JPH06508879A - 柔軟なコイルポリマーとサーモトロピック液晶セグメント化ブロックコポリマーの配合物 - Google Patents

柔軟なコイルポリマーとサーモトロピック液晶セグメント化ブロックコポリマーの配合物

Info

Publication number: JPH06508879A
Authority: JP; Japan
Prior art keywords: pbt; lcp; formulation; flexible coil; flexible
Prior art date: 1991-07-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP5502375A

Other languages

English (en)

Japanese (ja)

Inventor

フェリス、リチャード、ジェイ．

ジョ、ビュン−ウーク

Original Assignee

ユニバーシティ　オブ　マサチューセッツ　アット　アムハースト

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-07-08

Filing date

1992-07-07

Publication date

1994-10-06

1992-07-07 Application filed by ユニバーシティ　オブ　マサチューセッツ　アット　アムハースト filed Critical ユニバーシティ　オブ　マサチューセッツ　アット　アムハースト

1994-10-06 Publication of JPH06508879A publication Critical patent/JPH06508879A/ja

Status Pending legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 53
229920000642 polymer Polymers 0.000 title claims description 48
239000004974 Thermotropic liquid crystal Substances 0.000 title claims description 4
229920001400 block copolymer Polymers 0.000 title description 11
238000009472 formulation Methods 0.000 claims description 40
239000011159 matrix material Substances 0.000 claims description 28
-1 poly(ethylene terephthalate) Polymers 0.000 claims description 23
229920000728 polyester Polymers 0.000 claims description 18
229920000139 polyethylene terephthalate Polymers 0.000 claims description 12
239000005020 polyethylene terephthalate Substances 0.000 claims description 11
125000006850 spacer group Chemical group 0.000 claims description 10
150000001875 compounds Chemical class 0.000 claims description 5
229920001281 polyalkylene Polymers 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 3
125000003118 aryl group Chemical group 0.000 claims 1
229920001707 polybutylene terephthalate Polymers 0.000 description 95
239000000835 fiber Substances 0.000 description 27
229920000106 Liquid crystal polymer Polymers 0.000 description 21
239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 18
101800001509 Large capsid protein Proteins 0.000 description 12
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
238000002844 melting Methods 0.000 description 12
230000008018 melting Effects 0.000 description 12
229920001577 copolymer Polymers 0.000 description 10
230000007704 transition Effects 0.000 description 9
239000004973 liquid crystal related substance Substances 0.000 description 8
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 7
238000012545 processing Methods 0.000 description 7
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 6
206010061592 cardiac fibrillation Diseases 0.000 description 5
239000002131 composite material Substances 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
238000001125 extrusion Methods 0.000 description 5
239000007788 liquid Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
229920001778 nylon Polymers 0.000 description 5
230000036961 partial effect Effects 0.000 description 5
239000002245 particle Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 5
238000005809 transesterification reaction Methods 0.000 description 5
239000004677 Nylon Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000001816 cooling Methods 0.000 description 4
239000013256 coordination polymer Substances 0.000 description 4
230000002600 fibrillogenic effect Effects 0.000 description 4
239000000463 material Substances 0.000 description 4
239000000155 melt Substances 0.000 description 4
WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 3
229920001634 Copolyester Polymers 0.000 description 3
125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 3
239000000654 additive Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
238000001938 differential scanning calorimetry curve Methods 0.000 description 3
HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000004417 polycarbonate Substances 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000011160 research Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
229920002302 Nylon 6,6 Polymers 0.000 description 2
238000000137 annealing Methods 0.000 description 2
239000012300 argon atmosphere Substances 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
125000001309 chloro group Chemical group Cl* 0.000 description 2
239000013078 crystal Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
229920005570 flexible polymer Polymers 0.000 description 2
239000013022 formulation composition Substances 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
230000003189 isokinetic effect Effects 0.000 description 2
238000003760 magnetic stirring Methods 0.000 description 2
239000000178 monomer Substances 0.000 description 2
230000000877 morphologic effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
238000005191 phase separation Methods 0.000 description 2
238000001907 polarising light microscopy Methods 0.000 description 2
229920000515 polycarbonate Polymers 0.000 description 2
230000008569 process Effects 0.000 description 2
238000001878 scanning electron micrograph Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000007711 solidification Methods 0.000 description 2
230000008023 solidification Effects 0.000 description 2
239000012798 spherical particle Substances 0.000 description 2
238000001757 thermogravimetry curve Methods 0.000 description 2
GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical group Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical group COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
CGYGETOMCSJHJU-UHFFFAOYSA-N 2-chloronaphthalene Chemical compound C1=CC=CC2=CC(Cl)=CC=C21 CGYGETOMCSJHJU-UHFFFAOYSA-N 0.000 description 1
229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
229920008712 Copo Polymers 0.000 description 1
239000005264 High molar mass liquid crystal Substances 0.000 description 1
206010027476 Metastases Diseases 0.000 description 1
229920001410 Microfiber Polymers 0.000 description 1
101100084404 Mus musculus Prodh gene Proteins 0.000 description 1
239000004988 Nematic liquid crystal Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001263 acyl chlorides Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
BMNVSTGMESDKQV-UHFFFAOYSA-N biphenylene;terephthalic acid Chemical group C1=CC=C2C3=CC=CC=C3C2=C1.OC(=O)C1=CC=C(C(O)=O)C=C1 BMNVSTGMESDKQV-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
230000001788 irregular Effects 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
238000003754 machining Methods 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000003658 microfiber Substances 0.000 description 1
210000001724 microfibril Anatomy 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000012994 photoredox catalyst Substances 0.000 description 1
229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
108090000765 processed proteins & peptides Proteins 0.000 description 1
229940018489 pronto Drugs 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
238000012552 review Methods 0.000 description 1
239000011435 rock Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
238000004781 supercooling Methods 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000007039 two-step reaction Methods 0.000 description 1
238000003828 vacuum filtration Methods 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyesters Or Polycarbonates (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP5502375A 1991-07-08 1992-07-07 柔軟なコイルポリマーとサーモトロピック液晶セグメント化ブロックコポリマーの配合物 Pending JPH06508879A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US72660091A	1991-07-08	1991-07-08
US726,600		1991-07-08
PCT/US1992/005670 WO1993001238A1 (fr)	1991-07-08	1992-07-07	Melange d'un polymere en pelote souple et d'un copolymere bloc segmente a cristaux liquides thermotropes

Publications (1)

Publication Number	Publication Date
JPH06508879A true JPH06508879A (ja)	1994-10-06

Family

ID=24919263

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP5502375A Pending JPH06508879A (ja)	1991-07-08	1992-07-07	柔軟なコイルポリマーとサーモトロピック液晶セグメント化ブロックコポリマーの配合物

Country Status (4)

Country	Link
EP (1)	EP0593664A4 (fr)
JP (1)	JPH06508879A (fr)
CA (1)	CA2113114A1 (fr)
WO (1)	WO1993001238A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5508338A (en) *	1994-09-20	1996-04-16	Akzo Nobel Nv	Compatibilized blend of polycarbonate, polyester and liquid crystalline additive

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5465747A (en) *	1977-11-04	1979-05-26	Motoo Takayanagi	High molecular composite body
JP2505411B2 (ja) *	1986-03-24	1996-06-12	ポリプラスチックス株式会社	溶融時に異方性を示す樹脂組成物

1992
- 1992-07-07 EP EP19920915938 patent/EP0593664A4/en not_active Withdrawn
- 1992-07-07 CA CA 2113114 patent/CA2113114A1/fr not_active Abandoned
- 1992-07-07 JP JP5502375A patent/JPH06508879A/ja active Pending
- 1992-07-07 WO PCT/US1992/005670 patent/WO1993001238A1/fr not_active Ceased

Also Published As

Publication number	Publication date
CA2113114A1 (fr)	1993-01-21
WO1993001238A1 (fr)	1993-01-21
EP0593664A1 (fr)	1994-04-27
EP0593664A4 (en)	1994-06-15

Publication	Publication Date	Title
JPH06508880A (ja)	1994-10-06	サーモトロピック液晶セグメント化ブロックコポリマー
Dobb et al.	2005	Properties and applications of liquid-crystalline main-chain polymers
Dutta et al.	1990	Polymer blends containing liquid crystals: A review
CA1163740A (fr)	1984-03-13	Polycarbonate et polyester tout aromatique en melange
US4451611A (en)	1984-05-29	Process for forming blend of polyalkylene terephthalate and wholly aromatic polyester which exhibits an anisotropic melt phase
US4489190A (en)	1984-12-18	Blend of polyalkylene terephthalate and wholly aromatic polyester
US4408022A (en)	1983-10-04	Blend of polyalkylene terephthalate and wholly aromatic polyester and process for producing the same
EP0044177A2 (fr)	1982-01-20	Mélange de polysulfone et de polyester entièrement aromatique
EP0183433B1 (fr)	1989-06-21	Composition de polyester entièrement aromatique et de poly(ester-amide) capables de former une phase fondue anisotrope
Miller et al.	1995	Fibres from polypropylene and liquid-crystal polymer blends using compatibilizing agents: 1. Assessment of functional and non-functional polypropylene—acrylic acid compatibilizers
Hong et al.	1993	Rheological and physical properties of polyarylate/LCP blend systems
EP0618942A1 (fr)	1994-10-12	Melange d'une matrice de polyethylene-terephtalate et d'un copolymere en bloc a cristaux liquides thermotropiques
Kim et al.	1998	Effect of composition and molecular structure on the LC phase of PHB‐PEN‐PET ternary blend
Choi et al.	2015	Reinforcing properties of poly (trimethyleneterephthalate) by a thermotropic liquid crystal polymer
Yamada et al.	1986	Preparation of poly (p‐phenylene terephthalamide)/poly (vinyl chloride) molecular composite and its thermal and mechanical properties
Kim et al.	2000	Studies on the ternary blends of liquid crystalline polymer and polyesters
Chang et al.	1995	Blends of thermotropic liquid crystalline polyesters and poly (butylene terephthalate): Thermal, mechanical, and morphological properties
Joslin et al.	1994	Thermotropic liquid-crystalline polymers with flexible moieties blended with poly (ethylene terephthalate)
JPH0665705B2 (ja)	1994-08-24	ポリアルキレンテレフタレ−トと高分子量完全芳香族ポリエステルとのブレンドおよびその製法
EP0593664A1 (fr)	1994-04-27	Melange d'un polymere en pelote souple et d'un copolymere bloc segmente a cristaux liquides thermotropes
US5286838A (en)	1994-02-15	Thermotropic liquid crystalline polyamide
JPH0655883B2 (ja)	1994-07-27	非サ−モトロピツクおよびサ−モトロピツク全芳香族ポリエステルの溶融ブレンド
Prevorsek	1982	Recent advances in high-strength fibers and molecular composites
Yang et al.	2007	Synthesis of a random copolymer and its compatibility for thermotropic liquid crystalline polymer/poly (ether ether ketone) blends
Tendolkar et al.	1995	Thermotropic random copolyesters containing ethoxydiethyleneoxy-1, 4-phenylene and ethylene terephthalate units