JPH0641426A - Polyphenylene sulfide resin composition - Google Patents

Abstract

(57) [Summary] [Structure] (A) Number average molecular weight of 7,000 to 15,000
Polyphenylene sulfide resin having no cross-linked structure 9
0 to 50% by weight and (B) number average molecular weight of 3,000 to
20 to 150 parts by weight of (C) a fibrous or non-fibrous reinforcing material with respect to 100 parts by weight of a polyphenylene sulfide resin mixture consisting of 10 to 50% by weight of a polyphenylene sulfide resin having no crosslinked structure of 6000, (D) A polyphenylene sulfide resin composition obtained by melt-kneading 0.1 to 5 parts by weight of an alkoxysilane compound. [Effects] According to the present invention, a polyphenylene sulfide resin composition having few burrs generated during molding, excellent not only mechanical strength and heat resistance, but also excellent fluidity, and particularly useful for applications such as small precision parts by injection molding is obtained. To be

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention reduces the occurrence of burrs,
The present invention relates to a polyphenylene sulfide resin composition having excellent fluidity as well as mechanical strength and heat resistance.

[0002]

2. Description of the Related Art Polyphenylene sulfide resin (hereinafter P
Abbreviated as PS resin. ) Has excellent heat resistance, flame retardancy, rigidity and electrical insulation properties suitable for engineering plastics, so it is mainly used for injection molding and is used in various electrical parts, mechanical parts, automobile parts, etc. Is used for.

However, the PPS resin has a relatively large amount of burrs at the time of molding, and its use is limited particularly in applications such as small precision parts which require low burrs. In addition, in applications such as small precision parts, moldability is important as well as low burr, and there is a strong demand for good fluidity.

Under these circumstances, some studies have been made so far for the purpose of reducing the burr of the PPS resin. For example, a method of blending a highly crosslinked PPS resin as a property improving agent (JP-A-64-9266),
Method of adding silane compound to PPS resin
No. 251430), a specific linear PPS resin and a crosslinked PPS resin are used in combination with a base polymer, and a silane coupling agent is further used (JP-A-3-19).
7562).

[0005]

However, conventional techniques for reducing burrs, such as the addition of highly crosslinked PPS resin or the addition of silane compounds, have the problem of reducing the fluidity of the composition as a whole, and are particularly small. In injection molding applications for precision parts, there are problems such as defective filling and partial overfilling, and a material that is sufficiently satisfactory has not yet been obtained.

Therefore, the inventors of the present invention have made the PP excellent in both mechanical strength and fluidity, in addition to the above-mentioned various performances required for the PPS resin, that is, the generation of burrs is small.
As a result of extensive studies for the purpose of developing S resin, as a base polymer, a linear PPS resin having a specific molecular weight and a linear PPS resin having a specific molecular weight lower than this were used in combination at a certain ratio, and further The present inventors have found that a high-performance PPS resin composition satisfying all of the above-mentioned desired performances can be obtained by adding an alkoxysilane compound in combination, and arrived at the present invention.

[0007]

That is, the present invention is as follows.
(A) The number average molecular weight determined by gel permeation chromatography using 1-chloronaphthalene as a solvent is 7,000 to 1
5000, polyphenylene sulfide resin 90-5 having a total ash content of 0.3% by weight or less and having substantially no crosslinked structure
0% by weight and (B) 100 parts by weight of a polyphenylene sulfide resin mixture consisting of 10 to 50% by weight of a polyphenylene sulfide resin having a number average molecular weight of 3,000 to 6000 and having substantially no crosslinked structure determined in the same manner. , (C) 20 to 150 parts by weight of at least one fibrous or non-fibrous reinforcing material, (D) at least one functional group selected from an epoxy group, an amino group, an isocyanate group, a hydroxyl group, and a mercapto group. The present invention provides a polyphenylene sulfide resin composition obtained by melt-kneading 0.1 to 5 parts by weight of an alkoxysilane compound having a group.

The PPS resin used in the present invention is a repeating unit represented by the structural formula (1).

[Chemical 1] It is a polymer containing 70 mol% or more, more preferably 90 mol% or more, and if the repeating unit is less than 70 mol%, heat resistance is impaired, which is not preferable. Also PPS
The resin can comprise less than 30 mol% of the repeating unit of the repeating unit having the following structure.

[0009]

[Chemical 2] The PPS resin used as the component (A) in the present invention has a number average molecular weight of 7,000 to 15 determined by gel permeation chromatography using 1-chloronaphthalene as a solvent.
000, the total ash content is required to have a linear structure of 0.3% by weight or less. PPS that does not meet such conditions
When a resin is used as the component (A), it is difficult to obtain a sufficient burr reduction effect and sufficient mechanical strength and weld strength at the same time. Typical examples of the PPS resin satisfying the above conditions include M2888 and M2588 manufactured by Toray-Phillips Petroleum.

Unlike the component (A), the PPS resin used as the component (B) in the present invention must have a number average molecular weight of 3,000 to 6000 and substantially no crosslinked structure. . When the number average molecular weight is less than 3000, it is difficult to obtain sufficient mechanical strength and weld strength. The number average molecular weight is 6000.
When it exceeds, it is difficult to obtain excellent fluidity and sufficient burr reduction effect at the same time.

The method for producing the PPS resin of the present invention is not particularly limited as long as the above-mentioned requirements are satisfied, and it is a generally known method, that is, the method described in JP-B-45-3368 or JP-B-52-12240. It can be produced by the method described in 1. In the present invention, the PPS resin obtained as described above is subjected to various treatments such as washing with an organic solvent, hot water, an aqueous acid solution and the like, activation with a compound containing a functional group such as an acid anhydride group, an epoxy group, an isocyanate group. It is also possible to use it after doing.

The component (A) and the component (B) PPS resin are mixed in the range of 90 to 50% by weight of the component (A) PPS resin and 10 to 50% by weight of the component (B) PPS resin. It is preferably in the range of 20 to 40% by weight of the component (B) with respect to 80 to 60% by weight of the component (A). If the PPS resin of the component (A) exceeds 90% by weight, the effect of reducing burrs is not sufficient. If the PPS resin of the component (A) is less than 50% by weight, mechanical strength and weld strength are impaired, which is not preferable.

The fibrous or non-fibrous reinforcing material (C) in the present invention is 20 to 100 parts by weight of the PPS resin for the purpose of improving the heat resistance and strength of the PPS resin.
It is added at a ratio of 150 parts by weight.

As the fiber reinforcing material, glass fiber,
Examples thereof include alumina fiber, silicon carbide fiber, ceramic fiber, asbestos fiber, gypsum fiber, metal fiber, inorganic fiber such as potassium whisker titanate, and carbon fiber. As the non-fibrous reinforcing material, wollastonite, sericite, kaolin, mica, clay, bentonite, asbestos, talc, silicates such as alumina silicate, alumina, silicon chloride, magnesium oxide, zirconium oxide, titanium oxide, etc. Examples include metal compounds, carbonates such as calcium carbonate, magnesium carbonate and dolomite, sulfates such as calcium sulfate and barium sulfate, glass beads, boron nitride, silicon carbide and silica, which may be hollow.

These reinforcing materials can be used in combination of two or more, and if necessary, they can be pretreated with a silane coupling agent and a titanium coupling agent before use. Particularly preferred reinforcing materials are glass fibers and carbon fibers for fibrous reinforcing materials and wollastonite, talc and calcium carbonate for non-fibrous reinforcing materials.

The amount of the reinforcing material (C) compounded is in the range of 20 to 150 parts by weight with respect to 100 parts by weight of the PPS resin, but in view of the balance between heat resistance and mechanical strength of the resulting composition. , 40 to 100 parts by weight of the reinforcing material is preferable. If the compounding amount of the reinforcing material is less than 20 parts by weight, sufficient heat resistance and mechanical strength cannot be obtained, and conversely, if the compounding amount exceeds 150 parts by weight, the fluidity of the composition is significantly impaired, which is not preferable. . Next, the alkoxysilane compound used as the component (D) in the present invention has one or more epoxy groups, amino groups, isocyanate groups,
An alkoxysilane compound having a hydroxyl group or a mercapto group, specifically, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysisilane, 3-glycidoxypropylmethyldimethoxysilane, 3- Glycidoxypropylmethyldiethoxysilane, 2- (3,4-epoxycyclohexyl)
Ethyltrimethoxysilane, N- (2-aminoethyl)
-3-Aminopropyltrimethoxysilane, N- (2-
Aminoethyl) -3-aminopropylmethyldimethoxysilane, 3-aminopropyltrimethoxysilane, 3-
Aminopropyltriethoxysilane, 3-aminopropylmethyldiethoxysilane, N-phenylaminomethyltrimethoxysilane, N-phenylaminopropyltrimethoxysilane, dimethoxymethyl-3-piperazinopropylsilane, 3-piperazinopropyl Trimethoxysilane, 3-isocyanatopropyltrimethoxysilane,
3-isocyanatopropyltriethoxysilane, 3-isocyanatopropylmethyldimethoxysilane, 3-isocyanatopropylmethyldiethoxysilane, 3-isocyanatopropylethyldimethoxysilane, 3-hydroxypropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane Methoxysilane, 3-mercaptopropyltriethoxysilane, 3-mercaptomethyldimethoxysilane and the like can be mentioned.

These alkoxysilane compounds can be used alone or in the form of a mixture of two or more thereof. Among the above-mentioned alkoxysilane compounds, particularly preferable alkoxysilane compounds are 3-glycidoxypropyltrimethoxysilane. , N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, 3-isocyanatopropyltrimethoxysilane, 3-hydroxypropyltrimethoxysilane, and 3-mercaptopropyltrimethoxysilane.

The amount of the alkoxysilane compound (D) used in the present invention is 0.1 to 5 parts by weight, preferably 0.3 to 3 parts by weight, based on 100 parts by weight of the PPS resin.
Parts by weight. If the addition amount is less than 0.1 parts by weight, the effect of improving mechanical strength and weld strength is not sufficiently expressed,
Further, if it exceeds 5 parts by weight, the fluidity and mechanical strength of the composition are impaired, which is not preferable.

The PPS resin composition of the present invention contains a release agent, an antioxidant, a heat stabilizer, a lubricant, a crystal nucleating agent, an ultraviolet ray inhibitor, a colorant, and a flame retardant as long as the effects of the present invention are not impaired. Conventional additives such as and small amounts of other polymers can be added.

The method for preparing the PPS resin composition of the present invention is not particularly limited, but a mixture of raw materials is generally known such as a single-screw or twin-screw extruder, Banbury mixer, kneader and mixin roll. 280-3 supplied to the melt mixer
A typical example is a method of kneading at a temperature of 80 ° C., and the order of mixing raw materials is not particularly limited. In addition, the small amount additive component may be added before kneading after kneading and pelletizing the other components by the above method or the like.

The PPS resin composition obtained according to the present invention is a resin composition having less burr, excellent fluidity, and excellent moldability, and is used for electric / electronic parts, household / office electric appliance parts. , Machine-related parts, optical equipment / precision machinery-related parts, automobile / vehicle-related parts, and other various applications.

[0022]

The present invention will be described in more detail with reference to the following examples.

The number average molecular weight, weld strength, molding lower limit pressure, and burr length described in Examples and Comparative Examples were evaluated and measured according to the following methods.

Number average molecular weight: A gel permeation chromatograph manufactured by Waters Co., Ltd. was used, and the number average molecular weight was measured according to the method disclosed in the Journal of Polymer Science, Vol. 44 (1987) February 139-141.

Measurement of weld strength: AST having a gate at both ends and a weld line near the center of the test piece
M4 dumbbell pieces were molded using an injection molding machine with a mold clamping force of 20 tons at a cylinder temperature of 320 ° C and a mold temperature of 135 ° C, and the tensile strength was measured under the conditions of a strain rate of 5 mm / min and a fulcrum distance of 64 mm. Was done.

Evaluation of molding lower limit pressure: When the above flat plate molded article was injection-molded, the minimum injection pressure required to prevent defective filling was defined as the molding lower limit pressure. The lower the molding lower limit pressure, the better the fluidity.

Measurement of burr length: The length of the burr generated in the gap for degassing of the above flat plate molded article was measured. The shorter the burr length, the better the burr characteristics.

Reference Example Reference Example 1 In this Example and Comparative Example, M28 manufactured by Toray-Phillips Petroleum Co., Ltd. was used as the PPS resin of the component (A).
88 (PPS-1) and M2588 (PPS-2)
It was used. The number average molecular weight of the PPS resin is 1 each.
0000, 9000, total ash content is 0.07,
It was 0.08% by weight.

Reference Example 2 (Polymerization of PPS) 30% sodium hydrosulfide aqueous solution 4.6 in an autoclave
7 kg (25 mol of sodium hydrosulfide), 2.00 kg of 50% sodium hydroxide (25 mol of sodium hydroxide) and 8 kg of N-methyl-2-pyrrolidone (hereinafter abbreviated as NMP) are charged, and gradually heated to 205 ° C with stirring. The temperature was raised, and 4.1 l of distilled water containing 3.8 kg of water was removed. 1.4-dichlorobenzene 3.75k in the residual mixture
g (25.5 mol) and 2 kg of NMP added to give 23
The mixture was heated at 0 ° C for 1 hour and further at 260 ° C for 30 minutes. The reaction product was washed 5 times with warm water and dried under reduced pressure at 80 ° C. for 24 hours to obtain a powdered PPS resin (PPS resin having a number average molecular weight of 3700) (PPS).
-3) was obtained. The PPS resin was used in Examples and Comparative Examples.

Reference Example 3 (Polymerization of PPS) 30% sodium hydrosulfide aqueous solution 4.6 in an autoclave
7 kg, 2.00 kg of 50% sodium hydroxide and 8 kg of NMP were charged, the temperature was gradually raised to 205 ° C. with stirring, and 4.1 l of distilled water containing 3.8 kg of water was removed. 1.4-dichlorobenzene 3.75k in the residual mixture
g and 2 kg of NMP were added, and the mixture was heated at 230 ° C. for 1 hour and further at 260 ° C. for 2 hours. The reaction product was washed 5 times with warm water and dried under reduced pressure at 80 ° C. for 24 hours to obtain a powdered PPS resin (PPS-4) having a number average molecular weight of 5400. The PPS resin was used in Examples and Comparative Examples.

Example 1 PPS-1, PPS-3, 3-isocyanatopropyltrimethoxysilane and glass fiber were dry blended in the proportions shown in Table 1, and then screw type extruder set at a temperature of 320 ° C. After melt kneading, pelletizing was performed.
Using the obtained pellets, an ASTM No. 4 dumbbell piece and a flat plate molded article were molded under the conditions of a cylinder temperature of 320 ° C. and a mold temperature of 135 ° C. using an injection molding machine having a mold clamping force of 20 tons.

Table 2 shows the weld strength, molding lower limit pressure and burr length measured for the obtained test pieces.

Comparative Example 1 Dry blending, melt kneading, pelletizing, molding and evaluation of physical properties were carried out in the proportions shown in Table 1 in the same manner as in Example 1 except that PPS-3 was not used. The results are also shown in Table 2.

When the low molecular weight linear PPS resin was not blended, the fluidity was low and a sufficient burr reduction effect was not obtained.

Comparative Example 2 Dry blending, melt kneading, pelletizing, molding and evaluation of physical properties were carried out in the proportions shown in Table 1 in the same manner as in Example 1 except that PPS-1 was not used. The results are also shown in Table 2.

When the high molecular weight linear PPS resin was not blended, sufficient mechanical strength could not be obtained.

Comparative Example 3 Dry blending, melt kneading, in the proportions shown in Table 1 were conducted in the same manner as in Example 1 except that the silane compound was not added.
Pelletization, molding, and evaluation of physical properties were performed. The results are shown in Table 2.

It can be seen that when the silane compound is not added, sufficient mechanical strength and burr reduction effect cannot be obtained.

Examples 2 to 14 In the same manner as in Example 1, dry blending, melt kneading, pelletizing, and PPS resin, a reinforcing material, an alkoxysilane compound used in various ratios were used in the same manner as in Example 1. Molding and evaluation of physical properties were performed. The results are shown in Table 2.

The resin compositions obtained here were all excellent in strength, fluidity and low burr and of high practical value.

[0041]

[Table 1]

[Table 2]

[0042]

EFFECTS OF THE INVENTION The polyphenylene sulfide resin composition of the present invention has few burrs generated at the time of molding, mechanical strength,
Not only heat resistance but also excellent fluidity, it is particularly useful for applications such as small precision parts by injection molding.

Claims (1)

[Claims] 1. A substantially crosslinked structure having (A) a number average molecular weight of 7,000 to 15,000 and a total ash content of 0.3% by weight or less as determined by gel permeation chromatography using 1-chloronaphthalene as a solvent. 90 to 50% by weight of a polyphenylene sulfide resin having no polyphenylene sulfide resin, and (B) a polyphenylene sulfide resin having a number average molecular weight of 3,000 to 6000 determined in the same manner and having substantially no crosslinked structure 10
20 to 150 parts by weight of at least one kind of (C) a fibrous or non-fibrous reinforcing material with respect to 100 parts by weight of a polyphenylene sulfide resin mixture consisting of 50% by weight, (D)
A polyphenylene sulfide resin composition obtained by melt-kneading 0.1 to 5 parts by weight of an alkoxysilane compound having at least one functional group selected from an epoxy group, an amino group, an isocyanate group, a hydroxyl group, and a mercapto group.