JPH07166471A - Method for anti-staining processing for cellulosic fiber fabric - Google Patents
Method for anti-staining processing for cellulosic fiber fabricInfo
- Publication number
- JPH07166471A JPH07166471A JP34255093A JP34255093A JPH07166471A JP H07166471 A JPH07166471 A JP H07166471A JP 34255093 A JP34255093 A JP 34255093A JP 34255093 A JP34255093 A JP 34255093A JP H07166471 A JPH07166471 A JP H07166471A
- Authority
- JP
- Japan
- Prior art keywords
- fiber fabric
- cellulosic fiber
- cellulose
- present
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title abstract description 20
- 239000000835 fiber Substances 0.000 title abstract description 11
- 238000012545 processing Methods 0.000 title abstract description 11
- 238000010186 staining Methods 0.000 title 1
- 229920002678 cellulose Polymers 0.000 claims abstract description 12
- 239000001913 cellulose Substances 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 11
- 229920003043 Cellulose fiber Polymers 0.000 claims description 18
- 230000003373 anti-fouling effect Effects 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 7
- 238000003672 processing method Methods 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Treatment Of Fiber Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は，セルロース繊維布帛の
防汚加工方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for antifouling a cellulose fiber cloth.
【０００２】[0002]
【従来の技術】従来から，繊維布帛の防汚加工は盛んに
研究されているが，セルロース繊維，特に綿は，吸水性
を有するため，合成繊維に比べて汚れにくい，また, 汚
れても落ちやすいことから，防汚加工は合成繊維に対す
る研究が主流になっており，セルロース繊維に対する防
汚加工方法の研究開発はあまり行われていない。2. Description of the Related Art Conventionally, antifouling treatment of fiber cloth has been extensively studied, but since cellulose fiber, especially cotton has water absorption property, it is less likely to be soiled than synthetic fiber, and even if soiled, it can be removed. Because of its simplicity, research on synthetic fibers has become the mainstream for antifouling treatment, and research and development on methods for antifouling treatment on cellulose fibers have not been conducted much.
【０００３】セルロース繊維は，体の内部の汚れ等が付
着しても，洗濯によって容易に落とすことができるが，
口紅やファンデーション等の外部からの汚れが一旦付着
すると，洗濯によってもその汚れを容易に落とすことは
できなかった。Cellulose fibers can be easily removed by washing, even if dirt inside the body adheres to them.
Once stains from the outside such as lipstick and foundation adhered, they could not be easily removed even by washing.
【０００４】このような外部からの汚れに対してセルロ
ース繊維に防汚性能を付与する方法として，従来から，
セルロース繊維をより一層親水化して汚れ除去性を高め
るため，水溶性セルロース誘導体の処理液にセルロース
繊維布帛を浸漬して絞り，乾燥，熱処理することによ
り，同誘導体をセルロース繊維に付与する方法が行われ
ている。As a method for imparting antifouling performance to cellulose fibers against such dirt from the outside, conventionally,
In order to make the cellulose fibers more hydrophilic and improve the stain removability, a method of applying the derivatives to the cellulose fibers by dipping the cellulose fiber cloth in a treatment solution of a water-soluble cellulose derivative, squeezing, drying and heat treatment is performed. It is being appreciated.
【０００５】[0005]
【発明が解決しようとする課題】しかしながら，水溶性
セルロース誘導体の水溶液は粘度が高く，高い防汚性能
を付与するために高濃度溶液を用いると加工が困難にな
り，しかも加工布帛の風合が硬くなってしまう欠点を有
していた。However, the aqueous solution of the water-soluble cellulose derivative has a high viscosity, and if a high-concentration solution is used to impart high antifouling property, it becomes difficult to process it, and the texture of the processed fabric is not good. It had the drawback of becoming hard.
【０００６】本発明は，このような課題を解決しようと
するもので，柔軟なセルロース繊維布帛の風合を阻害す
ることなく，外部からの汚れに対する汚れ除去性能をセ
ルロース繊維布帛に付与することを目的とするものであ
る。The present invention is intended to solve such problems, and it is an object of the present invention to impart a stain-removing performance to stains from the outside to a cellulose fiber cloth without disturbing the texture of the flexible cellulose fiber cloth. It is intended.
【０００７】[0007]
【課題を解決するための手段】本発明は，上記目的を達
成するもので，次の構成よりなるものである。すなわ
ち，本発明は，水溶性セルロース誘導体と架橋剤を含む
処理液をセルロース繊維布帛の肌に接しない方の面の凸
部に付与し，しかる後に乾燥，熱処理することを特徴と
するセルロース繊維布帛の防汚加工方法を要旨とするも
のである。SUMMARY OF THE INVENTION The present invention achieves the above object and has the following configuration. That is, the present invention is characterized in that a treatment liquid containing a water-soluble cellulose derivative and a cross-linking agent is applied to the convex portion of the surface of the cellulose fiber cloth that does not come into contact with the skin, and then dried and heat-treated. The main point is the antifouling method.
【０００８】以下，本発明を詳細に説明する。The present invention will be described in detail below.
【０００９】本発明で用いるセルロース繊維布帛とは，
綿，麻，レーヨン等からなる織物，編物を意味し，特に
嵩高性のある編物が被加工布帛として好ましく用いられ
る。The cellulose fiber cloth used in the present invention is
It means a woven or knitted fabric made of cotton, hemp, rayon or the like, and a particularly bulky knitted fabric is preferably used as a fabric to be processed.
【００１０】本発明では，まず，上述のセルロース繊維
布帛に，その布帛の肌に接しない方の面の凸部に水溶性
セルロース誘導体と架橋剤を含む処理液を付与する。In the present invention, first, a treatment liquid containing a water-soluble cellulose derivative and a cross-linking agent is applied to the above-mentioned cellulose fiber cloth on the convex portion of the surface of the cloth which is not in contact with the skin.
【００１１】ここで用いる水溶性セルロース誘導体とし
てはカルボキシメチルセルロース，ヒドロキシエチルセ
ルロース，ヒドロキシプロピルセルロース，メチルセル
ロース，カルボキシメチルヒドロキシエチルセルロース
等を挙げることができる。これらの水溶性セルロース誘
導体は，繊維重量に対して0.１〜１０重量％の範囲で付
与するが，好ましくは0.３〜１重量％である。0.１重量
％未満では，十分な効果が得られず，また，１０重量％
を超えて使用すると，粘度が高くなり，処理液の含浸時
に絞液ロールが作動しにくくなるので好ましくない。Examples of the water-soluble cellulose derivative used here include carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose and carboxymethyl hydroxyethyl cellulose. These water-soluble cellulose derivatives are added in the range of 0.1 to 10% by weight, preferably 0.3 to 1% by weight, based on the weight of the fiber. If the amount is less than 0.1% by weight, the sufficient effect cannot be obtained.
If it is used over the range, the viscosity becomes high and the squeezing roll does not easily operate during impregnation of the treatment liquid, which is not preferable.
【００１２】架橋剤としては，グリオキザール系樹脂，
エポキシ系樹脂，ウレタン樹脂，メラミン樹脂等，一般
に繊維加工に使用されている架橋剤を用いることができ
る。この場合の架橋剤の付与量は，繊維重量に対して固
形分で４〜８重量％である。４重量％未満では，十分な
架橋効果が得られず，また，８重量％を超えて架橋剤を
付与しても，加工効果はもはやそれ以上向上し得ない傾
向にあるので不経済となる。As the cross-linking agent, glyoxal resin,
Crosslinking agents generally used for fiber processing such as epoxy resins, urethane resins, and melamine resins can be used. In this case, the amount of the cross-linking agent applied is 4 to 8% by weight in terms of solid content with respect to the fiber weight. If it is less than 4% by weight, a sufficient crosslinking effect cannot be obtained, and if the crosslinking agent is added in an amount of more than 8% by weight, the processing effect tends to be no longer improved, which is uneconomical.
【００１３】本発明方法では，上述の水溶性セルロース
誘導体と架橋剤の混合液を布帛の肌に接しない方の面
（表側）の凸部に付与するが，ここでいう布帛の片面の
凸部とは，布帛の組織で糸が表面に出ている部分を意味
するものである。このときの付与方法はスクリーン捺染
機，ローラー捺染機，泡加工機，スプレー加工機，コー
ティング加工機，キスコータ等，いずれの片面加工機を
使用しても加工を行うことができるが，布帛の片面の凸
部にのみ処理剤を付与するには，キスコータを使用する
のが最も合理的であり好ましい。In the method of the present invention, the above-mentioned mixed solution of the water-soluble cellulose derivative and the cross-linking agent is applied to the convex portion of the surface (front side) of the cloth which does not come into contact with the skin. The term "fabric structure" means a portion where threads are exposed on the surface. The application method at this time can be performed by using any one-side processing machine such as a screen printing machine, a roller printing machine, a foam processing machine, a spray processing machine, a coating processing machine, a kiss coater, etc. It is the most rational and preferable to use a kiss coater to apply the treatment agent only to the convex portions of.
【００１４】処理液の付与後，乾燥，熱処理を行う。乾
燥は，８０〜１８０℃で行い，乾燥後，１１０〜１８０
℃で数分間の熱処理を行う。１１０℃未満では，架橋剤
が十分に架橋せず，また，１８０℃を超えると，繊維の
黄変の原因になるため好ましくない。After applying the treatment liquid, drying and heat treatment are performed. Drying is performed at 80 to 180 ° C, and after drying, 110 to 180
Heat treatment is performed at ℃ for several minutes. If the temperature is lower than 110 ° C, the crosslinking agent is not sufficiently crosslinked, and if the temperature exceeds 180 ° C, it causes yellowing of the fiber, which is not preferable.
【００１５】上記の加工を施す前に，パッドドライ法等
通常の手法により柔軟加工を行うことにより，より一層
柔軟な加工布帛を得ることができる。Before carrying out the above-mentioned processing, a softer processed cloth can be obtained by carrying out soft processing by a usual method such as a pad dry method.
【００１６】本発明は，以上の構成を有するものであ
る。The present invention has the above configuration.
【００１７】[0017]
【作 用】外部からの汚れ，特に女性用衣類等で摩擦に
よって付着する口紅，ファンデーション等の化粧品汚れ
は，布帛の表面層にのみ付着していることが多い。本発
明方法のごとく，布帛の表側の凸部にのみ水溶性セルロ
ース誘導体による防汚処理を施すと，布帛は外部からの
固体汚れに対して防汚性能を発揮するようになり，しか
も肌に触れる側は，風合硬化の原因となる水溶性セルロ
ースが付与されていないので，綿等のセルロース繊維本
来の柔軟な風合特性を維持することができ，布帛の柔軟
性を阻害することなく，外部からの汚れに対する汚れ除
去性能をセルロース繊維布帛に付与することができる。[Working] Dirt from the outside, especially cosmetics such as lipsticks and foundations that adhere to women's clothing due to friction, often adhere only to the surface layer of the fabric. When the antifouling treatment with the water-soluble cellulose derivative is applied only to the convex portion on the front side of the fabric as in the method of the present invention, the fabric exhibits the antifouling property against solid stains from the outside and is in contact with the skin. Since the side does not have water-soluble cellulose that causes hand-curing, it is possible to maintain the original soft hand-feeling characteristics of cellulose fibers such as cotton, and without impairing the softness of the fabric. The cellulosic fiber cloth can be provided with a soil removal performance against soil from the soil.
【００１８】[0018]
【実施例】次に実施例を挙げて本発明を記述するが，実
施例における布帛の性能の測定，評価は，加工上がりの
試料について下記の方法で行った。 （１）汚れ除去性 試料の表面の２cm×２cm四方に，人工油性汚れ（ステア
リン酸１５％，オレイン酸１５％，牛脂硬化油１５％，
オリーブ油１５％，セチルアルコール１０％，コレステ
ロール５％，固形パラフィン２５％の混合物）0.５ｇを
塗布し，２０時間放置後，家庭洗濯（ＪＩＳ Ｌ−０２
１７，１０３法）した後の汚れの残存状態を，汚染用グ
レースケールで等級判別（５：良〜１：不良）した。 （２）剛軟度 ＪＩＳ Ｌ−１０９６（ハンドルオメーター法）によ
る。EXAMPLES Next, the present invention will be described with reference to examples. The measurement and evaluation of the performance of the fabrics in the examples were carried out by the following method for samples after processing. (1) Stain removal property A 2 cm x 2 cm square on the surface of the sample has artificial oily stains (stearic acid 15%, oleic acid 15%, beef tallow oil 15%,
0.5 g of a mixture of olive oil 15%, cetyl alcohol 10%, cholesterol 5%, and solid paraffin 25%) was applied and left for 20 hours, followed by home washing (JIS L-02).
The residual state of the stain after the (17, 103 method) was classified by the gray scale for contamination (5: good to 1: poor). (2) Bending flexibility According to JIS L-1096 (handle odometer method).
【００１９】実施例１ 通常の方法で糊抜き，精練，仕上げされた綿糸４０番単
糸引揃えによる編地の表鹿子（釜径２６吋，針密度２２
ゲージ）を用意し，これに下記処方１の処理液をキスコ
ータを用いて編地の凸部に付与し，１１０℃で２分間乾
燥した。Example 1 Outer fawn of a knitted fabric by de-sizing, scouring and finishing of cotton yarn No. 40 single yarn aligned by a conventional method (kettle diameter 26 inch, needle density 22
A gauge) was prepared, and the treatment liquid having the following formulation 1 was applied to the convex portion of the knitted fabric using a kiss coater, and dried at 110 ° C. for 2 minutes.
【００２０】 処方１ カルボキシメチルセルロース ２０ｇ／リットル （第一工業製薬株式会社製，水溶性セルロース誘導体） エラストロンＢＮ−６９ ５０ｇ／リットル （第一工業製薬株式会社製，ウレタン樹脂系架橋剤） エラストロンキャタリスト６４ 2.５ｇ／リットル （第一工業製薬株式会社製，ＢＮ−６９用触媒） ハイソフターＫ−１０ ３０ｇ／リットル （明成化学株式会社製，柔軟剤）Formulation 1 Carboxymethylcellulose 20 g / liter (Daiichi Kogyo Seiyaku Co., Ltd., water-soluble cellulose derivative) Elastron BN-69 50 g / liter (Daiichi Kogyo Seiyaku Co., Ltd., urethane resin cross-linking agent) Elastron Catalyst 64 2.5 g / l (Daiichi Kogyo Seiyaku Co., Ltd., catalyst for BN-69) High Softer K-10 30 g / l (Meisei Chemical Co., Ltd., softener)
【００２１】この後，ピンテンターを用いて，１６０℃
で２分間の乾熱処理を行い，本発明の防汚加工布を得
た。Thereafter, using a pin tenter, 160 ° C.
Was subjected to dry heat treatment for 2 minutes to obtain an antifouling processed cloth of the present invention.
【００２２】本発明との比較のため，本実施例における
処方１の処理液の付与を，キスコータに代えてパッダー
を用いた通常のパッドドライ法（ピックアップ率８０
％）で行うほかは，本実施例とまったく同一の方法によ
り比較用の加工布（比較例１）を得た。また，参考まで
に，未加工のもの（比較例２）を用意し，比較用に供し
た。For the purpose of comparison with the present invention, the treatment liquid of the formulation 1 in this example was applied by a conventional pad dry method (pickup rate 80 using a padder instead of a kiss coater).
%) To obtain a comparative work cloth (Comparative Example 1) by the same method as that of this example. For reference, an unprocessed product (Comparative Example 2) was prepared and used for comparison.
【００２３】本発明および比較用の加工布帛の性能を測
定，評価し，その結果を合わせて表１に示した。 The performances of the present invention and the processed fabric for comparison were measured and evaluated, and the results are shown in Table 1.
【００２４】表１より明らかなように，本発明方法によ
るセルロース繊維加工布帛は，良好な防汚性能を有し，
しかも柔軟性も優れていることが分かる。As is clear from Table 1, the cellulose fiber-treated cloth produced by the method of the present invention has good antifouling performance,
Moreover, it can be seen that the flexibility is also excellent.
【００２５】[0025]
【発明の効果】本発明方法によれば，セルロース繊維布
帛にその柔軟な風合を損ねることなく防汚性能を付与す
ることができる。このような性能を有する本発明の加工
布帛はワーキングウェア，スポーツウェア，ポロシャツ
等の素材として最適である。According to the method of the present invention, it is possible to impart antifouling performance to a cellulose fiber cloth without impairing its soft texture. The processed fabric of the present invention having such properties is most suitable as a material for working wear, sportswear, polo shirts and the like.
Claims (1)
処理液をセルロース繊維布帛の肌に接しない方の面の凸
部に付与し，しかる後に乾燥，熱処理することを特徴と
するセルロース繊維布帛の防汚加工方法。1. A cellulose fiber cloth characterized in that a treatment liquid containing a water-soluble cellulose derivative and a cross-linking agent is applied to the convex portions of the surface of the cellulose fiber cloth which is not in contact with the skin, and then dried and heat treated. Antifouling processing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34255093A JPH07166471A (en) | 1993-12-13 | 1993-12-13 | Method for anti-staining processing for cellulosic fiber fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34255093A JPH07166471A (en) | 1993-12-13 | 1993-12-13 | Method for anti-staining processing for cellulosic fiber fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07166471A true JPH07166471A (en) | 1995-06-27 |
Family
ID=18354623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34255093A Pending JPH07166471A (en) | 1993-12-13 | 1993-12-13 | Method for anti-staining processing for cellulosic fiber fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07166471A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006045756A (en) * | 2004-06-30 | 2006-02-16 | Aichi Prefecture | Fiber modification method and modified fiber |
| JP2007016322A (en) * | 2004-06-30 | 2007-01-25 | Aichi Prefecture | Method for modifying fibers |
| KR101153674B1 (en) * | 2004-06-30 | 2012-06-18 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Method for Modifying Fibers |
-
1993
- 1993-12-13 JP JP34255093A patent/JPH07166471A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006045756A (en) * | 2004-06-30 | 2006-02-16 | Aichi Prefecture | Fiber modification method and modified fiber |
| JP2007016322A (en) * | 2004-06-30 | 2007-01-25 | Aichi Prefecture | Method for modifying fibers |
| KR101153674B1 (en) * | 2004-06-30 | 2012-06-18 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Method for Modifying Fibers |
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