JPH06287107A - Gel-like emulsion cosmetic - Google Patents
Gel-like emulsion cosmeticInfo
- Publication number
- JPH06287107A JPH06287107A JP9853793A JP9853793A JPH06287107A JP H06287107 A JPH06287107 A JP H06287107A JP 9853793 A JP9853793 A JP 9853793A JP 9853793 A JP9853793 A JP 9853793A JP H06287107 A JPH06287107 A JP H06287107A
- Authority
- JP
- Japan
- Prior art keywords
- gel
- glycerin
- fatty acid
- present
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 10
- 239000000839 emulsion Substances 0.000 title abstract description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 19
- 229930195729 fatty acid Natural products 0.000 claims abstract description 19
- 239000000194 fatty acid Substances 0.000 claims abstract description 19
- -1 fatty acid ester Chemical class 0.000 claims abstract description 17
- 235000011187 glycerol Nutrition 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 5
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical class CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 description 12
- 239000000499 gel Substances 0.000 description 11
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 10
- WCDDVEOXEIYWFB-VXORFPGASA-N (2s,3s,4r,5r,6r)-3-[(2s,3r,5s,6r)-3-acetamido-5-hydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,5,6-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@@H]1C[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](C(O)=O)O[C@@H](O)[C@H](O)[C@H]1O WCDDVEOXEIYWFB-VXORFPGASA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229940014041 hyaluronate Drugs 0.000 description 6
- 229940058015 1,3-butylene glycol Drugs 0.000 description 5
- 235000019437 butane-1,3-diol Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 230000001771 impaired effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920002385 Sodium hyaluronate Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 229940010747 sodium hyaluronate Drugs 0.000 description 3
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- ADZAAKGRMMGJKM-UHFFFAOYSA-N oxiran-2-ylmethyl nitrate Chemical compound [O-][N+](=O)OCC1CO1 ADZAAKGRMMGJKM-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 206010016334 Feeling hot Diseases 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高温における安定性が
良好で優れた使用感を備え、且つ適度な粘度を有するゲ
ル状乳化化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gel-like emulsified cosmetic composition which has good stability at high temperatures, has an excellent feeling of use, and has an appropriate viscosity.
【０００２】[0002]
【従来技術および課題】従来より、ゲル状乳化化粧料は
クレンジング料、マッサージ料などとして応用されてい
るが、その特性からして安定な製剤は得難く、安定な製
剤とするためにゲル自体を高粘度にし、製剤のもつ機能
性、使用感などを犠牲にすることも見受けられた。ま
た、親水性ポリグリセリン脂肪酸エステルの開発に伴な
いゲル状乳化物での応用検討も数多くなされてきたが、
ポリグリセリン脂肪酸エステルに由来する粘着性によ
り、のびが悪いなど使用感に問題があった。そのために
親水性ポリグリセリン脂肪酸エステル以外の非イオン界
面活性剤の活用が図られ、例えばポリオキシエチレンソ
ルビット脂肪酸エステル、ポリオキシエチレングリセリ
ン脂肪酸エステルにジグリセリンの脂肪酸エステルを併
用する（特開平４ー２２４５０７号公報）、あるいは天
然界面活性物質を用いた例（特開平５ー４９１号公報、
特開平５ー４９１２号公報）などが開示されている。し
かしながら、安全性の観点からして、良好な安定性と優
れた使用感及び機能性を兼ね備えたポリグリセリン脂肪
酸エステルを含有したゲル状乳化化粧料の開発は切望さ
れるものである。2. Description of the Related Art Conventionally, gel-type emulsified cosmetics have been applied as cleansing agents, massage agents, etc. However, it is difficult to obtain a stable formulation due to their properties, and the gel itself is used to make a stable formulation. It was also found that the viscosity was increased and the functionality and usability of the formulation were sacrificed. In addition, along with the development of hydrophilic polyglycerin fatty acid ester, many application studies on gel emulsion have been made,
Due to the adhesiveness derived from polyglycerin fatty acid ester, there was a problem in the feeling of use such as poor spread. For that purpose, nonionic surfactants other than hydrophilic polyglycerin fatty acid ester are utilized, for example, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester and diglycerin fatty acid ester are used in combination (Japanese Patent Laid-Open No. 224507/1992). (Japanese Patent Laid-Open No. 5-491), or an example using a natural surface-active substance (Japanese Patent Laid-Open No. 5-491,
JP-A-5-4912) and the like are disclosed. However, from the viewpoint of safety, the development of a gel emulsion cosmetic containing a polyglycerin fatty acid ester having both good stability and excellent usability and functionality is earnestly desired.
【０００３】[0003]
【課題を解決するための手段】これらの課題を鑑み、本
発明者は鋭意検討した結果、親水性ポリグリセリン脂肪
酸エステルを配合する使用し易い適度な粘度のゲル状乳
化組成物にあって、ヒアルロン酸又はその塩を配合する
ことにより安定性の改善が図られることを見出し、遂に
本発明を完成するに至った。すなわち、本発明は液状
油、親水性ポリグリセリン脂肪酸エステル、グリセリ
ン、グリセリン以外の多価アルコール及びヒアルロン酸
塩を配合し、特に高温における安定性の改善を図り、使
用し易い適度な粘度と優れた使用感を有するゲル状乳化
組成物に関する。Means for Solving the Problems In view of these problems, the present inventors have made diligent studies, and as a result, in a gel emulsion composition having an appropriate viscosity and containing a hydrophilic polyglycerin fatty acid ester, hyalurone It was found that the stability can be improved by adding an acid or a salt thereof, and the present invention was finally completed. That is, the present invention is a liquid oil, hydrophilic polyglycerin fatty acid ester, glycerin, polyhydric alcohol other than glycerin and hyaluronate are blended to improve stability particularly at high temperature, and an appropriate viscosity that is easy to use and excellent The present invention relates to a gel emulsion composition having a feeling of use.
【０００４】以下に本発明をさらに詳しく説明する。本
発明における液状油は２５℃にて液状を呈するものであ
り、例えば、流動パラフィン、スクワランなどの炭化水
素油、オクタン酸セチル、ミリスチン酸イソプロピルな
どのエステル油、またトリオクタン酸グリセリン、オリ
ーブ油のような脂肪酸トリグリセリドなどがよく、高級
アルコール、高級脂肪酸類が主成分である液状油の場合
は高温安定性が損なわれるので不適当である。The present invention will be described in more detail below. The liquid oil in the present invention is liquid at 25 ° C., and examples thereof include hydrocarbon oils such as liquid paraffin and squalane, ester oils such as cetyl octanoate and isopropyl myristate, glycerin trioctanoate and olive oil. Fatty acid triglyceride and the like are preferable, and liquid oils containing higher alcohols and higher fatty acids as main components are unsuitable because the stability at high temperature is impaired.
【０００５】本発明に用いられる親水性ポリグリセリン
脂肪酸エステルは炭素数１２〜１８の脂肪酸とグリセリ
ン重合度６〜１０のポリグリセリンとからなり、構成脂
肪酸の飽和、不飽和あるいは直鎖、分岐の別、さらにエ
ステル置換度に関わらず、ポリグリセリン脂肪酸エステ
ルのＨＬＢが１０以上でなければならない。すなわち、
デカグリセリルモノステアレート（ＤＥＣＡＧＬＹＮ
１−Ｓ：日光ケミカルズ製）、デカグリセリルモノイソ
ステアレート（ＤＥＣＡＧＬＹＮ １−ＩＳ：日光ケミ
カルズ製）、デカグリセリルモノラウレート（ＤＥＣＡ
ＧＬＹＮ １−Ｌ：日光ケミカルズ製）ヘキサグリセリ
ルモノラウレート（ＨＥＸＡＧＬＹＮ１−Ｌ：日光ケミ
カルズ製）ヘキサグリセリルモノミリスチル（ＨＥＸＡ
ＧＬＹＮ １−Ｍ：日光ケミカルズ製）などが挙げら
れ、中でもＨＬＢ１１〜１５のデカグリセリルモノラウ
レート、ヘキサグセリルモノラウレートが好ましい。The hydrophilic polyglycerin fatty acid ester used in the present invention comprises a fatty acid having 12 to 18 carbon atoms and polyglycerin having a glycerin polymerization degree of 6 to 10, and the constituent fatty acids may be saturated, unsaturated, straight-chain or branched. Further, the HLB of the polyglycerin fatty acid ester must be 10 or more regardless of the degree of ester substitution. That is,
Decaglyceryl monostearate (DECAGLYN
1-S: Nikko Chemicals), decaglyceryl monoisostearate (DECAGLYN 1-IS: Nikko Chemicals), decaglyceryl monolaurate (DECA)
GLYN 1-L: manufactured by Nikko Chemicals) Hexaglyceryl monolaurate (HEXAGLYN 1-L: manufactured by Nikko Chemicals) Hexaglyceryl monomyristyl (HEXA)
GLYN 1-M: manufactured by Nikko Chemicals Co., Ltd., and the like, and among them, HLB11 to 15 decaglyceryl monolaurate and hexagceryl monolaurate are preferable.
【０００６】また、これら親水性ポリグリセリン脂肪酸
エステルは１種以上配合してもよく、その配合量は全組
成物に対して１〜６重量％の範囲が好ましい。親水性ポ
リグリセリン脂肪酸エステルの量がこの範囲内にない
と、ヒアルロン酸塩の配合効果が認められない程の油分
の分離を生じる。Further, one or more of these hydrophilic polyglycerin fatty acid esters may be blended, and the blending amount thereof is preferably in the range of 1 to 6% by weight based on the total composition. If the amount of the hydrophilic polyglycerin fatty acid ester is not within this range, separation of oil will occur to the extent that the effect of blending hyaluronate is not recognized.
【０００７】本発明に用いられるヒアルロン酸塩は鶏冠
などから抽出された天然品あるいは生化学的に産せられ
た合成品のいずれであってもよい。また、ヒアルロン酸
およびその塩の分子量には限定されないが、強いて言え
ば１００万〜１３０万の分子量のものが好適である。ヒ
アルロン酸塩の配合量は全組成物に対して０．００１〜
０．５重量％であり、配合量が０．００１重量％に満た
ないとゲルから水溶性成分の分離を生じ、０．５重量％
を越えるとゲルに粘りがでてきて、使用感が損なわれ
る。The hyaluronic acid salt used in the present invention may be either a natural product extracted from a chicken cob or the like or a biochemically produced synthetic product. Further, the molecular weight of hyaluronic acid and its salt is not limited, but if it is strong, one having a molecular weight of 1 to 1.3 million is preferable. The amount of hyaluronate added is 0.001 to the total composition.
0.5% by weight, and if the content is less than 0.001% by weight, separation of water-soluble components from the gel occurs,
If it exceeds, the gel becomes sticky and the usability is impaired.
【０００８】また、本発明に用いられるグリセリンを除
く多価アルコールは、例えばプロピレングリコール、
１，３−ブチレングリコール、マルチトール、ソルビト
ール等であり、このうちプロピレングリコール、１，３
−ブチレングリコールが好ましい。これら多価アルコー
ルは１種以上を配合してもよく、その配合量は全組成物
に対して０．５〜１０重量％の範囲であり、１〜５重量
％が好ましい。更には、グリセリンの配合量は２０〜６
０重量％の範囲がよく、特に３０〜６０重量％が好まし
い。グリセリンの量が２０重量％に満たないと使用感が
損なわれ、６０重量％を越えると使用時に温感がでてき
て使用感が損なわれる。The polyhydric alcohol other than glycerin used in the present invention is, for example, propylene glycol,
1,3-butylene glycol, maltitol, sorbitol, etc., of which propylene glycol, 1,3
-Butylene glycol is preferred. One or more of these polyhydric alcohols may be blended, and the blending amount thereof is in the range of 0.5 to 10% by weight, preferably 1 to 5% by weight, based on the total composition. Furthermore, the glycerin content is 20-6.
The range of 0% by weight is preferable, and 30 to 60% by weight is particularly preferable. If the amount of glycerin is less than 20% by weight, the feeling of use will be impaired, and if it exceeds 60% by weight, the feeling of warmth will appear during use and the feeling of use will be impaired.
【０００９】本発明はクレンジング、マッサージなどの
化粧料に用いられ、その目的に応じて、本発明の成分以
外に本発明を損なわない範囲で公知の成分、例えば紫外
線吸収剤、防腐剤、殺菌剤、酸化防止剤、色素、香料、
その他薬効成分などを適宜配合できる。The present invention is used for cosmetics such as cleansing and massage, and depending on the purpose, other than the components of the present invention, known components such as UV absorbers, preservatives and bactericides are used within a range not impairing the present invention. , Antioxidants, pigments, fragrances,
Other medicinal ingredients and the like can be appropriately mixed.
【００１０】[0010]
【実施例】以下に実施例をあげ、本発明をさらに詳しく
説明する。本発明は言うまでもなく実施例に限られるも
のでない、また実施例中の［％］は特にことわらないか
ぎり、［重量％］を示す。EXAMPLES The present invention will be described in more detail with reference to the following examples. Needless to say, the present invention is not limited to the examples, and [%] in the examples means [% by weight] unless otherwise specified.
【００１１】表１に示す実施例および比較例をグリセリ
ン、ヒアルロン酸塩を除く成分で予めゲルを製した後、
グリセリンとヒアルロン酸塩の混合物を添加して製造し
た。評価方法を示す。After gels were prepared in advance from the components shown in Table 1 with the exception of glycerin and hyaluronate,
It was prepared by adding a mixture of glycerin and hyaluronate. The evaluation method is shown.
【００１２】[0012]
【表１】 [Table 1]
【００１３】評価方法 １．安定性 本発明品および比較品を４０℃恒温に置き、６０日後分
離の状態を以下の基準で判定した。 ○：分離を認めない ×：上層あるいは下層に分離を認めるEvaluation method 1. Stability The product of the present invention and the comparative product were placed at a constant temperature of 40 ° C., and after 60 days, the state of separation was evaluated according to the following criteria. ○: Separation is not recognized ×: Separation is recognized in the upper or lower layer
【００１４】２．粘度 ２５℃で恒温にした本発明品及び比較品をブルックフィ
ールド型粘度計（スピンドル＃４）を用いて測定した。2. Viscosity The present invention product and the comparative product, which were kept at a constant temperature of 25 ° C., were measured using a Brookfield viscometer (spindle # 4).
【００１５】３．使用感 本発明品及び比較品を専門パネル５名に使用させ使用感
を以下の基準で評価した。 ○：全員が良好と評価 ×：良好と評価したパネルが４名以下3. Usability The present invention product and the comparative product were used by 5 specialized panels, and the usability was evaluated according to the following criteria. ○: All were evaluated as good ×: No more than 4 panelists evaluated as good
【００１６】表１の結果から、比較例に比べて、本発明
品では安定性、使用感に優れた使用し易いゲル状乳化組
成物であると言える。From the results of Table 1, it can be said that the product of the present invention is a gel-like emulsion composition which is superior in stability and feeling to use and is easy to use as compared with Comparative Examples.
【００１７】 実施例６ （クレンジングゲル） 成分 配合量（％） （Ａ成分） デカグリセリルモノラウレート ３．００ １、３ーブチレングリコール ２．００ 精製水 残部 流動パラフィン ５６．００ （Ｂ成分） グリセリン ３７．００ ヒアルロン酸ナトリウム ０．００２ 精製水 ０．２０ （Ｃ成分） 香料 ０．５０ 合計 １００．００Example 6 (Cleansing gel) Component Blending amount (%) (Component A) Decaglyceryl monolaurate 3.00 1,3-butylene glycol 2.00 Purified water balance Liquid paraffin 56.00 (Component B) Glycerin 37.00 Sodium hyaluronate 0.002 Purified water 0.20 (C component) Perfume 0.50 Total 100.00
【００１８】 実施例７ （マッサージ用ゲル） 成分 配合量（％） （Ａ成分） デカグリセリルモノステアレート ３．００ １、３ーブチレングリコール ２．００ 精製水 残部 流動パラフィン ２５．００ トリオクタン酸グリセリル ２５．００ （Ｂ成分） グリセリン ４２．００ ヒアルロン酸ナトリウム ０．００２ （Ｃ成分） 香料 ０．５０ 合計 １００．００Example 7 (Massage gel) Ingredient content (%) (A component) Decaglyceryl monostearate 3.00 1,3-butylene glycol 2.00 Purified water balance Liquid paraffin 25.00 Glyceryl trioctanoate 25 0.00 (Component B) Glycerin 42.00 Sodium hyaluronate 0.002 (Component C) Fragrance 0.50 Total 100.00
【００１９】 実施例８ （拭き取りメーク落とし） 成分 配合量（％） （Ａ成分） デカグリセリルモノミリステート １．５０ ヘキサグリセリルモノラウレート １．５０ １、３ーブチレングリコール ２．００ 精製水 残部 流動パラフィン ４０．００ （Ｂ成分） グリセリン ４２．００ ヒアルロン酸ナトリウム ０．００１ （Ｃ成分） 香料 ０．５０ 合計 １００．００ これら実施例６〜８はいずれも安定性、使用感に優れた
ゲル状乳化化粧料であった。Example 8 (Wipe off make-up) Ingredient blending amount (%) (A ingredient) Decaglyceryl monomyristate 1.50 Hexaglyceryl monolaurate 1.50 1,3-Butylene glycol 2.00 Purified water balance Flow Paraffin 40.00 (Component B) Glycerin 42.00 Sodium hyaluronate 0.001 (Component C) Perfume 0.50 Total 100.00 All of these Examples 6 to 8 are gel emulsions excellent in stability and usability. It was cosmetics.
【００２０】[0020]
【発明の効果】本発明によるとヒアルロン酸塩の配合効
果により、安定性の向上が図られた使用感に優れたゲル
状乳化化粧料を提供できる。EFFECTS OF THE INVENTION According to the present invention, it is possible to provide a gel-like emulsified cosmetic composition having improved stability due to the incorporation effect of hyaluronate.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ａ６１Ｋ 7/02 Ａ 9051−4Ｃ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI technical display location A61K 7/02 A 9051-4C
Claims (1)
ステル、ヒアルロン酸塩、グリセリン及びグリセリン以
外の多価アルコールを含有し、その粘度が５０００〜４
００００ｃｐｓであることを特徴とするゲル状乳化化粧
料1. A liquid oil, a hydrophilic polyglycerin fatty acid ester, a hyaluronic acid salt, glycerin and a polyhydric alcohol other than glycerin are contained, and the viscosity thereof is 5,000 to 4.
Gel emulsified cosmetic characterized by being 0000 cps
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9853793A JPH06287107A (en) | 1993-03-31 | 1993-03-31 | Gel-like emulsion cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9853793A JPH06287107A (en) | 1993-03-31 | 1993-03-31 | Gel-like emulsion cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06287107A true JPH06287107A (en) | 1994-10-11 |
Family
ID=14222443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9853793A Withdrawn JPH06287107A (en) | 1993-03-31 | 1993-03-31 | Gel-like emulsion cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06287107A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09143044A (en) * | 1995-11-17 | 1997-06-03 | White Lilly:Kk | Basic cosmetic without containing antimicrobial agent and germicide |
| US5928653A (en) * | 1996-01-10 | 1999-07-27 | L'oreal | Cleansing or makeup removing composition comprising a polyholoside and methods for preparing and using this composition |
| JP2002255791A (en) * | 2001-02-23 | 2002-09-11 | Lion Corp | W / O / W composite emulsion and method for producing the same |
| JP2004331573A (en) * | 2003-05-08 | 2004-11-25 | Noevir Co Ltd | Solid polyhydric alcohol base |
| WO2011070620A1 (en) * | 2009-12-10 | 2011-06-16 | Kawakita Hiromi | Cosmetic |
| WO2022044781A1 (en) * | 2020-08-28 | 2022-03-03 | 日本コルマー株式会社 | Gel composition |
| CN117430730A (en) * | 2023-10-12 | 2024-01-23 | 上海紫邦生物医药有限公司 | Hyaluronic acid ester and its preparation method and application |
-
1993
- 1993-03-31 JP JP9853793A patent/JPH06287107A/en not_active Withdrawn
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09143044A (en) * | 1995-11-17 | 1997-06-03 | White Lilly:Kk | Basic cosmetic without containing antimicrobial agent and germicide |
| US5928653A (en) * | 1996-01-10 | 1999-07-27 | L'oreal | Cleansing or makeup removing composition comprising a polyholoside and methods for preparing and using this composition |
| JP2002255791A (en) * | 2001-02-23 | 2002-09-11 | Lion Corp | W / O / W composite emulsion and method for producing the same |
| JP2004331573A (en) * | 2003-05-08 | 2004-11-25 | Noevir Co Ltd | Solid polyhydric alcohol base |
| WO2011070620A1 (en) * | 2009-12-10 | 2011-06-16 | Kawakita Hiromi | Cosmetic |
| JP5680549B2 (en) * | 2009-12-10 | 2015-03-04 | 裕美 川北 | Cosmetics |
| WO2022044781A1 (en) * | 2020-08-28 | 2022-03-03 | 日本コルマー株式会社 | Gel composition |
| JP2022039549A (en) * | 2020-08-28 | 2022-03-10 | 日本コルマー株式会社 | Gel-like composition |
| CN117430730A (en) * | 2023-10-12 | 2024-01-23 | 上海紫邦生物医药有限公司 | Hyaluronic acid ester and its preparation method and application |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20000704 |