JPH07242515A - Oil-based point make-up cosmetic - Google Patents
Oil-based point make-up cosmeticInfo
- Publication number
- JPH07242515A JPH07242515A JP6028494A JP6028494A JPH07242515A JP H07242515 A JPH07242515 A JP H07242515A JP 6028494 A JP6028494 A JP 6028494A JP 6028494 A JP6028494 A JP 6028494A JP H07242515 A JPH07242515 A JP H07242515A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- tar
- acyllysine
- oil
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 27
- 239000000980 acid dye Substances 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 13
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004472 Lysine Substances 0.000 claims description 8
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 3
- 238000004043 dyeing Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 7
- 238000004381 surface treatment Methods 0.000 abstract description 4
- PDQICKRFOKDJCH-UHFFFAOYSA-N 6-amino-2-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCCCN PDQICKRFOKDJCH-UHFFFAOYSA-N 0.000 abstract description 2
- 125000002252 acyl group Chemical group 0.000 abstract description 2
- 125000001931 aliphatic group Chemical group 0.000 abstract description 2
- 239000012670 alkaline solution Substances 0.000 abstract description 2
- 238000011033 desalting Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 239000004359 castor oil Substances 0.000 description 5
- 235000019438 castor oil Nutrition 0.000 description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000010828 elution Methods 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- -1 Yellow No. 4 Chemical compound 0.000 description 3
- 239000001023 inorganic pigment Substances 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- OLDGKSQBWGEFNM-UHFFFAOYSA-N 6-amino-2-(hexadecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCCCCCC(=O)NC(C(O)=O)CCCCN OLDGKSQBWGEFNM-UHFFFAOYSA-N 0.000 description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 2
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000013077 scoring method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- GYDYJUYZBRGMCC-INIZCTEOSA-N (2s)-2-amino-6-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NCCCC[C@H](N)C(O)=O GYDYJUYZBRGMCC-INIZCTEOSA-N 0.000 description 1
- DEAFEFSHUVGNFC-JTQLQIEISA-N (2s)-6-amino-2-(hexanoylamino)hexanoic acid Chemical compound CCCCCC(=O)N[C@H](C(O)=O)CCCCN DEAFEFSHUVGNFC-JTQLQIEISA-N 0.000 description 1
- VWYVABSAUVXYNS-QFIPXVFZSA-N (2s)-6-amino-2-(octadecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCCN VWYVABSAUVXYNS-QFIPXVFZSA-N 0.000 description 1
- UBVSIAHUTXHQTD-UHFFFAOYSA-N 2-n-(4-bromophenyl)-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(NC=2C=CC(Br)=CC=2)=N1 UBVSIAHUTXHQTD-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- WLDHEUZGFKACJH-ZRUFZDNISA-K Amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1\N=N\C1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-ZRUFZDNISA-K 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- DVHIYVOBSKWPJD-SFHVURJKSA-N N-myristoyl lysine Chemical compound CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCCCN DVHIYVOBSKWPJD-SFHVURJKSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 description 1
- YJVBLROMQZEFPA-UHFFFAOYSA-L acid red 26 Chemical compound [Na+].[Na+].CC1=CC(C)=CC=C1N=NC1=C(O)C(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=C12 YJVBLROMQZEFPA-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- VQHHOXOLUXRQFQ-UHFFFAOYSA-L dipotassium;4,5,6,7-tetrachloro-2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 VQHHOXOLUXRQFQ-UHFFFAOYSA-L 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000012732 erythrosine Nutrition 0.000 description 1
- 230000008921 facial expression Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、皮膚や唇への色素染着
性がないために、安全性に優れ、なおかつ化粧効果にも
優れる油性ポイントメイクアップ化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oily point make-up cosmetic composition which is excellent in safety and cosmetic effects because it has no dyeing property on the skin and lips.
【０００２】[0002]
【従来の技術および発明が解決しようとする課題】従
来、油性ポイントメイクアップ化粧料は鮮明な色調で、
皮膚や唇に塗布して色彩を施し、艶を与え、表情を魅力
的に見せるために用いられてきた。鮮やかな色調を得る
ため、また化粧崩れを改善するために、その配合成分と
して有色顔料やタール色素が多用されている。また、こ
の色調を持続させるため、様々な工夫がこらされてい
る。例えば、特開昭６１−６９７０９号公報には、Ｎ−
アシルリジンを無機顔料に表面処理して、化粧崩れ等を
改善する開示がされている。しかし、皮膚や唇への色素
染着性がないために、安全性に優れ、なおかつ化粧効果
にも優れる油性ポイントメイクアップ化粧料に関する点
で、十分でなかった。一方、本発明に係わる着色剤とし
ては、その製品の用途から、ベンガラ、黄酸化鉄、黒酸
化鉄、グンジョウ、酸化チタンなどに代表される無機顔
料に比べて鮮やかな色みを持ち、天然色素よりも鮮やか
な発色を示す、タール色素を配合することが好ましい。2. Description of the Related Art Conventionally, oily point makeup cosmetics have a clear color tone,
It has been used to apply color to the skin and lips to give it shine, and to make facial expressions attractive. Colored pigments and tar dyes are often used as ingredients for obtaining a vivid color tone and improving makeup deterioration. In addition, various measures have been taken to maintain this color tone. For example, in JP-A-61-69709, N-
It has been disclosed that surface treatment of an acyl lysine with an inorganic pigment improves cosmetic discoloration and the like. However, it is not sufficient in terms of oil-based point makeup cosmetics, which is excellent in safety and cosmetic effects because it has no dyeing property to the skin and lips. On the other hand, the colorant according to the present invention has a vivid color as compared with inorganic pigments represented by red iron oxide, yellow iron oxide, black iron oxide, red iron oxide, titanium oxide, etc. due to the use of the product, and is a natural pigment. It is preferable to add a tar dye showing a brighter color.
【０００３】しかしながら、タール色素はその種類によ
って差はあるが、水や溶媒に溶出して、皮膚や唇に染着
するという特性を有するものが多い。これらの色素のう
ち溶出の程度の大きなものは、通常アルミニウム、バリ
ウムまたはジルコニウム等でレーキ化したものを用いる
が、レーキ化しても溶出を完全に抑制することは困難で
ある。そして、これらの溶出性を有する色素を油性ポイ
ントメイクアップ化粧料に配合する場合、皮膚や唇に染
着するという安全性上の問題があり、その使用に当たっ
ては、配合量などの点でさまざまな制約を考慮しなけれ
ばならなかった。一方、前記公報には、有機粉体につい
て、水や溶媒に溶出して、皮膚や唇に染着するという課
題を解決するための、示唆も記載もされていない。However, although tar dyes differ depending on their types, many tar dyes have the property of being dissolved in water or a solvent and dyed on the skin or lips. Of these dyes, those having a large degree of elution are usually those laked with aluminum, barium, zirconium or the like, but it is difficult to completely suppress the elution even when laked. And when compounding these dyes with elution properties into oily point makeup cosmetics, there is a safety problem of dyeing on the skin and lips, and in using them, there are various factors such as the amount of compounding. I had to consider the constraints. On the other hand, the above publication does not suggest or describe the organic powder for solving the problem of being dissolved in water or a solvent and being dyed on the skin or the lips.
【０００４】この問題を解決する手段として、着色剤と
してタール色素を使用しないことが考えられるが、その
ような油性ポイントメイクアップ化粧料ではごく限られ
た色調しか作り出すことができず、皮膚や唇に塗布して
色彩をほどこし、艶をあたえ、表情を魅力的に見せると
いうポイントメイクアップ化粧料の本来の目的を十分に
果たせない。As a means for solving this problem, it is considered not to use tar pigments as colorants, but such oily point makeup cosmetics can produce only a very limited color tone, and thus skin and lips. Applying to, applying color, giving luster, and making the expression look attractive. The original purpose of makeup cosmetics cannot be fully fulfilled.
【０００５】本発明者は、タール色素を油性ポイントメ
イクアップ化粧料に用いるという前提で、タール色素の
持つ問題点、すなわち色素染着性による皮膚障害、化粧
効果の不十分さを解決せんとして、鋭意検討を行った結
果、Ｎ−アシルリジンによって表面処理されたタール色
素およびそのレーキ類を配合することによって、色素の
溶出性、皮膚や唇への染着性がほとんどないために安全
性が極めて高く、またこの表面処理によって色素の皮膚
や唇への付着性が向上し、化粧くずれしにくい油性ポイ
ントメイクアップ化粧料を得られることを見いだし、本
発明を完成するに至った。On the premise that the tar dye is used in an oily point make-up cosmetics, the present inventor intends to solve the problems of the tar dye, that is, the skin damage due to the dye stainability and the insufficient cosmetic effect. As a result of diligent studies, by incorporating a tar pigment surface-treated with N-acyllysine and its lakes, the elution of the pigment and the dyeing property on the skin and the lips are hardly observed, and therefore the safety is extremely high. Furthermore, they have found that this surface treatment improves the adhesion of the pigment to the skin and lips, and that an oily point makeup cosmetic that does not easily lose the makeup can be obtained, and has completed the present invention.
【０００６】すなわち本発明は、色素の皮膚や唇への染
着を抑制し、安全性が高いと同時に化粧効果の持続に優
れる油性ポイントメイクアップ化粧料を提供することを
目的とするものである。[0006] That is, an object of the present invention is to provide an oily point make-up cosmetic composition which suppresses the dyeing of the pigment on the skin and the lips, and is highly safe and at the same time excellent in the cosmetic effect lasting. .
【０００７】[0007]
【課題を解決するための手段】上記の目的を達成するた
めに、本発明の油性ポイントメイクアップ化粧料は、つ
ぎのような構成をとる。すなわち、処理物１００重量部
に対して１〜２０重量部のＮ−アシルリジンで表面処理
されたタール色素を含有することを特徴とする油性ポイ
ントメイクアップ化粧料である。In order to achieve the above object, the oily point makeup cosmetic of the present invention has the following constitution. That is, the oily point makeup cosmetic is characterized by containing 1 to 20 parts by weight of the tar dye surface-treated with N-acyl lysine based on 100 parts by weight of the treated product.
【０００８】以下に本発明の構成を詳説する。本発明に
用いられるＮ−アシルリジンとしては、炭素数８〜２２
の脂肪族アシル基を１つ以上分子内に有するものであっ
て、例えばＮ−カプロイルリジン、Ｎ−ラウロイルリジ
ン、Ｎ−ミリストイルリジン、Ｎ−パルミトイルリジ
ン、Ｎ−ステアロイルリジン、およびＮ−ココイルリジ
ン等が挙げられるが、それらの中で、炭素数１２のＮ−
ラウロイルリジンが特に好ましい。The structure of the present invention will be described in detail below. The N-acyl lysine used in the present invention has 8 to 22 carbon atoms.
Which has one or more aliphatic acyl groups in the molecule, such as N-caproyl lysine, N-lauroyl lysine, N-myristoyl lysine, N-palmitoyl lysine, N-stearoyl lysine, and N-cocoyl lysine. Among them, among them, N- having 12 carbon atoms
Lauroyl lysine is particularly preferred.
【０００９】本発明に用いられるタール色素は、化粧品
に使用できるタール色素のうち、酸性染料に分類される
ものであり、それらを列記するならば、赤色２号、赤色
３号、赤色１０２号、赤色１０４号、赤色１０５号、赤
色１０６号、黄色４号、黄色５号、緑色３号、青色１
号、青色２号、赤色２０１号、赤色２２７号、赤色２３
０号の（１）、赤色２３０号の（２）、赤色２３１号、
赤色２３２号、橙色２０５号、橙色２０７号、黄色２０
１号、黄色２０２号の（１）、黄色２０２号の（２）、
黄色２０３号、緑色２０１号、緑色２０４号、緑色２０
５号、青色２０２号、青色２０３号、青色２０５号、褐
色２０１号、赤色４０１号、赤色５０２号、赤色５０３
号、赤色５０４号、赤色５０６号、橙色４０２号、黄色
４０２号、黄色４０３号の（１）、黄色４０６号、黄色
４０７号、緑色４０１号、緑色４０２号、紫色４０１
号、黒色４０１号およびこれらのレーキ類が挙げられ
る。また、化粧効果の持続性向上という観点では、これ
ら酸性染料以外のタール色素にも適用できる。The tar pigments used in the present invention are classified into acid dyes among the tar pigments that can be used in cosmetics. To list them, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1
No. 2, Blue No. 2, Red No. 201, Red No. 227, Red No. 23
No. 0 (1), Red 230 (2), Red 231
Red No. 232, Orange No. 205, Orange No. 207, Yellow 20
No. 1, Yellow No. 202 (1), Yellow No. 202 (2),
Yellow 203, Green 201, Green 204, Green 20
No. 5, Blue No. 202, Blue No. 203, Blue No. 205, Brown No. 201, Red No. 401, Red No. 502, Red No. 503
No. 1, Red 504, Red 506, Orange 402, Yellow 402, Yellow 403 (1), Yellow 406, Yellow 407, Green 401, Green 402, Purple 401
No. 401, Black No. 401 and their lakes. Further, from the viewpoint of improving the sustainability of the cosmetic effect, it can be applied to tar pigments other than these acid dyes.
【００１０】タール色素およびそのレーキ類の表面処理
をするＮ−アシルリジンの量は、処理物１００重量部に
対し１〜２０重量部が好ましく、さらに好ましくは５〜
１０重量部である。The amount of N-acyl lysine for surface-treating tar dyes and lakes thereof is preferably 1 to 20 parts by weight, more preferably 5 to 100 parts by weight.
10 parts by weight.
【００１１】Ｎ−アシルリジンでタール色素およびその
レーキ類を表面処理する方法としては、例えばタール色
素を酸性水溶液に分散した溶液に、Ｎ−アシルリジンを
強アルカリ溶液中に溶解させた溶液を投入し、撹拌し、
ついで脱塩した後、乾燥、粉砕するという方法がある。As a method of surface-treating a tar dye and its lakes with N-acyl lysine, for example, a solution in which a tar dye is dispersed in an acidic aqueous solution is charged with a solution in which N-acyl lysine is dissolved in a strong alkaline solution. Stir,
Then, after desalting, there is a method of drying and crushing.
【００１２】本発明で用いる、Ｎ−アシルリジン処理タ
ール色素およびそのレーキ類の配合量は、製剤総量を基
準として、０．１〜６０．０重量％が好ましい。The blending amount of the N-acyllysine-treated tar dye and its lakes used in the present invention is preferably 0.1 to 60.0% by weight based on the total amount of the formulation.
【００１３】本発明の油性ポイントメイクアップ化粧料
には、必須成分であるＮ−アシルリジンにより表面処理
されたタール色素およびそのレーキ類以外に、本発明の
目的を損なわない範囲で、パラフィン、セレシン、ミツ
ロウ、キャンデリラロウ等の固形油性原料、ワセリン、
ラノリン、イソステアリン酸硬化ヒマシ油等のペースト
状油性原料、流動パラフィン、スクワラン、シリコーン
油、ヒマシ油等の液状油性原料、ベンガラ、黄酸化鉄、
黒酸化鉄、グンジョウ、酸化チタン、雲母チタン等の無
機顔料、タルク、マイカ等の体質顔料、抗酸化剤、防腐
剤、および香料等を配合することができる。In the oily point makeup cosmetic of the present invention, in addition to the tar dye surface-treated with N-acyllysine which is an essential component and its lakes, paraffin, ceresin, and Solid oily materials such as beeswax and candelilla wax, vaseline,
Paste-like oily raw materials such as lanolin, isostearic acid hydrogenated castor oil, liquid oily raw materials such as liquid paraffin, squalane, silicone oil, castor oil, red iron oxide, yellow iron oxide,
Inorganic pigments such as black iron oxide, red iron oxide, titanium oxide, and mica titanium, extender pigments such as talc and mica, antioxidants, preservatives, and fragrances can be added.
【００１４】本発明の油性ポイントメイクアップ化粧料
は、常法に従って、例えば、口紅、アイシャドウ、フェ
ースカラー等の剤型に製造し、使用することが可能であ
る。The oily point make-up cosmetic composition of the present invention can be manufactured into a dosage form such as lipstick, eye shadow, face color and the like according to a conventional method and used.
【００１５】[0015]
【実施例】以下、実施例および比較例を挙げ本発明を詳
説するが、これらに限定されるものではない。また、本
発明に使用した方法および評価項目は下記の通りであ
る。なお、実施例に示す％とは重量％である。EXAMPLES The present invention will be described in detail below with reference to examples and comparative examples, but the invention is not limited thereto. The methods and evaluation items used in the present invention are as follows. In addition,% shown in the examples is% by weight.
【００１６】（評価試験方法）女性パネラー９５名を用
い、実施例試料と比較例試料を塗布し、４時間の化粧も
ちを５点採点法で評価した。さらに、クレンジング料に
てふきとる際に、皮膚や唇への色素の染着具合を比較し
同じく５点採点法で評価した。 〔化粧もち〕 ５： 良い ４： やや良い ３： 普通 ２： やや悪い １： 悪い 〔ふきとり時の染着具合〕 ５： 簡単にきれいにふきとれた ４： ややふきとるのに手間がかかった ３： ふきとるのに手間がかかったが、色は残らなかっ
た ２： 少し色がのこってしまったが気にはならない程度
である １： 色が残ってしまった(Evaluation test method) Using 95 female panelists, the sample of the example and the sample of the comparative example were applied, and the makeup glutinousness for 4 hours was evaluated by the 5-point scoring method. Furthermore, when wiped off with a cleansing agent, the degree of dyeing of the pigment on the skin and the lips was compared, and the same 5 point scoring method was used. [Makeup] 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Poor [Dyeing condition when wiping off] 5: Easy and clean wiped 4: Somewhat troublesome to wipe off 3: Wipe off It took a lot of time, but the color didn't remain 2: The color was a little overgrown but not noticeable 1: The color remained
【００１７】実施例１〜２、比較例１〜２（口紅） 表１に記載の通り、本発明に係わる成分を配合した実施
例および無配合の比較例を、下記組成のオイルベースに
加えて通常の方法で調製した。これらにつき、前記試験
を行った。Examples 1 and 2 and Comparative Examples 1 and 2 (lipstick) As shown in Table 1, examples in which the components according to the present invention were blended and non-blended comparative examples were added to an oil base having the following composition. Prepared in the usual way. For these, the above-mentioned test was conducted.
【００１８】 〔成 分 名〕 ％ １．キャンデリラロウ ５．０ ２．セレシン ８．０ ３．マイクロスタリンワックス ５．０ ４．ワセリン １５．０ ５．ヒマシ油 ２０．０ ６．リンゴ酸ジイソステアリル １２．０ ７．２−オクチルドデカノール ６．０ （計） （７１．０）[Component name]% 1. Candelilla Row 5.0 2. Ceresin 8.0 3. Microstarin wax 5.0 4. Vaseline 15.0 5. Castor oil 20.0 6. Diisostearyl malate 12.0 7.2-Octyldodecanol 6.0 (total) (71.0)
【００１９】[0019]
【表１】 [Table 1]
【００２０】実施例３〜４、比較例３〜４（アイシャド
ウ） 表２に記載の通り、本発明に係わる成分を配合した実施
例および無配合の比較例を、下記組成のオイルベースに
加えて通常の方法で調製した。これらにつき、前記試験
を行った。Examples 3 to 4 and Comparative Examples 3 to 4 (Eyeshadow) As shown in Table 2, the examples in which the components according to the present invention were blended and the non-blended comparative examples were added to the oil base having the following composition. And prepared by a usual method. For these, the above-mentioned test was conducted.
【００２１】 〔成 分 名〕 ％ １．キャンデリラロウ ６．０ ２．カルナウバロウ ３．０ ３．マイクロスタリンワックス ９．０ ４．ヒマシ油 ２０．０ ５．ラノリン ８．０ ６．ミリスチン酸イソプロピル １２．０ （計） （５８．０）[Component name]% 1. Candelilla Row 6.0 2. Carnauba Blow 3.0 3. Microstarin wax 9.0 4. Castor oil 20.0 5. Lanolin 8.0 6. Isopropyl myristate 12.0 (total) (58.0)
【００２２】[0022]
【表２】 [Table 2]
【００２３】実施例５〜６、比較例５〜６（フェースカ
ラー） 表３に記載の通り、本発明に係わる成分を配合した実施
例および無配合の比較例を、下記組成のオイルベースに
加えて通常の方法で調製した。これらにつき、前記試験
を行った。Examples 5 to 6 and Comparative Examples 5 to 6 (Face Color) As shown in Table 3, the examples in which the components according to the present invention were blended and the non-blended comparative examples were added to the oil base having the following composition. And prepared by a usual method. For these, the above-mentioned test was conducted.
【００２４】 〔成 分 名〕 ％ １．パラフィン ８．０ ２．オゾケライト ６．０ ３．ミツロウ ２．０ ４．イソステアリン酸硬化ヒマシ油 １０．０ ５．トリオクタン酸グリセリル ６．０ （計） （３２．０）[Component name]% 1. Paraffin 8.0 2. Ozokelite 6.0 3. Beeswax 2.0 4. Isostearic acid hydrogenated castor oil 10.0 5. Glyceryl trioctanoate 6.0 (total) (32.0)
【００２５】[0025]
【表３】 [Table 3]
【００２６】各実施例および比較例の試験結果を一括し
て、表４に示す。The test results of each Example and Comparative Example are collectively shown in Table 4.
【００２７】[0027]
【表４】 [Table 4]
【００２８】表４に記載した通り、実施例１〜２の口
紅、実施例３〜４のアイシャドウ、実施例５〜６のフェ
ースカラーは、化粧もちが良く、また皮膚や唇への染着
性も低いことがわかる。As shown in Table 4, the lipsticks of Examples 1 and 2, the eye shadows of Examples 3 and 4, and the face colors of Examples 5 and 6 had good makeup lasting and were dyed on the skin and lips. It can be seen that the sex is low.
【００２９】[0029]
【発明の効果】本発明の油性ポイントメイクアップ化粧
料は、皮膚や唇への染着がなく、化粧効果の持続に優れ
る。また、皮膚や唇への染着がないため安全性に優れる
ことは明らかである。EFFECTS OF THE INVENTION The oily point makeup cosmetics of the present invention do not stain the skin and lips and are excellent in sustaining the cosmetic effect. Further, it is clear that it is excellent in safety because it does not stain the skin or lips.
Claims (2)
たタール色素およびそのレーキ類を少なくとも１種以上
含有することを特徴とする油性ポイントメイクアップ化
粧料。1. An oily point make-up cosmetic comprising at least one tar pigment surface-treated with N-acyl lysine and its lakes.
料である請求項１記載の油性ポイントメイクアップ化粧
料。2. The oily point makeup cosmetic according to claim 1, wherein the tar dye and its lakes are acid dyes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6028494A JPH07242515A (en) | 1994-03-03 | 1994-03-03 | Oil-based point make-up cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6028494A JPH07242515A (en) | 1994-03-03 | 1994-03-03 | Oil-based point make-up cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07242515A true JPH07242515A (en) | 1995-09-19 |
Family
ID=13137704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6028494A Pending JPH07242515A (en) | 1994-03-03 | 1994-03-03 | Oil-based point make-up cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07242515A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5851426A (en) * | 1996-06-17 | 1998-12-22 | Shin-Etsu Chemical Co., Ltd. | Twisted nematic liquid crystal composition containing a silacyclohexane compound |
| JP2006273829A (en) * | 2005-03-25 | 2006-10-12 | Ookemu Tsusho Kk | Powder for cosmetic and the resultant cosmetic |
-
1994
- 1994-03-03 JP JP6028494A patent/JPH07242515A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5851426A (en) * | 1996-06-17 | 1998-12-22 | Shin-Etsu Chemical Co., Ltd. | Twisted nematic liquid crystal composition containing a silacyclohexane compound |
| JP2006273829A (en) * | 2005-03-25 | 2006-10-12 | Ookemu Tsusho Kk | Powder for cosmetic and the resultant cosmetic |
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