JPH06340522A - Hair cosmetics - Google Patents

Abstract

(57) [Summary] [Structure] The following components (A) and (B): (A) General formula (1) (In the formula, R ¹ represents a hydrogen atom or a methyl group, R ² represents an alkyl group having 1 to 5 carbon atoms, and m represents a number of 3 to 6). ) A hair cosmetic containing a cationic surfactant. [Effect] The hair does not have a sticky feeling or oiliness, imparts a good feeling, has an excellent effect of preventing damage to split ends and broken hair, and has less squeaky feeling after rinsing.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair cosmetic composition, and more specifically, it contains a specific polyalkylene glycol monoalkyl ether and a cationic surfactant to impart a good feel to the hair and suppress damage to the hair. The present invention relates to a hair cosmetic having an effect and having less squeaky feeling after rinsing.

[0002]

2. Description of the Related Art Conventionally, the problems to be solved by the invention
In order to improve the feel of hair, hair cosmetics contain a cationic surfactant such as a mono- or di-linear long-chain alkyl quaternary ammonium salt or a mono- or di-branched long-chain alkyl quaternary ammonium salt. It is compounded. Further, in recent years, in order to obtain a better feeling, such cationic surfactants have been used in combination with higher alcohols, glycerides, oils and fats such as liquid paraffin, and the like.

However, these conventional hair cosmetics have a drawback in that the feel of the hair, that is, the conditioning effect such as flexibility, moisturizing feeling, smoothness and antistatic effect, is insufficient. Therefore, in regard to the moist feeling among the feels, a method of supplementing with the use of oils and fats is taken, but this method has stickiness and oiliness, and the conditioning effect particularly in a dry state is insufficient. I still had the problem. Furthermore, the conventional hair cosmetics have not been sufficiently effective in preventing damage.

For this reason, hair which is not sticky or greasy, has an excellent conditioning effect, and has a sufficient hair damage preventing effect, is used in combination with a dialkylene glycol monoalkyl ether and a cationic surfactant. Cosmetics (JP-A-3-41015) have been proposed. However, in this hair cosmetic,
In particular, there was a drawback that there was a squeaky feeling after rinsing the hair.

Therefore, there has been a demand for a hair cosmetic composition which is excellent in preventing hair damage and has no squeaky feeling.

[0006]

Under such circumstances, as a result of intensive studies by the present inventors, as a result of using a specific polyalkylene glycol monoalkyl ether in combination with a cationic surfactant, Not only does it prevent damage due to swelling, but it also has a moisturizing effect after it is taken into the hair, giving it a moist feeling even in dry conditions.
The present invention has been completed by finding that an excellent hair cosmetic which gives excellent conditioning effects such as flexibility and smoothness and has less squeaky feeling after rinsing can be obtained.

That is, the present invention provides the following components (A) and (B): (A) General formula (1)

[0008]

[Chemical 2]

(In the formula, R ¹ represents a hydrogen atom or a methyl group, R ² represents an alkyl group having 1 to 5 carbon atoms, and m represents 3 to
The present invention provides a hair cosmetic containing a polyalkylene glycol monoalkyl ether (B) cationic surfactant represented by the formula (6).

The polyalkylene glycol monoalkyl ether of the component (A) used in the present invention is represented by the above general formula (1), and particularly preferably m = 3 in the formula, for example, triethylene glycol. Monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether, triethylene glycol monopentyl ether, triethylene glycol monoisopropyl ether, triethylene glycol mono t-butyl ether, tripropylene glycol monomethyl ether , Tripropylene glycol monoethyl ether, tripropylene glycol monopropyl ether, tripropylene glycol monobutyl ether, tripropy Glycol monopentyl ether, tripropylene glycol monoisopropyl ether, tripropylene glycol monobutyl t- butyl ether, and the like. Of these, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, and triethylene glycol monobutyl ether are particularly preferable.

The component (A) is preferably added to the hair cosmetic composition of the present invention in an amount of 1.0 to 50.0% by weight (hereinafter simply referred to as%), particularly 5.0 to 30.0%.

Examples of the cationic surfactant as the component (B) include quaternary ammonium salts represented by the following general formula (2) or (3).

[0013]

[Chemical 3]

(Wherein R ³ , R ⁴ , R ⁵ and R ⁶ ,
At least one is an alkoxy group having a total carbon number of 8 to 28,
An alkenyloxy group, an alkanoylamino group or an alkenoylamino group, which represents an alkyl group or an alkenyl group which may be substituted, the remainder being a benzyl group and a carbon number of 1 to 5;
Represents an alkyl group or a hydroxyalkyl group. R ⁷ represents an alkylene group having 2 to 3 carbon atoms, X ⁻ represents a halogen ion or an organic anion, and n represents an integer of 1 to 20).

Among these cationic surfactants, the quaternary ammonium salt represented by the general formula (2) is particularly preferable, and more preferable examples of the general formula (2) include the following general formulas (4) to (). Examples include branched quaternary ammonium salts represented by 6).

[0016]

[Chemical 4]

The branched quaternary ammonium salt represented by the general formula (4) is usually synthesized by using, for example, an oxo alcohol having 8 to 16 carbon atoms as a raw material, and an example thereof is an alkyl derived from oxo alcohol. Examples thereof include a dialkyldimethylammonium salt having a group, a dialkylmethylhydroxyethylammonium salt, and a dialkylmethylbenzylammonium salt.

In the present invention, the branching rate of R ^{8 in} the formula (4) is usually 10 to 100%, and particularly 1
It is preferably 0 to 50%. Further, those having a total carbon number of R ⁸ of ⁸ to 16 are used, but those having a constant distribution are preferable, and those having the distribution shown below are particularly preferable.

C _{8 to} C ₁₁ : 5% or less C ₁₂ : 10 to 35% C ₁₃ : 15 to 40% C ₁₄ : 20 to 45% C ₁₅ : 5 to 30% C ₁₆ : 5% or less

A specific example of such a branched quaternary ammonium salt is dialkyldimethylammonium chloride having an alkyl group having 8 to 16 carbon atoms and a branching rate of 10 to 50%.

Further, the fourth branch represented by the general formula (5)
The primary ammonium salt is usually a Guerbet alcohol having 8 to 28 carbon atoms.

[0022]

[Chemical 5]

It is synthesized using as a raw material. Preferable examples of the branched quaternary ammonium salt include alkyl trimethyl ammonium salt having an alkyl group derived from Guerbet alcohol, alkyl dimethyl benzyl ammonium salt, dialkyl dimethyl ammonium salt,
Examples thereof include dialkylmethylhydroxyethylammonium salt and dialkylmethylbenzylammonium salt. Furthermore, among these, particularly preferred specific examples are:
Examples thereof include 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride and di-2-octyldodecyldimethylammonium chloride.

Methyl branch No. 4 represented by the general formula (6)
Examples of the primary ammonium salt include those in which the sum of s and t is 15.

Specific examples of X ⁻ which is a counter ion of the quaternary ammonium salt represented by the general formulas (2), (3), (4), (5) and (6) are chlorine, iodine and bromine. Halogen ions such as; and organic anions such as methosulfate, ethosulfate, metphosphate, and ethophosphate.

The cationic surfactant as the component (B) may be a quaternary ammonium type compound represented by the general formula (7).

[0027]

[Chemical 6]

[In the formula, R ¹⁶ is a linear or branched carbon number 7
~ 21 alkyl group or alkenyl group, R ¹⁷ , R
¹⁸ and R ¹⁹ are the same or different and represent an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group, and M is -CONG-
(G is a hydrogen atom or an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms), -O- or -COO-, and Y is a hydrogen atom, an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms, or a formula.

[0029]

[Chemical 7]

The group represented by However, when G is an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group,
Y is not an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group. Z represents a hydrogen atom or a hydroxy group, A represents a halogen ion or an organic anion, u represents a number of 2 or 3, and v represents an integer of 0 or 1 to 5.
However, when v = 1, Z represents a hydrogen atom or a hydroxy group, and when v = 0, 2, 3, 4, 5 Z represents a hydrogen atom.]

These quaternary ammonium type compounds (7)
Of these, particularly the compound represented by the general formula (8)

[0032]

[Chemical 8]

(Wherein R ¹⁶ , R ¹⁷ , R ¹⁸ , R ¹⁹ , G,
Y, Z, A, u and v have the same meanings as described above), and further a compound represented by the general formula (9)

[0034]

[Chemical 9]

(Wherein R ¹⁶ , R ¹⁷ , R ¹⁸ , R ¹⁹ and A have the same meanings as described above).

These quaternary ammonium type compounds can be produced according to known methods, and of these, for example, the compound represented by the general formula (9) can be produced according to the following reaction formula.

[0037]

[Chemical 10]

That is, a fatty acid (R ¹⁶ CO ₂ H) is reacted with aminoethylethanolamine represented by the general formula (10) to produce an imidazoline derivative represented by the general formula (11), and then this derivative is treated with an alkali. After the treatment with, the compound is reacted with the compound represented by the general formula (12) for quaternization to synthesize the quaternary ammonium salt type compound represented by the general formula (9). In addition, it is more preferable to use a salt that is subsequently desalted by electrodialysis or the like.

Further, as the cationic surfactant as the component (B), an asymmetric di-carboxylic acid represented by the general formula (13) is used.
Examples thereof include quaternary ammonium salts or amine salts having a long-chain alkyl group or alkenyl group (hereinafter referred to as asymmetric ammonium salts).

[0040]

[Chemical 11]

[In the formula, R ²⁰ is 8 total carbon atoms having a branched chain.
To R 28, R ²¹ represents a straight-chain alkyl or alkenyl group having 8 to 22 carbon atoms, and R ²² and R ²³
Are the same or different and each represents an alkyl group having 1 to 4 carbon atoms or a hydrogen atom (provided that both R ²² and R ²³ are hydrogen atoms), and X ′ is a halogen atom or 1 to 4 carbon atoms.
4 shows an alkyl sulfate of 4]

These asymmetric ammonium salts are obtained according to a known method starting from a branched alcohol and a linear amine (Japanese Patent Laid-Open No. 62-149648), examples of which are derived from the alcohol and the amine. Examples thereof include dialkyldimethylammonium salt, monoalkylmonoalkenyldimethylammonium salt and the like. Examples of the counter ion of these ammonium salts include halogen ions such as chlorine, bromine and iodine, and alkyl sulfates such as methosulfate and ethosulfate.

In the above general formula (13), R ²⁰ is a group selected from branched alkyl groups having a total of 8 to 28 carbon atoms, and R ²¹ is a linear alkyl group having 8 to 22 carbon atoms or alkenyl. R ²² and R ²³ are the same or different and are an alkyl group having 1 to 4 carbon atoms or a hydrogen atom (provided that both R ²² and R ²³ are hydrogen atoms). . Examples of the alkyl group derived from branched alcohol represented by R ²⁰ are 2- (3-methylhexyl) -7-methyl-1-decyl group and 2- (1-
Methyl-3,3-dimethylbutyl) -5-methyl-7,
Examples thereof include alkyl groups derived from Guerbet alcohol or oxo method alcohol such as 7-dimethyloctyl group and 2-hexyl-1-decyl group. Here, the Guerbet type alcohol is generally represented by the following formula (14).

[0044]

[Chemical 12]

An alcohol represented by the formula (wherein w represents an integer of 4 to 14). Further, the oxo-type alcohol is a general term for alcohols obtained by the oxo method using α-olefin as a raw material or alcohols obtained using the same as a raw material, for example, the following formula (15)

[0046]

[Chemical 13]

(In the formula, R ²⁴ represents an alkyl group having 1 to 5 carbon atoms, R ²⁵ represents an alkyl group having 5 to 10 carbon atoms, and R ²⁵
The total number of carbon atoms of ²⁴ and R ²⁵ is 10 to 11), or an alcohol represented by the following formula (16).

[0048]

[Chemical 14]

Specific examples of the alcohol as a raw material for deriving these alkyl groups include Fine Oxocole 140, 1600, 180, 180N manufactured by Nissan Kagaku Co., Ltd.
1800, 2000, 2600, decanol, tridecanol, Mitsubishi Kasei Kogyo Co., Ltd. Diadol 18G, Mitsubishi Yuka Co., Ltd. Dovanol 23-I, Exxon Chemical Co., Ltd. EXXAL18, EXXAL20, Emery Co., Ltd. Emazol 871 Alternatively, isostearyl alcohol obtained by converting 87 into a methyl ester by a conventional method and reducing it can be mentioned.

Examples of the linear alkyl group or alkenyl group represented by R ²¹ are dodecyl, octadecyl,
Examples include groups such as oleyl and docosyl. Preferred examples of asymmetric ammonium salts include N-2-
(3-Methylhexyl) -7-methyl-1-decyl-N
-Dodecyl-N, N-dimethylammonium chloride, N-2- (3-methylhexyl) -7-methyl-1
-Decyl-N-octyl-N, N-dimethylammonium chloride, N-2-hexyl-1-decyl-N-dodecyl-N, N-dimethylammonium chloride, those represented by the following formula (17), and the like. .

[0051]

[Chemical 15]

(In the formula, R ²⁴ and R ²⁵ have the same meanings as described above, and the total number of carbon atoms of R ²⁴ and R ²⁵ is 10 to 11)

When these asymmetric ammonium salts are used as a hair rinse agent, they are excellent in flexibility, especially when the hair is dry.

These components (B) can be used alone or in combination of two or more, and are contained in the hair cosmetic composition of the present invention in an amount of 0.01 to 20.0%, particularly 0.2 to 10.0%. It is preferable to mix them.

The hair cosmetic composition of the present invention refers to all of the cosmetic compositions applied to the hair, for example, pre-shampoo, shampoo, hair conditioner, hair conditioner, hair treatment, set lotion, broth styling lotion, hair. Spray, foam styling agent, gel styling agent, hair liquid, hair tonic, hair cream, permanent wave first agent,
Includes permanent wave second agent, permanent hair dye, temporary hair dye, and the like.

Also, as a dosage form, an aqueous solution, an ethanol solution, an emulsion, a suspension, a
Various forms such as gel, liquid crystal, solid type, and aerosol can be used.

Further, in addition to the above-mentioned essential components, the hair cosmetic composition of the present invention may appropriately contain components usually used in hair cosmetic compositions, depending on its use. For example, anionic surfactants such as alkylbenzene sulfonates, alkyl ether sulfates, olefin sulfonates, α-sulfo fatty acid esters, amino acid type surfactants, phosphate ester type surfactants, sulfosuccinate type surfactants, etc. Amphoteric surfactants such as sulfonic acid type surfactants, betaine type surfactants, alkylamine oxides, imidazoline type surfactants; polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, alkanolamides and their alkylene oxide additions One or a combination of two or more kinds of compounds, esters of polyhydric alcohols and fatty acids, alkyl ethers of polyhydric alcohols, sorbitan fatty acid esters, nonionic surfactants such as alkyl saccharide-based surfactants, Various hair It can be used in accordance with the performance of the treating agent. Particularly, when the hair cosmetic composition of the present invention is a shampoo, amino acid surfactants, phosphate ester surfactants, α-sulfone among the above surfactants are taken into consideration in consideration of the irritancy to the skin and hair. It is preferable to use a fatty acid ester, an imidazoline type surfactant, an alkyl saccharide type surfactant or the like as the main washing surfactant.

When a surfactant other than the component (B) is added to the hair cosmetic composition of the present invention, 0.01 to 40.0%,
It is particularly preferable to add 0.05 to 20.0%.

The hair cosmetic composition of the present invention contains a cationized cellulose derivative, a cationic starch, a cationized guar gum derivative, a diallyl quaternary ammonium salt / acrylamide copolymer, in order to improve the feel of hair and skin.
One or more kinds of cationic polymers such as quaternized polyvinylpyrrolidone derivative and polyglycol polyamine condensate can be blended.

Preferred specific examples of these cationic polymers include, for example, a molecular weight of about 100,000 to 3,000.
Cationized cellulose having a cationization degree of about 10,000, a cationized starch having a cationization degree of about 0.01 to 1 and a cationization degree of about 0.0.
1 to 1 cationized guar gum (made by Celanese, Jaguar, etc.), molecular weight about 30,000 to 2,000,000
0 diallyl quaternary ammonium salt / acrylamide copolymer having a molecular weight of about 10,000 to 2,000,000 and a cationic nitrogen content in the vinyl polymer of 0.004 to
0.2% of a quaternized polyvinylpyrrolidone derivative, a polyglycol polyamine condensate having an alkyl group having 6 to 20 carbon atoms, adipic acid / dimethylaminohydroxypropyldiethylenetriamine copolymer (Sands, caltaletin, etc.) JP-A-53-139734
And the cationic polymers described in JP-A-60-36407. The hair cosmetic composition of the present invention includes:
When a cationic polymer is blended, 0.05 to 20.
It is preferable to add 0%, particularly 0.1 to 10.0%.

The hair cosmetic composition of the present invention further comprises dimethylpolysiloxane, methylphenylpolysiloxane, amino-modified silicone, fatty acid-modified silicone, alcohol-modified silicone, and aliphatic alcohol in order to further improve the feel of hair and skin. One or more kinds of silicone derivatives such as modified silicone, polyether modified silicone, epoxy modified silicone, fluorine modified silicone, cyclic silicone, and alkyl modified silicone can be blended. Such silicone derivative may be a single substance or a latex composition emulsion-polymerized according to the method described in JP-B-56-38609.

Of these silicone derivatives, dimethylpolysiloxane (polymerization degree of 500 or more), polyether-modified silicone, amino-modified silicone, cyclic silicone and the like are particularly preferable because they give a good feel to hair. When a silicone derivative is added to the hair cosmetic composition of the present invention, 0.01 to 20.0%, particularly 0.05 to 1%
It is preferable to add 0.0%.

Further, in the cosmetic of the present invention, a component usually used in hair cosmetics, for example, a feel improver such as higher fatty acid salt, alkylamine oxide, fatty acid alkanolamide, squalene and lanolin; propylene glycol,
Glycerin, sorbitol, the following general formula (18)

[0064]

[Chemical 16]

Moisturizers such as amide derivatives represented by: Viscosity modifiers such as methyl cellulose, carboxyvinyl polymer, hydroxyethyl cellulose, polyoxyethylene glycol distearate, ethanol; Pearling agents; Perfumes; Dyes; UV absorbers; Oxidation Inhibitors; fungicides such as triclosan and trichlorocarban; anti-inflammatory agents such as potassium glycyrrhizinate and tocopherol acetate; antidandruff agents such as zinc pyrithione and octopirox; preservatives such as methylparaben and butylparaben; It is also possible to optionally add it within a range that does not impair it.

The hair cosmetic composition of the present invention can be prepared by using a known acidic or alkaline drug used in ordinary hair cosmetic compositions.
It is preferable to adjust the pH to 3 to 10, particularly pH 4 to 8.

[0067]

EFFECTS OF THE INVENTION The hair cosmetic composition of the present invention has no sticky feeling or oily feeling on the hair, imparts a good feeling to the hair, and is excellent in preventing damage to split ends and broken hair of the hair, and is rinsed. There is little squeaky feeling afterwards.

[0068]

EXAMPLES Next, the present invention will be described with reference to examples.
The invention is not limited by these examples.

Example 1 A hair treatment composition having the composition shown in Table 1 was produced by a conventional method and its performance was evaluated. The results are shown in Table 1. (Evaluation method) (1) Bundle about 20 g (about 15 to 20 cm) of hair of a Japanese woman who has undergone a beauty treatment such as cold perm or bleach,
After washing with shampoo, 2 g of the hair treatment composition was uniformly applied to the hair, followed by rinsing with running water for 30 seconds, and then towel drying to evaluate the wet condition. Further, it was dried with a drier and evaluated during the drying. Table 1 shows the comprehensive evaluation results including the evaluations when wet and when dry.
Shown in.

Flexibility: A: Very soft ○: Soft Δ: Neither hard nor soft. X: Hard. Slip (no squeak): ◎: No squeak. ○: Neither can be said. Δ: There is squeak. X: Very squeaky. Moisture feeling: ◎: Very moist. ○: Moisturizes. Δ: Neither can be said. X: Not moisturized.

(2) With a hair bundle treated in the same manner as in (1), the split ends generation after brushing a certain number of times was compared with that before brushing and evaluated according to the following criteria. A: No increase in split ends is observed. ○: Almost no increase in split ends is observed. Δ: Some increase in split ends is observed. X: Many split ends increased.

[0072]

[Table 1]

Example 2 A shampoo composition having the composition shown in Table 2 was produced by a conventional method and its performance was evaluated. The results are shown in Table 2.

(Evaluation Method) (1) Approximately 20 g (about 15 to about 30 g of hair of a Japanese woman who has never been subjected to cosmetic treatment such as cold perm or bleach).
(20 cm) and bundle this hair with warm water at about 40 ° C., apply 1 g of shampoo composition evenly and foam for 1 minute, rinse hair with running water, soften hair after drying, smooth (squeaky About) and moist feeling,
The evaluation was performed according to the same criteria as in Example 1. (2) With a hair bundle treated in the same manner as in (1), the split ends generation after brushing a certain number of times was compared with that before brushing, and evaluated according to the same criteria as in Example 1.

[0075]

[Table 2]

Example 3 A hair treatment composition having the composition shown in Table 3 was produced by a conventional method, and its performance evaluation test was conducted in the same manner as in Example 1. The results are shown in Table 3.

[0077]

[Table 3]

Example 4 The present invention product 8 and the comparative product 8 having the following composition were subjected to a pairwise comparison by 10 panelists in terms of softness, oiliness, moistness, smoothness and split ends generation, and all the results were obtained. The item average 8: 2 was significantly favored by the product 8 of the present invention.

[0079]

[Table 4]

Example 5 Hair rinse composition:

Table 5 (Components) (%) (1) N- (2-decyl) tetradecyl-N, N, N-trimethylammonium chloride 1.0 (2) Stearyl trimethylammonium chloride 0.5 (3) Triethylene glycol Monoethyl ether 20.0 (4) Cetostearyl alcohol 3.0 (5) Zinc pyrithione 0.3 (6) Methylparaben 0.2 (7) Perfume 0.4 (8) Ion-exchanged water balance meter 100

Example 6 Styling lotion composition:

Table 6 (Components) (%) (1) N- (2-decyl) tetradecyl-N, N, N-trimethylammonium chloride 0.5 (2) Polyethylene glycol 0.5 (3) Tripropylene glycol monoethyl Ether 20.0 (4) Acrylic resin liquid 5.0 (5) Polyethylene glycol 1.0 (6) Methacrylic acid ester polymer 1.0 (7) Ethanol 20.0 (8) Perfume 0.3 (9) Water Balance meter 100

Example 7 Conditioning Mousse Composition:

Table 7 (Component) (%) (1) N- (2-decyl) tetradecyl-N, N, N-trimethylammonium chloride 0.5 (2) Octyldodecyl myristate 1.0 (3) Dipropylene glycol 1.0 (4) Triethylene glycol monopentyl ether 20.0 (5) Glycerin 2.5 (6) Liquid paraffin 2.5 (7) Polyoxyethylene sorbitan monostearate 0.2 (8) Ethanol 5 (9 ) Methylparaben 0.1 (10) Perfume 0.1 (11) Propellant (LPG) 10 (12) Water balance meter 100

Example 8 Permanent Wave First Agent:

[Table 8] (Components) (%) (1) Ammonium thioglycolate 6.0 (2) Ammonia water 3.0 (3) Frost DS (Disodium edetate) 0.5 (4) Triethylene glycol monomethyl ether 20.0 (5) N- (2-decyl) tetradecyl-N, N, N-trimethylammonium chloride 2.0 (6) Water balance meter 100

Example 9 Permanent Wave Second Agent:

[Table 9] (Component) (%) (1) Sodium bromate 8.0 (2) N- (2-decyl) tetradecyl-N, N, N-trimethylammonium chloride 2.0 (3) Tripropylene glycol mono Isopropyl ether 20.0 (4) Water balance meter 100

Example 10 Shampoo composition:

Table 10 (Component) (%) (1) N-lauroyl-N'-carboxymethyl-N '-(2-hydroxyethyl) ethylenediamine TEA salt 10 (2) Triethylene glycol monobutyl ether 5 (3) Polyoxy Ethylene (5) Disodium lauryl sulfosuccinate 5 (4) Lauric acid diethanolamide 2 (5) Coconut oil fatty acid amide propyl betaine 2 (6) Distearyldimethylammonium chloride 0.1 (7) Cationized cellulose (Polymer JR400, UCC 0.15 (8) Fragrance 0.5 (9) Dye Appropriate amount (10) Water balance meter 100

Claims (1)

[Claims] 1. The following components (A) and (B): (A) General formula (1) (In the formula, R ¹ represents a hydrogen atom or a methyl group, R ² represents an alkyl group having 1 to 5 carbon atoms, and m represents a number of 3 to 6) A polyalkylene glycol monoalkyl ether (B ) A hair cosmetic containing a cationic surfactant.