JPH073158Y2 - Heat exchange tank - Google Patents

Heat exchange tank

Info

Publication number
JPH073158Y2
JPH073158Y2 JP1987044961U JP4496187U JPH073158Y2 JP H073158 Y2 JPH073158 Y2 JP H073158Y2 JP 1987044961 U JP1987044961 U JP 1987044961U JP 4496187 U JP4496187 U JP 4496187U JP H073158 Y2 JPH073158 Y2 JP H073158Y2
Authority
JP
Japan
Prior art keywords
heat exchange
tank
pipe
cooling
flange portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP1987044961U
Other languages
Japanese (ja)
Other versions
JPS63154965U (en
Inventor
佐吉 川角
富夫 陶山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoshizaki Electric Co Ltd
Original Assignee
Hoshizaki Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoshizaki Electric Co Ltd filed Critical Hoshizaki Electric Co Ltd
Priority to JP1987044961U priority Critical patent/JPH073158Y2/en
Publication of JPS63154965U publication Critical patent/JPS63154965U/ja
Application granted granted Critical
Publication of JPH073158Y2 publication Critical patent/JPH073158Y2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Confectionery (AREA)

Description

【考案の詳細な説明】 〔産業上の利用分野〕 本考案は冷却槽、加熱槽等熱交換槽に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial field of application] The present invention relates to a heat exchange tank such as a cooling tank and a heating tank.

〔従来技術〕[Prior art]

熱交換槽の一形式として、有底筒状の槽の外周に熱媒体
が流通する熱交換パイプを上下方向に多段に巻回してな
る熱交換槽がある。特公昭60-48143号公報にはこの種形
式の熱交換槽の一例である冷却槽が示されている。
As one type of heat exchange tank, there is a heat exchange tank in which a heat exchange pipe through which a heat medium flows is wound around a bottomed cylindrical tank in multiple stages in the vertical direction. Japanese Patent Publication No. 60-48143 discloses a cooling tank which is an example of this type of heat exchange tank.

〔考案が解決しようとする問題点〕[Problems to be solved by the invention]

ところで、この種形式の熱交換槽においては、熱交換パ
イプ内を流通する熱媒体と槽内に収容する被熱交換物と
の間で熱交換させて被熱交換物を冷却または加熱するも
のであることから、これら両者間の熱交換効率を可能な
かぎり高めることが望ましい。しかしながら、熱交換パ
イプの互いに隣接する巻回部の内周と槽の外周間には大
きな空隙が存在しており、この空隙が熱交換効率を大き
く低下させる原因となっている。また、熱交換パイプが
槽の外周に的確に巻回されない場合には、熱交換パイプ
内を熱媒体が的確に流通しなくて、これも熱交換効率を
低下させる原因となる。
By the way, in this type of heat exchange tank, heat is exchanged between the heat medium flowing in the heat exchange pipe and the heat exchange object housed in the tank to cool or heat the heat exchange object. Therefore, it is desirable to increase the heat exchange efficiency between them as much as possible. However, there is a large gap between the inner circumference of the adjacent winding portions of the heat exchange pipe and the outer circumference of the tank, and this gap causes a large decrease in heat exchange efficiency. Further, when the heat exchange pipe is not properly wound around the outer circumference of the tank, the heat medium does not flow properly in the heat exchange pipe, which also causes a decrease in heat exchange efficiency.

従って、本考案の目的は、上記した各問題を解消するこ
とにより熱交換効率が高い熱交換槽を煩雑な製作作業を
要することなく提供することにある。
Therefore, an object of the present invention is to provide a heat exchange tank having a high heat exchange efficiency by solving the above-mentioned problems without requiring a complicated production work.

〔問題点を解決するための手段〕[Means for solving problems]

本考案はかかる目的を達成すべく上記した形式の熱交換
槽において、前記槽の底部外周に前記熱交換パイプのパ
イプ径を略ピッチとする所定のリード角で外周に沿って
螺旋状に延びる円弧状の鍔部を設けるとともに、前記熱
交換パイプの巻回開始部に前記鍔部の下側端部に掛止固
定される掛止片を設けた。
In order to achieve the above object, the present invention provides a heat exchange tank of the above-mentioned type, in which a circle extending spirally along the outer periphery of the bottom portion of the tank at a predetermined lead angle with the pipe diameter of the heat exchange pipe being a substantially pitch. An arc-shaped brim portion is provided, and a hooking piece that is hooked and fixed to a lower end portion of the brim portion is provided at a winding start portion of the heat exchange pipe.

[考案の作用・効果] 本考案による熱交換槽においては、熱交換パイプの掛止
片を鍔部の下側端部に掛止固定した状態にて、熱交換パ
イプが鍔部の上面に接するようにして熱交換パイプを鍔
部に沿って巻回すれば、鍔部のリード角が熱交換パイプ
のパイプ径を略ピッチとするものであるため、熱交換パ
イプは巻き始めから巻き終わりに至るまで互いに接する
ようにして槽の外周に所定のリード角で上下方向に多段
に巻回される。したがって、熱交換パイプの槽外周に接
触する長さが最大限に長くなるとともに、巻き始めから
巻き終わりに至るまで所定のリード角で巻回されて流路
抵抗を略均一とされた熱交換パイプ内を熱媒体が的確に
流通し、高い熱交換効率が得られる。
[Operation and effect of the device] In the heat exchange tank according to the present invention, the heat exchange pipe contacts the upper surface of the flange part with the hooking piece of the heat exchange pipe being hooked and fixed to the lower end of the flange part. When the heat exchange pipe is wound along the flange portion in this way, the lead angle of the flange portion makes the pipe diameter of the heat exchange pipe substantially equal to the pitch. Up to the outer circumference of the tank at a predetermined lead angle so as to be in contact with each other. Therefore, the length of the heat exchange pipe in contact with the outer circumference of the tank is maximized, and the heat exchange pipe is wound at a predetermined lead angle from the beginning to the end of winding to make the flow path resistance substantially uniform. The heat medium flows through the inside accurately, and high heat exchange efficiency is obtained.

また、熱交換パイプの掛止片を鍔部の下側端部に掛止固
定した状態にて熱交換パイプが巻回されるものであるた
め、熱交換パイプの巻回作業が容易であり、当該熱交換
槽を容易に製作することができる。
Also, since the heat exchange pipe is wound in a state where the hook piece of the heat exchange pipe is hooked and fixed to the lower end of the collar portion, the work of winding the heat exchange pipe is easy, The heat exchange tank can be easily manufactured.

[実施例] 以下本考案を図面に基づいて説明するに、第1図には本
考案に係る熱交換槽の一実施例である冷却槽10が示され
ている。当該冷却槽10は第9図に示すように冷凍回路に
組込れ、アイスクリーム製造装置、製氷装置の冷却槽と
して使用される。なお、同図において符号21は圧縮機を
示しており、同圧縮機21は接続管路22a、22b、22cを介
して凝縮器23および冷却槽10に互いに接続されて、循環
回路が形成されている。また、接続管路22bにはドライ
ヤ24とキャピラリチューブ25が介装され、かつ接続管路
22a,22b間のバイパス管路22dには電磁開閉弁26が介装さ
れている。かかる冷凍回路においては冷却媒体は開閉弁
26の閉成時管路22a→22b→22cを循環し、開閉弁26が開
成されると管路22a→22b→22cを循環する。
[Embodiment] The present invention will be described below with reference to the drawings. FIG. 1 shows a cooling tank 10 which is an embodiment of a heat exchange tank according to the present invention. As shown in FIG. 9, the cooling tank 10 is incorporated into a refrigeration circuit and used as a cooling tank for an ice cream manufacturing apparatus and an ice making apparatus. In the figure, reference numeral 21 indicates a compressor, and the compressor 21 is connected to the condenser 23 and the cooling tank 10 via connection pipe lines 22a, 22b, 22c to form a circulation circuit. There is. Further, a dryer 24 and a capillary tube 25 are interposed in the connection pipeline 22b, and
An electromagnetic opening / closing valve 26 is interposed in the bypass line 22d between the lines 22a and 22b. In such a refrigeration circuit, the cooling medium is an on-off valve.
When 26 is closed, it circulates through the pipelines 22a → 22b → 22c, and when the on-off valve 26 is opened, it circulates through the pipelines 22a → 22b → 22c.

しかして、冷却槽10は第1図および第2図に示すように
有底の円筒槽11、冷却パイプ12、皿状の支持プレート13
を主要構成部材とし、断熱材層19中に埋設されている。
円筒槽11は上端開口部側へ漸次拡開するテーパ状を呈し
ており、その底部中央部には排出孔11aを備えている。
As shown in FIGS. 1 and 2, the cooling tank 10 has a bottomed cylindrical tank 11, a cooling pipe 12, and a dish-shaped support plate 13.
And is embedded in the heat insulating material layer 19.
The cylindrical tank 11 has a taper shape that gradually expands toward the upper end opening side, and has a discharge hole 11a in the center of the bottom part thereof.

支持プレート13は第1図〜第4図に示すように皿状を呈
し、底部円板13aと、その外周縁に一体的に設けられて
冷却パイプ12のパイプ径を略ピッチとする所定のリード
角で外周に沿って螺旋状に延びる円弧状の鍔部13bを備
えている。底部円板13aの中央部には、円筒槽11の排出
孔11aより大径の開口部13cが形成されており、かつ同開
口部13cの内周縁に一対の内向フランジ部13d、13dが互
いに対向して形成されている。各内向フランジ部13dは
底部円板13aの下面から所定間隔を保って位置してお
り、後述する排水管の接続パイプの接続部として機能す
る。鍔部13bは円弧状のプレート部13b1と、その外周縁
に一体的に形成されて下方へ折れ曲がる傾斜部13b2とか
らなり、第3図にて詳細に示したように、底部円板13a
の外周縁にて略7/8周延びている。かかる支持プレート1
3は円筒槽11の底部にこれと同心的に外嵌してスポット
溶接にて固着されており、円筒槽11の排出孔11aが支持
プレート13の開口部13cの中央に臨んでいる。
The support plate 13 has a dish shape as shown in FIGS. 1 to 4, and is provided with a bottom disc 13a and an outer periphery of the bottom disc 13a integrally with each other, and a predetermined lead having a pipe diameter of the cooling pipe 12 of substantially a pitch. It is provided with an arc-shaped brim portion 13b that spirally extends along the outer periphery at the corners. An opening 13c having a diameter larger than that of the discharge hole 11a of the cylindrical tank 11 is formed in the center of the bottom disk 13a, and a pair of inward flange portions 13d, 13d are opposed to each other on the inner peripheral edge of the opening 13c. Is formed. Each inward flange portion 13d is located at a predetermined distance from the lower surface of the bottom disc 13a, and functions as a connecting portion of a connecting pipe of a drain pipe described later. The collar portion 13b is composed of an arc-shaped plate portion 13b1 and an inclined portion 13b2 integrally formed on the outer peripheral edge thereof and bent downward, and as shown in detail in FIG.
Extends about 7/8 around the outer edge. Such support plate 1
3 is concentrically fitted to the bottom of the cylindrical tank 11 and fixed by spot welding, and the discharge hole 11a of the cylindrical tank 11 faces the center of the opening 13c of the support plate 13.

冷却パイプ12は円筒状の長尺のもので、その巻回開始部
には第5図(a)、(b)に示すように掛止片12aが溶
接されている。この掛止片12aと冷却パイプ12の外周間
の間隔は、支持プレート13の鍔部13bにおけるプレート
部13b1の下側端部13b3が嵌合する大きさに形成されてい
る。かかる冷却パイプ12は上記掛止片12aを鍔部13bの下
側端部13b3に掛止することにより固定され、円筒槽11の
外周に予じめ貼着された可撓性材料からなる被覆層14の
外周に鍔部13bのプレート部13b1の上面に沿って巻回さ
れる。これにより、冷却パイプ12は鍔部13bのプレート
部13b1に応じた所定のリード角にて上下方向に多段に巻
回されるとともに、冷却パイプ12の互いに隣接する巻回
部12b、12bと円筒槽11の外周11b間には第6図に示すよ
うに被覆層14が変形して充填される。鍔部13bにおける
傾斜部13b2は、冷却パイプ12の巻回初期におけるプレー
ト部13b1へのガイドと損傷を防止すべく機能する。な
お、被覆層14は熱伝導性で可撓性材料からなるものであ
るが、本実施例においてはブチルゴム中にカーボンおよ
びアルミナの粉末を混練したものを使用している。ま
た、冷却パイプ12の巻回終端部12cは円筒槽11の上方外
周部に固着した取付片11cにハンダ着けされている。
The cooling pipe 12 has a long cylindrical shape, and a hooking piece 12a is welded to the winding start portion thereof as shown in FIGS. 5 (a) and 5 (b). The interval between the hooking piece 12a and the outer circumference of the cooling pipe 12 is formed to have a size such that the lower end portion 13b3 of the plate portion 13b1 of the flange portion 13b of the support plate 13 is fitted. The cooling pipe 12 is fixed by hooking the hooking piece 12a to the lower end 13b3 of the collar 13b, and a covering layer made of a flexible material preliminarily adhered to the outer periphery of the cylindrical tank 11. It is wound around the outer periphery of 14 along the upper surface of the plate portion 13b1 of the collar portion 13b. Thereby, the cooling pipe 12 is wound in multiple stages in the vertical direction at a predetermined lead angle corresponding to the plate portion 13b1 of the collar portion 13b, and the winding portions 12b and 12b adjacent to each other of the cooling pipe 12 and the cylindrical tank are provided. A coating layer 14 is deformed and filled between the outer peripheries 11b of 11 as shown in FIG. The inclined portion 13b2 of the flange portion 13b functions to prevent the guide portion and the damage to the plate portion 13b1 in the initial winding of the cooling pipe 12. The coating layer 14 is made of a thermally conductive and flexible material, but in this embodiment, butyl rubber mixed with carbon and alumina powder is used. The winding end portion 12c of the cooling pipe 12 is soldered to a mounting piece 11c fixed to the upper outer peripheral portion of the cylindrical tank 11.

かかる状態における冷却槽10は第2図および第3図に示
す状態を呈しており、同冷却槽10には第7図および第8
図に示す接続パイプ15が組付けられる。接続パイプ15は
合成樹脂製のもので、パイプ部15aとその一端に一体的
に設けた一対の取付フランジ部15b、15bを備えている。
各取付フランジ部15bはパイプ部15aの中心を中心とする
同一半径の扇形状を呈していて、支持プレート13の開口
部13cに嵌合する大きさに形成されている。各フランジ
部15bの下面には、下方へ突出するストッパ部15cと一端
側へ漸次肉厚が薄くなるテーパ部15dが形成されてい
て、各フランジ部15bを支持プレート13の開口部13cに嵌
合させてパイプ部15aを持って第3図の矢印A方向に回
動させると、各フランジ部15bはそのテーパ部15d側から
支持プレート13の各内向フランジ部13dと円筒槽11の下
面間に嵌入し、そのストッパ部15cが同フランジ部13dの
端部に当接してそれ以上の回動を規制される。これによ
り、接続パイプ15は円筒槽11の底部に液密的かつ取外し
可能に組付けられ、同槽11の排出孔11aに組付けられ
る。かかる冷却槽10はその内部に直接水を収容して製氷
用冷却槽として、またアイスクリームの素地を入れた容
器を収容してアイスクリーム製造用の冷却槽として使用
される。
The cooling tank 10 in such a state has the state shown in FIGS. 2 and 3, and the cooling tank 10 has the states shown in FIGS.
The connecting pipe 15 shown in the figure is assembled. The connection pipe 15 is made of synthetic resin and includes a pipe portion 15a and a pair of mounting flange portions 15b and 15b integrally provided at one end thereof.
Each mounting flange portion 15b has a fan shape with the same radius centered on the center of the pipe portion 15a, and is formed in a size that fits into the opening portion 13c of the support plate 13. The lower surface of each flange portion 15b is formed with a stopper portion 15c projecting downward and a taper portion 15d whose thickness gradually decreases toward one end side, and each flange portion 15b is fitted into the opening 13c of the support plate 13. When the pipe portion 15a is held and rotated in the direction of arrow A in FIG. Then, the stopper portion 15c comes into contact with the end portion of the flange portion 13d and further rotation is restricted. As a result, the connection pipe 15 is liquid-tightly and detachably attached to the bottom of the cylindrical tank 11 and is attached to the discharge hole 11a of the tank 11. The cooling tank 10 is used as a cooling tank for ice making by directly storing water therein and as a cooling tank for manufacturing ice cream by storing a container containing a base material of ice cream.

かかる構成の冷却槽10においては、冷却パイプ12の互い
に隣接する巻回部12bと円筒槽11の外周11b間には可撓性
の被覆層14が充填されているため、従来これら両者11
b、12b間に形成される如何なる形状の空隙も解消され、
かつ当該被覆層14が熱伝導性の材料からなるため、冷却
媒体と円筒槽11内の水、アイスクリーム素地間の熱の伝
達は冷却パイプ12と円筒槽11との接触部のみならず、被
覆層14を介しても大量に伝達される。従って、かかる冷
却槽10における冷却効率は極めて高い。
In the cooling tank 10 having such a configuration, since the flexible coating layer 14 is filled between the winding portion 12b of the cooling pipe 12 and the outer periphery 11b of the cylindrical tank 11 which are adjacent to each other, both 11
Eliminates any voids formed between b and 12b,
And since the coating layer 14 is made of a heat conductive material, the transfer of heat between the cooling medium and the water in the cylindrical tank 11 and the ice cream base is not limited to the contact portion between the cooling pipe 12 and the cylindrical tank 11, and is also covered. A large amount is also transmitted through the layer 14. Therefore, the cooling efficiency in the cooling tank 10 is extremely high.

また、冷却パイプ12の掛止片12aを鍔部13bの下側端部13
b3に掛止固定した状態にて、冷却パイプ12が鍔部13bの
上面に接するようにして冷却パイプ12を鍔部13bに沿っ
て巻回すれば、鍔部13bのリード角が冷却パイプ12のパ
イプ径を略ピッチとするものであるため、冷却パイプ12
は巻き始めから巻き終わりに至るまで互いに接するよう
にして円筒槽11の外周に所定のリード角で上下方向に多
段に巻回される。したがって、冷却パイプ12の槽外周に
接触する長さが最大限に長くなるとともに、巻き始めか
ら巻き終わりに至るまで所定のリード角で巻回されて流
路抵抗を略均一とされた冷却パイプ12内を冷却媒体が的
確に流通し、高い熱交換効率が得られる。
In addition, the hook 12a of the cooling pipe 12 is attached to the lower end 13 of the collar 13b.
When the cooling pipe 12 is wound and fixed along b3 so that the cooling pipe 12 is in contact with the upper surface of the flange portion 13b, the cooling pipe 12 is wound along the flange portion 13b. Since the diameter of the pipes is approximately the pitch, the cooling pipe 12
Are wound around the outer circumference of the cylindrical tank 11 at predetermined lead angles in multiple stages in the vertical direction so as to be in contact with each other from the beginning to the end of winding. Therefore, the length of the cooling pipe 12 in contact with the outer circumference of the bath is maximized, and the cooling pipe 12 is wound at a predetermined lead angle from the beginning of winding to the end of winding to make the flow path resistance substantially uniform. The cooling medium circulates properly inside, and high heat exchange efficiency is obtained.

また、冷却パイプ12の掛止片12aを鍔部13bの下側端部13
b3に掛止固定した状態にて冷却パイプ12が巻回されるも
のであるため、冷却パイプ12の巻回作業が容易であり、
当該冷却槽を容易に製作することができる。
In addition, the hook 12a of the cooling pipe 12 is attached to the lower end 13 of the collar 13b.
Since the cooling pipe 12 is wound in a state of being locked and fixed to b3, the winding work of the cooling pipe 12 is easy,
The cooling tank can be easily manufactured.

なお、本実施例においては本考案に係る熱交換槽として
冷却槽の例を示したが、本考案は槽の外周に加熱媒体が
流通する加熱パイプを巻回してなる加熱槽に対しても同
様に実施し得る。
In the present embodiment, the example of the cooling tank is shown as the heat exchange tank according to the present invention, but the present invention is the same for the heating tank formed by winding the heating pipe through which the heating medium flows around the outer circumference of the tank. Can be carried out.

【図面の簡単な説明】[Brief description of drawings]

第1図は本考案の一実施例に係る冷却槽の縦断面図、第
2図は断熱材層に埋設する前の冷却槽の側面図、第3図
は同冷却槽の底面図、第4図は支持プレートの側面図、
第5図(a)、(b)は冷却パイプの巻回開始部の拡大
縦断側面図および縦断正面図、第6図は第2図の矢印VI
-VI線方向の拡大縦断面図、第7図は接続パイプの拡
大、面図、第8図は第7図の矢印VIII-VIII線方向の縦
断面図、第9図は冷却槽が組込まれる冷凍回路の概略構
成図である。 符号の説明 10……冷却槽、12……冷却パイプ、12a……掛止片、13
……支持プレート、13b……鍔部、13b3……下側端部。
FIG. 1 is a longitudinal sectional view of a cooling tank according to an embodiment of the present invention, FIG. 2 is a side view of the cooling tank before being embedded in a heat insulating material layer, and FIG. 3 is a bottom view of the cooling tank. The figure shows a side view of the support plate,
5 (a) and 5 (b) are enlarged longitudinal side views and longitudinal front views of the winding start portion of the cooling pipe, and FIG. 6 is an arrow VI in FIG.
-Enlarged vertical sectional view in the direction of the VI line, FIG. 7 is an enlarged sectional view of the connecting pipe, FIG. 8 is a vertical sectional view in the direction of arrows VIII-VIII in FIG. 7, and FIG. It is a schematic block diagram of a refrigeration circuit. Explanation of code 10 …… Cooling tank, 12 …… Cooling pipe, 12a …… Latching piece, 13
…… Support plate, 13b …… Collar, 13b3 …… Lower end.

Claims (1)

【実用新案登録請求の範囲】[Scope of utility model registration request] 【請求項1】有底筒状の槽の外周に熱媒体が流通する熱
交換パイプを上下方向に多段に巻回してなる熱交換槽に
おいて、前記槽の底部外周に前記熱交換パイプのパイプ
径を略ピッチとする所定のリード角で外周に沿って螺旋
状に延びる円弧状の鍔部を設けるとともに、前記熱交換
パイプの巻回開始部に前記鍔部の下側端部に掛止固定さ
れる掛止片を設けたことを特徴とする熱交換槽。
1. A heat exchange tank in which a heat exchange pipe, in which a heat medium flows, is wound around the outer circumference of a bottomed cylindrical tank in multiple stages in the vertical direction, and a pipe diameter of the heat exchange pipe is around the bottom outer circumference of the tank. Is provided with an arc-shaped flange portion that extends spirally along the outer periphery at a predetermined lead angle with a substantially pitch, and is fixed to the lower end of the flange portion at the winding start portion of the heat exchange pipe. A heat exchange tank that is equipped with a hanging piece.
JP1987044961U 1987-03-26 1987-03-26 Heat exchange tank Expired - Lifetime JPH073158Y2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1987044961U JPH073158Y2 (en) 1987-03-26 1987-03-26 Heat exchange tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1987044961U JPH073158Y2 (en) 1987-03-26 1987-03-26 Heat exchange tank

Publications (2)

Publication Number Publication Date
JPS63154965U JPS63154965U (en) 1988-10-12
JPH073158Y2 true JPH073158Y2 (en) 1995-01-30

Family

ID=30863266

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1987044961U Expired - Lifetime JPH073158Y2 (en) 1987-03-26 1987-03-26 Heat exchange tank

Country Status (1)

Country Link
JP (1) JPH073158Y2 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5040260Y2 (en) * 1971-06-08 1975-11-18
JPS6048143A (en) * 1983-08-25 1985-03-15 Ube Ind Ltd Method for producing catalyst for producing unsaturated acids

Also Published As

Publication number Publication date
JPS63154965U (en) 1988-10-12

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