JPH07229057A - Antimicrobial glass fiber product and its production - Google Patents
Antimicrobial glass fiber product and its productionInfo
- Publication number
- JPH07229057A JPH07229057A JP6045010A JP4501094A JPH07229057A JP H07229057 A JPH07229057 A JP H07229057A JP 6045010 A JP6045010 A JP 6045010A JP 4501094 A JP4501094 A JP 4501094A JP H07229057 A JPH07229057 A JP H07229057A
- Authority
- JP
- Japan
- Prior art keywords
- glass fiber
- antibacterial
- fiber product
- resin
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】
【目的】耐久性に優れた抗菌性，防黴性を有するガラス
繊維製品及びその製造方法を提供する。
【構成】抗菌性を有する金属イオンを担持しているゼオ
ライト系粒子と樹脂とカップリング剤とを含有する処理
液にガラス繊維製品を浸漬したのち、乾燥する。ガラス
繊維製品に上記ゼオライト系粒子を樹脂とカップリング
剤とで固定化する。(57) [Abstract] [Purpose] To provide a glass fiber product having excellent durability, antibacterial property and antifungal property, and a method for producing the same. [Structure] A glass fiber product is immersed in a treatment liquid containing zeolite particles supporting antibacterial metal ions, a resin and a coupling agent, and then dried. The zeolite particles are fixed to a glass fiber product with a resin and a coupling agent.
Description
【０００１】[0001]
【産業上の利用分野】本発明は、優れた抗菌効果を有す
るガラス繊維製品及びその製造方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glass fiber product having an excellent antibacterial effect and a method for producing the same.
【０００２】[0002]
【従来の技術】ガラス繊維製品は、機械的特性，不燃性
等に非常に優れているため、建築内装材等に広く用いら
れているが、特に近年になり、清潔な環境が要求される
調理室，食堂，医療関係施設をはじめ、工場施設，オフ
ィスビル等においては、抗菌性，防黴性等を有するもの
が強く要望されている。中でも医療関係においては、メ
シチリン耐性黄色ブドウ球菌（以下、「ＭＲＳＡ」と略
記する）の感染を防ぐ目的からＭＲＳＡに対する抗菌作
用のあるものが切望されている。2. Description of the Related Art Glass fiber products are widely used as interior materials for construction because they are very excellent in mechanical properties and incombustibility. There is a strong demand for antibacterial and antifungal substances in rooms, cafeterias, medical facilities, factory facilities, office buildings and the like. Among them, in the medical field, those having an antibacterial action against MRSA have been earnestly desired for the purpose of preventing infection with mesitillin-resistant Staphylococcus aureus (hereinafter abbreviated as “MRSA”).
【０００３】従来、天然繊維や合成繊維に抗菌性や防黴
性を付与する方法としては、後加工で抗菌剤や防黴剤を
付着させる方法が知られている。また、合成繊維に抗菌
性や防黴性を付与する方法としては、抗菌性を有する金
属粉末を添加混合して紡糸する方法が知られている。Conventionally, as a method of imparting antibacterial and antifungal properties to natural fibers and synthetic fibers, a method of attaching an antibacterial or antifungal agent in post-processing is known. As a method of imparting antibacterial properties and antifungal properties to synthetic fibers, a method of adding and mixing an antibacterial metal powder and spinning it is known.
【０００４】しかしながら、ガラス繊維に対し後加工に
より抗菌剤を付着させた場合には、その効果が耐久性に
乏しいものであるという問題点がある。また、金属粉末
を添加混合して紡糸する方法は、ガラス繊維の紡糸温度
が千数百℃と極めて高温であるため、金属粉末を添加混
合してガラス繊維を紡糸するのは容易ではない。このた
め、耐久性に優れた抗菌効果を有するガラス繊維製品
は、未だ満足すべきものがないのが現状である。However, when the antibacterial agent is adhered to the glass fiber by post-processing, there is a problem that the effect is poor in durability. In addition, in the method of adding and mixing the metal powder and spinning the glass fiber, the spinning temperature of the glass fiber is as high as 1,000s of hundreds of degrees Celsius, so it is not easy to add and mix the metal powder to spin the glass fiber. Therefore, at present, there is still no satisfactory glass fiber product having excellent antibacterial effect and durability.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、耐久性のよ
い抗菌性，防黴性を有するガラス繊維製品及びその製造
方法を提供することを目的としている。SUMMARY OF THE INVENTION It is an object of the present invention to provide a durable glass fiber product having antibacterial and antifungal properties and a method for producing the same.
【０００６】[0006]
【課題を解決するための手段】本発明の抗菌性ガラス繊
維製品は、ガラス繊維よりなる製品において、抗菌作用
を有する金属イオンを担持しているゼオライト系粒子と
樹脂とカップリング剤とがガラス繊維の表面に施与され
ていることを特徴とするものである。The antibacterial glass fiber product of the present invention is a product comprising glass fibers, wherein the zeolite-based particles carrying metal ions having an antibacterial action, the resin and the coupling agent are glass fibers. It is characterized in that it is applied to the surface of.
【０００７】また、本発明の製造方法は、ガラス繊維製
品を、抗菌作用を有する金属イオンを担持しているゼオ
ライト系粒子と樹脂とカップリング剤とを含有する処理
液で処理することを特徴とするものである。Further, the production method of the present invention is characterized in that the glass fiber product is treated with a treatment liquid containing zeolite particles carrying metal ions having an antibacterial action, a resin and a coupling agent. To do.
【０００８】本発明に用いられるガラス繊維製品とは、
ガラス繊維からなる製品一般を言うものであり、例えば
ガラス繊維織物，ガラス繊維製不織布，ガラステープ，
ガラス糸，ガラスマット，ガラスペーパー等を挙げるこ
とができる。また、ガラス繊維の組成は特に限定される
ものでなく、例えばＥガラス（電気用無アルカリガラ
ス），Ｓガラス（高強度ガラス），Ｄガラス（低誘電ガ
ラス），Ａガラス（耐酸用ガラス），Ｃガラス（化学用
含アルカリガラス），石英ガラス等を挙げることができ
る。The glass fiber product used in the present invention is
This refers to general products made of glass fiber, such as glass fiber woven fabric, glass fiber non-woven fabric, glass tape,
Examples thereof include glass thread, glass mat, and glass paper. The composition of the glass fiber is not particularly limited, and includes, for example, E glass (non-alkali glass for electric use), S glass (high strength glass), D glass (low dielectric glass), A glass (glass for acid resistance), C glass (chemically containing alkali glass), quartz glass, etc. can be mentioned.
【０００９】本発明に用いられる抗菌性を有する金属イ
オンを担持しているゼオライト系粒子（以下、「抗菌性
ゼオライト」と略記する）とは、特公昭６３−５４０１
３号公報に開示されているようなものである。Zeolite particles carrying metal ions having antibacterial properties used in the present invention (hereinafter abbreviated as "antibacterial zeolite") are disclosed in Japanese Examined Patent Publication No. 63-5401.
This is as disclosed in Japanese Patent Laid-Open No.
【００１０】即ち、銀，銅，亜鉛，鉄，クロム，ニッケ
ル，錫，水銀等の抗菌作用を有する金属イオンの１種又
は２種以上をイオン交換により担持するゼオライトであ
って、好ましくは銀，銅，亜鉛から選ばれた金属イオン
を担持するものである。このようなものとしては具体的
には、「バクテキラー」（商品名、鐘紡製）として市販
されているものを挙げることができる。That is, a zeolite carrying one or more metal ions having an antibacterial action such as silver, copper, zinc, iron, chromium, nickel, tin and mercury by ion exchange, preferably silver, It carries metal ions selected from copper and zinc. As such a thing, what is marketed as "Bactekiller" (brand name, made by Kanebo) can be specifically mentioned.
【００１１】ゼオライトは一般に三次元的に発達した骨
格構造を有するアルミノシリケートであって、一般には
Ａl2Ｏ3 を基準にして、ｘＭ2/n Ｏ・Ａl2Ｏ3 ・ｙＳｉ
Ｏ2・ｚＨ2 Ｏで表される。ここで、Ｍはイオン交換可
能な金属イオンを表し、通常は１価又は２価の金属であ
り、ｎはこの原子価に対応する。一方、ｘ及びｙはそれ
ぞれ金属酸化物，シリカの係数であり、ｚは結晶水の数
を表している。[0011] Zeolite is a generally aluminosilicate having a three dimensionally developed skeletal structure, typically based on the Al 2 O 3, xM 2 / n O · Al 2 O 3 · ySi
It is represented by O 2 · zH 2 O. Here, M represents an ion-exchangeable metal ion, which is usually a monovalent or divalent metal, and n corresponds to this valence. On the other hand, x and y are the coefficients of metal oxide and silica, respectively, and z is the number of crystal water.
【００１２】ゼオライトの形状は粉末粒子状であり、そ
の粒子径は数ミクロンから数十ミクロンのものが好まし
い。また、金属イオンはゼオライト粒子にイオン交換に
より担持されたものであり、イオン交換によらず単に吸
着あるいは付着したものでは抗菌効果及びその持続性が
不十分である。The zeolite is in the form of powder particles, and the particle diameter thereof is preferably several microns to several tens of microns. Further, the metal ions are carried on the zeolite particles by ion exchange, and the antibacterial effect and its sustainability are insufficient if the metal ions are simply adsorbed or adhered without depending on the ion exchange.
【００１３】本発明においてガラス繊維に施与する抗菌
性ゼオライトの量は、ガラス繊維重量に対し、好ましく
は０．２〜１０重量％、更に好ましくは０．４〜６重量
％である。The amount of the antibacterial zeolite applied to the glass fiber in the present invention is preferably 0.2 to 10% by weight, more preferably 0.4 to 6% by weight, based on the weight of the glass fiber.
【００１４】本発明に用いられる樹脂は、後述する溶剤
に分散又は溶解するものであり、例えばアクリル系樹
脂，ポリウレタン系樹脂，ポリ酢酸ビニル系樹脂，ポリ
エステル系樹脂，ポリ塩化ビニル系樹脂，エポキシ系樹
脂，フェノール系樹脂，メラミン系樹脂，シリコーン系
樹脂、あるいはこれらの共重合物、混合物等を挙げるこ
とができるが、作業の安全性の観点から好ましくは水に
分散しエマルジョンを形成する樹脂である。本発明にお
いて、ガラス繊維に対する樹脂の施与量は、好ましくは
０．１〜１０重量％、更に好ましくは０．２〜５重量％
である。樹脂の付着量が多過ぎると、ガラス繊維製品の
不燃性が損なわれることになる。The resin used in the present invention is one that is dispersed or dissolved in a solvent described later, and is, for example, an acrylic resin, a polyurethane resin, a polyvinyl acetate resin, a polyester resin, a polyvinyl chloride resin, an epoxy resin. Examples thereof include resins, phenolic resins, melamine resins, silicone resins, and copolymers and mixtures thereof, but from the viewpoint of work safety, resins that are dispersed in water to form an emulsion are preferable. . In the present invention, the amount of the resin applied to the glass fiber is preferably 0.1 to 10% by weight, more preferably 0.2 to 5% by weight.
Is. If the amount of resin adhered is too large, the nonflammability of the glass fiber product will be impaired.
【００１５】本発明に用いるカップリング剤としては、
シラン系カップリング剤、チタネート系カップリング剤
等を挙げることができるが、従来公知のカップリング剤
から使用する樹脂と相溶性のよいものを適宜選択すれば
よい。本発明において、ガラス繊維に対するカップリン
グ剤の施与量は、０．０１〜１．０重量％程度が好まし
い。As the coupling agent used in the present invention,
Examples of the coupling agent include a silane coupling agent and a titanate coupling agent, and conventionally known coupling agents having a good compatibility with the resin used may be appropriately selected. In the present invention, the amount of the coupling agent applied to the glass fiber is preferably about 0.01 to 1.0% by weight.
【００１６】本発明の方法で抗菌性ガラス繊維製品を製
造するには、上記ガラス繊維製品を、前記抗菌性ゼオラ
イトと樹脂とカップリング剤とを溶剤で溶解又は分散せ
しめた処理液で処理すればよい。かかる処理液での処理
方法は、例えばガラス繊維製品を処理液に浸漬したのち
絞液し乾燥する方法、処理液をガラス繊維製品にスプレ
ー等により吹き付けて付着せしめたのち乾燥する方法、
ガラス繊維製品に処理液を塗布したのち乾燥する方法等
を挙げることができるが、特にこれらに限定されるもの
ではなく、ガラス繊維の表面に処理液を付着せしめたの
ち乾燥する方法であれば、公知の適宜な方法で行えばよ
い。In order to produce an antibacterial glass fiber product by the method of the present invention, the glass fiber product is treated with a treatment liquid in which the antibacterial zeolite, resin and coupling agent are dissolved or dispersed in a solvent. Good. The treatment method with such a treatment liquid is, for example, a method in which a glass fiber product is dipped in the treatment liquid and then squeezed and dried, a method in which the treatment liquid is sprayed onto the glass fiber product and then adhered, and then dried.
Examples of the method include applying a treatment liquid to a glass fiber product and then drying the same, but are not particularly limited thereto, and a method of drying the treatment liquid after the treatment liquid is adhered to the surface of the glass fiber, It may be performed by a known appropriate method.
【００１７】上記処理液の溶剤としては、前記抗菌性ゼ
オライトと樹脂とカップリング剤とを分散又は溶解しう
るものであれば、公知の溶剤から適宜選択すればよい。
このような溶剤としては、例えば水，アセトン，トルエ
ン，キシレン，メタノール，酢酸エチル，メチルエチル
ケトン等を挙げることができるが、本発明においては、
前述したように作業の安全性の観点から水が好ましい。The solvent for the treatment liquid may be appropriately selected from known solvents as long as it can disperse or dissolve the antibacterial zeolite, the resin and the coupling agent.
Examples of such a solvent include water, acetone, toluene, xylene, methanol, ethyl acetate, and methyl ethyl ketone. In the present invention,
As described above, water is preferable from the viewpoint of work safety.
【００１８】上記処理液中における抗菌性ゼオライトの
濃度は、例えば０．２〜１０重量％程度に調整される。
また、処理液中における樹脂の配合量は、抗菌性ゼオラ
イト１重量部に対し０．１〜１０重量部程度が好まし
く、処理液中におけるカップリング剤の配合量は０．０
１〜１重量％程度が好ましい。The concentration of the antibacterial zeolite in the treatment liquid is adjusted to, for example, about 0.2 to 10% by weight.
The amount of the resin blended in the treatment liquid is preferably about 0.1 to 10 parts by weight per 1 part by weight of the antibacterial zeolite, and the amount of the coupling agent blended in the treatment liquid is 0.0.
About 1 to 1% by weight is preferable.
【００１９】本発明の方法では、上記処理液をガラス繊
維製品に付着させたのち乾燥するが、乾燥後にガラス繊
維製品に付着固定化される固形分量は、ガラス繊維製品
の重量に対し、好ましくは０．１〜３０重量％、更に好
ましくは０．１〜１０重量％である。In the method of the present invention, the treatment liquid is adhered to the glass fiber product and then dried. The solid content adhered and fixed to the glass fiber product after drying is preferably relative to the weight of the glass fiber product. It is 0.1 to 30% by weight, more preferably 0.1 to 10% by weight.
【００２０】本発明においては、樹脂とカップリング剤
との相乗効果により、抗菌性ゼオライトを強固にガラス
繊維に固定化するものである。したがって、本発明にお
いては、樹脂又はカップリング剤のいずれかが欠けた場
合には、抗菌性ゼオライトは脱落し易くなり、摩擦堅牢
度に優れた耐久性のよい抗菌性，防黴性を付与すること
ができない。In the present invention, the antibacterial zeolite is firmly fixed to the glass fiber by the synergistic effect of the resin and the coupling agent. Therefore, in the present invention, when either the resin or the coupling agent is lacking, the antibacterial zeolite is likely to fall off and imparts excellent antibacterial and antifungal properties with excellent friction fastness. I can't.
【００２１】尚、上記処理液には、ガラス繊維製品に着
色を施すために、必要に応じ顔料等の着色剤を適宜添加
混合してもよい。また、本発明の抗菌性ガラス繊維製品
を細かく粉砕して粉末状にすれば、抗菌性，防黴性を有
するガラスパウダーを得ることもできる。In order to color the glass fiber product, a colorant such as a pigment may be appropriately added to and mixed with the treatment liquid. Further, when the antibacterial glass fiber product of the present invention is finely pulverized into a powder, a glass powder having antibacterial and antifungal properties can be obtained.
【００２２】[0022]
【実施例】以下、実施例により本発明を具体的に説明す
る。尚、その前に本明細書における評価方法について説
明する。EXAMPLES The present invention will be specifically described below with reference to examples. Before that, the evaluation method in this specification will be described.
【００２３】〈抗菌試験１〉衛生加工製品の加工効果評
価試験方法に準拠し、シェークフラスコ法で菌種として
大腸菌を用い、抗菌作用の耐久性の尺度として、洗濯を
０，１，５回実施後の試料について、シェーク１時間後
の滅菌率を求めた。<Antibacterial test 1> In accordance with the test method for evaluating the effect of sanitary processed products, Escherichia coli was used as the bacterial species in the shake flask method, and washing was performed 0, 1, 5 times as a measure of durability of antibacterial action. For the latter sample, the sterilization rate after 1 hour of shaking was determined.
【００２４】〈抗菌試験２〉衛生加工製品の加工効果評
価試験方法に準拠し、シェークフラスコ法で菌種として
ＭＲＳＡ ＫＢ−１００５を用い、シェーク６時間後の
１ml当たりの生菌数を求めた。尚、初期菌数は４．３×
１０6 cells/mlであった。<Antibacterial test 2> According to the test method for evaluating the effect of processing sanitary products, MRSA KB-1005 was used as the bacterial species in the shake flask method, and the viable cell count per 1 ml after 6 hours of shaking was determined. The initial number of bacteria is 4.3 x
It was 10 6 cells / ml.
【００２５】実施例１ 経糸としてガラス繊維糸ＥＣＤＥ１５０−１／２を用
い、密度が５３本／２５mmで、緯糸としてガラス繊維糸
ＥＣＤＥ７５−１／２（嵩高加工糸）を用い、密度が３
０本／２５mmの綾織ガラス繊維織物（商品名：テキスト
グラスＫＳ４２００、鐘紡製）を、４００℃で２０時間
ヒートクリーニングし、付着糊剤を除去した。Example 1 A glass fiber yarn ECDE150-1 / 2 was used as a warp, a density was 53 yarns / 25 mm, and a glass fiber yarn ECDE75-1 / 2 (bulk processed yarn) was used as a weft yarn, and a density was 3
A 0/25 mm twill weave glass fiber woven fabric (trade name: Text Glass KS4200, manufactured by Kanebo) was heat-cleaned at 400 ° C. for 20 hours to remove the attached sizing agent.
【００２６】次に、抗菌性ゼオライトとして銀イオンを
担持した平均粒径３〜５μｍの抗菌性ゼオライト（商品
名：バクテキラーＢＭ１０２Ａ、鐘紡製）を３重量％、
樹脂として水分散アクリル系エマルジョン（固形分４０
重量％）を５重量％、カップリング剤としてγ−グリシ
ドキプロピルトリメトキシシランを０．１重量％、及び
顔料を２．５重量％、水に混合し分散溶解した処理液を
得た。この処理液に前記ガラス繊維織物を浸漬し、絞液
したのち乾燥し、本発明の抗菌性ガラス繊維製品を得
た。得られた抗菌性ガラス繊維製品は、処理により施与
された固形分が元のガラス繊維製品重量に対し約４重量
％であり、その結果は表１に示す通りであった。3% by weight of antibacterial zeolite (trade name: BACTEKILLER BM102A, manufactured by Kanebo) having an average particle diameter of 3 to 5 μm and carrying silver ions as the antibacterial zeolite,
Water-dispersed acrylic emulsion as resin (solid content 40
5% by weight), 0.1% by weight of γ-glycidoxypropyltrimethoxysilane as a coupling agent, and 2.5% by weight of a pigment were mixed and dispersed in water to obtain a treatment liquid. The glass fiber woven fabric was dipped in this treatment liquid, squeezed and dried to obtain an antibacterial glass fiber product of the present invention. In the obtained antibacterial glass fiber product, the solid content applied by the treatment was about 4% by weight based on the original weight of the glass fiber product, and the results are shown in Table 1.
【００２７】実施例２ 実施例１において処理液に混合した抗菌性ゼオライトの
混合量を３重量％に代えて１重量％とした以外は、実施
例１と同様にして抗菌性ガラス繊維製品を得た。得られ
た抗菌性ガラス繊維製品の結果は、表１に示す通りであ
った。Example 2 An antibacterial glass fiber product was obtained in the same manner as in Example 1 except that the mixing amount of the antibacterial zeolite mixed in the treatment liquid in Example 1 was changed to 3% by weight. It was The results of the obtained antibacterial glass fiber product are as shown in Table 1.
【００２８】比較例１ 実施例１において処理液に加えた抗菌性ゼオライトを加
えなかった以外は、実施例１と同様にしてガラス繊維製
品を得た。得られたガラス繊維製品の結果は、表１に示
す通りであった。Comparative Example 1 A glass fiber product was obtained in the same manner as in Example 1 except that the antibacterial zeolite added to the treatment liquid in Example 1 was not added. The results of the obtained glass fiber products are as shown in Table 1.
【００２９】比較例２ 実施例２において処理液に加えたカップリング剤を加え
なかった以外は、実施例２と同様にしてガラス繊維製品
を得た。得られたガラス繊維製品の結果は、表１に示す
通りであった。Comparative Example 2 A glass fiber product was obtained in the same manner as in Example 2 except that the coupling agent added to the treatment liquid in Example 2 was not added. The results of the obtained glass fiber products are as shown in Table 1.
【００３０】[0030]
【表１】 注）抗菌試験２における、初期生菌数は４．３×１０6
であった。[Table 1] Note: The initial viable cell count in antibacterial test 2 is 4.3 × 10 6.
Met.
【００３１】[0031]
【発明の効果】本発明の抗菌性ガラス繊維製品は、抗菌
性ゼオライトを樹脂及びカップリング剤と共に施与した
ため、抗菌性ゼオライトが脱落し難く、耐久性に優れた
抗菌性，防黴性を得ることができる。特に、ＭＲＳＡに
対し優れた抗菌効果を奏するものである。The antibacterial glass fiber product of the present invention is obtained by applying antibacterial zeolite together with a resin and a coupling agent, so that the antibacterial zeolite is hard to drop off and has excellent durability and antibacterial property and antifungal property. be able to. In particular, it has an excellent antibacterial effect against MRSA.
【００３２】このため、本発明の抗菌性ガラス繊維製品
は、不燃性等のガラス繊維製品が本来有する特性も生か
し、建築内装用材料，医療関係用材料，工場施設用材
料，オフィスビル用材料等、幅広い用途に使用できるた
め、産業上極めて有用なものである。Therefore, the antibacterial glass fiber product of the present invention makes full use of the inherent properties of the glass fiber product such as non-combustibility, and is used as a material for building interiors, a material for medical use, a material for factory facilities, a material for office buildings, etc. Since it can be used for a wide range of purposes, it is extremely useful industrially.
【００３３】本発明の方法によれば、抗菌性ゼオライト
をガラス繊維製品に耐久性よく固定化することができる
ため、持続性に優れた抗菌性，防黴性を有する抗菌性ガ
ラス繊維製品を、安定且つ効率よく製造することができ
る。According to the method of the present invention, since the antibacterial zeolite can be immobilized on the glass fiber product with good durability, the antibacterial glass fiber product having excellent antibacterial and antifungal properties with excellent durability can be obtained. It can be manufactured stably and efficiently.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｄ０６Ｍ 13/50 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location D06M 13/50
Claims (2)
作用を有する金属イオンを担持しているゼオライト系粒
子と樹脂とカップリング剤とがガラス繊維の表面に施与
されていることを特徴とする抗菌性ガラス繊維製品。1. A product comprising glass fiber, wherein zeolite particles carrying metal ions having an antibacterial action, a resin and a coupling agent are applied to the surface of the glass fiber. Glass fiber products.
属イオンを担持しているゼオライト系粒子と樹脂とカッ
プリング剤とを含有する処理液で処理することを特徴と
する抗菌性ガラス繊維製品の製造方法。2. An antibacterial glass fiber product characterized in that the glass fiber product is treated with a treatment liquid containing zeolite particles carrying metal ions having an antibacterial action, a resin and a coupling agent. Production method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04501094A JP3218266B2 (en) | 1994-02-18 | 1994-02-18 | Antibacterial glass fiber product and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04501094A JP3218266B2 (en) | 1994-02-18 | 1994-02-18 | Antibacterial glass fiber product and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07229057A true JPH07229057A (en) | 1995-08-29 |
| JP3218266B2 JP3218266B2 (en) | 2001-10-15 |
Family
ID=12707399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP04501094A Expired - Fee Related JP3218266B2 (en) | 1994-02-18 | 1994-02-18 | Antibacterial glass fiber product and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3218266B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100388630B1 (en) * | 2000-12-04 | 2003-06-25 | 한국에너지기술연구원 | Manufacturing Method for Glass Fiber Reinforced Activated Carbon/Zeolite Composite Adsorbent with Waste Water Treatment Using Mixture of Zeolite and Phenolic Resin |
| KR100423095B1 (en) * | 2002-02-20 | 2004-03-16 | 한국화학연구원 | Method for preparing activated carbon-supported fibers using the inorganic fiber materials |
| US10131574B2 (en) | 2013-06-17 | 2018-11-20 | Corning Incorporated | Antimicrobial glass articles and methods of making and using same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101494303B1 (en) * | 2010-10-07 | 2015-02-23 | 소토미 타케다 | Process for producing antibacterial and antiviral glass fiber material |
-
1994
- 1994-02-18 JP JP04501094A patent/JP3218266B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100388630B1 (en) * | 2000-12-04 | 2003-06-25 | 한국에너지기술연구원 | Manufacturing Method for Glass Fiber Reinforced Activated Carbon/Zeolite Composite Adsorbent with Waste Water Treatment Using Mixture of Zeolite and Phenolic Resin |
| KR100423095B1 (en) * | 2002-02-20 | 2004-03-16 | 한국화학연구원 | Method for preparing activated carbon-supported fibers using the inorganic fiber materials |
| US10131574B2 (en) | 2013-06-17 | 2018-11-20 | Corning Incorporated | Antimicrobial glass articles and methods of making and using same |
| US10676394B2 (en) | 2013-06-17 | 2020-06-09 | Corning Incorporated | Antimicrobial glass articles and methods of making and using same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3218266B2 (en) | 2001-10-15 |
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