JPH07179608A - ポリマー中にあるスルホキシド基を還元する方法 - Google Patents

ポリマー中にあるスルホキシド基を還元する方法

Info

Publication number: JPH07179608A
Authority: JP; Japan
Prior art keywords: carried out; active hydrogen; reaction; polymer; sulfoxide
Prior art date: 1993-10-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP6244148A

Other languages

English (en)

Japanese (ja)

Inventor

Georg Dr Frank

ゲオルク・フランク

Andreas Schleicher

アンドレアス・シュライヒャー

Juergen Kulpe

ユルゲン・クルペ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-10-07

Filing date

1994-10-07

Publication date

1995-07-18

1994-10-07 Application filed by Hoechst AG filed Critical Hoechst AG

1995-07-18 Publication of JPH07179608A publication Critical patent/JPH07179608A/ja

Status Pending legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 19
238000000034 method Methods 0.000 title claims description 14
125000003375 sulfoxide group Chemical group 0.000 title description 5
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
239000001257 hydrogen Substances 0.000 claims abstract description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 14
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 12
229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
125000002947 alkylene group Chemical group 0.000 claims abstract description 3
125000000732 arylene group Chemical group 0.000 claims abstract description 3
238000006243 chemical reaction Methods 0.000 claims description 11
230000005855 radiation Effects 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
229910052717 sulfur Inorganic materials 0.000 claims description 5
239000011593 sulfur Substances 0.000 claims description 5
239000000725 suspension Substances 0.000 claims description 5
238000005984 hydrogenation reaction Methods 0.000 claims description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
239000001301 oxygen Substances 0.000 claims description 3
SLGBZMMZGDRARJ-UHFFFAOYSA-N Triphenylene Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C2=C1 SLGBZMMZGDRARJ-UHFFFAOYSA-N 0.000 claims description 2
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
239000010953 base metal Substances 0.000 claims description 2
125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 2
150000002431 hydrogen Chemical class 0.000 claims description 2
125000005647 linker group Chemical group 0.000 claims description 2
125000004957 naphthylene group Chemical group 0.000 claims description 2
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
229920006395 saturated elastomer Polymers 0.000 claims description 2
125000005580 triphenylene group Chemical group 0.000 claims description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
239000007848 Bronsted acid Substances 0.000 claims 1
238000006552 photochemical reaction Methods 0.000 claims 1
238000002360 preparation method Methods 0.000 abstract description 2
125000001118 alkylidene group Chemical group 0.000 abstract 1
238000007796 conventional method Methods 0.000 abstract 1
238000006722 reduction reaction Methods 0.000 description 16
238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 14
238000001228 spectrum Methods 0.000 description 10
150000003462 sulfoxides Chemical class 0.000 description 9
229920000412 polyarylene Polymers 0.000 description 8
-1 polyphenylene Polymers 0.000 description 7
239000000835 fiber Substances 0.000 description 6
229920000265 Polyparaphenylene Polymers 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
238000010586 diagram Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
150000003568 thioethers Chemical class 0.000 description 3
229910002703 Al K Inorganic materials 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
238000002329 infrared spectrum Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
230000003595 spectral effect Effects 0.000 description 2
239000011701 zinc Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
229920000049 Carbon (fiber) Polymers 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
229910003110 Mg K Inorganic materials 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000004917 carbon fiber Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000009905 homogeneous catalytic hydrogenation reaction Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000000465 moulding Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
230000005469 synchrotron radiation Effects 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/18—Polysulfoxides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
- C08G75/0213—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur
- C08G75/0218—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur containing oxygen
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/025—Preparatory processes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Emergency Medicine (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP6244148A 1993-10-07 1994-10-07 ポリマー中にあるスルホキシド基を還元する方法 Pending JPH07179608A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE4334198A DE4334198A1 (de)	1993-10-07	1993-10-07	Verfahren zur Reduktion von Sulfoxidgruppen in Polymeren
DE4334198.5		1993-10-07

Publications (1)

Publication Number	Publication Date
JPH07179608A true JPH07179608A (ja)	1995-07-18

Family

ID=6499620

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6244148A Pending JPH07179608A (ja)	1993-10-07	1994-10-07	ポリマー中にあるスルホキシド基を還元する方法

Country Status (14)

Country	Link
EP (1)	EP0648798A1 (2)
JP (1)	JPH07179608A (2)
KR (1)	KR950011505A (2)
CN (1)	CN1109476A (2)
AU (1)	AU7417794A (2)
BR (1)	BR9404005A (2)
CA (1)	CA2133802A1 (2)
CZ (1)	CZ246994A3 (2)
DE (1)	DE4334198A1 (2)
HU (1)	HUT70861A (2)
PL (1)	PL305330A1 (2)
RU (1)	RU94037244A (2)
TW (1)	TW283154B (2)
ZA (1)	ZA947811B (2)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR100417086B1 (ko) *	1995-12-30	2004-06-23	고려화학 주식회사	열및자외선동시경화형수지를이용한도막조성물
US7094364B2 (en)	2003-11-26	2006-08-22	General Electric Company	Method of authenticating polymers, authenticatable polymers, methods of making authenticatable polymers and authenticatable articles, and articles made there from
US7169615B2 (en)	2003-11-26	2007-01-30	General Electric Company	Method of authenticating polymers, authenticatable polymers, methods of making authenticatable polymers and authenticatable articles, and articles made there from

1993
- 1993-10-07 DE DE4334198A patent/DE4334198A1/de not_active Withdrawn
1994
- 1994-09-17 TW TW083108620A patent/TW283154B/zh active
- 1994-09-23 AU AU74177/94A patent/AU7417794A/en not_active Abandoned
- 1994-10-04 EP EP94115585A patent/EP0648798A1/de not_active Withdrawn
- 1994-10-05 HU HU9402851A patent/HUT70861A/hu unknown
- 1994-10-05 CN CN94117054A patent/CN1109476A/zh active Pending
- 1994-10-06 PL PL94305330A patent/PL305330A1/xx unknown
- 1994-10-06 BR BR9404005A patent/BR9404005A/pt not_active Application Discontinuation
- 1994-10-06 KR KR1019940025510A patent/KR950011505A/ko not_active Withdrawn
- 1994-10-06 CZ CZ942469A patent/CZ246994A3/cs unknown
- 1994-10-06 ZA ZA947811A patent/ZA947811B/xx unknown
- 1994-10-06 RU RU94037244/04A patent/RU94037244A/ru unknown
- 1994-10-06 CA CA002133802A patent/CA2133802A1/en not_active Abandoned
- 1994-10-07 JP JP6244148A patent/JPH07179608A/ja active Pending

Also Published As

Publication number	Publication date
HU9402851D0 (en)	1995-01-30
ZA947811B (en)	1995-05-24
EP0648798A1 (de)	1995-04-19
CZ246994A3 (en)	1995-04-12
CA2133802A1 (en)	1995-04-08
BR9404005A (pt)	1995-06-27
CN1109476A (zh)	1995-10-04
HUT70861A (en)	1995-11-28
AU7417794A (en)	1995-04-27
RU94037244A (ru)	1996-09-10
TW283154B (2)	1996-08-11
PL305330A1 (en)	1995-04-18
DE4334198A1 (de)	1995-04-13
KR950011505A (ko)	1995-05-15

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