC-114, CFC-115, dimethyl ether and L.I. P. The aerosol foam paint according to claim 1, which is one kind of G or a mixture of two or more kinds.
脂、アルデヒド系樹脂、フタル酸系樹脂、ＰＶＡ系樹脂
およびスチレン／マレイン酸系樹脂の一種または二種以
上の混合物である請求項１または２記載のエアゾール型
発泡ペイント。3. The resin according to claim 1, which is one or a mixture of two or more of acrylic resin, ketone resin, aldehyde resin, phthalic acid resin, PVA resin and styrene / maleic acid resin. 2. Aerosol type foam paint according to 2.
度以下の易揮発性溶剤の内、いずれか一種または二種以
上を任意に組み合わせて含有する請求項１、２または３
記載のエアゾール型発泡ペイント。4. A water-based surfactant, a plasticizer, or a volatile solvent having a boiling point of about 60.degree.
Aerosol type foam paint described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33652092A JPH06145562A (en) | 1992-11-05 | 1992-11-05 | Aerosol foaming paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33652092A JPH06145562A (en) | 1992-11-05 | 1992-11-05 | Aerosol foaming paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06145562A true JPH06145562A (en) | 1994-05-24 |
Family
ID=18299980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33652092A Pending JPH06145562A (en) | 1992-11-05 | 1992-11-05 | Aerosol foaming paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06145562A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003528968A (en) * | 2000-03-31 | 2003-09-30 | シェミケール ド ブラジル プロドゥトス アウトモーティボス リミタダ | Foamed aqueous composition, its use, and method of temporarily defining a defined distance in sports |
| US7416999B2 (en) * | 2003-06-06 | 2008-08-26 | Uwe Arnold | Net containing visible lettering and method for applying visible lettering to nets |
-
1992
- 1992-11-05 JP JP33652092A patent/JPH06145562A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003528968A (en) * | 2000-03-31 | 2003-09-30 | シェミケール ド ブラジル プロドゥトス アウトモーティボス リミタダ | Foamed aqueous composition, its use, and method of temporarily defining a defined distance in sports |
| US7416999B2 (en) * | 2003-06-06 | 2008-08-26 | Uwe Arnold | Net containing visible lettering and method for applying visible lettering to nets |
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