JPH0672015A - Ink jet recording mat film - Google Patents
Ink jet recording mat filmInfo
- Publication number
- JPH0672015A JPH0672015A JP4218592A JP21859292A JPH0672015A JP H0672015 A JPH0672015 A JP H0672015A JP 4218592 A JP4218592 A JP 4218592A JP 21859292 A JP21859292 A JP 21859292A JP H0672015 A JPH0672015 A JP H0672015A
- Authority
- JP
- Japan
- Prior art keywords
- film
- ink
- ink jet
- jet recording
- water resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 230000003746 surface roughness Effects 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 25
- 239000011248 coating agent Substances 0.000 abstract description 24
- 239000007787 solid Substances 0.000 abstract description 17
- 239000000463 material Substances 0.000 abstract description 16
- 239000011347 resin Substances 0.000 abstract description 14
- 229920005989 resin Polymers 0.000 abstract description 14
- 239000006224 matting agent Substances 0.000 abstract description 12
- 230000001788 irregular Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 58
- 238000012937 correction Methods 0.000 description 27
- 238000000034 method Methods 0.000 description 23
- 239000010410 layer Substances 0.000 description 20
- 238000001035 drying Methods 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 15
- 230000000740 bleeding effect Effects 0.000 description 14
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 12
- -1 acrylic cation Chemical class 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229940015043 glyoxal Drugs 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 238000013461 design Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000012463 white pigment Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 235000008753 Papaver somniferum Nutrition 0.000 description 1
- 240000001090 Papaver somniferum Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、インクジェットプリン
ター、プロッターに使用される記録材料に関し、特にＣ
ＡＤ用第二原図フィルムとして適性の優れた記録シート
を提供するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a recording material used for ink jet printers and plotters, and particularly C
A recording sheet excellent in suitability as a second original drawing film for AD is provided.
【０００２】[0002]
【従来の技術】設計製図分野においては、従来の手書き
による図面の作成方法からコンピューターを使用したＣ
ＡＤシステムが普及して来た。これに伴い電子計算機の
周辺機器として、プロッター（プリンタープロッター）
の使用が増大している。プロッターを記録方式で分類す
ると、ペンプロッター、静電プロッター、感熱プロッタ
ー、インクジェットプロッターに大別できる。インクジ
ェット記録方式は基本的には普通紙に記録できること、
および無騒音、現像、定着プロセスを必要とせず、かつ
容易にフルカラー記録が行なえることから、低価格化と
相まってワープロ、プリンター、複写機、プロッターな
どに近年急速に普及している。2. Description of the Related Art In the field of design and drafting, the conventional method for creating a drawing by hand is used to
AD systems have become popular. Along with this, a plotter (printer plotter) as a peripheral device of the electronic computer
The use of is increasing. When plotters are classified by recording method, they can be roughly classified into pen plotters, electrostatic plotters, thermal plotters, and inkjet plotters. Inkjet recording system basically can record on plain paper,
In addition, since it is easy to perform full-color recording without noise, development, and fixing processes, it has been rapidly popularized in word processors, printers, copying machines, plotters, etc. in recent years in combination with cost reduction.
【０００３】ところでインクジェット記録材料に要求さ
れる基本的性能は、 ａ．画像濃度が高く、ドット形状が円形でかつ滲みやム
ラがなく、ドット周辺がシャープで解像度が高いこと。 ｂ．インクの吸収速度が速く乾燥性に優れ、かつインク
が重なった時、インク同士が混ざらない等のカラー記録
性が良いこと。 ｃ．記録後の寸法変化が少なく、カール、波打ち、変形
が無いこと。 などが挙げられ、インクの乾燥性を支配する吸収性とド
ットの拡がり（滲み）という相反する性質を両立させる
ことが技術的課題である。By the way, the basic performance required for an ink jet recording material is as follows. High image density, circular dot shape, no blurring or unevenness, sharp dot periphery, and high resolution. b. The ink absorption speed is fast, the drying property is excellent, and the color recording properties are good such that the inks do not mix when they overlap. c. There is little dimensional change after recording and there is no curling, waviness, or deformation. And the like, and it is a technical subject to make the absorptivity that governs the drying property of the ink and the contradictory properties of spread (bleeding) of dots compatible.
【０００４】インクジェット記録紙には、基本的に上質
紙などの普通紙を使用できるが、カラー記録または設計
用の高画質な図面用途には普通紙では不十分であり、シ
ート表面にコート層を設け、顔料、バインダーなどを最
適化したコート紙タイプのインクジェット記録紙が適し
ている。Plain paper such as high-quality paper can be basically used as the ink jet recording paper, but plain paper is not sufficient for high-quality drawing use for color recording or design, and a coat layer is formed on the sheet surface. Inkjet recording paper of the coated paper type, which is provided with optimized pigments and binders, is suitable.
【０００５】従来これら問題点を解決する技術手段とし
て、特開昭５５−５８３０号公報に「支持体およびその
表面に設けられたインク吸収層から成り、不透明度が5
5.0乃至97.5％、インク吸収層の吸収性が 1.5乃至18.0
ミリメートル／分である事を特徴とするインクジェット
記録用シート」が、そしてインク吸収層を形成する顔料
として「白色顔料としては、例えば、クレー、タルク、
けいそう土、炭酸カルシウム、硫酸カルシウム、硫酸バ
リウム、酸化チタン、酸化亜鉛、硫化亜鉛、サチンホワ
イト、けい酸アルミニウム、リトポン等が、単独あるい
は２種以上の混合物として使用され」と記載されてい
る。As a conventional technical means for solving these problems, Japanese Patent Laid-Open No. 55830/1985 discloses that "a support and an ink absorption layer provided on the surface of the support have an opacity of 5".
5.0 to 97.5%, the absorption of the ink absorption layer is 1.5 to 18.0
An ink jet recording sheet characterized by having a diameter of mm / min. ”And a pigment forming an ink absorbing layer“ a white pigment includes, for example, clay, talc,
Diatomaceous earth, calcium carbonate, calcium sulfate, barium sulfate, titanium oxide, zinc oxide, zinc sulfide, satin white, aluminum silicate, lithopone, etc. are used alone or as a mixture of two or more kinds ".
【０００６】しかしながら、これら白色顔料を多孔性イ
ンク吸収層に用いているために層自体が不透明であり、
得られるインクジェット記録用シートは不透明度が55.0
乃至97.5％であり、本願発明の目的である第二原図フィ
ルム用に必要な透明度が70％以上のインクジェット記録
用マットフィルムは得られない。However, since these white pigments are used in the porous ink absorbing layer, the layer itself is opaque,
The resulting inkjet recording sheet has an opacity of 55.0.
It is 9 to 97.5%, and a matte film for inkjet recording having a transparency of 70% or more, which is the object of the present invention for the second original drawing film, cannot be obtained.
【０００７】一方ＯＨＰフィルム等高透明用記録材料と
して、特開昭６０−１３２７８５号公報、特開昭６０−
１４５８７９号公報に、ポリビニルピロリドン等水溶性
樹脂の膨潤による吸水性を利用する事が、特開昭６０−
１４３９９１号公報では、第４級アンモニウム塩基を持
つアクリルカチオン樹脂のカチオン基が、水性インク
（直接染料または酸性染料）中のアニオン基とイオン結
合し、染料の不溶性を利用することが開示されている。
しかしながらこれら透明なインクジェット記録シート
も、ＣＡＤ用第２原図マットフィルムとしては、下記の
理由で満足できる品質ではない。On the other hand, as a recording material for high transparency such as an OHP film, JP-A-60-132785 and JP-A-60-
Japanese Patent Application Laid-Open No. 60-1985 discloses the use of water absorption due to swelling of a water-soluble resin such as polyvinylpyrrolidone.
JP-A-143991 discloses that the cation group of an acrylic cation resin having a quaternary ammonium salt group is ionically bonded to an anion group in an aqueous ink (direct dye or acid dye) to utilize the insolubility of the dye. .
However, even these transparent inkjet recording sheets are not of satisfactory quality as the second original drawing mat film for CAD for the following reasons.
【０００８】ＣＡＤ用第２原図材料としては、ジアゾコ
ピー用の第２原図である場合や、あるいは内容をチェッ
クする必要のある設計図面やプログラムリストである場
合は、記録シートは透明でなければならないが、その他
下記の品質特性を満足させる事が最も重要である。 １．鉛筆による筆記性および再筆記性。 ２．ケシゴム等による消去性。 ３．塗膜の削刀性。 ４．引張り、引裂き等機械的強度。 ５．耐水性、耐熱性、耐光性等の長期保存性。As the CAD second original material, the recording sheet must be transparent if it is a diazo second original, or if it is a design drawing or program list whose contents need to be checked. However, it is most important to satisfy the following quality characteristics. 1. Pencil writing and rewriting. 2. Erasability with poppy rubber etc. 3. The sharpness of the coating film. 4. Mechanical strength such as pulling and tearing. 5. Long-term storage properties such as water resistance, heat resistance, and light resistance.
【０００９】特に、耐水性、透明性、強度が要求される
用途には、ポリエステルフィルムを支持体とした材料が
使用されており、インクジェット記録適性、ＣＡＤ用第
２原図適性を兼ね備えたインクジェット記録用マットフ
ィルムが切望されている。本願は、これら問題点の両立
が技術的課題である。In particular, for applications in which water resistance, transparency and strength are required, a material having a polyester film as a support is used. For inkjet recording having both inkjet recording suitability and CAD second original drawing suitability. A matte film is coveted. In the present application, it is a technical problem to satisfy both of these problems.
【００１０】本発明者等は、ポリエチレンテレフタレー
トフィルムにマット化剤を含む従来型のインクジェット
用塗工液を塗布する事を試みたが、耐水性を付与させる
と、インクのヨリが発生しベタ画像部が均一なインクジ
ェット記録材料で、かつ高透明な第２原図用紙を得る事
は出来なかった。The present inventors have attempted to apply a conventional ink jet coating liquid containing a matting agent to a polyethylene terephthalate film, but when water resistance is imparted, the ink is twisted and a solid image is produced. It was not possible to obtain a highly transparent second original drawing sheet with an inkjet recording material having a uniform part.
【００１１】[0011]
【発明が解決しようとする課題】本発明は、記録時のイ
ンク乾燥性が速くインクのヨリが無くベタ画像部が均一
なインクジェット記録材料であり、更に第２原図用紙と
して高透明で耐水性に優れたインクジェット記録用マッ
トフィルムを提供する事を目的とするものである。DISCLOSURE OF THE INVENTION The present invention is an ink jet recording material which has a fast ink drying property at the time of recording and is free from ink twisting and has a uniform solid image portion. Further, it is highly transparent and water resistant as a second original sheet. It is intended to provide an excellent matte film for inkjet recording.
【００１２】[0012]
【課題を解決するための手段】本発明者等は、このよう
な問題点を解決するため鋭意研究に励んだ結果、ポリエ
チレンテレフタレート等のプラスチックフィルムシート
を支持体として用いて、シリカ等のマット化剤を含み、
グリオキザール等で耐水化処理された親水性樹脂を主成
分とした塗布層の三次元表面粗さＳＲａを、 1.0〜2.0
μｍの範囲とする事により、記録時のインク乾燥性が速
くベタ画像部が均一で高透明で耐水性に優れたインクジ
ェット記録用マットフィルムを完成せしめるに至った。Means for Solving the Problems The inventors of the present invention have earnestly studied to solve the above problems, and as a result, a plastic film sheet such as polyethylene terephthalate is used as a support to form a matte material such as silica. Including agents
The three-dimensional surface roughness SRa of the coating layer containing a hydrophilic resin as a main component, which is water-resistant with glyoxal, is 1.0 to 2.0.
By setting the thickness in the range of μm, an ink jet recording matte film having fast ink drying property at the time of recording, uniform solid image portion, high transparency and excellent water resistance has been completed.
【００１３】[0013]
【作用】本発明に使用する支持体には、ポリエステル、
ポリエチレン、ポリプロピレン、トリアセテート、ポリ
カーボネート等透明なフィルムであればいかなるプラス
チックシートも使用できるが、好ましくは２軸に延伸処
理されたポリエチレンテレフタレートフィルムが最も適
している。ポリエチレンテレフタレートフィルムに、親
水性樹脂を主体としたインク受理層が直接接着しないと
きは、アンカーコート層を前もって塗布しても構わない
し、あるいはフィルム製膜中にアンカーコート処理され
た易接着フィルムを使用することもできる。フィルムシ
ートの少なくとも片面に、インク受理層を設ける。イン
ク受理層は、親水性樹脂とマット化剤を主成分とした層
である。The support used in the present invention includes polyester,
Although any plastic sheet can be used as long as it is a transparent film such as polyethylene, polypropylene, triacetate, or polycarbonate, a biaxially stretched polyethylene terephthalate film is most suitable. When the ink receiving layer composed mainly of a hydrophilic resin does not adhere directly to the polyethylene terephthalate film, the anchor coat layer may be applied in advance, or an anchor-coated easy-adhesion film is used during film formation. You can also do it. An ink receiving layer is provided on at least one side of the film sheet. The ink receiving layer is a layer containing a hydrophilic resin and a matting agent as main components.
【００１４】本発明で用いられる親水性樹脂は、例えば
水溶性樹脂として酸化でんぷん、エーテル化でんぷん、
ゼラチン、カゼイン、メチルセルロース、カルボキシメ
チルセルロース、ヒドロキシメチルセルロース、エチレ
ン無水マレイン酸共重合物、ポリビニルアルコール等が
挙げられる。また水分散型樹脂としては、ＳＢＲラテッ
クス、アクリルエマルジョン、塩化ビニルエマルジョ
ン、酢酸ビニルエマルジョン等が使用できる。The hydrophilic resin used in the present invention is, for example, water-soluble resin such as oxidized starch, etherified starch,
Examples thereof include gelatin, casein, methyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose, ethylene-maleic anhydride copolymer, polyvinyl alcohol and the like. As the water-dispersible resin, SBR latex, acrylic emulsion, vinyl chloride emulsion, vinyl acetate emulsion or the like can be used.
【００１５】本発明ではインク受理層の耐水性が必要な
ため、樹脂単独で耐水性を有している場合は必要ない
が、そうでない時はグリオキザール等の耐水化剤を使用
して耐水性を付与させる。しかしこれらの樹脂単独で
は、インク乾燥性、インク滲み等インクジェット記録の
基本的問題点が解決できないので、ポリビニルピロリド
ン、カチオン性樹脂等公知の材料を添加配合し、これら
の問題点の解決が図られている。In the present invention, the water resistance of the ink receiving layer is required, so it is not necessary if the resin alone has water resistance. If not, a water repellent such as glyoxal is used for water resistance. Give it. However, since these resins alone cannot solve the basic problems of ink jet recording such as ink dryness and ink bleeding, polyvinyl pyrrolidone, a known material such as a cationic resin are added and blended to solve these problems. ing.
【００１６】更に本発明では、筆記適性等の第２原図適
性を持たせるために、マット化剤を配合する。一般にイ
ンクジェット塗工液には白色顔料が使用されるが、筆記
性改良に効果はあるものの、透明度70％以上のマットフ
ィルムは得られない。本願では、プラスチックピグメン
ト、シリカ等のマット化剤を主として使用する。添加部
数は10％〜50％の範囲で配合する事ができる。10％以下
では、筆記画線の鮮明性、濃度が不十分であり、一方50
％を越えると、70％以上の透明度は得られない。Further, in the present invention, a matting agent is blended in order to have the suitability for the second original drawing such as the suitability for writing. In general, a white pigment is used in the inkjet coating liquid, but it is effective in improving the writability, but a matte film having a transparency of 70% or more cannot be obtained. In the present application, matting agents such as plastic pigments and silica are mainly used. The number of parts to be added can be mixed in the range of 10% to 50%. If it is less than 10%, the sharpness and density of the writing stroke are insufficient, while 50
When it exceeds%, the transparency of 70% or more cannot be obtained.
【００１７】ところで、親水性樹脂を主成分とした耐水
性を有するインク受理層に、インクジェット記録を行う
とインクの拡がりが不十分でヨリが発生し、ベタ部の画
像品質が著しく低下する。これは耐水性を付与したイン
ク受理層の濡れ性が悪いために発生する現象であり、三
次元表面粗さ計で測定したＳＲａを 1.0〜2.0 μｍの範
囲とする必要がある。By the way, when ink-jet recording is carried out on a water-resistant ink-receiving layer containing a hydrophilic resin as a main component, the spread of the ink is insufficient and the ink is liable to be twisted, so that the image quality of a solid portion is remarkably deteriorated. This is a phenomenon that occurs due to poor wettability of the ink receiving layer to which water resistance is imparted, and SRa measured by a three-dimensional surface roughness meter needs to be in the range of 1.0 to 2.0 μm.
【００１８】ＳＲａが 1.0μｍ未満ではインクのヨリが
発生し、本願の問題点を解決する事ができず、一方 2.0
μｍを越えるとインク受理層表面が粗すぎて、鉛筆等で
筆記したときの画線のシャープ性、濃度が不十分とな
る。ＳＲａの数値を 1.0〜2.0μｍの範囲とするために
は、マット化剤の平均粒径および分散の程度により調整
する。If SRa is less than 1.0 μm, the ink may be twisted, and the problems of the present invention cannot be solved.
If it exceeds μm, the surface of the ink receiving layer is too rough, and the sharpness of image lines and the density when writing with a pencil are insufficient. In order to set the numerical value of SRa within the range of 1.0 to 2.0 μm, it is adjusted by the average particle size of the matting agent and the degree of dispersion.
【００１９】インク受理層は、グラビアコート、バーコ
ート、ロールコート等公知の塗工方式により厚さ１〜20
μｍ、好ましくは３〜１０μｍの範囲に塗布される。塗
布量は、透明度70％以上となる様に、更に配合するマッ
ト化剤の平均粒径から三次元表面粗さが本発明の範囲と
なる様に決定される。The ink receiving layer has a thickness of 1 to 20 by a known coating method such as gravure coating, bar coating and roll coating.
[mu] m, preferably 3 to 10 [mu] m. The coating amount is determined so that the transparency becomes 70% or more, and the three-dimensional surface roughness falls within the range of the present invention from the average particle size of the matting agent further added.
【００２０】[0020]
【実施例】以下実施例により、本発明を更に詳細に説明
する。The present invention will be described in more detail with reference to the following examples.
【００２１】（実施例１）塗工基材として、厚さ 100μ
ｍのポリエステルフィルム（東レ（株）製Ｑ８０Ｄ）を
使用した。インク受理層用塗工液は、ポリビニルアルコ
ールＰＶＡ４２０（クラレ（株）製）10％溶液 100部
に、ポリビニルピロリドンＫ−３０（ＧＡＦ社製）20％
溶液を10部、グリオキザールを２部添加した。更にマッ
ト化剤として、シリカ顔料サイロイド６３（富士デヴィ
ゾン社製）20％水分散液をホモミキサーにて１時間分散
し、塗工液に30部配合し、水20部、メタノール30部を加
え、10分間攪拌した。Example 1 As a coating base material, a thickness of 100 μm
m polyester film (Q80D manufactured by Toray Industries, Inc.) was used. The coating liquid for the ink receiving layer is polyvinyl alcohol PVA420 (Kuraray Co., Ltd.) 10% solution 100 parts, polyvinylpyrrolidone K-30 (GAF) 20%
10 parts of the solution and 2 parts of glyoxal were added. Furthermore, as a matting agent, 20% aqueous dispersion of silica pigment Syloid 63 (manufactured by Fuji Devison Co., Ltd.) was dispersed by a homomixer for 1 hour, 30 parts of the coating solution was mixed, and 20 parts of water and 30 parts of methanol were added, Stir for 10 minutes.
【００２２】塗工液をロールコートで塗布し、乾燥器に
て 110℃２分乾燥した。得られたインクジェット用マッ
トフィルムは、塗布厚 7.0μｍ、透明度76.5％、ＳＲａ
値1.5 μｍであった。なお表面粗さＳＲａ値は、三次元
表面粗さ計（Ｋ．Ｋ小坂研究所製、ＳＥ−３０ＡＫ）で
測定した中心面平均粗さＳＲａで表示した。The coating solution was applied by roll coating and dried in a dryer at 110 ° C. for 2 minutes. The obtained matte film for inkjet has a coating thickness of 7.0 μm, transparency of 76.5%, SRa
The value was 1.5 μm. The surface roughness SRa value is indicated by the center surface average roughness SRa measured by a three-dimensional surface roughness meter (KK Kosaka Laboratory, SE-30AK).
【００２３】マットフィルムを、インクジェットプロッ
ターDesignJet C1633B（ＨＰ製）で記録したところ、イ
ンク乾燥時間は１分以内と早く、滲み・ヨリの無いベタ
部均一性に優れた記録フィルムであり、かつ塗膜は耐水
性を有しており、画線濃度が高くシャープであり鉛筆筆
記性も良好であった。When the matte film was recorded by an inkjet plotter DesignJet C1633B (manufactured by HP), the ink drying time was as short as 1 minute or less, and it was a recording film excellent in the uniformity of the solid part without bleeding or twisting, and the coating film. Had water resistance, had a high image density, was sharp, and had good pencil writability.
【００２４】（実施例２）75μｍのポリエステルフィル
ム（帝人（株）製ルミラーＨＳ７５）に、アンカー剤と
して水分散型ポリエステル樹脂バイロナールＭＤ１４０
０（東洋紡（株）製）を 0.5ｇ/m2 塗布して基材とし
た。塗工液として、ポリビニルアルコールＫＨ−１７
（日本合成（株）製）10％溶液 100部に、カチオン性ア
クリル樹脂ＳＴ−１０００（三菱油化（株）製）を20
部、グリオキザールを５部添加し、更に、マット化剤と
して、プラスチック顔料エポスターＭ３０（日本触媒
（株）製）20％液に、ノニオン性界面活性剤ノニオンＮ
Ｓ２１０（日本油脂（株）製）を対顔料１％添加後ホモ
ミキサーにて１時間分散後塗工液に30部配合し、更に水
30部、メタノール30部を加え、10分間攪拌した。Example 2 A water-dispersible polyester resin Vylonal MD140 was used as an anchoring agent on a 75 μm polyester film (Lumirror HS75 manufactured by Teijin Ltd.).
0 (manufactured by Toyobo Co., Ltd.) was applied at 0.5 g / m 2 to obtain a base material. As a coating liquid, polyvinyl alcohol KH-17
20 parts of cationic acrylic resin ST-1000 (manufactured by Mitsubishi Petrochemical Co., Ltd.) in 100 parts of 10% solution (manufactured by Nippon Gosei Co., Ltd.)
Parts, and 5 parts of glyoxal, and as a matting agent, a 20% liquid of a plastic pigment Eposter M30 (manufactured by Nippon Shokubai Co., Ltd.) and a nonionic surfactant Nonion N
After adding 1% of S210 (Nippon Oil & Fats Co., Ltd.) to the pigment, dispersing it for 1 hour with a homomixer and blending 30 parts with the coating liquid, and further adding water.
30 parts and 30 parts of methanol were added and stirred for 10 minutes.
【００２５】この液をバーコートで塗布し、乾燥器にて
110℃２分乾燥した。得られたインクジェット用マット
フィルムは、塗布厚 4.0μｍ、透明度81.6％、ＳＲａ値
1.4μｍであった。This liquid is applied by bar coating and dried in a dryer.
It was dried at 110 ° C. for 2 minutes. The obtained inkjet matte film has a coating thickness of 4.0 μm, transparency of 81.6%, and SRa value.
It was 1.4 μm.
【００２６】このインクジェット用マットフィルムを、
インクジェットプリンターＢＪ１０Ｖ（キャノン（株）
製）で記録したところ、インク乾燥時間は１分以内と早
く、滲み・ヨリが無くベタ部の均一性に優れた記録フィ
ルムであり、かつ塗膜は耐水性を有しており、画線濃度
が高くシャープであり鉛筆筆記性も良好であった。This ink jet matte film is
Inkjet printer BJ10V (Canon Inc.)
Recording), the ink drying time was as short as 1 minute or less, there was no bleeding or twisting, and the uniformity of solid areas was excellent, and the coating film had water resistance, and the image density was high. It was sharp and sharp, and the pencil writability was also good.
【００２７】（比較例１）実施例１のポリビニルアルコ
ールをＰＶＡ １０５（クラレ（株）製造）に変更し、
グリオキザールを未添加の他は、同一条件にてサンプル
を作製した。このインクジェット用マットフィルムを、
実施例１と同様に評価したところ、インク乾燥時間は１
分以内と早く、滲み・ヨリが無くベタ部の均一性には優
れた記録フィルムであったが、塗膜の耐水性は有してお
らず、第２原図フィルムとしては不適であった。(Comparative Example 1) The polyvinyl alcohol of Example 1 was changed to PVA 105 (produced by Kuraray Co., Ltd.),
Samples were prepared under the same conditions except that glyoxal was not added. This inkjet mat film
When evaluated in the same manner as in Example 1, the ink drying time was 1
The recording film was as fast as within a minute and free from bleeding and twisting and was excellent in the uniformity of the solid portion, but the coating film did not have water resistance and was unsuitable as the second original film.
【００２８】（比較例２）実施例１のシリカをサイロイ
ド１５０に変更した他は同一条件にてサンプルを製造し
た。得られたインクジェット用マットフィルムは、透明
度54.8％と透明性は低く、ＳＲａ値は 0.6μｍであっ
た。このインクジェット用マットフィルムを、実施例１
と同様に評価したところ、インク乾燥時間は１分以内と
早く、滲みは良好であるが、ヨリが発生し、特にベタ部
の均一性に劣っていた。Comparative Example 2 A sample was manufactured under the same conditions except that the silica of Example 1 was changed to Syloid 150. The obtained matte film for inkjet has a low transparency of 54.8% and an SRa value of 0.6 μm. This inkjet matte film was used in Example 1.
When the same evaluation as described above was carried out, the ink drying time was as short as 1 minute or less, and the bleeding was good, but twisting occurred, and especially the uniformity of the solid portion was poor.
【００２９】（比較例３）実施例１のシリカをサイロイ
ド６２０に変更した他は同一条件にてサンプルを製造し
た。得られたインクジェット用マットフィルムは、透明
度85.3％、ＳＲａ値は 2.5μｍであった。このインクジ
ェット用マットフィルムを、実施例１と同様に評価した
ところ、インク乾燥時間は１分以内と早く、滲み・ヨリ
の発生が無く、ベタ部の均一性も良好な記録フィルムで
あったが、画線濃度が低く、シャープ性に書け鉛筆筆記
適性は有していなかった。Comparative Example 3 A sample was manufactured under the same conditions except that the silica of Example 1 was changed to Syloid 620. The obtained inkjet matte film had a transparency of 85.3% and an SRa value of 2.5 μm. When this inkjet matte film was evaluated in the same manner as in Example 1, the ink drying time was as short as 1 minute or less, no bleeding or twisting occurred, and the solidity of the recording film was good, but The image density was low, and the sharpness was not writable and the pencil writing suitability was not obtained.
【００３０】[0030]
【発明の効果】以上の様に、本発明では、インクの乾燥
性が早く、かつ滲み、ヨリの無い被記録材であり、透明
度70％以上で耐水性が有り、鉛筆筆記性の良好な第２原
図適性をも兼ね備えたインクジェット記録用マットフィ
ルムが得られる。As described above, according to the present invention, a recording material having fast ink drying property and free from bleeding and twisting, having a transparency of 70% or more, having water resistance, and having good pencil writing property. (2) A matte film for inkjet recording having both original drawing suitability can be obtained.
─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成４年９月２５日[Submission date] September 25, 1992
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１０[Correction target item name] 0010
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１０】本発明者等は、ポリエチレンテレフタレー
トフィルムにマット化剤を含む従来型のインクジェット
用塗工液を塗布する事を試みたが、耐水性を付与させる
と、インクのビーディングが発生しベタ画像部が均一な
インクジェット記録材料で、かつ高透明な第２原図用紙
を得る事は出来なかった。The present inventors have tried to coat a polyethylene terephthalate film with a conventional ink jet coating liquid containing a matting agent. However, when water resistance is imparted, beading of the ink occurs and a solid image is produced. It was not possible to obtain a highly transparent second original drawing sheet with an inkjet recording material having a uniform image portion.
【手続補正２】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１１[Correction target item name] 0011
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１１】[0011]
【発明が解決しようとする課題】本発明は、記録時のイ
ンク乾燥性が速くインクのビーディングが無くベタ画像
部が均一なインクジェット記録材料であり、更に第２原
図用紙として高透明で耐水性に優れたインクジェット記
録用マットフィルムを提供する事を目的とするものであ
る。DISCLOSURE OF THE INVENTION The present invention is an ink jet recording material which has a fast ink drying property at the time of recording and has no beading of ink and a uniform solid image portion. Further, it is highly transparent and water resistant as a second original paper. It is an object of the present invention to provide an excellent inkjet recording matte film.
【手続補正３】[Procedure 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１７[Correction target item name] 0017
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１７】ところで、親水性樹脂を主成分とした耐水
性を有するインク受理層に、インクジェット記録を行う
とインクの拡がりが不十分でビーディングが発生し、ベ
タ部の画像品質が著しく低下する。これは耐水性を付与
したインク受理層の濡れ性が悪いために発生する現象で
あり、三次元表面粗さ計で測定したＳＲａを１．０〜
２．０μｍの範囲とする必要がある。By the way, when ink-jet recording is carried out on a water-resistant ink-receiving layer containing a hydrophilic resin as a main component, ink spreading is insufficient and beading occurs, resulting in a marked deterioration in image quality of solid areas. This is a phenomenon that occurs because the wettability of the ink receiving layer to which water resistance is imparted is poor, and SRa measured by a three-dimensional surface roughness meter is 1.0 to
It must be in the range of 2.0 μm.
【手続補正４】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１８[Correction target item name] 0018
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１８】ＳＲａが１．０μｍ未満ではインクのビー
ディングが発生し、本願の問題点を解決する事ができ
ず、一方２．０μｍを越えるとインク受理層表面が粗す
ぎて、鉛筆等で筆記したときの画線のシャープ性、濃度
が不十分となる。ＳＲａの数値を１．０〜２．０μｍの
範囲とするためには、マット化剤の平均粒径および分散
の程度により調整する。When SRa is less than 1.0 μm, ink beading occurs and the problems of the present invention cannot be solved. On the other hand, when SRa exceeds 2.0 μm, the surface of the ink receiving layer is too rough, and writing with a pencil or the like is necessary. When this is done, the sharpness of the image lines and the density become insufficient. In order to set the numerical value of SRa within the range of 1.0 to 2.0 μm, it is adjusted by the average particle size of the matting agent and the degree of dispersion.
【手続補正５】[Procedure Amendment 5]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２３[Name of item to be corrected] 0023
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２３】マットフィルムを、インクジェットプロッ
ターＤｅｓｉｇｎＪｅｔ Ｃ１６３３Ｂ（ＨＰ製）で記
録したところ、インク乾燥時間は１分以内と早く、滲み
・ビーディングの無いベタ部均一性に優れた記録フィル
ムであり、かつ塗膜は耐水性を有しており、画線濃度が
高くシャープであり鉛筆筆記性も良好であった。When the matte film was recorded with an ink jet plotter DesignJet C1633B (manufactured by HP), the ink drying time was as short as 1 minute or less, and it was a recording film excellent in the uniformity of solid areas without bleeding or beading and being coated. The film was water resistant, had a high image density, was sharp, and had good pencil writing properties.
【手続補正６】[Procedure correction 6]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２６[Correction target item name] 0026
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２６】このインクジェット用マットフィルムをイ
ンクジェットプリンターＢＪ１０Ｖ（キャノン（株）
製）で記録したところ、インク乾燥時間は１分以内と早
く、滲み・ビーディングが無くベタ部の均一性に優れた
記録フィルムであり、かつ塗膜は耐水性を有しており、
画線濃度が高くシャープであり鉛筆筆記性も良好であっ
た。This ink jet matte film is used as an ink jet printer BJ10V (Canon Co., Ltd.).
Recording), the ink drying time was as short as 1 minute or less, there was no bleeding or beading, and the solid part was excellent in uniformity, and the coating film had water resistance.
The image density was high and sharp, and the pencil writability was also good.
【手続補正７】[Procedure Amendment 7]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２７[Name of item to be corrected] 0027
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２７】（比較例１）実施例１のポリビニルアルコ
ールをＰＶＡ １０５（クラレ（株）製造）に変更し、
グリオキザールを未添加の他は、同一条件にてサンプル
を作製した。このインクジェット用マットフィルムを、
実施例１と同様に評価したところ、インク乾燥時間は１
分以内と早く、滲み・ビーディングが無くベタ部の均一
性には優れた記録フィルムであったが、塗膜の耐水性は
有しておらず、第２原図フィルムとしては不適であっ
た。(Comparative Example 1) The polyvinyl alcohol of Example 1 was changed to PVA 105 (produced by Kuraray Co., Ltd.),
Samples were prepared under the same conditions except that glyoxal was not added. This inkjet mat film
When evaluated in the same manner as in Example 1, the ink drying time was 1
The recording film was as fast as within a minute, had no bleeding / beading, and was excellent in the uniformity of solid areas, but the coating film did not have water resistance and was unsuitable as the second original film.
【手続補正８】[Procedure Amendment 8]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２８[Correction target item name] 0028
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２８】（比較例２）実施例１のシリカをサイロイ
ド１５０に変更した他は同一条件にてサンプルを製造し
た。得られたインクジェット用マットフィルムは、透明
度５４．８％と透明性は低く、ＳＲａ値は０．６μｍで
あった。このインクジェット用マットフィルムを、実施
例１と同様に評価したところ、インク乾燥時間は１分以
内と早く、滲みは良好であるが、ビーディングが発生
し、特にベタ部の均一性に劣っていた。Comparative Example 2 A sample was manufactured under the same conditions except that the silica of Example 1 was changed to Syloid 150. The obtained matte film for inkjet had low transparency with a transparency of 54.8% and an SRa value of 0.6 μm. When this matte film for inkjet was evaluated in the same manner as in Example 1, the ink drying time was as short as 1 minute or less, the bleeding was good, but beading occurred, and the uniformity of the solid part was particularly poor. .
【手続補正９】[Procedure Amendment 9]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２９[Name of item to be corrected] 0029
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２９】（比較例３）実施例１のシリカをサイロイ
ド６２０に変更した他は同一条件にてサンプルを製造し
た。得られたインクジェット用マットフィルムは、透明
度８５．３％、ＳＲａ値は２．５μｍであった。このイ
ンクジェット用マットフィルムを、実施例１と同様に評
価したところ、インク乾燥時間は１分以内と早く、滲み
・ビーディングの発生が無く、ベタ部の均一性も良好な
記録フィルムであったが、画線濃度が低く、シャープ性
に欠け鉛筆筆記適性は有していなかった。Comparative Example 3 A sample was manufactured under the same conditions except that the silica of Example 1 was changed to Syloid 620. The obtained matte film for inkjet had a transparency of 85.3% and an SRa value of 2.5 μm. When this matte film for inkjet was evaluated in the same manner as in Example 1, the ink drying time was as short as 1 minute or less, no bleeding or beading occurred, and the uniformity of solid portions was good. However, the image density was low, the sharpness was lacking, and pencil writing aptitude was not obtained.
【手続補正１０】[Procedure Amendment 10]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００３０[Name of item to be corrected] 0030
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００３０】[0030]
【発明の効果】以上の様に、本発明では、インクの乾燥
性が早く、かつ滲み、ビーディングの無い被記録材であ
り、透明度７０％以上で耐水性が有り、鉛筆筆記性の良
好な第２原図適性をも兼ね備えたインクジェット記録用
マットフィルムが得られる。INDUSTRIAL APPLICABILITY As described above, according to the present invention, a recording material having fast ink drying property, no bleeding and no beading, transparency of 70% or more, water resistance and good pencil writing property. A matte film for inkjet recording having the suitability for the second original image can be obtained.
Claims (1)
次元表面粗さ計で測定したＳＲａが 1.0〜2.0 μｍの範
囲にある耐水性を有したインク受理層が設けられた事を
特徴とする透明度70％以上のインクジェット記録用マッ
トフィルム。1. A transparency 70 characterized in that at least one surface of a film sheet is provided with a water-resistant ink-receiving layer having SRa in the range of 1.0 to 2.0 μm as measured by a three-dimensional surface roughness meter. % Or more matte film for inkjet recording.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4218592A JP2594205B2 (en) | 1992-07-24 | 1992-07-24 | Matte film for inkjet recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4218592A JP2594205B2 (en) | 1992-07-24 | 1992-07-24 | Matte film for inkjet recording |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0672015A true JPH0672015A (en) | 1994-03-15 |
| JP2594205B2 JP2594205B2 (en) | 1997-03-26 |
Family
ID=16722379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4218592A Expired - Fee Related JP2594205B2 (en) | 1992-07-24 | 1992-07-24 | Matte film for inkjet recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2594205B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11321079A (en) * | 1998-05-19 | 1999-11-24 | Konica Corp | Cationic composite fine particle dispersion solution, manufacture of the same, and ink jet recording paper |
| JP2006327204A (en) * | 2006-07-18 | 2006-12-07 | Konica Minolta Holdings Inc | Manufacturing method of cation nature compound particle dispersion for ink jet recording papers, and manufacturing process of ink jet recording paper |
| JP2015110321A (en) * | 2013-08-09 | 2015-06-18 | キヤノンファインテック株式会社 | Recording medium, recorded matter, and manufacturing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56157A (en) * | 1979-06-18 | 1981-01-06 | Ricoh Kk | High molecular sheet for ink jetting recording |
| JPS61199980A (en) * | 1985-03-04 | 1986-09-04 | Canon Inc | Light transmissive recording material |
| JPS62141194A (en) * | 1985-12-17 | 1987-06-24 | 日本製紙株式会社 | Sheet for ink jet recording |
| JPS62214985A (en) * | 1986-03-18 | 1987-09-21 | Tomoegawa Paper Co Ltd | Recording sheet |
| JPH0230582A (en) * | 1988-07-21 | 1990-01-31 | Somar Corp | Recording film |
-
1992
- 1992-07-24 JP JP4218592A patent/JP2594205B2/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56157A (en) * | 1979-06-18 | 1981-01-06 | Ricoh Kk | High molecular sheet for ink jetting recording |
| JPS61199980A (en) * | 1985-03-04 | 1986-09-04 | Canon Inc | Light transmissive recording material |
| JPS62141194A (en) * | 1985-12-17 | 1987-06-24 | 日本製紙株式会社 | Sheet for ink jet recording |
| JPS62214985A (en) * | 1986-03-18 | 1987-09-21 | Tomoegawa Paper Co Ltd | Recording sheet |
| JPH0230582A (en) * | 1988-07-21 | 1990-01-31 | Somar Corp | Recording film |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11321079A (en) * | 1998-05-19 | 1999-11-24 | Konica Corp | Cationic composite fine particle dispersion solution, manufacture of the same, and ink jet recording paper |
| JP2006327204A (en) * | 2006-07-18 | 2006-12-07 | Konica Minolta Holdings Inc | Manufacturing method of cation nature compound particle dispersion for ink jet recording papers, and manufacturing process of ink jet recording paper |
| JP2015110321A (en) * | 2013-08-09 | 2015-06-18 | キヤノンファインテック株式会社 | Recording medium, recorded matter, and manufacturing method thereof |
| US9789677B2 (en) | 2013-08-09 | 2017-10-17 | Canon Finetech Nisca Inc. | Recording medium, recorded matter, and methods of manufacturing the medium and the matter |
| US10576724B2 (en) | 2013-08-09 | 2020-03-03 | Canon Finetech Nisca Inc. | Recording medium, recorded matter, and methods of manufacturing the medium and the matter |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2594205B2 (en) | 1997-03-26 |
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