JPH07304604A - Cleaning agent - Google Patents
Cleaning agentInfo
- Publication number
- JPH07304604A JPH07304604A JP12061694A JP12061694A JPH07304604A JP H07304604 A JPH07304604 A JP H07304604A JP 12061694 A JP12061694 A JP 12061694A JP 12061694 A JP12061694 A JP 12061694A JP H07304604 A JPH07304604 A JP H07304604A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning agent
- propanediol
- bromo
- hydroxybenzoate
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 9
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims abstract description 14
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims abstract description 12
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 23
- 239000003599 detergent Substances 0.000 claims description 23
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 claims description 23
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 claims description 5
- 239000000539 dimer Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 18
- 239000007787 solid Substances 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 230000002070 germicidal effect Effects 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- DYRDKSSFIWVSNM-UHFFFAOYSA-N acetoacetanilide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1 DYRDKSSFIWVSNM-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 20
- 239000000126 substance Substances 0.000 description 14
- 230000002378 acidificating effect Effects 0.000 description 12
- 239000003899 bactericide agent Substances 0.000 description 12
- 241000894006 Bacteria Species 0.000 description 11
- 229910021529 ammonia Inorganic materials 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000003814 drug Substances 0.000 description 8
- 229940079593 drug Drugs 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000012528 membrane Substances 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 229960000686 benzalkonium chloride Drugs 0.000 description 3
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 230000002459 sustained effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- XIBIADJKGLWYMV-UHFFFAOYSA-N 1-bromo-2-nitropropane-1,3-diol Chemical compound OCC(C(O)Br)[N+]([O-])=O XIBIADJKGLWYMV-UHFFFAOYSA-N 0.000 description 1
- YTIXGBHAPNMOKU-UHFFFAOYSA-N 2-nitropropane-1,3-diol Chemical compound OCC(CO)[N+]([O-])=O YTIXGBHAPNMOKU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、清浄剤に関するもの
で、例えば、男子用トイレの便器内やトイレの洗浄水タ
ンク内等に設置し、洗浄水に接触することにより成分を
徐々に溶出して便器や排水管（トラップ）内におけるス
ケールの付着、悪臭を防止すると共に、カビの発生を抑
制する清浄剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent, which is installed, for example, in a toilet bowl of a men's toilet or a wash water tank of a toilet, and gradually elutes the components by contact with wash water. The present invention relates to a cleaning agent that prevents scale from adhering to a toilet bowl or drain pipe (trap) and foul odors, and suppresses the generation of mold.
【０００２】[0002]
【従来の技術】トイレ、特に男子用トイレの便器や排水
管内においては、細菌の代謝による有機物の分解によっ
て多量のアンモニアが発生してｐＨが上昇し、これに伴
い尿中のカルシウムイオンが同じく尿中に含まれるリン
酸イオンと結合し難溶性のリン酸カルシウムを生成した
り、空気中より供給される炭酸ガスと反応し不溶性の炭
酸カルシウムを生成する。これらが便器や配水管に付着
し、尿石と称されているスケールとして、トイレの悪臭
や汚れの原因となっている。2. Description of the Related Art In toilets, especially in toilets for men's toilets and drainage pipes, a large amount of ammonia is generated due to the decomposition of organic substances due to the metabolism of bacteria, and the pH is increased. It combines with phosphate ions contained therein to form sparingly soluble calcium phosphate, or reacts with carbon dioxide gas supplied from the air to form insoluble calcium carbonate. These adhere to toilet bowls and water pipes, and as scales called urine stones, they cause odors and stains on toilets.
【０００３】従来、このスケールの生成を防止するため
に、スルファミン酸等の酸性物質を利用した薬剤が使用
されている。これは、トイレの便器や排水管内のｐＨが
８〜８．５に上昇した場合にスケールが生成する点に着
目し、酸性物質を添加することによりｐＨの上昇を抑制
してスケールの生成を未然に防止しようとするものであ
る。Conventionally, in order to prevent the formation of this scale, a drug utilizing an acidic substance such as sulfamic acid has been used. Focusing on the fact that scale is generated when the pH in the toilet bowl or drainage pipe of a toilet rises to 8 to 8.5, the increase in pH is suppressed by adding an acidic substance, and the scale is generated in advance. It is something to try to prevent.
【０００４】また、アンモニアの発生原因である細菌の
活動を抑え、これによりｐＨの上昇及びスケール生成を
防止するために、塩化ベンザルコニウム等の殺菌剤も使
用されている。In addition, bactericides such as benzalkonium chloride are also used in order to suppress the activity of bacteria, which is the cause of generation of ammonia, and thereby prevent the rise of pH and the formation of scale.
【０００５】[0005]
【発明が解決しようとする課題】しかし、便器や排水管
内でｐＨが上昇する現象は、上記の通り細菌の代謝する
アンモニアによる作用であるが、このｐＨ上昇は、まず
細菌周辺で部分的にｐＨの上昇が起こるものであり、ま
た、便器や排水管内で壁面に細菌が繁殖すると、その細
菌の膜の周辺にカルシウムイオンが吸着され、濃度が高
くなることが判明した。その結果、従来の酸性物質を利
用した薬剤を使用して便器や排水管内全体のｐＨを７．
０前後に抑制しても、細菌の膜周辺では部分的にｐＨの
上昇及び高濃度のカルシウムイオンが存在する状態とな
り、細菌の膜周辺におけるスケールの生成を防止するこ
とはできない。仮に、細菌の膜周辺におけるｐＨ上昇を
抑制しようとすると、酸性物質を大量に添加する必要が
あり、通常の容量の薬剤では消失までの期間が非常に短
くなってしまい、頻繁に薬剤を補充する必要がある。ま
た、消失までの期間を長くしようとすると、薬剤の大き
さを巨大にする必要があって実用的でない。However, the phenomenon that the pH rises in the toilet bowl or drainage pipe is due to the action of ammonia metabolized by the bacteria as described above. It was also found that when the bacteria propagate on the wall surface in the toilet bowl or drainage pipe, calcium ions are adsorbed around the bacteria membrane and the concentration increases. As a result, the pH of the entire toilet bowl and drainage pipe was adjusted to 7.
Even if it is suppressed to around 0, the increase in pH and the presence of high-concentration calcium ions are partially present around the bacterial membrane, and it is not possible to prevent the generation of scale around the bacterial membrane. If we try to suppress the increase in pH around the bacterial membrane, it is necessary to add a large amount of acidic substances, and with a normal volume of the drug, the period until disappearance is very short, and the drug is frequently replenished. There is a need. Further, if it is attempted to prolong the period until the drug disappears, the size of the drug needs to be enormous, which is not practical.
【０００６】また、従来の酸性物質を利用した薬剤で
は、固体成形する場合、有効成分である酸性物質以外の
基剤を必要とするために、有効成分である酸性物質の相
対濃度が低下すると共に、有効成分である酸性物質と基
剤との間に相溶性がないため成分が不均質となり、使用
中常に一定の効果を得ることができなかった。Further, in the case of a conventional drug using an acidic substance, a base other than the acidic substance which is the active ingredient is required for solid molding, so that the relative concentration of the acidic substance which is the active ingredient decreases. Since there is no compatibility between the acidic substance as the active ingredient and the base, the ingredients became inhomogeneous, and it was not possible to always obtain a certain effect during use.
【０００７】さらに、従来の酸性物質を利用した薬剤を
用いてｐＨを低下させると、スケール生成の原因となる
細菌の活動は抑えることができるが、カビに対して優先
種である細菌の活動が抑制された結果、今度はｐＨ低下
に強いカビの活動が活発となって大量に繁殖し、これが
黒い汚れとなって便器や排水管内に付着し、メンテナン
ス上問題となっていた。[0007] Furthermore, if the pH is lowered by using a conventional drug using an acidic substance, the activity of bacteria that cause scale formation can be suppressed, but the activity of bacteria, which is a priority species against mold, is suppressed. As a result of the suppression, the mold activity that is strong against the pH lowering became active and propagated in large quantities, which became black stains and adhered to the inside of the toilet bowl and drainage pipe, which was a problem for maintenance.
【０００８】また、従来の塩化ベンザルコニウム等の殺
菌剤では、大量に添加しなければスケール生成を防止す
ることはできなかった。In addition, conventional bactericides such as benzalkonium chloride cannot prevent scale formation unless they are added in large amounts.
【０００９】本発明は、上記した従来の酸性物質を利用
した薬剤や殺菌剤の持つ欠点を解消するためになされた
ものであり、少量でスケールの生成及び悪臭を防止する
と共に、カビの繁殖も抑えることのできる清浄剤を提供
することを目的とするものである。The present invention has been made in order to solve the above-mentioned drawbacks of the conventional chemicals and bactericides using an acidic substance, and prevents the generation of scales and odors with a small amount and also the growth of mold. It is intended to provide a detergent that can be suppressed.
【００１０】[0010]
【課題を解決するための手段】本発明は、細菌の活動を
抑えることにより、アンモニアの発生及びこれに伴うｐ
Ｈ上昇を抑制し、スケールの生成を防止しようとするも
のである。本発明者は、殺菌剤であるＰ−ヒドロキシ安
息香酸ブチル、アセト酢酸メタキシリダイド、アセト酢
酸アリニド又はアセト酢酸オルトトルイダイドの１種以
上を基剤とし、これに同じく殺菌剤である２−ブロモ−
２ニトロ−１，３−プロパンジオールを混合することに
より、制菌作用が高く少量でスケールの生成及び悪臭を
防止すると共に、カビの繁殖も抑えることのできる清浄
剤が形成されることを見出し、本発明を完成した。According to the present invention, by suppressing the activity of bacteria, the generation of ammonia and the accompanying p
It is intended to suppress the increase in H and prevent the generation of scale. The present inventor uses, as a base, one or more kinds of bactericides such as butyl P-hydroxybenzoate, acetoacetic acid metaxylidide, acetoacetic acid alinide or acetoacetic acid orthotoluidide, and a bactericidal agent such as 2-bromo-
It was found that by mixing 2nitro-1,3-propanediol, a detergent having a high bacteriostatic effect, preventing scale formation and malodor with a small amount, and suppressing mold growth can be formed. The present invention has been completed.
【００１１】従って、本発明に係る清浄剤は、Ｐ−ヒド
ロキシ安息香酸ブチル、アセト酢酸メタキシリダイド、
アセト酢酸アリニド又はアセト酢酸オルトトルイダイド
（グループ１）の１種以上を及び２−ブロモ−２ニトロ
−１，３−プロパンジオール（グループ２）を含有する
ことを特徴とするものである。Therefore, the detergent according to the present invention comprises butyl P-hydroxybenzoate, acetoacetic acid metaxylide,
It is characterized by containing at least one kind of acetoacetic acid alinide or acetoacetic acid orthotoluidide (group 1) and 2-bromo-2nitro-1,3-propanediol (group 2).
【００１２】上記Ｐ−ヒドロキシ安息香酸ブチル、アセ
ト酢酸メタキシリダイド、アセト酢酸アリニド又はアセ
ト酢酸オルトトルイダイド（グループ１）の１種以上
は、２０〜９０重量％、好ましくは３０〜７０重量％、
また２−ブロモ−２ニトロ−１，３−プロパンジオール
（グループ２）は１０〜８０重量％、好ましくは３０〜
７０重量％の配合量とするのが望ましい。One or more of the above-mentioned butyl P-hydroxybenzoate, metaxylacetoacetate, alinide acetoacetate or orthotoluidide acetoacetate (Group 1) is 20 to 90% by weight, preferably 30 to 70% by weight,
Further, 2-bromo-2nitro-1,3-propanediol (group 2) is 10 to 80% by weight, preferably 30 to
It is desirable that the compounding amount be 70% by weight.
【００１３】[0013]
【作用】本発明の清浄剤は、細菌の膜上に吸着する性質
を持ち、吸着後、細菌の活動を阻害してアンモニアの発
生が抑制されｐＨの上昇が抑えられると共に、カルシウ
ムイオンの細菌周辺への吸着を防止するため、スケール
の付着が防止される。また、カビの活動も抑制されるた
め、カビの発生も防止できる。The detergent of the present invention has a property of adsorbing on the bacterial membrane, and after adsorbing, it inhibits the activity of bacteria to suppress the generation of ammonia and suppresses the increase of pH, and at the same time, the calcium ion surrounds the bacteria. To prevent the adhesion of scale to the scale. In addition, since the activity of mold is also suppressed, the occurrence of mold can be prevented.
【００１４】また、基剤として殺菌剤であるＰ−ヒドロ
キシ安息香酸ブチル、アセト酢酸メタキシリダイド、ア
セト酢酸アリニド又はアセト酢酸オルトトルイダイドの
１種以上を使用することから、同じく殺菌剤である２−
ブロモ−２ニトロ−１，３−プロパンジオールとの相乗
効果によって少量でも有効にスケールの生成及び悪臭を
防止できる。Further, since one or more kinds of bactericides such as butyl P-hydroxybenzoate, acetoacetic acid metaxylidide, acetoacetic acid alinide or acetoacetic acid orthotoluidide are used as a base, the same bactericidal agent 2-
Due to the synergistic effect with bromo-2nitro-1,3-propanediol, it is possible to effectively prevent scale formation and malodor even in a small amount.
【００１５】さらに、本発明のグループ１の化合物とグ
ループ２の化合物は、相溶性があるため、固体成形され
た清浄剤の成分が均一となり、安定した効果を持続でき
る。Furthermore, since the compound of group 1 and the compound of group 2 of the present invention are compatible with each other, the components of the solid molded detergent are uniform and the stable effect can be maintained.
【００１６】また、本発明の清浄剤は徐溶性に優れてい
るため、消失までに一定量を安定的に供給することがで
きる。基剤であるＰ−ヒドロキシ安息香酸ブチル、アセ
ト酢酸メタキシリダイド、アセト酢酸アリニド又はアセ
ト酢酸オルトトルイダイドの種類及びその配合量を適宜
選択することにより、溶解速度（時間）を調節すること
ができる。Further, since the detergent of the present invention is excellent in sustained solubility, it is possible to stably supply a constant amount before it disappears. The dissolution rate (time) can be adjusted by appropriately selecting the type of butyl P-hydroxybenzoate, acetoacetic acid metaxylideide, acetoacetic acid alinide, or acetoacetic acid orthotoluidide as the base material and the compounding amount thereof.
【００１７】尚、グループ１の化合物の１種以上を、２
０〜９０重量％、好ましくは３０〜７０重量％、またグ
ループ２の化合物を１０〜８０重量％、好ましくは３０
〜７０重量％の配合量として清浄剤を形成した場合が、
制菌作用及びカビ繁殖防止効果が高く、効果的にスケー
ルの生成・悪臭・カビ繁殖防止を実現することができ
る。It should be noted that at least one compound of Group 1 is added to 2
0 to 90% by weight, preferably 30 to 70% by weight and 10 to 80% by weight, preferably 30
When the detergent is formed in an amount of ˜70% by weight,
It has a high bacteriostatic effect and a fungal growth prevention effect, and can effectively achieve scale generation, malodor and mold reproduction prevention.
【００１８】[0018]
【実施例】以下に本発明を、実施例により説明するが、
本発明はこれに限定されるものではない。EXAMPLES The present invention will be described below with reference to examples.
The present invention is not limited to this.
【００１９】実施例１〜３及び比較例１ Ｐ−ヒドロキシ安息香酸ブチルを３０重量％、２−ブロ
モ−２ニトロ−１，３−プロパンジオールを７０重量％
の組成物配合で混合し、固体成形した清浄剤（実施例
１）、アセト酢酸メタキシリダイドを５０重量％、２−
ブロモ−２ニトロ−１，３−プロパンジオールを５０重
量％の組成物配合で混合し、固体成形した清浄剤（実施
例２）、アセト酢酸アリニドを７０重量％、２−ブロモ
−２ニトロ−１，３−プロパンジオールを３０重量％の
組成物配合で混合し、固体成形した清浄剤（実施例３）
を各４０ｇ種々のトイレで使用した場合の清浄剤消滅ま
での日数、排水管内のｐＨ、排水管内のカビの発生、ア
ンモニアの発生濃度、スケール発生の有無を測定し、比
較例１と共に表１に示す。比較例１は、パラジクロルベ
ンゼンを５０重量％、酸性物質であるスルファミン酸を
５０重量％の組成物配合で混合し、固体成形した従来の
酸性物質を利用した薬剤４０ｇである。Examples 1 to 3 and Comparative Example 1 30% by weight of butyl P-hydroxybenzoate and 70% by weight of 2-bromo-2nitro-1,3-propanediol.
50% by weight of acetoacetic acid meta-xylidide mixed with the composition of the above composition and solid-molded detergent (Example 1), 2-
Bromo-2nitro-1,3-propanediol was mixed in a composition formulation of 50% by weight, a solid molded detergent (Example 2), 70% by weight of alinide acetoacetate, 2-bromo-2nitro-1. , 3-Propanediol in a composition formulation of 30% by weight and solid molded detergent (Example 3)
40g each, the number of days until the cleaning agent disappears when used in various toilets, the pH in the drainage pipe, the generation of mold in the drainage pipe, the concentration of ammonia generation, and the presence or absence of scale are measured, and Table 1 is shown together with Comparative Example 1. Show. Comparative Example 1 is 40 g of a drug using a conventional acidic substance, which was solid-molded by mixing paradichlorobenzene in an amount of 50% by weight and sulfamic acid as an acidic substance in an amount of 50% by weight.
【表１】 [Table 1]
【００２０】本実施例１〜３の清浄剤は、２０日後、４
０日後においてもアンモニアの発生濃度が検出限界以下
であることから、長期間細菌の活動を抑えることができ
るものである。また、スケールの発生も見られず、優れ
たスケール防止効果を示している。また、カビの発生も
見られないことから、カビに対しても有効である。さら
に、清浄剤消失までの日数が長いことから、徐溶性に優
れ、長期間にわたって安定した効果を持続できるもので
ある。After 20 days, the cleaning agents of Examples 1 to 3 were treated with 4
Since the generation concentration of ammonia is below the detection limit even after 0 day, the activity of bacteria can be suppressed for a long period of time. In addition, no generation of scale was observed, indicating an excellent scale prevention effect. It is also effective against mold since no mold is observed. Furthermore, since the number of days until the detergent disappears is long, it is excellent in sustained dissolution and can maintain a stable effect for a long period of time.
【００２１】Ｐ−ヒドロキシ安息香酸ブチルを３０重量
％、２−ブロモ−２ニトロ−１，３−プロパンジオール
を７０重量％の組成物配合で混合し、固体成形した上記
実施例１の清浄剤を、新鮮な尿１００ｍｌ＋水道水１０
０ｍｌに対し、５ｐｐｍ、１０ｐｐｍ、５０ｐｐｍ添加
後、３０℃の恒温槽中に投入し、２４時間後、４８時間
後、７２時間後のアンモニア濃度、ｐＨ、スケール量を
観察した。その結果を比較例２〜４と共に表２、表３及
び表４に示す。比較例２は酸性物質であるスルファミン
酸、比較例３は殺菌剤である塩化ベンザルコニウム、比
較例４は殺菌剤である２−ブロモ−２ニトロ−１，３−
プロパンジオールを、それぞれ新鮮な尿１００ｍｌ＋水
道水１００ｍｌに対し、５ｐｐｍ、１０ｐｐｍ、５０ｐ
ｐｍ添加後、３０℃の恒温槽中に投入し、２４時間後、
４８時間後、７２時間後のアンモニア濃度、ｐＨ、スケ
ール量を観察したものである。30% by weight of butyl P-hydroxybenzoate and 70% by weight of 2-bromo-2nitro-1,3-propanediol were mixed in a composition formulation to obtain a solid molded detergent of Example 1 above. , Fresh urine 100ml + tap water 10
After adding 5 ppm, 10 ppm, and 50 ppm to 0 ml, the mixture was placed in a constant temperature bath at 30 ° C., and the ammonia concentration, pH, and scale amount were observed after 24 hours, 48 hours, and 72 hours. The results are shown in Tables 2, 3, and 4 together with Comparative Examples 2-4. Comparative Example 2 is sulfamic acid which is an acidic substance, Comparative Example 3 is a bactericide benzalkonium chloride, and Comparative Example 4 is a bactericide 2-bromo-2nitro-1,3-.
Propanediol is added to 100 ml of fresh urine + 100 ml of tap water at 5 ppm, 10 ppm, and 50 p, respectively.
After adding pm, put into a constant temperature bath at 30 ° C., and after 24 hours,
It is an observation of the ammonia concentration, pH, and scale amount after 48 hours and 72 hours.
【表２】 [Table 2]
【表３】 [Table 3]
【表４】 [Table 4]
【００２２】この観察結果に示されるように、本実施例
の清浄剤は、少量でもアンモニアの発生を抑えることが
でき、またスケールの発生も見られず、優れた制菌効
果、スケール防止効果を奏するものである。また、本実
施例の清浄剤に含まれるグループ２の殺菌剤２−ブロモ
−２ニトロ−１，３−プロパンジオールを単独で使用し
た比較例４の観察結果との対比から明らかなように、本
実施例の清浄剤はグループ１の殺菌剤Ｐ−ヒドロキシ安
息香酸ブチルと、グループ２の殺菌剤２−ブロモ−２ニ
トロ−１，３−プロパンジオールとの相乗効果によっ
て、制菌効果及びスケール防止効果の向上が実現されて
いる。As can be seen from these observation results, the detergent of this example can suppress the generation of ammonia even in a small amount, and the generation of scale is not observed, and thus the detergent has an excellent antibacterial effect and scale prevention effect. It plays. In addition, as is clear from the comparison with the observation result of Comparative Example 4 in which the bactericide 2-bromo-2nitro-1,3-propanediol of Group 2 contained in the detergent of this Example was used alone, The detergents of the Examples are synergistically effective by the synergistic effect of the group 1 germicide P-hydroxybenzoate butyl and the group 2 germicide 2-bromo-2nitro-1,3-propanediol. Has been realized.
【００２３】[0023]
【発明の効果】本発明の清浄剤は、基剤として用いる殺
菌剤であるＰ−ヒドロキシ安息香酸ブチル、アセト酢酸
メタキシリダイド又はアセト酢酸アリニドの１種以上と
同じく殺菌剤である２−ブロモ−２ニトロ−１，３−プ
ロパンジオールとの相乗効果によって、少量でも有効に
スケールの生成を防止できる。また、カビの活動も抑制
するため、カビの発生も防止できる。さらに、本発明の
清浄剤に含まれるグループ１の化合物とグループ２の化
合物は、相溶性があるため、固体成形された清浄剤の成
分が均一となり、安定した効果を持続できる。また、本
発明の清浄剤は徐溶性に優れているため、消失までに一
定量を安定的に供給することができると共に、基剤であ
るＰ−ヒドロキシ安息香酸ブチル、アセト酢酸メタキシ
リダイド又はアセト酢酸アリニドの種類及びその配合量
を適宜選択することにより、溶解速度（時間）を調節す
ることができる。EFFECTS OF THE INVENTION The detergent of the present invention is a bactericide used as a base, such as butyl P-hydroxybenzoate, acetoacetic acid metaxylidide or acetoacetic acid alinide, and a bactericidal agent such as 2-bromo-2nitro. Due to the synergistic effect with -1,3-propanediol, the formation of scale can be effectively prevented even in a small amount. In addition, since the activity of mold is also suppressed, the occurrence of mold can be prevented. Furthermore, since the compound of group 1 and the compound of group 2 contained in the detergent of the present invention are compatible with each other, the components of the detergent molded in a solid form are uniform and a stable effect can be maintained. Further, since the detergent of the present invention is excellent in sustained dissolution, it can be stably supplied in a constant amount until it disappears, and at the same time, butyl P-hydroxybenzoate, acetoacetic acid metaxylidide or acetoacetic acid alinide can be used as a base. The dissolution rate (time) can be adjusted by appropriately selecting the type and the blending amount thereof.
フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ａ０１Ｎ 37:10） (Ａ０１Ｎ 33/20 37:22） Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display area A01N 37:10) (A01N 33/20 37:22)
Claims (3)
酢酸メタキシリダイド、アセト酢酸アリニド又はアセト
酢酸オルトトルイダイド（グループ１）の１種以上及び
２−ブロモ−２ニトロ−１，３−プロパンジオール（グ
ループ２）を含有することを特徴とする清浄剤。1. One or more of butyl P-hydroxybenzoate, metaxylacetacetoacetate, alinide acetoacetate or orthotoluideide acetoacetate (group 1) and 2-bromo-2nitro-1,3-propanediol (group 2). ) Is contained in the detergent.
酢酸メタキシリダイド、アセト酢酸アリニド又はアセト
酢酸オルトトルイダイド（グループ１）の１種以上を２
０〜９０重量％及び２−ブロモ−２ニトロ−１，３−プ
ロパンジオール（グループ２）を１０〜８０重量％含有
することを特徴とする請求項１記載の清浄剤。2. One or more of butyl P-hydroxybenzoate, acetoacetic acid meta-xylidide, acetoacetic acid alinide or acetoacetic acid orthotoluidide (group 1) is used as a dimer.
The cleaning agent according to claim 1, which comprises 0 to 90% by weight and 10 to 80% by weight of 2-bromo-2nitro-1,3-propanediol (Group 2).
酢酸メタキシリダイド、アセト酢酸アリニド又はアセト
酢酸オルトトルイダイド（グループ１）の１種以上を３
０〜７０重量％及び２−ブロモ−２ニトロ−１，３−プ
ロパンジオール（グループ２）を３０〜７０重量％含有
することを特徴とする請求項２記載の清浄剤。3. At least one of butyl P-hydroxybenzoate, acetoacetic acid metaxylidide, acetoacetic acid alinide or acetoacetic acid orthotoluidide (group 1) is used in an amount of 3 or more.
The detergent according to claim 2, which comprises 0 to 70% by weight and 30 to 70% by weight of 2-bromo-2nitro-1,3-propanediol (Group 2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12061694A JP3292590B2 (en) | 1994-05-10 | 1994-05-10 | Detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12061694A JP3292590B2 (en) | 1994-05-10 | 1994-05-10 | Detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07304604A true JPH07304604A (en) | 1995-11-21 |
| JP3292590B2 JP3292590B2 (en) | 2002-06-17 |
Family
ID=14790657
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12061694A Expired - Fee Related JP3292590B2 (en) | 1994-05-10 | 1994-05-10 | Detergent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3292590B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001072502A (en) * | 1999-09-03 | 2001-03-21 | Nippon Soda Co Ltd | Slimicide |
| JP2003335605A (en) * | 1998-09-04 | 2003-11-25 | Nippon Soda Co Ltd | Slime-preventing agent |
| US6927199B2 (en) | 1998-09-01 | 2005-08-09 | Nippon Soda Co., Ltd | Slime remover and slime preventing/removing agent containing a clathrate compound |
| JP2013249431A (en) * | 2012-06-02 | 2013-12-12 | Koseiken:Kk | Scale growth-suppressing type degerming/deodorizing cleanser |
-
1994
- 1994-05-10 JP JP12061694A patent/JP3292590B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6927199B2 (en) | 1998-09-01 | 2005-08-09 | Nippon Soda Co., Ltd | Slime remover and slime preventing/removing agent containing a clathrate compound |
| US7098174B2 (en) | 1998-09-01 | 2006-08-29 | Nippon Soda Co., Ltd. | Slime remover and slime preventing/removing agent |
| JP2003335605A (en) * | 1998-09-04 | 2003-11-25 | Nippon Soda Co Ltd | Slime-preventing agent |
| JP2001072502A (en) * | 1999-09-03 | 2001-03-21 | Nippon Soda Co Ltd | Slimicide |
| JP2013249431A (en) * | 2012-06-02 | 2013-12-12 | Koseiken:Kk | Scale growth-suppressing type degerming/deodorizing cleanser |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3292590B2 (en) | 2002-06-17 |
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