JPH0717785A - Production of decorated article using ceramic product as substrate - Google Patents
Production of decorated article using ceramic product as substrateInfo
- Publication number
- JPH0717785A JPH0717785A JP18911193A JP18911193A JPH0717785A JP H0717785 A JPH0717785 A JP H0717785A JP 18911193 A JP18911193 A JP 18911193A JP 18911193 A JP18911193 A JP 18911193A JP H0717785 A JPH0717785 A JP H0717785A
- Authority
- JP
- Japan
- Prior art keywords
- ceramic product
- coupling agent
- silane coupling
- resin
- decorative material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000758 substrate Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 6
- 230000001681 protective effect Effects 0.000 claims abstract description 5
- 238000005034 decoration Methods 0.000 claims description 5
- 239000011888 foil Substances 0.000 abstract description 11
- 239000011521 glass Substances 0.000 abstract description 9
- 229910052571 earthenware Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- -1 pressed flowers Substances 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、タイル、ガラス、セラ
ミックス等の窯業製品からなる装飾材料の製造方法に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a decorative material composed of ceramic products such as tiles, glass and ceramics.
【０００２】[0002]
【従来の技術】タイル、ガラス、セラミックス等の窯業
製品は、一般に、安定して不活性な表面を有することに
特徴を有するものである。従って、その製造工程におい
て、着色されることはあっても、タイル等の製品になっ
てからは、着色し難いものでされたおり、それらを製品
になった後の加工で、装飾品に仕上げることは、なされ
ていなかった。Ceramic products such as tiles, glass and ceramics are generally characterized by having a stable and inert surface. Therefore, even though it may be colored in the manufacturing process, it is difficult to color it after it becomes a product such as tiles, and it is processed into a decorative product by processing them. That wasn't done.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、このような
従来の技術常識を破り、窯業製品に金属箔や写真等の装
飾材を適用し、新規な装飾品に仕上げる方法を提供する
ことを課題とする。DISCLOSURE OF THE INVENTION The present invention breaks this conventional technical common sense and provides a method for applying a decorative material such as a metal foil or a photograph to a ceramic product to finish a new decorative product. It is an issue.
【０００４】[0004]
【課題を解決するための手段】本発明では、既に、焼成
により窯業製品として仕上がったタイル、ガラス、セラ
ミックス等の表面に、シランカップリング剤を塗布し、
該塗布面を加熱し、シランカップリング剤を硬化させた
後に、適当な接着剤を塗布し、その上に装飾材を接着
し、乾燥後、該装飾材を覆うように、樹脂保護膜を形成
することによって、上記課題を解決した。According to the present invention, a silane coupling agent is applied to the surface of a tile, glass, ceramics or the like which has already been finished as a ceramic product by firing.
After heating the coated surface to cure the silane coupling agent, an appropriate adhesive is applied, a decorative material is adhered on the adhesive, and after drying, a resin protective film is formed so as to cover the decorative material. By doing so, the above problem was solved.
【０００５】即ち、本発明では、シランカップリング剤
の塗布によって、不活性な窯業製品の表面の接着性を改
良し、その上に接着剤層を介して装飾材を接着し、更
に、保護膜を形成することによって、タイルやガラス等
の表面を美しく装飾可能としたのである。That is, in the present invention, the adhesion of the surface of an inert ceramic product is improved by applying a silane coupling agent, and a decorative material is adhered on the surface by an adhesive layer, and a protective film is further formed. By forming the, the surface of tiles, glass, etc. can be beautifully decorated.
【０００６】シランカップリング剤としては、市販のも
のがいずれも使用できる。なお、シランカップリング剤
の硬化は、その塗布面を、瞬時的に４００℃以上、５０
０〜８００℃程度に焼いて実施するのが好ましい。Any commercially available silane coupling agent can be used. In addition, the curing of the silane coupling agent is carried out by instantaneously applying a 50 °
It is preferable to carry out baking at about 0 to 800 ° C.
【０００７】シランカップリング剤表面に塗布される接
着剤は、装飾材の種類に合わせて選べばよく、例えば、
金属箔等を装飾材として使用する場合は、エポキシ樹脂
等の使用が好ましく、写真や着色紙等を装飾材として使
用する場合は、デンプン、ポバール、アラビアゴム、酢
酸ビニル系樹脂、アクリル系樹脂、ウレタン系樹脂等が
いずれも使用できるが、水性糊剤を使用するのが好まし
く、特に、酢酸ビニル系樹脂やアクリル系樹脂の水性エ
マルジョンの使用が好ましい。The adhesive applied to the surface of the silane coupling agent may be selected according to the type of decoration material.
When using a metal foil or the like as a decoration material, it is preferable to use an epoxy resin or the like, and when using a photograph or colored paper or the like as a decoration material, starch, poval, gum arabic, vinyl acetate resin, acrylic resin, Any urethane-based resin or the like can be used, but it is preferable to use an aqueous sizing agent, and it is particularly preferable to use an aqueous emulsion of vinyl acetate-based resin or acrylic resin.
【０００８】金属箔をエポキシ樹脂等の無溶媒の接着剤
で接着する場合には、減圧下で、２００℃以上というよ
うな高温加熱することによって、接着剤層に金属箔が埋
め込まれた非常に妙味ある製品を得ることができる。な
お、水性糊剤等の通常の接着剤を使用する場合、通常の
乾燥条件（例えば風乾あるいは８０〜１２０℃程度の乾
燥）が適用されてよいのは、勿論である。When the metal foil is adhered with a solventless adhesive such as an epoxy resin, the metal foil is embedded in the adhesive layer by heating at a high temperature of 200 ° C. or higher under reduced pressure. You can get a wonderful product. In addition, when using a normal adhesive such as an aqueous paste, it goes without saying that normal drying conditions (for example, air drying or drying at about 80 to 120 ° C.) may be applied.
【０００９】装飾材としては、金属、木材、竹材、押し
花、プラスチック片、繊維、金属箔、色箔、写真、装飾
紙等がいずれも使用できる。また、その上に保護膜を形
成するための樹脂としては、アクリル樹脂、ウレタン樹
脂、メラミン樹脂、尿素樹脂及び紫外線硬化型樹脂（Ｕ
Ｖ樹脂）等がいずれも適用できる。As the decorative material, any of metal, wood, bamboo, pressed flowers, plastic pieces, fibers, metal foil, colored foil, photographs, decorative paper and the like can be used. Moreover, as a resin for forming a protective film thereon, an acrylic resin, a urethane resin, a melamine resin, a urea resin and an ultraviolet curable resin (U
V resin) or the like can be applied.
【００１０】[0010]
【実施例】次に、本発明を実施例に従って、更に詳しく
説明する。 実施例１ 白く焼き上げたタイルの表面にシランカップリング剤
（信越化学工業社製のオルガノシランＫＢＥ９０３をイ
ソプロパノールで２％に希釈したもの）を塗布し、軽く
拭い、６００〜８００℃のバーナーの火炎を吹きつける
ことにより、該カップリング剤を硬化させ、その上に２
液性エポキシ樹脂を塗布し、更に、金箔の粉末を模様状
に置き、減圧下で、２５０℃に加熱した。金箔は、樹脂
層に埋め込まれた状態で、美しい金属光沢を放つ模様と
して、安定して固着された。更に、保護層として、透明
なウレタン樹脂液を表面に塗布した製品は、表面が平滑
で、金箔模様で美しく装飾されたタイルとなり、屋内装
飾品等として、広く活用できるものとなった。なお、こ
の製品は、１００℃の沸水中に２０時間浸漬しても、何
ら変化のない、非常に耐久性のよいものであった。EXAMPLES Next, the present invention will be described in more detail with reference to examples. Example 1 A silane coupling agent (organosilane KBE903 manufactured by Shin-Etsu Chemical Co., Ltd., diluted to 2% with isopropanol) was applied to the surface of a white-baked tile, wiped lightly, and a flame of a burner at 600 to 800 ° C. was applied. The coupling agent is hardened by spraying and 2
Liquid epoxy resin was applied, and gold foil powder was placed in a pattern and heated to 250 ° C. under reduced pressure. The gold foil, which was embedded in the resin layer, was stably fixed as a pattern giving off a beautiful metallic luster. Further, a product having a transparent urethane resin liquid applied to the surface as a protective layer has a smooth surface and is beautifully decorated with a gold foil pattern, and can be widely used as an interior decoration product. In addition, this product had no change even when immersed in boiling water at 100 ° C. for 20 hours, and had very good durability.
【００１１】実施例２ 白いタイルの表面に、実施例１と同様の方法で、シラン
カップリング剤の硬化層を形成し、その上に、水溶性の
糊剤を塗布し、写真を貼着し、自然乾燥後、写真の上か
らタイル全面に透明なアクリル系樹脂を塗布した。その
結果、写真が埋め込まれたような外観を有するタイルを
得ることができた。Example 2 A hardened layer of a silane coupling agent was formed on the surface of a white tile in the same manner as in Example 1, a water-soluble sizing agent was applied onto the hardened layer, and a photograph was attached. After natural drying, a transparent acrylic resin was applied to the entire surface of the tile from the top of the photograph. As a result, it was possible to obtain a tile having an appearance in which a photograph was embedded.
【００１２】実施例３ タイルの代わりにガラスを使用して、実施例１と同様の
方法を実施した。透明なガラスの一部に箔模様が形成さ
れた、非常に妙味ある製品を得ることができた。Example 3 The same procedure as in Example 1 was carried out using glass instead of tile. It was possible to obtain a very attractive product in which a foil pattern was formed on a part of transparent glass.
【００１３】実施例４ 陶器の壺の表面に、実施例１と同様の方法で、金属箔模
様を形成した。その結果、従来の陶芸品には見られな
い、非常に美しい金属箔模様を有する壺を得ることがで
きた。Example 4 A metal foil pattern was formed on the surface of the pot of the pottery in the same manner as in Example 1. As a result, it was possible to obtain a vase having a very beautiful metal foil pattern, which is not found in conventional pottery.
【００１４】[0014]
【発明の効果】本発明では、タイル、ガラス、陶器、レ
ンガ等の表面に、種々の装飾材を貼着して、容易に、耐
久性ある装飾品に仕上げることができる。例えば、写真
や雑誌のグラビヤ等をタイルや陶器等の表面に一体化さ
せ、壁装材等として使用可能とする。また、金属箔等の
適用により、タイルやガラス等を、従来になく、高貴な
外観を呈するものに変えることができるので、これらの
適用範囲が非常に広くなる。INDUSTRIAL APPLICABILITY According to the present invention, various decorative materials can be attached to the surfaces of tiles, glass, pottery, bricks, etc. to easily finish durable decorative articles. For example, a photo or magazine gravure or the like is integrated with the surface of a tile, a pottery, or the like so that it can be used as a wall covering or the like. Further, by applying a metal foil or the like, the tile, the glass, or the like can be changed to one having a noble appearance unlike ever before, so that the range of application thereof is extremely wide.
Claims (1)
カップリング剤を塗布し、該塗布面を加熱し、シランカ
ップリング剤を硬化させた後、接着剤を塗布し、その上
に装飾材を接着し、乾燥後、該装飾材を覆うように、樹
脂保護膜を形成することを特徴とする窯業製品を基材と
する装飾品の製造方法。1. A silane coupling agent is applied to the surface of a base material made of a ceramic product, the applied surface is heated to cure the silane coupling agent, and then an adhesive is applied, and the decoration is applied thereon. A method for producing a decorative article using a ceramic product as a base material, which comprises bonding a material, drying the resin, and then forming a resin protective film so as to cover the decorative material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18911193A JPH0717785A (en) | 1993-06-30 | 1993-06-30 | Production of decorated article using ceramic product as substrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18911193A JPH0717785A (en) | 1993-06-30 | 1993-06-30 | Production of decorated article using ceramic product as substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0717785A true JPH0717785A (en) | 1995-01-20 |
Family
ID=16235562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18911193A Pending JPH0717785A (en) | 1993-06-30 | 1993-06-30 | Production of decorated article using ceramic product as substrate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0717785A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2740390A1 (en) * | 1995-10-27 | 1997-04-30 | Masson Patrick | PROCESS FOR DECORATING NATURAL OR RECONSTITUTED STONE |
| FR2776235A1 (en) * | 1998-03-17 | 1999-09-24 | Azzeddine Blidi | Protective and decorative coating for solid support |
| US6136382A (en) * | 1997-12-29 | 2000-10-24 | Deco Patents, Inc. | Method and compositions for decorating vitreous articles with radiation curable inks having improved adhesion and durability |
| JP2015081202A (en) * | 2013-10-21 | 2015-04-27 | 富士電機株式会社 | Resin film forming method |
| EP3556736B1 (en) * | 2018-04-17 | 2023-10-25 | Schott Ag | Printed device component |
| CN119282020A (en) * | 2024-09-25 | 2025-01-10 | 中国科学院金属研究所 | A method for preparing yttrium oxide coating by ultrasonic impregnation of modified ceramic core |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55100242A (en) * | 1978-10-18 | 1980-07-31 | Fr Deyuko Soc | Covering of glass or ceramic article |
-
1993
- 1993-06-30 JP JP18911193A patent/JPH0717785A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55100242A (en) * | 1978-10-18 | 1980-07-31 | Fr Deyuko Soc | Covering of glass or ceramic article |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2740390A1 (en) * | 1995-10-27 | 1997-04-30 | Masson Patrick | PROCESS FOR DECORATING NATURAL OR RECONSTITUTED STONE |
| EP0770502A1 (en) * | 1995-10-27 | 1997-05-02 | Masson, Patrick | Process for decorating natural or reconstituted stone |
| US6136382A (en) * | 1997-12-29 | 2000-10-24 | Deco Patents, Inc. | Method and compositions for decorating vitreous articles with radiation curable inks having improved adhesion and durability |
| FR2776235A1 (en) * | 1998-03-17 | 1999-09-24 | Azzeddine Blidi | Protective and decorative coating for solid support |
| JP2015081202A (en) * | 2013-10-21 | 2015-04-27 | 富士電機株式会社 | Resin film forming method |
| EP3556736B1 (en) * | 2018-04-17 | 2023-10-25 | Schott Ag | Printed device component |
| CN119282020A (en) * | 2024-09-25 | 2025-01-10 | 中国科学院金属研究所 | A method for preparing yttrium oxide coating by ultrasonic impregnation of modified ceramic core |
| CN119282020B (en) * | 2024-09-25 | 2025-11-21 | 中国科学院金属研究所 | Method for preparing yttrium oxide coating by ultrasonic impregnation of modified ceramic core |
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