JPH0760241A - Activated carbon-using adsorption apparatus - Google Patents

Activated carbon-using adsorption apparatus

Info

Publication number
JPH0760241A
JPH0760241A JP20776193A JP20776193A JPH0760241A JP H0760241 A JPH0760241 A JP H0760241A JP 20776193 A JP20776193 A JP 20776193A JP 20776193 A JP20776193 A JP 20776193A JP H0760241 A JPH0760241 A JP H0760241A
Authority
JP
Japan
Prior art keywords
tower
activated carbon
adsorption
towers
series
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20776193A
Other languages
Japanese (ja)
Inventor
Takao Hashizume
隆夫 橋爪
Katsumi Cho
克美 長
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP20776193A priority Critical patent/JPH0760241A/en
Publication of JPH0760241A publication Critical patent/JPH0760241A/en
Pending legal-status Critical Current

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  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

PURPOSE:To provide an activated carbon-using adsorption apparatus whose waste water treatment function is improved by surely carrying out discharge and exchange of old activated carbon while putting the advanced points of a treatment liquid-uptaking type activated carbon-using adsorption tower and a multistage type adsorption tower to practical use. CONSTITUTION:In an activated carbon-using apparatus wherein three or more treatment liquid-uptaking type activated carbon-using towers 2-5 are installed and among them at least two towers are arranged in series and the rest of the towers are used as spare towers, when the adsorption power of the activated carbon of a first tower 2 arranged in series lowers, the supply of raw water is switched to a second tower 3 to use the second tower 3 as a first tower and a spare tower 5 is used as a final tower arranged in a series. The activated carbon is discharged from the lower part of the initially first tower 2 and new charcoal from a activated carbon supplying apparatus 22 is exchanged with the previous carbon to make the first tower as a spare tower and those processes are successively repeated.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は下水処理装置や産業廃水
処理装置、特にし尿処理装置において使用される活性炭
吸着装置に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sewage treatment apparatus and an industrial wastewater treatment apparatus, and more particularly to an activated carbon adsorption apparatus used in a night soil treatment apparatus.

【0002】[0002]

【従来の技術】この種の汚水処理の活性炭吸着装置とし
て、従来は図2に示されるような処理液上向流式活性炭
吸着塔が活性炭の補給、抜出し等が容易な処理装置とし
て使用されているが、このものは1塔のみで使用されて
いるため、処理の間に活性炭中に水の通り道が形成され
て水の短絡を生じるケースが多く、活性炭の吸着性能を
充分に活用することができず、従って充分な処理水質を
確保できない不具合を生じかねないものであった。また
一般に活性炭の吸着処理水質は活性炭の充填高さにより
左右され、例えば3m充填した場合と1.5m充填した
塔を2塔直列に接続した場合では後者の方の水質が優れ
ている場合が多い。これは前述したように充填された活
性炭中に水の通り道が形成されるため、1塔式よりも多
塔式の方が水の通り道が形成される危険性を分散できる
ためと考えられるからである。このため活性炭吸着体を
上下方向に多段に積み重ねたものや、処理吸着塔を横方
向に多段化したものが提案された。処理吸着塔を横方向
に多段化して装置高さを低くしたものとして、例えば特
開平3−137905号公報に記載されたものがある。
この例では処理液上向流式活性炭吸着塔において、処理
液である原水を下から上に流し、古くなった活性炭は部
分的に下から引抜き、新しい活性炭を上から補給する方
式を基本とするもので、多段の吸着塔の下部を連通管で
連結し、同連通管に設置したバルブを開閉して活性炭を
原水供給側に順次移送できるようにして、活性炭の吸着
能力を充分に活用できるようにしたものである。
2. Description of the Related Art As an activated carbon adsorbing device for treating sewage of this type, conventionally, an upflow type activated carbon adsorbing tower for treating liquid as shown in FIG. 2 has been used as a treating device for easily replenishing and withdrawing activated carbon. However, since this is used in only one tower, there are many cases in which a water passage is formed in the activated carbon during the treatment, causing a short circuit of water, and it is possible to fully utilize the adsorption performance of activated carbon. Therefore, there was a possibility that a problem that sufficient treated water quality could not be secured could occur. Generally, the quality of the adsorbed water of activated carbon depends on the filling height of activated carbon. For example, in the case of 3 m packed and 1.5 m packed towers connected in series, the latter is often superior in water quality. . This is because water passages are formed in the filled activated carbon as described above, and it is considered that the risk of water passages being formed can be dispersed in the multi-tower type rather than in the one-tower type. is there. For this reason, it has been proposed that the activated carbon adsorbents are vertically stacked in multiple stages and that the treated adsorption towers are horizontally stacked in multiple stages. An example of a treatment adsorption tower in which the height of the apparatus is lowered by horizontally arranging the adsorption tower is disclosed in, for example, JP-A-3-137905.
In this example, in the upflow type activated carbon adsorption tower of the treatment liquid, the raw water as the treatment liquid is made to flow from the bottom to the top, the old activated carbon is partially withdrawn from the bottom, and new activated carbon is supplied from the top. By connecting the lower part of the multi-stage adsorption tower with a communication pipe and opening and closing the valve installed in the communication pipe, the activated carbon can be sequentially transferred to the raw water supply side so that the adsorption capacity of the activated carbon can be fully utilized. It is the one.

【0003】[0003]

【発明が解決しようとする課題】しかしながら前記の例
にあっては、連結管中を原水供給側(上流側)へ活性炭
を移送させるためには、各吸着塔内の水圧と塔内液に依
存するように構成されているため、活性炭充填高さと塔
内の水深との関係が密接に関連し、古くなった飽和吸着
性活性炭の充分な排出或いは移送のためには、塔内水深
に余裕を見込む必要があった。また各吸着塔間を活性炭
移送のための連結管で移送するように構成されているた
め、処理液の供給のための配管系と別に活性炭移送のた
めの連結管を設ける必要があり、装置が複雑化し、また
下流側の活性炭の上流側への使いまわしにより活性炭の
吸着能力を活用するものであるため、なお万全な処理能
力を確保できるとは言い難いものであった。本発明は前
記のような従来装置における課題を解決して、処理液上
向流式活性炭吸着塔における長所を充分に活用して、下
方から吸着能力が劣化する活性炭が排出される活性炭吸
着装置において、処理液供給系の配管の改良によって簡
単な構成により多段式吸着塔における古い活性炭の確実
な排出を実現することで処理能力を充分に高めることを
可能にするものである。
However, in the above example, in order to transfer the activated carbon through the connecting pipe to the raw water supply side (upstream side), it depends on the water pressure in each adsorption tower and the liquid in the tower. Therefore, in order to sufficiently discharge or transfer the old saturated adsorptive activated carbon, there is a margin in the water depth in the tower. I had to anticipate. Further, since it is configured to transfer between the adsorption towers by a connecting pipe for transferring activated carbon, it is necessary to provide a connecting pipe for transferring activated carbon in addition to a piping system for supplying the treatment liquid. It is difficult to say that a sufficient processing capacity can be ensured because the adsorption capacity of activated carbon is utilized by making it complicated and by reusing the activated carbon on the downstream side to the upstream side. The present invention solves the problems in the conventional apparatus as described above, and in the activated carbon adsorbing apparatus in which activated carbon whose adsorbing capacity deteriorates is discharged from below by fully utilizing the advantages of the treated liquid upflow activated carbon adsorbing tower. By improving the piping of the treatment liquid supply system, the treatment capacity can be sufficiently enhanced by realizing the reliable discharge of old activated carbon in the multistage adsorption tower with a simple structure.

【0004】[0004]

【課題を解決するための手段】このため本発明は、処理
液上向流式活性炭吸着塔を3塔以上配置し、そのうちの
少なくとも2塔を直列に配置し、残りの塔を予備塔とし
て用いる活性炭吸着装置において、直列に配置した第1
塔目の活性炭の吸着能力が低下した時に原水の供給を第
2塔目に切り替え、第2塔目を第1塔目として使用する
と共に、予備塔を直列配置の最終塔として使用し、かつ
当初の第1塔目の活性炭を下方から排出し新炭と入れ替
えて予備塔とし、本操作を順次繰り返すように構成して
なるもので、これを課題解決のための手段とするもので
ある。
Therefore, according to the present invention, three or more treated liquid upflow activated carbon adsorption columns are arranged, at least two of them are arranged in series, and the remaining columns are used as preliminary columns. In the activated carbon adsorbing device, the first arranged in series
When the adsorption capacity of the activated carbon of the tower decreases, the supply of raw water is switched to the second tower, the second tower is used as the first tower, and the preliminary tower is used as the final tower in series, and at the beginning The activated carbon in the first tower is discharged from below and replaced with new coal to form a preliminary tower, and this operation is sequentially repeated. This is a means for solving the problem.

【0005】[0005]

【作用】本発明ではバルブの選択的開閉により、処理液
である原水が処理液上向流式活性炭吸着塔第1塔の下部
より流入してオーバーフローで流出し、第2塔の下部へ
流入する。同様に処理液は第2塔の上部から第3塔の下
部へ流入してオーバーフローで流出し、処理水となる。
第4塔は予備塔である。第1塔の活性炭の吸着能力が低
下した時は、第1塔の処理を停止して第4塔による処理
を開始すべくバルブを閉じ、他のバルブを開けて第2塔
〜第4塔を直列に接続し、第2塔目より通水する。その
後第1塔の下部のバルブを開けて古い活性炭を抜き、更
に活性炭供給装置により新炭を補給する。同様に順次第
2塔目の活性炭を交換する時は使用する吸着塔を第3
塔、第4塔、第1塔の順で原水を流し、第3塔目の活性
炭を交換する時は第4塔、第1塔、第2塔の順で原水を
流し、この操作を繰り返す。こうして多段の各吸着塔の
1つを順次予備塔とする、所謂メリーゴーランド方式と
することで、古くなった飽和吸着性活性炭をその吸着塔
のみにて確実に排出して新しい活性炭と交換することが
可能となり、処理液上向流式活性炭吸着塔の特性を充分
活用して、古くなった下方の活性炭から排出することが
できるので、多段式吸着塔の利点と相俟って充分な汚水
処理能力を発揮することができる。
In the present invention, by selectively opening and closing the valve, raw water, which is the treatment liquid, flows into the treatment liquid upward flow activated carbon adsorption tower from the lower part of the first tower, flows out through the overflow, and flows into the lower part of the second tower. . Similarly, the treatment liquid flows into the lower portion of the third tower from the upper portion of the second tower and overflows to become treated water.
The fourth tower is a reserve tower. When the adsorption capacity of the activated carbon of the first tower is lowered, the valve is closed to stop the treatment of the first tower and start the treatment by the fourth tower, and the other valves are opened to open the second to fourth towers. Connect in series and pass water from the second tower. After that, the valve at the bottom of the first tower is opened to remove the old activated carbon, and new carbon is replenished by the activated carbon supply device. Similarly, when sequentially replacing the activated carbon of the second tower, the adsorption tower used should be the third
The raw water is made to flow in the order of the tower, the fourth tower, and the first tower. When the activated carbon of the third tower is replaced, the raw water is made to flow in the order of the fourth tower, the first tower, and the second tower, and this operation is repeated. In this way, by adopting the so-called merry-go-round system in which one of the multi-stage adsorption towers is successively used as a preliminary tower, it is possible to reliably discharge old saturated adsorptive activated carbon only in the adsorption tower and replace it with new activated carbon. It becomes possible, and by fully utilizing the characteristics of the upflow type activated carbon adsorption tower of the treatment liquid, it can be discharged from the old lower activated carbon, and in combination with the advantage of the multi-stage adsorption tower, sufficient wastewater treatment capacity. Can be demonstrated.

【0006】[0006]

【実施例】以下本発明を図面の実施例について説明する
と、図1は本発明による4塔式の装置例であり、処理液
上向流式活性炭吸着塔を第1塔から第4塔2〜5を横方
向に多段に配置したもので、このうち第1塔から第3塔
2〜4を処理液である原水1の流れにおいて直列に配置
し、残りの第4塔5を予備塔とするものである。原水1
の配管系に対して、各吸着塔の下部には原水1の供給を
受ける際に選択的に開とされるバルブ6〜9を介設した
供給管が配管され、各吸着塔が第1塔として機能する際
に自らのバルブを開とする。また原水1の流れに対して
上流側となる各吸着塔の下部には上流側の吸着塔の上部
からオーバーフローした処理液の供給を受けるように配
管され、前記バルブ6〜9を介設した供給管に接続され
る。同配管中にはそれぞれバルブ14〜17が介設され
ていて、通常は処理液の多段直列塔の処理のために開と
されているが、当該吸着塔が第1塔として機能する場合
には、同吸着塔の1つ上流の吸着塔が予備塔となるた
め、対応するバルブは閉じられて上流側からの処理液は
流入してこない。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below with reference to the embodiments of the drawings. FIG. 1 shows an example of a four-column type apparatus according to the present invention. 5 are arranged in multiple stages in the lateral direction, of which the first to third towers 2 to 4 are arranged in series in the flow of the raw water 1 which is the treatment liquid, and the remaining fourth tower 5 is used as a preliminary tower. It is a thing. Raw water 1
In the lower part of each adsorption tower, a supply pipe provided with valves 6 to 9 selectively opened when receiving the supply of the raw water 1 is connected to each adsorption tower, and each adsorption tower is a first tower. When it functions as, it opens its own valve. Further, the lower part of each adsorption tower on the upstream side of the flow of the raw water 1 is piped so as to receive the supply of the processing liquid overflowing from the upper part of the upstream adsorption tower, and the supply via the valves 6-9 is provided. Connected to the pipe. Valves 14 to 17 are respectively provided in the pipes and are normally opened for the treatment of the multistage serial column of the treatment liquid. However, when the adsorption column functions as the first column, Since the adsorption tower upstream of the adsorption tower is a preliminary tower, the corresponding valve is closed and the processing liquid from the upstream does not flow in.

【0007】次に各吸着塔の上部からオーバーフローし
て処理液を下流の吸着塔に流す配管から、前記各バルブ
14〜17が介設された供給管と分岐されて処理水23
の配管系と連結される配管には、それぞれバルブ11〜
13が介設される。これらのバルブ11〜13は対応す
る吸着塔が処理の最終塔(予備塔の1つ前)となる場合
にのみ開とされる。更に各吸着塔の下部には古くなった
飽和吸着性活性炭を排出するためのバルブ18〜21が
設けられ、上方には新しい活性炭をそれぞれの吸着塔に
各別に供給するための活性炭吸着装置22が配置されて
いる。
Next, the treated water 23 is branched from the supply pipe in which each of the valves 14 to 17 is interposed from the pipe that overflows from the upper part of each adsorption tower and flows the processing liquid to the downstream adsorption tower.
The valves connected to the piping system of
13 is provided. These valves 11 to 13 are opened only when the corresponding adsorption tower is the final tower (one before the preliminary tower) of the treatment. Further, valves 18 to 21 for discharging old saturated adsorptive activated carbon are provided at the bottom of each adsorption tower, and an activated carbon adsorption device 22 for supplying new activated carbon to each adsorption tower is provided above. It is arranged.

【0008】以上のような構成において、バルブ6〜1
7の選択的開閉により、処理液である原水1が処理液上
向流式活性炭吸着塔第1塔2の下部より流入してオーバ
ーフローで流出し、第2塔3の下部へ流入する。同様に
処理液は第2塔3の上部から第3塔4の下部へ流入して
オーバーフローで流出し、処理水23となる。第4塔5
は予備塔である。第1塔2の活性炭の吸着能力が低下し
た時は、第1塔2の処理を停止して第4塔5による処理
を開始すべく6,12,15のバルブを閉じ、7,1
3,17のバルブを開けて第2塔〜第4塔3,4,5を
直列に接続し、第2塔目より通水する。その後第1塔2
の下部のバルブ18を開けて古い活性炭を抜き、更に活
性炭供給装置22により新炭を補給する。同様に順次第
2塔目の活性炭を交換する時は使用する吸着塔を第3
塔、第4塔、第1塔の順で原水を流し、第3塔目の活性
炭を交換する時は第4塔、第1塔、第2塔の順で原水を
流し、この操作を繰り返す。
In the above structure, the valves 6-1
By selectively opening and closing 7, the raw water 1 as the treatment liquid flows in from the lower part of the first upflow type activated carbon adsorption tower 1 for the treatment liquid, flows out by overflow, and flows into the lower part of the second tower 3. Similarly, the treatment liquid flows from the upper part of the second tower 3 into the lower part of the third tower 4 and flows out by overflow to become treated water 23. 4th tower 5
Is a reserve tower. When the adsorption capacity of the activated carbon of the first tower 2 decreases, the valves of 6, 12, 15 are closed to stop the treatment of the first tower 2 and start the treatment of the fourth tower 5,
The valves 3 and 17 are opened to connect the second to fourth towers 3, 4 and 5 in series, and water is passed from the second tower. Then the first tower 2
The valve 18 in the lower part of the column is opened to remove old activated carbon, and new carbon is replenished by the activated carbon supply device 22. Similarly, when sequentially replacing the activated carbon of the second tower, the adsorption tower used should be the third
The raw water is made to flow in the order of the tower, the fourth tower, and the first tower. When the activated carbon of the third tower is replaced, the raw water is made to flow in the order of the fourth tower, the first tower, and the second tower, and this operation is repeated.

【0009】[0009]

【発明の効果】以上詳細に説明した如く本発明によれ
ば、処理液上向流式活性炭吸着塔1塔で処理する場合に
比べ、装置高さがコンパクトな複数塔直列で処理するた
め通り路形成による水の短絡現象を分散防止でき、水質
を安定させることができることは勿論のこと、劣化した
活性炭の交換を各塔毎に行なうので、塔から塔への活性
炭の移送が不要であり、運転操作が容易となる。しかも
多段の各吸着塔の1つを順次予備塔とする、所謂メリー
ゴーランド方式とすることで、古くなった飽和吸着性活
性炭をその吸着塔のみにて確実に排出して新しい活性炭
と交換することが可能となり、処理液上向流式活性炭吸
着塔の特性を充分活用して、古くなった下方の活性炭か
ら排出することができるので、多段式吸着塔の利点と相
俟って充分な汚水処理能力を発揮することができる。
As described in detail above, according to the present invention, compared with the case where the treatment liquid is carried out by one upflow type activated carbon adsorption tower, the height of the apparatus is small, and a plurality of towers are used for treatment in series. It is possible not only to prevent the short circuit phenomenon of water due to formation but also to stabilize the water quality, but since deteriorated activated carbon is exchanged for each tower, it is not necessary to transfer activated carbon from one tower to another. Easy to operate. Moreover, by adopting the so-called merry-go-round system, in which one of the multi-stage adsorption towers is sequentially used as a preliminary tower, it is possible to reliably discharge the old saturated adsorptive activated carbon and replace it with new activated carbon. It becomes possible, and by fully utilizing the characteristics of the upflow type activated carbon adsorption tower of the treatment liquid, it can be discharged from the old lower activated carbon, and in combination with the advantage of the multi-stage adsorption tower, sufficient wastewater treatment capacity. Can be demonstrated.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例に係る活性炭吸着装置の系統図
である。
FIG. 1 is a system diagram of an activated carbon adsorption device according to an embodiment of the present invention.

【図2】従来の単塔式処理装置の系統図である。FIG. 2 is a system diagram of a conventional single-tower processing apparatus.

【符号の説明】[Explanation of symbols]

1 原水 2 処理液上向流式活性炭吸着塔第1塔 3 処理液上向流式活性炭吸着塔第2塔 4 処理液上向流式活性炭吸着塔第3塔 5 処理液上向流式活性炭吸着塔第4塔 6〜21 バルブ 22 活性炭供給装置 23 処理水 1 Raw water 2 Treatment liquid upward flow activated carbon adsorption tower 1st tower 3 Treatment liquid upward flow activated carbon adsorption tower 2nd tower 4 Treatment liquid upward flow activated carbon adsorption tower 3rd tower 5 Treatment liquid upward flow activated carbon adsorption Tower 4th tower 6-21 Valve 22 Activated carbon supply device 23 Treated water

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 処理液上向流式活性炭吸着塔を3塔以上
配置し、そのうちの少なくとも2塔を直列に配置し、残
りの塔を予備塔として用いる活性炭吸着装置において、
直列に配置した第1塔目の活性炭の吸着能力が低下した
時に原水の供給を第2塔目に切り替え、第2塔目を第1
塔目として使用すると共に、予備塔を直列配置の最終塔
として使用し、かつ当初の第1塔目の活性炭を下方から
排出し新炭と入れ替えて予備塔とし、本操作を順次繰り
返すように構成したことを特徴とする活性炭吸着装置。
1. An activated carbon adsorption device in which three or more treated liquid upflow type activated carbon adsorption columns are arranged, at least two columns of which are arranged in series, and the remaining columns are used as spare columns.
When the adsorption capacity of the activated carbon in the first tower arranged in series decreases, the supply of raw water is switched to the second tower, and the second tower is set to the first tower.
It is used as a tower, and a spare tower is used as the final tower in series, and the first activated carbon of the first tower is discharged from below and replaced with fresh coal to make a spare tower, and this operation is repeated in sequence. An activated carbon adsorption device characterized in that
JP20776193A 1993-08-23 1993-08-23 Activated carbon-using adsorption apparatus Pending JPH0760241A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010104896A (en) * 2008-10-29 2010-05-13 Ohbayashi Corp Water treatment apparatus and method for operating the same
JP2013198834A (en) * 2012-03-23 2013-10-03 Swing Corp Operation method of biological treatment apparatus of water
CN107055675A (en) * 2017-06-20 2017-08-18 陕西省石油化工研究设计院 COD is adsorbed in a kind of coal chemical industrial waste water three layer of four tower adsorption method and system
CN109896633A (en) * 2017-12-08 2019-06-18 南京工大开元环保科技(滁州)有限公司 The complete processing system of the multiple depth of chemical industry biochemical tail water and method
CN116534945A (en) * 2023-03-28 2023-08-04 中国恩菲工程技术有限公司 Series stage number design method for cascade adsorption process

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010104896A (en) * 2008-10-29 2010-05-13 Ohbayashi Corp Water treatment apparatus and method for operating the same
JP2013198834A (en) * 2012-03-23 2013-10-03 Swing Corp Operation method of biological treatment apparatus of water
CN107055675A (en) * 2017-06-20 2017-08-18 陕西省石油化工研究设计院 COD is adsorbed in a kind of coal chemical industrial waste water three layer of four tower adsorption method and system
CN107055675B (en) * 2017-06-20 2023-05-26 陕西化工研究院有限公司 Three-layer four-tower adsorption method and system for COD adsorption in coal chemical wastewater
CN109896633A (en) * 2017-12-08 2019-06-18 南京工大开元环保科技(滁州)有限公司 The complete processing system of the multiple depth of chemical industry biochemical tail water and method
CN116534945A (en) * 2023-03-28 2023-08-04 中国恩菲工程技术有限公司 Series stage number design method for cascade adsorption process

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