JPH0655663B2 - Cosmetic composition - Google Patents
Cosmetic compositionInfo
- Publication number
- JPH0655663B2 JPH0655663B2 JP3700785A JP3700785A JPH0655663B2 JP H0655663 B2 JPH0655663 B2 JP H0655663B2 JP 3700785 A JP3700785 A JP 3700785A JP 3700785 A JP3700785 A JP 3700785A JP H0655663 B2 JPH0655663 B2 JP H0655663B2
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- component
- kaolin
- amount
- uniformly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 40
- 239000002537 cosmetic Substances 0.000 title claims description 30
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 51
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 49
- 239000005995 Aluminium silicate Substances 0.000 claims description 32
- 235000012211 aluminium silicate Nutrition 0.000 claims description 32
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 32
- 239000002245 particle Substances 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- 239000006071 cream Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000010419 fine particle Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000903 blocking effect Effects 0.000 description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000454 talc Substances 0.000 description 6
- 229910052623 talc Inorganic materials 0.000 description 6
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 5
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- 229940057995 liquid paraffin Drugs 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000000475 sunscreen effect Effects 0.000 description 4
- 230000002087 whitening effect Effects 0.000 description 4
- -1 Polyoxyethylene Polymers 0.000 description 3
- 235000013871 bee wax Nutrition 0.000 description 3
- 239000012166 beeswax Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229940032094 squalane Drugs 0.000 description 3
- 239000000516 sunscreening agent Substances 0.000 description 3
- 229940099259 vaseline Drugs 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229950006451 sorbitan laurate Drugs 0.000 description 2
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- NASRDENTZCCAPN-UHFFFAOYSA-N OC([Na])=O Chemical compound OC([Na])=O NASRDENTZCCAPN-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 229960004881 homosalate Drugs 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000037311 normal skin Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
【発明の詳細な説明】 発明の分野 本発明は、日焼け止めとして用いられる化粧料組成物に
関する。Description: FIELD OF THE INVENTION The present invention relates to a cosmetic composition used as a sunscreen.
従来技術 酸化チタン粉末は、従来より、化粧品用顔料として広く
使用されている。特に、最大粒径０．１μ以下で、平均
粒径５〜５０ｍμの微粒子酸化チタン粉末は、紫外線遮
断効果が著しいところから、最近、日焼け止めの化粧料
用として種々検討が加えられている。しかしながら、か
かる微粒子酸化チタンは、表面エネルギーが大きく、こ
れを用いて化粧品を製造した場合、製造時における均一
な分散が困難であり、また、貯蔵中においては凝集物を
形成する傾向がある。さらに、例えば、水使用によるケ
ーキ状ファンデーション中にかかる微粒子酸化チタンを
配合した場合には、使用時、化粧品が皮膚に均一に塗布
されず、仕上がりが非常に悪いなど化粧料として重大な
欠点がある。2. Description of the Related Art Titanium oxide powder has been widely used as a pigment for cosmetics. In particular, fine particle titanium oxide powder having a maximum particle size of 0.1 μm or less and an average particle size of 5 to 50 μm has a remarkable effect of blocking ultraviolet rays, and thus various studies have recently been added for use as sunscreen cosmetics. However, such fine particle titanium oxide has a large surface energy, and when a cosmetic product is produced using this, it is difficult to uniformly disperse it during production, and it tends to form an aggregate during storage. Furthermore, for example, when such fine particle titanium oxide is blended in a cake-like foundation by using water, there is a serious defect as a cosmetic such that the cosmetic is not uniformly applied to the skin during use and the finish is very poor. .
発明の概要 そこで本発明者らは、紫外線遮断効果に優れた酸化チタ
ンを均一かつ安定に配合した化粧料組成物を得るべく鋭
意検討を行なった結果、酸化チタンにより被覆されたカ
オリン粒子を用いることにより、前記問題点が解決しう
ることを見出し本発明を完成するに至った。SUMMARY OF THE INVENTION Therefore, the inventors of the present invention have conducted diligent studies to obtain a cosmetic composition in which titanium oxide having an excellent ultraviolet blocking effect is uniformly and stably blended, and as a result, use of kaolin particles coated with titanium oxide is performed. As a result, they have found that the above problems can be solved, and completed the present invention.
すなわち、本発明は、酸化チタン粒子により被覆された
カオリン粒子を配合したことを特徴とする化粧料組成物
を提供するものである。That is, the present invention provides a cosmetic composition containing kaolin particles coated with titanium oxide particles.
本発明化粧料組成物によれば、酸化チタンとカオリン粒
子とを単に別々に混合した場合に比し、多量の酸化チタ
ンを配合しえ、はるかに紫外線遮断効果が高く、しかも
均質で安定な化粧料組成物が得られ、皮膚に適用した場
合の仕上がりも良好で、化粧を行なった場合の外観なら
びに日焼け止め効果に優れる。According to the cosmetic composition of the present invention, a large amount of titanium oxide can be blended as compared with the case where titanium oxide and kaolin particles are simply mixed separately, and the effect of blocking ultraviolet rays is much higher, and the cosmetic composition is homogeneous and stable. The resulting composition is excellent in finish when applied to the skin, and is excellent in appearance when applied to makeup and sunscreen effect.
発明の詳説 本発明化粧料組成物に配合される酸化チタン被覆カオリ
ンは、適宜のチタニウム塩に対し所定量のカオリン粒子
（粒径約０．５〜３０μｍ）を添加し、カオリンの存在
下に該チタニウム塩を加水分解し、ついで、常法により
ろ過、洗浄、乾燥した後、焼成を行なうことにより得ら
れる。かかる酸化チタン被覆カオリンの製造方法の一例
を具体的に挙げれば、１５ｇ／（Ｔｉｏ２換算）の硫
酸チタニル水溶液１中に、平均粒径２μのカオリン１
３５ｇを添加し、撹拌しながら加熱、沸騰させて２時間
保持する。生成物をろ過、水洗し、得られたケーキを分
離して１１０℃にて乾燥する。さらに８００℃程度にて
３０分間焼成を行ない本発明にて用いる酸化チタン被覆
カオリンを得る。DETAILED DESCRIPTION OF THE INVENTION The titanium oxide-coated kaolin blended in the cosmetic composition of the present invention is prepared by adding a predetermined amount of kaolin particles (particle diameter of about 0.5 to 30 μm) to an appropriate titanium salt, and adding the kaolin particles in the presence of kaolin. It can be obtained by hydrolyzing a titanium salt, then filtering, washing and drying by a conventional method, and then firing. To give a concrete example of the method for producing such titanium oxide-coated kaolin, kaolin 1 having an average particle size of 2 μ is added to an aqueous solution 1 of 15 g / (Tio 2 equivalent) titanyl sulfate.
Add 35 g, heat with stirring, boil and hold for 2 hours. The product is filtered, washed with water, the cake obtained is separated and dried at 110 ° C. Further, calcination is performed at about 800 ° C. for 30 minutes to obtain the titanium oxide-coated kaolin used in the present invention.
かかる方法にて得られた酸化チタン被覆カオリンは、母
体となるカオリン粒子表面に二酸化チタンの微粒子が被
覆されている。In the titanium oxide-coated kaolin obtained by such a method, fine particles of titanium dioxide are coated on the surface of the kaolin particles as the base.
つぎに、該酸化チタン被覆カオリンを配合して製造した
試験クリームの紫外線遮断効果（ＳＰＦ：Sun Protecti
on Factor）、透明性、ブルーミング、安定性につき、
従来の微粒子酸化チタン（平均粒径８ｍμ）とカオリン
との混合物を配合したクリームの場合と比較して第１表
に示す。Next, the ultraviolet ray blocking effect (SPF: Sun Protecti) of the test cream produced by blending the titanium oxide-coated kaolin
on Factor), transparency, blooming, stability,
The results are shown in Table 1 in comparison with a conventional cream containing a mixture of fine particulate titanium oxide (average particle size 8 mμ) and kaolin.
また、該酸化チタン被覆カオリンを用いて製造した試験
ケーキ状ファンデーションのＳＰＦ、製造時の分散性、
使用時の色味の差および使用時の仕上がりにつき評価し
た結果を同様にして第２表に示す。Further, SPF of a test cake-like foundation produced using the titanium oxide-coated kaolin, dispersibility during production,
The evaluation results of the difference in color tone during use and the finish during use are similarly shown in Table 2.
なお、以下において％とあるは、すべて重量％を意味す
る。In the following, "%" means "% by weight".
各試験化粧料組成物は、つぎの組成および製造方法によ
り得た。Each test cosmetic composition was obtained by the following composition and manufacturing method.
(a)試験クリームの組成： 成分Ａ 配合量（％） 固形パラフィン 5.0 ミツロウ 4.0 マイクロクリスタリンワックス 4.0 ワセリン 7.0 スクワラン 30.0 ポリオキシエチレンモノ ラウリン酸ソルビタン(20EO) 1.0 セスキオレイン酸ソルビタン 4.0 成分Ｂ 配合量（％） 精製水 残部 成分Ｃ 配合量（％） 酸化チタン被覆カオリン［Ｉ］、 第１表に記載 または酸化チタンとカオリンとの 混合物［II］（酸化チタン／［Ｉ］ または［II］の比は第１表に記載） タルク 5.0 上記成分Ｃを均一に混合し、これに成分Ｂに加え、７０
℃にてよく分散する。別に、成分Ａを７０℃で加熱、溶
解し、これに前記混合物を加え、ホモミキサーで均一に
乳化する。乳化後、３０℃まで冷却し製品とする。(a) Composition of test cream: Component A content (%) Solid paraffin 5.0 Beeswax 4.0 Microcrystalline wax 4.0 Vaseline 7.0 Squalane 30.0 Polyoxyethylene mono sorbitan laurate (20EO) 1.0 Sorbitan sesquioleate 4.0 Component B content (%) ) Purified water balance Component C content (%) Titanium oxide-coated kaolin [I], as shown in Table 1 or mixture [II] of titanium oxide and kaolin (titanium oxide / [I] or [II] ratio is Talc 5.0 The above component C is uniformly mixed and added to the component B. 70
Disperse well at ℃. Separately, Component A is heated and dissolved at 70 ° C., the above mixture is added thereto, and the mixture is uniformly emulsified with a homomixer. After the emulsification, the product is cooled to 30 ° C.
(b)ケーキ状ファンデーションの組成： 成分Ａ 配合量（％） 酸化チタン被覆カオリン［Ｉ］、 第１表に記載 または酸化チタンとカオリン［II］ との混合物（酸化チタン／［Ｉ］ または［II］の比は第１表に記載） タルク 残部 ベンガラ 1.0 黄酸化鉄 2.5 黒酸化鉄 0.05 成分Ｂ 配合量（％） 流動パラフィン 8.5 ＩＰＰ 1.0 セスキオレイン酸ソルビタン 3.0 プロピレングリコール 2.5 パラベン 0.2 成分Ｃ 配合量（％） 香料 0.25 上記成分Ａをヘンシェルミキサーで５分間撹拌する。一
方、他の容器にて７０℃に加温溶解した成分Ｂを前記成
分Ａに滴下しながら撹拌混合する。ついで、該混合物に
成分Ｃを加えて１分間撹拌混合し、得られた混合物を一
定量ずつ金皿に充填し、ケーキ状ファンデーションを製
造する。(b) Composition of cake-like foundation: Component A content (%) Titanium oxide-coated kaolin [I], listed in Table 1 or a mixture of titanium oxide and kaolin [II] (titanium oxide / [I] or [II] The ratio is shown in Table 1) Talc balance Bengala 1.0 Yellow iron oxide 2.5 Black iron oxide 0.05 Component B compounding amount (%) Liquid paraffin 8.5 IPP 1.0 Sorbitan sesquioleate 3.0 Propylene glycol 2.5 Paraben 0.2 Component C compounding amount (%) ) Fragrance 0.25 Stir the above component A with a Henschel mixer for 5 minutes. On the other hand, the component B melted by heating at 70 ° C. in another container is added dropwise to the component A while stirring and mixing. Then, the component C is added to the mixture and the mixture is stirred and mixed for 1 minute, and the mixture thus obtained is filled in a gold plate in a predetermined amount to prepare a cake-like foundation.
これら各化粧料組成物の評価は、つぎの方法により行な
った。Each of these cosmetic compositions was evaluated by the following methods.
(1)ＳＰＦ 光源：東芝ＦＬ２０Ｓ・Ｅ−３０ ３本 中心波長 ３０６nm 被照射部位までの距離 ６０cm 被照射部位：日本人、色白肌および普通肌の成人男女の
背部 試験化粧料塗布量：０．２ｇ／１００cm2 上記の条件によりＦＤＡに定められたＳＰＦの測定法に
準じ、光量一定とし照射時間を３〜６０分で変化させ、
試験化粧料未塗布部位と塗布部位との最小紅斑惹起紫外
線量（ＭＥＤ）の比を次式により求めた。(1) SPF Light source: Toshiba FL20S ・ E-30 3 central wavelength 306nm Distance to irradiated area 60cm Irradiated area: back of adult men and women of Japanese, fair skin and normal skin Application amount of cosmetics: 0.2g / 100 cm 2 According to the SPF measurement method defined by FDA under the above conditions, the light amount is kept constant and the irradiation time is changed from 3 to 60 minutes.
The ratio of the minimum erythema-inducing ultraviolet light dose (MED) between the test cosmetic non-application site and the application site was determined by the following formula.
ＳＰＦ値＝試験化粧料塗布部位のＭＥＤ／試験化粧料未
塗布部位のＭＥＤ 測定値の妥当性は、ＦＤＡ法の標準サンスクリーン（８
％ホモサレートローション）によって確認した（ｎ＝２
０以上）。SPF value = MED of test cosmetic application site / MED of test cosmetic non-application site is appropriate for the standard sunscreen (8) of FDA method.
% Homosalate lotion) (n = 2)
0 or more).
(2)透明性 前記試験クリームを肌に延ばしたとき、白味が認められ
るか、否かを１０名のパネラーにより評価した。(2) Transparency When the test cream was spread on the skin, whether or not whiteness was observed was evaluated by 10 panelists.
〇：１０名とも白味を認めない △：１〜５名が白味を認める ×：６名以上が白味を認める (3)ブルーミング 前記試験クリームを肌に延ばしたとき、ブルーミング
（青味）が認められるか、否かを１０名のパネラーによ
り評価した。なお、このブルーミングは、従来の微粒子
酸化チタンを配合した化粧料で生じやすい。◯: No whiteness was observed in 10 people. Δ: 1 to 5 people recognized whiteness. ×: 6 people or more recognized whiteness. (3) Blooming When the test cream was spread on the skin, blooming (blueness) was observed. Whether or not was observed was evaluated by 10 panelists. It should be noted that this blooming is likely to occur in the conventional cosmetics containing fine particulate titanium oxide.
〇：１０名とも青味を認めない △：１〜５名が青味を認める ×：６名以上が青味を認める (4)安定性 試験クリームを製造後、５０℃にて一週間放置し、凝集
（ツブ）の有無を観察し、つぎの基準で評価した。◯: No bluish color was observed in 10 people. Δ: 1 to 5 people recognized bluish color. ×: 6 or more people recognized bluish color. (4) Stability After manufacturing the test cream, leave it for 1 week at 50 ° C. Then, the presence or absence of aggregation (tub) was observed and evaluated according to the following criteria.
〇：異常なし △：微かなツブが認められる ×：明らかなツブが認められる (5)分散性 プレスして得られた試験ケーキ状ファンデーション中の
不均一な固まり（微粒子酸化チタン）の有無を観察し、
つぎの基準で評価した。◯: No abnormality Δ: Small lumps are recognized ×: Clear lumps are recognized (5) Dispersibility Observe the presence or absence of non-uniform lumps (fine titanium oxide particles) in the test cake foundation obtained by pressing. Then
The following criteria were used for evaluation.
〇：不均一な固まり、なし △：不均一な固まりが、微かに認められる ×：不均一な固まり、あり (6)色味の差 試験ケーキ状ファンデーションの製品そのものの色と、
肌に塗布した際の色味との差の有無を１０名のパネラー
により評価した。なお、この色味の差は、従来の微粒子
酸化チタンを配合した化粧料で生じやすい。◯: Non-uniform lump, none △: Non-uniform lump is slightly observed ×: Non-uniform lump, Yes (6) Difference in color tone The color of the test cake foundation product itself,
The presence or absence of a difference in color when applied to the skin was evaluated by 10 panelists. It should be noted that this difference in tint is likely to occur in the conventional cosmetics containing fine particle titanium oxide.
〇：９名以上が同一と判断する △：２〜５名が差有りと判断する ×：６名以上が差有りと判断する (6)仕上がり感 試験ケーキ状ファンデーションを水を用いて肌に塗布す
る。塗布した粉が凝集を起こして塗布部位周辺に白く粉
が集まる現象（白化）の有無、または、仕上がりムラの
有無をつぎの基準により評価する。◯: 9 people or more are judged to be the same Δ: 2 to 5 people are judged to be different ×: 6 people or more are judged to be different (6) Finished feeling test A cake foundation is applied to the skin using water. To do. The presence or absence of a phenomenon (whitening) in which the applied powder agglomerates to collect white powder around the application site or the presence or absence of unevenness in finish is evaluated according to the following criteria.
〇：白化は生じない △：わずかに白化が生じる（または、粉っぽい仕上が
り） ×：白化が生じる（または、塗りムラが生じる） 第１表および第２表より明らかなごとく、酸化チタン被
覆カオリンを配合した本発明のクリームおよびケーキ状
ファンデーションは、いずれも従来の微粒子酸化チタン
をカオリンとともに単に混合して配合した化粧料組成物
より遥かに広範囲の配合量にて化粧料に配合することが
可能であり優れた紫外線遮断効果が得られるとともに化
粧料として好ましい性状を示す。◯: No whitening occurs Δ: Slight whitening occurs (or powdery finish) ×: Whitening occurs (or coating unevenness occurs) As is clear from Tables 1 and 2, the creams and cake foundations of the present invention containing titanium oxide-coated kaolin are both obtained from a cosmetic composition obtained by simply mixing conventional particulate titanium oxide with kaolin. It can be blended into cosmetics in a far wider range of amounts, and an excellent UV blocking effect can be obtained, and it exhibits favorable properties as a cosmetic.
また、酸化チタン被覆カオリンに対する酸化チタンの被
覆量は、１〜５０％が好ましい。被覆量が、１％未満の
場合は紫外線遮断効果が充分でなく、一方、５０％を越
えると、化粧料としての諸性質が低下する。なお、かか
る酸化チタン被覆カオリンの組成物全体に対する配合量
は、化粧料の形態に応じて９０％以下の範囲にて適宜変
化させてよい。Further, the coating amount of titanium oxide with respect to the titanium oxide-coated kaolin is preferably 1 to 50%. When the coating amount is less than 1%, the ultraviolet ray blocking effect is not sufficient, while when it exceeds 50%, various properties as a cosmetic material are deteriorated. The amount of the titanium oxide-coated kaolin with respect to the entire composition may be appropriately changed within the range of 90% or less depending on the form of the cosmetic.
さらに、本発明の化粧料組成物には、従来の微粒子酸化
チタンを３％以下配合しても良い。Furthermore, the cosmetic composition of the present invention may contain conventional fine particle titanium oxide in an amount of 3% or less.
本発明の化粧料組成物としては、例えば、ケーキ状また
は乳液状のファンデーション、白粉、リップスティッ
ク、乳液、クリームなどが挙げられる。これらの化粧料
組成物を製造するには、前記酸化チタン被覆カオリンを
配合し、それぞれ常法により処理を行なう。Examples of the cosmetic composition of the present invention include cake-like or emulsion-type foundations, white powder, lipsticks, emulsions, creams and the like. In order to produce these cosmetic compositions, the above-mentioned titanium oxide-coated kaolin is blended and treated by a conventional method.
実施例 以下に本発明を実施例にもとづき、さらに詳細に説明す
る。Examples Hereinafter, the present invention will be described in more detail with reference to Examples.
実施例１ つぎの組成により、ケーキ状ファンデーションを製造し
た。Example 1 A cake-like foundation was produced with the following composition.
成分Ａ 配合量（％） 酸化チタン被覆カオリン （被覆量１０％） 50.0 微粒子酸化チタン （平均粒径８ｍμ） 3.0 タルク 29.3 ベンガラ 0.6 黄酸化鉄 1.5 黒酸化鉄 0.15 成分Ｂ 配合量（％） 流動パラフィン 8.5 パルミチン酸イソプロピル 1.0 セスキオレイン酸ソルビタン 3.0 プロピレングリコール 2.5 パラベン 0.2 成分Ｃ 配合量（％） 香料 0.25 成分Ａをヘンシェルミキサーで５分間撹拌する。Ingredient A Amount (%) Titanium oxide-coated kaolin (Amount 10%) 50.0 Fine particle titanium oxide (Average particle size 8 mμ) 3.0 Talc 29.3 Bengal 0.6 Iron oxide yellow 1.5 Iron oxide black black 0.15 Ingredient B (%) Liquid paraffin 8.5 Isopropyl palmitate 1.0 Sorbitan sesquioleate 3.0 Propylene glycol 2.5 Paraben 0.2 Component C content (%) Perfume 0.25 Component A is stirred for 5 minutes with a Henschel mixer.
一方、他の容器にて７０℃に加温溶解した成分Ｂを前記
成分Ａに滴下しながら撹拌混合し、ついで、成分Ｃを加
えて１分間撹拌混合し、得られた混合物を一定量ずつ金
皿に充填して、ケーキ状ファンデーションを製造した。On the other hand, while stirring and mixing component B, which was heated and dissolved at 70 ° C. in another container, with component A, the component C was added and the mixture was stirred and mixed for 1 minute. The dish was filled to produce a cake foundation.
該ファンデーション製造において、酸化チタンは均一に
分散し、また、使用に際して、皮膚に均一な塗布を行う
ことができ、仕上がりが非常に良好であった。In the production of the foundation, titanium oxide was uniformly dispersed, and when used, the skin could be uniformly applied, and the finish was very good.
実施例２ つぎの組成により、乳液状ファンデーションを製造し
た。Example 2 A milky liquid foundation was produced with the following composition.
成分Ａ 配合量（％） 流動パラフィン 4.0 モノステアリン酸グリセリン 2.0 ステアリン酸 3.0 ラノリン 2.0 固型パラフィン 0.5 モノステアリン酸プロピレン グリコール 0.5 パラオキシ安息香酸プロピル 0.1 成分Ｂ 配合量（％） 精製水 57.2 トリエタノールアミン 1.0 カルボキシメチルセルロース ナトリウム 0.2 ベントナイト 0.5 モノステアリン酸ポリオキシ エチレンソルビタン 1.5 プロピレングリコール 7.5 成分Ｃ 配合量（％） 酸化チタン被覆カオリン （被覆量３０％） 10.0 微粒子酸化チタン （平均粒径８ｍμ） 2.0 タルク 5.0 ベンガラ 0.7 黄酸化鉄 2.0 黒酸化鉄 0.3 成分Ａおよび成分Ｂを各々別個の容器で８０℃まで加温
溶解後、成分Ｂを成分Ａに投入する。１０分間撹拌し、
さらに成分Ｃを投入した後、１５分間撹拌し、３０℃ま
で冷却して乳液状ファンデーションを製造した。Ingredient A Amount (%) Liquid paraffin 4.0 Glycerin monostearate 2.0 Stearic acid 3.0 Lanolin 2.0 Solid paraffin 0.5 Propylene glycol monostearate 0.5 Propyl paraoxybenzoate 0.1 Ingredient B amount (%) Purified water 57.2 Triethanolamine 1.0 Carboxy Sodium methyl cellulose 0.2 Bentonite 0.5 Polyoxyethylene sorbitan monostearate 1.5 Propylene glycol 7.5 Component C content (%) Titanium oxide coated kaolin (30% coating amount) 10.0 Fine titanium oxide (average particle size 8 mμ) 2.0 Talc 5.0 Bengala 0.7 Yellow iron oxide 2.0 Iron oxide black 0.3 Component A and component B are dissolved by heating to 80 ° C. in separate containers, and then component B is added to component A. Stir for 10 minutes,
After further adding the component C, the mixture was stirred for 15 minutes and cooled to 30 ° C. to prepare a milky liquid foundation.
該ファンデーション製造において、酸化チタンは均一に
分散して貯蔵中も凝集を起こさず、また、使用に際し
て、皮膚に均一な塗布を行うことができ、仕上がりが非
常に良好であった。In the production of the foundation, titanium oxide was uniformly dispersed and did not agglomerate during storage, and when used, it could be applied uniformly to the skin, and the finish was very good.
実施例３ つぎの組成により、白粉を製造した。Example 3 A white powder was produced with the following composition.
成分Ａ 配合量（％） 酸化チタン被覆カオリン （被覆量１％） 90.0 タルク 5.0 黄酸化鉄 1.5 ベンガラ 1.4 黒酸化鉄 0.1 成分Ｂ 配合量（％） スクワラン 2.2 セスキオレイン酸ソルビタン 0.5 成分Ｃ 配合量（％） 香料 0.3 成分Ａをヘンシェルミキサーで５分間撹拌する。Ingredient A Blending amount (%) Titanium oxide coated kaolin (Coating amount 1%) 90.0 Talc 5.0 Yellow iron oxide 1.5 Bengala 1.4 Black iron oxide 0.1 Component B blending amount (%) Squalane 2.2 Sorbitan sesquioleate 0.5 Component C blending amount (%) ) Fragrance 0.3 Stir component A with a Henschel mixer for 5 minutes.
一方、成分Ｂを他の容器を用い７０℃にて均一に溶融
し、前記成分Ａに滴下しながら撹拌混合を行なう。さら
に、成分Ｃを滴下後、１分間撹拌混合し、アトマイザー
により粉砕し製品を得る。On the other hand, Component B is uniformly melted at 70 ° C. in another container, and stirred and mixed while being added dropwise to Component A. Further, after dropping component C, the mixture is stirred and mixed for 1 minute and pulverized by an atomizer to obtain a product.
該白粉製造において、酸化チタンは均一に分散し、ま
た、使用に際して、皮膚に均一な塗布を行うことがで
き、仕上がりが非常に良好であった。In the production of the white powder, titanium oxide was uniformly dispersed, and when used, the skin could be uniformly applied, and the finish was very good.
実施例４ つぎの組成により、リップスティックを製造した。Example 4 A lipstick was produced with the following composition.
成分Ａ 配合量（％） 酸化チタン被覆カオリン （被覆量２０％） 5.0 雲母末 5.0 赤色２０２号 0.5 赤色２０４号 0.5 成分Ｂ 配合量（％） キャンデリラロウ 7.0 固形パラフィン 7.0 ミツロウ 5.0 カルナウバロウ 5.0 ヒマシ油 44.8 ミリスチン酸イソプロピル 10.0 成分Ｃ 配合量（％） 香料 0.2 成分Ａおよびヒマシ油の一部を乳鉢を用いて均一に混練
し、顔料部とする。成分Ｂの残部を加熱溶解し、これに
前記顔料部を加え、ホモミキサーで均一に分散し、さら
に、成分Ｃを添加、分散する。これを型に流し込みんで
スティック状に急冷し、得られた固形物を容器に固定
し、フレーミングを行ない製品とする。Ingredient A Blending amount (%) Titanium oxide coated kaolin (Coating amount 20%) 5.0 Mica powder 5.0 Red 202 No. 0.5 Red No. 204 0.5 Component B blending amount (%) Candelilla wax 7.0 Solid paraffin 7.0 Beeswax 5.0 Carnauba wax 5.0 Castor oil 44.8 Isopropyl myristate 10.0 Component C blending amount (%) Fragrance 0.2 Component A and a part of castor oil are uniformly kneaded in a mortar to form a pigment part. The rest of the component B is melted by heating, the above-mentioned pigment part is added thereto, and the mixture is uniformly dispersed with a homomixer, and further the component C is added and dispersed. This is poured into a mold and rapidly cooled in a stick shape, and the obtained solid matter is fixed to a container and framing is performed to obtain a product.
該リップスティック製造において、酸化チタンは均一に
分散し、また、使用に際して、唇に均一な塗布を行うこ
とができ、仕上がりが非常に良好であった。In the production of the lipstick, titanium oxide was uniformly dispersed, and when used, the lips could be uniformly applied, and the finish was very good.
実施例５ つぎの組成により、乳液を製造した。Example 5 An emulsion was prepared with the following composition.
成分Ａ 配合量（％） ステアリン酸 3.0 セチルアルコール 1.5 ワセリン 5.0 流動パラフィン 12.0 パラオキシエチレンモノオレイン酸 エステル（１０ＥＯ） 2.5 成分Ｂ 配合量（％） ポリエチレレングリコール １５００ 2.0 トリエタノールアミン 1.0 精製水 71.5 酸化チタン被覆カオリン （被覆量５０％） 1.0 成分Ｃ 配合量（％） 香料 0.5 成分Ｂを加熱し、７０℃にて均一に分散する。別個に成
分Ａを７０℃にて加熱、溶解し、前記成分Ｂに加え、ホ
モミキサーを用いて均一に乳化する。乳化後、さらに撹
拌しながら３０℃まで冷却し製品とする。Ingredient A Amount (%) Stearic acid 3.0 Cetyl alcohol 1.5 Vaseline 5.0 Liquid paraffin 12.0 Paraoxyethylene monooleate (10EO) 2.5 Ingredient B amount (%) Polyethylene glycol 1500 2.0 Triethanolamine 1.0 Purified water 71.5 Titanium oxide coating Kaolin (Coating amount 50%) 1.0 Component C Blending amount (%) Fragrance 0.5 Component B is heated and uniformly dispersed at 70 ° C. Separately, the component A is heated and dissolved at 70 ° C., added to the component B, and homogenized using a homomixer. After emulsification, the product is cooled to 30 ° C. with further stirring.
該乳液製造において、酸化チタンは均一に分散して貯蔵
中も凝集を起こさず、また、使用に際して、皮膚に均一
な塗布を行うことができ、仕上がりが非常に良好であっ
た。In the production of the emulsion, titanium oxide was uniformly dispersed and did not agglomerate during storage, and when used, it was possible to apply it uniformly to the skin, and the finish was very good.
実施例６ つぎの組成によりクリームを製造した。Example 6 A cream was produced with the following composition.
成分Ａ 配合量（％） 固形パラフィン 5.0 ミツロウ 4.0 マイクロクリスタリンワックス 4.0 ワセリン 7.0 スクワラン 30.0 ポリオキシエチレンモノ ラウリン酸ソルビタン(20EO) 1.0 セスキオレイン酸ソルビタン 4.0 成分Ｂ 配合量（％） 精製水 20.0 成分Ｃ 配合量（％） 酸化チタン被覆カオリン （被覆量５％） 20.0 タルク 5.0 上記成分Ｃを均一に混合し、成分Ｂに加え、７０℃にて
よく分散する。別に、成分Ａを７０℃で加熱、溶解し、
これに前記混合物を加え、ホモミキサーで均一に乳化す
る。乳化後、３０℃まで冷却し製品とする。Ingredient A Ingredient (%) Solid paraffin 5.0 Beeswax 4.0 Microcrystalline wax 4.0 Vaseline 7.0 Squalane 30.0 Polyoxyethylene mono sorbitan laurate (20EO) 1.0 Sorbitan sesquioleate 4.0 Ingredient B (%) Purified water 20.0 Ingredient C Ingredient (%) Titanium oxide-coated kaolin (coating amount 5%) 20.0 Talc 5.0 The above component C is uniformly mixed, added to the component B, and dispersed well at 70 ° C. Separately, the component A is heated and melted at 70 ° C.,
The above mixture is added to this, and the mixture is uniformly emulsified with a homomixer. After the emulsification, the product is cooled to 30 ° C.
該クリーム製造において、酸化チタンは均一に分散して
貯蔵中も凝集を起こさず、また、使用に際して、皮膚に
均一な塗布を行うことができ、仕上がりが非常に良好で
あった。In the production of the cream, titanium oxide was uniformly dispersed and did not agglomerate during storage, and it was possible to apply it uniformly to the skin during use, and the finish was very good.
Claims (2)
を配合したことを特徴とする化粧料組成物。1. A cosmetic composition comprising kaolin particles coated with titanium oxide.
に対する酸化チタンの被覆量が、１〜５０重量％である
前記第１項の化粧料組成物。2. The cosmetic composition according to claim 1, wherein the coating amount of titanium oxide is 1 to 50% by weight based on the whole kaolin coated with titanium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3700785A JPH0655663B2 (en) | 1985-02-25 | 1985-02-25 | Cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3700785A JPH0655663B2 (en) | 1985-02-25 | 1985-02-25 | Cosmetic composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61197511A JPS61197511A (en) | 1986-09-01 |
| JPH0655663B2 true JPH0655663B2 (en) | 1994-07-27 |
Family
ID=12485635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3700785A Expired - Fee Related JPH0655663B2 (en) | 1985-02-25 | 1985-02-25 | Cosmetic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0655663B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU87030A1 (en) * | 1987-10-28 | 1989-05-08 | Oreal | USE IN COSMETICS OF NEW SUBSTANCES AS INFRARED RADIATION REFLECTORS, COSMETIC COMPOSITIONS CONTAINING THEM AND THEIR USE FOR THE PROTECTION OF THE HUMAN SKIN AGAINST INFRARED RADIATION |
| JP6352242B2 (en) * | 2013-03-14 | 2018-07-04 | 水澤化学工業株式会社 | White pigment for paint |
-
1985
- 1985-02-25 JP JP3700785A patent/JPH0655663B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61197511A (en) | 1986-09-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |