JPH07329452A - Delivery slip - Google Patents

Abstract

(57) [Abstract] [Purpose] To provide a delivery slip that facilitates reuse of an adherend, is suitable for automatic processing by a machine, and has a low manufacturing cost. [Structure] The delivery slip 10 includes a second sheet 12 as a surface base material. An antistatic layer 16 is formed on the back surface of the second sheet 12. On the back surface of the antistatic layer 16,
The adhesive layer 18 is formed. On the back surface of the adhesive layer 18,
The peel control layer 20 is formed. A first sheet 22 as a transparent support is temporarily attached to the back surface of the peeling control layer 20. An adhesive layer 26 is formed on the back surface of the first sheet 22. On the back surface of the pressure-sensitive adhesive layer 26, a third release paper is formed.
Sheet 28 is temporarily attached. The second sheet 12, the first sheet 22, and the third sheet 28 are each made of PE.
Formed from T. Since the first sheet 22 is made of a transparent material, it is easy to reuse the adherend A as a shipping container.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a delivery slip, and more particularly to a delivery slip attached to an article for home delivery.

[0002]

2. Description of the Related Art A conventional delivery voucher is formed by stacking a plurality of paper vouchers and temporarily fixing one end of the vouchers to form a booklet. The multiple slips that make up the delivery slip are
For example, it is used for copy, billing, tabulation, and delivery. Ruled lines and item names are printed on the front surface of each slip, and a pressure-sensitive ink layer for pressure-sensitive copying is formed on the back surface. Therefore, by writing the conventional delivery slip on the uppermost slip, each of the middle or lowermost slips is also copied at once. Further, an adhesive layer is provided on the back surface of the lowermost slip.
With this adhesive layer, the delivery slip can be directly attached to an adherend such as a cardboard.

[0003]

However, the paper delivery slip directly attached to the adherend has a weak strength as compared with the strong adhesive strength of the adhesive, so that it cannot be adhered after use. It is difficult to remove it cleanly from the body and often remains partially. Then, information such as the destination may be complicated, and the aesthetics of the adherend may be impaired. Therefore, it is difficult to reuse an adherend such as a cardboard box to which a delivery slip is once attached for delivery again.
Further, the conventional booklet-shaped delivery slip has a complicated manufacturing process and requires a high manufacturing cost. Further, since the conventional delivery slip is made of paper, it is weak against moisture and easily wrinkles and stains, so that it is difficult to perform automatic processing by a machine and, for example, cannot be printed by a laser printer.

Therefore, a main object of the present invention is to provide a delivery slip that facilitates reuse of an adherend and is suitable for automatic processing by a machine and has a low manufacturing cost.

[0005]

A delivery slip according to the present invention is a transparent first sheet and a second sheet that is detachably temporarily attached to the surface of the first sheet and is used for displaying information. And a pressure-sensitive adhesive layer formed on the back surface of the first sheet, and a third sheet releasably temporarily attached to the pressure-sensitive adhesive layer.
It is a delivery slip. Further, the third sheet may be formed of the same material as the second sheet to prevent curling. Further, a back surface treatment layer for preventing curling may be formed on the back surface of the third sheet. Further, the first sheet, the second sheet, and the third sheet may be made of synthetic resin. Moreover, you may form a peeling adjustment layer between a 1st sheet and a 2nd sheet. Further, an antistatic layer may be formed on the back surface of the second sheet.

[0006]

The delivery slip according to the present invention is adhered to an adherend such as a cardboard box by the adhesive layer exposed by peeling off the third sheet. Information such as a delivery destination and a barcode is written on the surface of the second sheet and used as a slip. In addition, since the first sheet is made of a transparent material, after the second sheet is peeled off, the letters and the like printed on the adherend itself are not covered up and are inconspicuous. Therefore, the information such as the destination does not get complicated, and the aesthetics of the adherend is not impaired.

When the third sheet is made of the same material as the second sheet, or when the back surface treatment layer is formed on the back surface of the third sheet, curling of the delivery slip is prevented. .

Further, when the peeling control layer is formed between the first sheet and the second sheet, the peeling force when peeling the first sheet from the second sheet is adjusted appropriately. It In addition, the peeling control layer does not cause unnecessary tackiness after peeling the first sheet.

Further, when the antistatic layer is formed on the back surface of the second sheet, the charging is prevented when the second sheet is peeled from the front surface of the first sheet.

Furthermore, when the first sheet, the second sheet, and the third sheet are each made of synthetic resin, the water resistance is improved and wrinkles and stains are less likely to occur.

[0011]

According to the delivery slip of the present invention,
Since the first sheet is transparent, it is easy to reuse an adherend such as a cardboard box as a shipping container. Further, since the second sheet temporarily attached on the first sheet is used as a slip, automatic processing by a machine is easy,
For example, printing with a laser printer or the like becomes possible.
Further, since the delivery slip according to the present invention is a single laminated body formed by temporarily attaching the first sheet, the second sheet and the third sheet, Can be omitted, the manufacturing process can be simplified, and the manufacturing cost can be reduced.

The above-mentioned objects, other objects, features and advantages of the present invention will become more apparent from the detailed description of the embodiments below with reference to the drawings.

[0013]

1 is a perspective view showing an embodiment of the present invention, and FIG. 2 is a perspective view showing its usage. further,
FIG. 3 is a cross-sectional schematic view thereof. Delivery slip 1 shown in FIG.
0 contains the 2nd sheet 12 as what is called a surface base material. In this embodiment, the second sheet 12 is formed of a PET (polyethylene terephthalate) film having a thickness of 38 μm, for example. In the second sheet 12,
A plurality of cutting lines 14 are formed in parallel. Second sheet 1
2 is divided into strips 12a, 12b, 12c by a cutting line 14 and peeled off, and used as slips for billing, billing, counting, and delivery, respectively.

A cutting line 14 is formed on the surface of the second sheet 12.
A ruled line or, for example, a bar code that symbolizes information about a destination or the like is printed or printed on each piece divided by. The surface of the second sheet 12 is subjected to treatment such as corona discharge in order to improve printability. Here, improvement of printability includes improvement of suitability for printing with a laser printer, imprinting with a seal stamp, writing with a ballpoint pen, or the like.
By performing the process for improving the printability, it becomes easy to print or write, and it becomes difficult for ink or the like to disappear after printing or writing. The second sheet 12 is not limited to PET, but may be polyester, stretched polypropylene, unstretched polypropylene, cellophane, nylon, polyvinyl alcohol, polystyrene, polypropylene, polyethylene, polyvinyl chloride, or the like.
It may be formed using a material such as polycarbonate.
For each strip 12a-12c divided by the cutting line 14,
Information such as the addressee of the delivery destination is entered by the user.

An antistatic layer 16 is formed on the back surface of the second sheet 12. The antistatic layer 16 is formed by thinly applying a coating type antistatic agent having ion conductivity, such as acrylic resin, on the back surface of the second sheet 12. The antistatic layer 16 is for preventing inconvenience during automatic processing by a machine. That is, in this delivery slip 10, since each sheet is formed using a film made of a synthetic resin, when peeling the second sheet 12 from the first sheet 22 described later,
Static electricity is generated and is easily charged, in which case there is a problem during automatic processing by a machine. Therefore, in order to prevent such an inconvenience, the antistatic layer 16 is provided.

An adhesive layer 18 is provided on the back surface of the antistatic layer 16.
Is formed. In this example, the adhesive layer 18
Is on the back surface of the second sheet 12 and the peeling adjustment layer 20 described later.
And the peeling adjustment layer 20
The second sheet 12 and the later-described first sheet 22 are temporarily attached. For the adhesive layer 18, a mixture of polyurethane resin and polyisocyanate, diisocyanate monomer, rosin derivative, terpene resin, petroleum-based resin, etc. can be selected. It can be the agent layer 18. In addition,
In this embodiment, the term "adhesion" means that the pieces cannot be peeled off easily, and the term "temporary attachment" means that the pieces are temporarily attached so that they can be peeled off relatively easily.

The second sheet 1 is provided on the back surface of the adhesive layer 18.
A peeling adjustment layer 20 is formed for temporarily attaching 2 to a first sheet 22 described later. The peeling adjustment layer 20 appropriately adjusts the peeling force when peeling the second sheet 12 from the first sheet 22 described later. The peeling adjustment layer 20 is a mixture of a resin and a peeling control material and has a property of being temporarily adhered to the sheet surface, and the peeling force is adjusted by the mixture ratio thereof. In this example, a mixture of a polyester-based polyurethane resin and a vinyl chloride / vinyl acetate copolymer in a ratio of 9: 1 is used. However, when the peeling adjustment layer 20 alone is used,
Since it is unstable and may cause so-called squealing and separation, the adhesive layer 18 is provided and the peeling adjustment layer 20 is provided on the second sheet 1.
Stabilized by bonding to 2. The peel adjusting layer 20 of this embodiment is formed by the adhesive layer 18 to the second sheet 12
Since it is adhered to the first sheet 22, it is peeled off together with the second sheet 12 at the interface with the first sheet 22 described later. In addition, after the second sheet 12 is peeled off, if a tackiness remains on the back surface of the second sheet 12 and the front surface of the first sheet 22, a problem occurs in the subsequent work such as automatic processing by a machine. However, in this embodiment, by providing the peeling adjustment layer 20, the tackiness or the tackiness after peeling the second sheet 12 can be eliminated. Peeling adjustment layer 20
Is formed by thinly applying a material in which a resin and a release control agent are mixed. As the resin for forming the peeling adjustment layer 20, polyester-based polyurethane resin, polyvinyl methyl ether, polyamide resin,
Polyvinyl ethyl ether, polyvinyl isobutyl ether, polyester resin, carboxyl modified acrylic resin, chlorinated polypropylene, polyethylene wax, ethylene-acrylic acid copolymer, styrene-isoprene
Styrene block copolymer, ethylene ethyl acrylate resin, terpene resin, paraffin wax, styrene-butadiene-styrene block copolymer, microcrystalline wax, montan wax, cellulose acetate, cellulose acetate butyrate, cellulose acetate cabrate, nitrocellulose, Methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, polyvinyl acetate, vinyl acetate vinyl chloride copolymer, polyvinyl chloride, polyvinyl formal, polyvinyl butyral,
Polyvinyl alcohol, polyvinyl ether, vinyl acetate copolymer, acrylic resin, carboxyl-modified acrylic resin, methacrylic resin, vinyl acetate copolymer,
Polystyrene, polyamide, thermoplastic polyester, polyether, SBS, SIS, NBR, SBR, waxes, polyurethane resin, cellulose propionate,
EVA, acrylic vinyl acetate copolymer resin, etc. can be selected, and these can be used alone or as a mixture of two or more kinds. As the release control material for forming the release control layer 20, vinyl chloride vinyl acetate copolymer, nitrocellulose, or the like can be selected, and these can be used alone or as a mixture of two or more kinds.

A transparent first sheet 22 as a so-called intermediate layer is temporarily attached to the back surface of the peeling control layer 20. First
The sheet 22 of 2 serves as a support for the second sheet 12. As shown in FIG. 3, since the first sheet 22 is formed shorter than the second sheet 12, the notch 24 is formed at the end thereof. By hooking a nail or the like on the cutout 24, the upper layer is easily peeled from the peeling adjustment layer 20. In this embodiment, the first sheet 22 is formed of a colorless and transparent PET film having a thickness of 16 μm, for example. The first sheet 22 is not limited to PET, but is formed using a material such as polyester, stretched polypropylene, unstretched polypropylene, cellophane, nylon, polyvinyl alcohol, polystyrene, polypropylene, polyethylene, polyvinyl chloride, or polycarbonate. You may. Further, an adhesive layer 26 is formed on the back surface of the first sheet 22. The pressure-sensitive adhesive layer 26 of this embodiment is for adhering the delivery slip 10 to an adherend such as a cardboard box as a delivery container so as not to be easily peeled off.

On the back surface of the adhesive layer 26, a silicon-processed third sheet 28 is temporarily attached. Third sheet 28
Has the role of so-called release paper, and the delivery slip 1
When 0 is attached to the adherend, it is peeled off and removed. In this embodiment, the third sheet 28 is formed of the same material as the above-mentioned second sheet 12 and first sheet 22 in order to prevent the entire delivery slip 10 from curling. That is, since the release paper made of paper conventionally used is different from the second sheet 12 in the humidity in the atmosphere and the degree of expansion and contraction due to heat when passing through the laser printer, curling is likely to occur. Therefore, in this embodiment, by making the material of the third sheet 28 as the release paper the same as the material of the second sheet 12, the degree of expansion and contraction of the front surface and the back surface of the delivery slip is balanced to curl. Prevented.

Next, with reference to FIG. 1 and FIG. 2, the use condition of this embodiment will be described. In the delivery slip 10 of this embodiment, the adherend A such as a cardboard box is provided by the adhesive layer 26 exposed by peeling off the third sheet 28.
Affixed to. The second sheet 12 has a surface on which information such as a delivery destination and a barcode is written, and is used as a slip. The second sheet 12 is divided into strips 12a to 12c by the cutting line 14 and is peeled off. The strips 12a to 12c are peeled off and used for each department, for example, as slips for copy, billing, tabulation, and delivery.

When the second sheet 12 is peeled off, the transparent first sheet 22 is exposed. Since the first sheet 22 is made of a colorless and transparent material, it does not obscure the letters and the like printed on the adherend A itself without covering it. Therefore, unlike the prior art, there is no risk that information such as the destination will be complicated, and the aesthetics of an adherend such as a cardboard box used as a shipping container will not be impaired. Therefore, it becomes easy to reuse the adherend A as a shipping container.

Further, the delivery slip 10 is a single laminated product formed by temporarily attaching a plurality of sheets, so that the manufacturing process can be simplified and the manufacturing cost can be reduced. Further, after the second sheet 12 is peeled off, unnecessary peeling is not caused by the action of the peeling adjustment layer 20. Further, the antistatic layer 16 prevents electrification when the second sheet 12 is separated from the surface of the first sheet 22. Further, the first sheet 22, the second sheet 12, and the third sheet
Since each of the sheets 28 is made of synthetic resin, it has high water resistance and is less likely to cause wrinkles or stains. For these reasons, it is suitable for automatic processing by a machine and can be printed by, for example, a laser printer.

FIG. 4 is a schematic sectional view showing another embodiment of the present invention. In the delivery slip shown in FIG. 4, the third sheet 28 as so-called release paper is made of high-quality paper that is PVA-treated and silicon-treated. Then, on the back surface of the third sheet 28, a back surface treatment layer 30 for preventing curling and improving slidability is formed. The back surface treatment layer 30 includes a back surface treatment agent and a lubricant. The lubricant is for preventing paper jam caused by poor slipperiness of the delivery slip 10 when passing through the laser printer. The back surface treating agent can be selected from materials such as acrylic / styrene, acrylic / styrene / wax, and synthetic rubber / wax, and these can be used alone or as a mixture of two or more kinds. The lubricant can be selected from low-molecular weight polyolefin, vinyl acetate-based copolymerized polyolefin, low-density polyolefin, zinc stearate, etc., and these can be used alone or as a mixture of two or more kinds. Also in the embodiment shown in FIG. 4, the same effect as described above can be obtained.

FIG. 5 is a schematic sectional view showing still another embodiment of the present invention. In the embodiment shown in FIG. 5, the antistatic layer 16 is not formed, and charging is prevented by incorporating fine particles of a conductive substance into the adhesive layer 18. By incorporating fine particles of a conductive substance into the adhesive layer 18, the conductivity is enhanced, and the generated static electricity can be discharged to prevent the accumulation of static electricity. Adhesive layer 18 of the embodiment shown in FIG.
Is formed from a mixture of a so-called dry laminating adhesive, a vinyl chloride-vinyl acetate copolymer as a peeling control agent, and carbon black as a conductive substance. The electrically conductive substance can be selected from carbon black, doutite, alzeride, graphite, and antimony pentafluoride such as polyacetylene, and these substances can be used alone or as a mixture of two or more thereof.

In the embodiment shown in FIG. 5, the adhesion between the second sheet 12 and the adhesive layer 18 and the adhesion between the first sheet 22 and the adhesive layer 18 are formed without forming the peeling adjustment layer 20. The same effect as described above can be obtained by adjusting the adhesive force of. That is, the second sheet 12 is formed of PET having a thickness of 50 μm, for example, and the back surface thereof is corona-treated to improve the adhesiveness. On the other hand, by forming the first sheet 22 from a material having a small surface energy, such as OPP having a thickness of 40 μm, the adhesiveness is reduced. In this case, when the force required for peeling the second sheet 12 from the adhesive layer 18 is a and the force required for peeling the first sheet 22 from the adhesive layer 18 is b, a> b Is formed to satisfy Therefore, the adhesive layer 18 is applied to the second sheet 12
To the first sheet 22, but is only temporarily attached to the first sheet 22. Thus, in the embodiment shown in FIG.
The second sheet 12 includes the adhesive layer 18 and the first sheet 22.
Since it is peeled off at the interface with and, the same effect as described above can be obtained.

FIG. 6 is a schematic sectional view showing still another embodiment of the present invention. In this embodiment, the peel control layer 20
The adhesive force and the peeling force of the adhesive layer 18 are adjusted by adding the filler and the peeling control material to the adhesive layer 18 without forming the, and adjusting the addition amounts thereof.
The adhesive force between the adhesive layer 18 and each sheet is also adjusted depending on the presence or absence of corona treatment. For example, when the back surface of the second sheet 12 is corona-treated, the adhesive layer 18
Adheres firmly to the second sheet 12. And the second
The sheet 12 is peeled off at the interface between the adhesive layer 18 and the first sheet 22. In addition, for example, when the surface of the first sheet 22 is corona-treated, the adhesive layer 1
8 firmly adheres to the first sheet 22. Then, the second sheet 12 is peeled off at the interface between the second sheet 12 and the adhesive layer 18. The adhesive can be selected from polyurethane resin + polyisocyanate, diisocyanate monomer, rosin derivative, terpene resin, petroleum resin, and the like, and these can be used alone or as a mixture of two or more kinds. As a filler,
Fine powder silica gel, acrylic silicon, sodium silicate, calcium silicate, silicon carbide, aluminum silicate, calcium carbonate, titanium oxide, magnesium carbonate,
Aluminum hydroxide, magnesium hydroxide, zinc oxide,
It can be selected from magnesium oxide, aluminum oxide, calcium phosphate and the like, and these can be used alone or as a mixture of two or more kinds. Further, the release control material can be selected from vinyl chloride, vinyl acetate copolymer, nitrocellulose and the like, and these can be used alone or in a mixture of two or more kinds.

Further, in the embodiment shown in FIG. 6, charging is prevented by adding a surfactant into the adhesive layer 18 without forming the antistatic layer 16. That is, the hydrophilic group of the surfactant absorbs moisture in the air to increase the electric conductivity. As a result, the electric resistance is reduced and charging is prevented. Examples of this surfactant include fluorine compounds, primary amine salts, tertiary amines, quaternary ammonium compounds, pyridine derivatives, sulfated oils, soaps, sulfated ester oils, sulfated amide oils, and olefin sulfates. Salts, fatty alcohol sulfate ester salts, alkyl sulfate ester salts, fatty acid ethyl sulfonates, alkyl sulfonates, alkylnaphthalene sulfonates, alkylbenzene sulfonates, mixtures of naphthalene sulfonic acid and formalin, succinate sulfonates, Phosphate ester salts, polyhydric alcohol partial fatty acid esters, fatty alcohol ethylene oxide adducts, fatty acid ethylene oxide adducts, alkylphenol ethylene oxide adducts, polyhydric alcohol partial fatty acid ester ethylene oxide Id adducts, carboxylic acid derivatives can be selected from imidazoline derivatives, it can be used a mixture of these alone, or two or more. Also in the embodiment shown in FIG. 6, the same effect as described above can be obtained.

[Brief description of drawings]

FIG. 1 is a perspective view showing an embodiment of the present invention.

FIG. 2 is a perspective view showing a usage state of the embodiment shown in FIG.

FIG. 3 is a schematic sectional view of the embodiment shown in FIG.

FIG. 4 is a schematic sectional view showing another embodiment of the present invention.

FIG. 5 is a schematic sectional view showing still another embodiment of the present invention.

FIG. 6 is a schematic sectional view showing another embodiment of the present invention.

[Explanation of symbols]

 10 Delivery slip 12 Second sheet 14 Cutting line 16 Antistatic layer 18 Adhesive layer 20 Peeling adjustment layer 22 First sheet 24 Notch 26 Adhesive layer 28 Third sheet 30 Backside treatment layer

Claims (6)

[Claims] 1. A transparent first sheet, a second sheet which is releasably temporarily attached to the surface of the first sheet and is used for displaying information, and an adhesive formed on the back surface of the first sheet. A delivery slip including an agent layer and a third sheet that is removably temporarily attached to the adhesive layer. 2. The third sheet is formed of the same material as the second sheet to prevent curling.
The delivery slip according to claim 1. 3. The delivery slip according to claim 1, further comprising a back surface treatment layer formed on the back surface of the third sheet to prevent curling. 4. The first sheet, the second sheet,
The delivery slip according to any one of claims 1 to 3, wherein each of the third sheet and the third sheet is made of synthetic resin. 5. The delivery slip according to claim 1, further comprising a peeling adjustment layer formed between the first sheet and the second sheet. 6. The delivery slip according to claim 1, further comprising an antistatic layer formed on the back surface of the second sheet.