JPH0765647A - Superconducting conductor and superconducting magnet device - Google Patents
Superconducting conductor and superconducting magnet deviceInfo
- Publication number
- JPH0765647A JPH0765647A JP5215382A JP21538293A JPH0765647A JP H0765647 A JPH0765647 A JP H0765647A JP 5215382 A JP5215382 A JP 5215382A JP 21538293 A JP21538293 A JP 21538293A JP H0765647 A JPH0765647 A JP H0765647A
- Authority
- JP
- Japan
- Prior art keywords
- superconducting
- conduit
- insulating layer
- insulating
- superconducting conductor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E40/00—Technologies for an efficient electrical power generation, transmission or distribution
- Y02E40/60—Superconducting electric elements or equipment; Power systems integrating superconducting elements or equipment
Landscapes
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
(57)【要約】
【目的】 ケーブル・イン・コンジット型の超電導コイ
ルを化合物系の超電導材を用いて製作する場合、 800℃
程度の熱処理を経験した後も絶縁性能を損うことのない
超電導導体を提供する。
【構成】 超電導線(Nb3Sn,Nb3Al等)
(1)をコンジット(2)に収納し、さらにその外周に
無機物の電気絶縁材(3)を配置して製作される内部冷
却型超電導導体において、コンジット材(2)と電気絶
縁材(3)を導体使用温度(-269℃)から化合物超電導
導体生成に必要な(約 800℃)までの熱膨張率(熱収縮
率)がほぼ等しい材料で構成する。
(57) [Summary] [Purpose] 800 ° C when a cable-in-conduit type superconducting coil is manufactured using compound superconducting materials.
(EN) Provided is a superconducting conductor which does not impair the insulating performance even after undergoing a heat treatment of a certain degree. [Structure] Superconducting wire (Nb3Sn, Nb3Al, etc.)
An internal cooling type superconducting conductor manufactured by accommodating (1) in a conduit (2) and further arranging an inorganic electrical insulating material (3) around the conduit (2) and the electrical insulating material (3). Is composed of a material with a coefficient of thermal expansion (thermal contraction rate) that is approximately the same from the temperature at which the conductor is used (-269 ° C) to the temperature (about 800 ° C) required for producing the compound superconducting conductor.
Description
【0001】[0001]
【産業上の利用分野】本発明は、高温の熱処理を経験す
る超電導マグネットの電気絶縁方法の改良に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improved method for electrically insulating a superconducting magnet that undergoes high temperature heat treatment.
【0002】[0002]
【従来の技術】例えば、核融合装置等に用いられる強制
冷却型超電導マグネットに用いられる超電導導体などで
は、その導体の層間あるいはターン間絶縁材料としてカ
プトンやエポキシレジンなどの有機材料が用いられてい
た。これらの絶縁材の耐熱温度はせいぜい 200℃程度で
あり、 800℃程度の熱処理を必要とする化合物系の超電
導材料を用いる場合には、絶縁処理は熱処理後に行う必
要があった。また、無機物系の絶縁材は耐熱性は優れて
いるものの熱処理過程を経験した後には、機械的に脆弱
化したり、あるいは被絶縁材との熱膨張率の差などのた
めにクラックが発生し絶縁材として機能しなくなること
が多い。2. Description of the Related Art For example, in a superconducting conductor used in a forced cooling type superconducting magnet used in a nuclear fusion device or the like, an organic material such as Kapton or epoxy resin is used as an insulating material between layers of the conductor or between turns. . The heat-resistant temperature of these insulating materials is at most about 200 ° C., and when using a compound-based superconducting material that requires heat treatment at about 800 ° C., the insulating treatment had to be performed after the heat treatment. In addition, although the inorganic insulating material has excellent heat resistance, after undergoing the heat treatment process, it is mechanically weakened, or cracks occur due to the difference in the coefficient of thermal expansion from the material to be insulated, etc. Often does not function as a material.
【0003】[0003]
【発明が解決しようとする課題】化合物系の超電導導体
は、熱処理後にはセラミックになるため曲げなどの変形
に非常に弱く、巻線形成後に熱処理を経験する場合に
は、その後の絶縁処理が非常に困難であった。本発明の
目的は、 800℃程度の熱処理を経験した後も絶縁材が、
その機能を失わない構成を提供することである。Since the compound type superconducting conductor becomes ceramic after heat treatment, it is very vulnerable to deformation such as bending, and if the heat treatment is performed after the winding formation, the subsequent insulation treatment is extremely difficult. It was very difficult. The object of the present invention is to make the insulating material, even after undergoing heat treatment at about 800 ° C.,
It is to provide a configuration that does not lose its function.
【0004】[0004]
【課題を解決するための手段】上記の目的を達成するた
めには、超電導材あるいはコンジット材等の被絶縁物に
耐熱性に優れかつ前記被絶縁物と熱膨張率の等しい無機
絶縁材料であるアルミナやジルコニアをコーティングし
て構成することが有効である。さらに、そのコーティン
グ方法としては超電導材にコーティングに際する熱履歴
などの影響が少ないスパッタリング法を用いることが好
ましい。In order to achieve the above object, an insulating material such as a superconducting material or a conduit material is an inorganic insulating material having excellent heat resistance and a thermal expansion coefficient equal to that of the insulating material. It is effective to coat with alumina or zirconia. Further, as the coating method, it is preferable to use a sputtering method in which the superconducting material is less affected by heat history during coating.
【0005】[0005]
【作用】上述した無機絶縁材は極低温(4K)から熱処
理温度(1000K)までの熱膨張率がNb3Sn材あるい
はコンジット材であるチタンやInColoy908などの被絶縁
物と等しいため熱処理行程で熱履歴による熱応力を受け
ることがなく、結果として有機系の絶縁物であってもク
ラックを生じることがなく電気絶縁性能を維持すること
ができる。The above-mentioned inorganic insulating material has the same coefficient of thermal expansion from cryogenic temperature (4K) to heat treatment temperature (1000K) as that of the insulating material such as Nb3Sn material or titanium which is conduit material or InColoy908. It is not subjected to thermal stress, and as a result, even if it is an organic insulating material, it is possible to maintain electrical insulation performance without cracking.
【0006】[0006]
【実施例】以下、本発明の一実施例について図1を用い
て説明する。図1において1及び2はそれぞれNb3S
n超電導線およびチタンあるいはInColoy908のコンジッ
ト材を示している。このコンジット材2の表面に耐熱、
耐摩擦、耐摩耗、耐腐食性に優れた性能を有するアルミ
ナ、ジルコニア等のセラミックス3を数10μm程度コー
ティングして構成する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIG. In FIG. 1, 1 and 2 are Nb3S, respectively.
n shows a superconducting wire and a conduit material of titanium or InColoy908. Heat resistance on the surface of this conduit material 2,
Ceramics 3 such as alumina and zirconia, which have excellent abrasion resistance, abrasion resistance, and corrosion resistance, are coated on the order of several tens of μm.
【0007】化合物系の超電導線などでは、超電導物質
を生成するために 800℃程度の高温処理を行うが、高い
耐熱性を有する無機物質を使用すれば熱的には問題を生
じない。しかしながら被絶縁物であるコンジット材など
と熱膨張率の異なる物質を用いた場合は、熱膨張率の差
によって生じる熱応力によって絶縁物にクラック等が生
じ電気絶縁性能を損なうことになる。本実施例では超電
導物質の熱歪による劣化を防ぐためにコンジット材2と
して純チタンやInColoy908を使用した場合に適する絶縁
材料3として、アルミナやジルコニアを使用する。この
絶縁材3はチタン等のコンジット材と熱膨張率がほぼ等
しいため熱処理行程を経験しても二物質間の熱応力が生
じることがなくクラック等に発生を防ぐことができ結果
として電気絶縁性能を損なうことがない。また、セラミ
ック材のコーティング方法として低温( 150℃)で処理
できるスパッタリング法を用いることで、熱処理前の超
電導物質に悪影響を及ぼすことがない絶縁処理作業が可
能となる。In the case of a compound type superconducting wire or the like, a high temperature treatment of about 800 ° C. is carried out in order to produce a superconducting substance, but if an inorganic substance having high heat resistance is used, no thermal problem will occur. However, when a material having a thermal expansion coefficient different from that of a conduit material, which is an object to be insulated, is used, cracks or the like occur in the insulating material due to thermal stress caused by the difference in thermal expansion coefficient, and the electrical insulation performance is impaired. In this embodiment, alumina or zirconia is used as the insulating material 3 that is suitable when pure titanium or InColoy 908 is used as the conduit material 2 in order to prevent deterioration due to thermal strain of the superconducting material. Since this insulating material 3 has a thermal expansion coefficient substantially equal to that of a conduit material such as titanium, even if a heat treatment process is performed, thermal stress between the two substances does not occur and cracks can be prevented from occurring, resulting in electrical insulation performance. Will not hurt. Also, by using a sputtering method that can be processed at a low temperature (150 ° C) as a method for coating a ceramic material, it is possible to perform an insulation processing operation that does not adversely affect the superconducting material before heat treatment.
【0008】以上の構成により核融合炉等に使用される
ケーブル・イン・コンジット型の超電導コイルを化合物
系の超電導材を用いて製作する場合、熱処理前に絶縁処
理作業が行うことができ、超電導導体の性能劣化を生じ
にくい構成を提供することができる。When the cable-in-conduit type superconducting coil used in a fusion reactor or the like is manufactured by using the compound type superconducting material with the above-mentioned structure, the insulation treatment can be performed before the heat treatment. It is possible to provide a configuration in which performance deterioration of the conductor does not easily occur.
【0009】また、大型の超電導コイル等では構造材や
コンジット材に無機物をコーティングすることが難しい
場合があり、このような場合、図2に示すように薄いチ
タンテープ(数十ミクロン)等に無機絶縁物を数ミクロ
ンをコーティングしたテープを用いて絶縁する方法が有
効である。また、このテープを導体のような棒状のもの
に巻き付けて使用する場合テープの曲げが生じた部分で
無機絶縁物にクラックが発生するため、その角部にはL
型に成形された同種のテープ等を配置して置きこれに上
記テープを巻き付ける方法が有効である。In some cases, it is difficult to coat a structural material or conduit material with an inorganic material in a large superconducting coil. In such a case, as shown in FIG. 2, a thin titanium tape (several tens of microns) or the like is coated with an inorganic material. It is effective to insulate the insulator with a tape coated with several microns. Also, when this tape is wound around a rod-shaped object such as a conductor, cracks occur in the inorganic insulating material at the bent portions of the tape.
A method of arranging and placing the same type of tape or the like formed in a mold and winding the tape around this is effective.
【0010】[0010]
【発明の効果】以上の説明のように、本発明による構成
の超電導導体では、被絶縁材と熱膨張率の等しい無機絶
縁材料をコーティングを行うことで、熱処理後にも絶縁
能力を損なわない信頼性の高い超電導導体を提供するこ
とができる。As described above, the superconducting conductor of the present invention is coated with an inorganic insulating material having the same coefficient of thermal expansion as that of the material to be insulated, so that the insulating ability is not deteriorated even after the heat treatment. It is possible to provide a high superconducting conductor.
【図1】本発明の一実施例に係る超電導導体の断面構成
図FIG. 1 is a sectional configuration diagram of a superconducting conductor according to an embodiment of the present invention.
【図2】本発明による超電導導体の絶縁構成図FIG. 2 is an insulation configuration diagram of a superconducting conductor according to the present invention.
1 超電導線 2 コンジット 3 無機物系絶縁材 4 無機絶縁テープ 5 L型無機絶縁テープ 1 Superconducting wire 2 Conduit 3 Inorganic insulating material 4 Inorganic insulating tape 5 L type inorganic insulating tape
Claims (5)
納し、さらにその外周に無機物の電気絶縁層を形成して
製作される内部冷却型の超電導導体において、前記コン
ジット材と前記絶縁層を導体使用温度(-269℃)から化
合物系超電導導体生成のための熱処理温度(約 800℃)
までの熱膨張率(熱収縮率)がほぼ等しい材料を用いて
構成したことを特徴とする超電導導体。1. An internal cooling type superconducting conductor manufactured by housing a compound superconducting wire in a conduit or the like, and further forming an electrically insulating layer of an inorganic material on the outer periphery thereof, wherein the conduit material and the insulating layer are conductors. From the operating temperature (-269 ℃) to the heat treatment temperature (about 800 ℃) to generate the compound superconductor
The superconducting conductor is composed of materials having substantially the same thermal expansion coefficient (thermal contraction coefficient).
は、Nb3Al材を使用し、かつ前記コンジット材とし
て純Ti(チタン)あるいはInColoy908等前記超電導線
と前記温度範囲で熱収縮率の等しい材料を用いるととも
に、前記絶縁層として前記超電導線およびコンジット材
と前記温度範囲で熱収縮率の等しいアルミナ(Al2 O
3 )あるいはジルコニア(ZrO2 )を用いたことを特
徴とする請求項1に記載の超電導導体。2. A Nb3Sn material or an Nb3Al material is used as the superconducting wire, and pure Ti (titanium) or InColoy 908 is used as the conduit material, and a material having the same thermal contraction coefficient in the temperature range as the superconducting wire is used. As the insulating layer, the superconducting wire and the conduit material are made of alumina (Al 2 O) having the same thermal shrinkage in the temperature range.
3 ) Or zirconia (ZrO 2 ) is used, The superconducting conductor according to claim 1.
オンプレーティング法等を用い、数ミクロン〜数十ミク
ロンのコーティング層にて形成したことを特徴とする請
求項1に記載の超電導導体。3. The superconducting conductor according to claim 1, wherein the insulating layer is formed of a coating layer of several microns to several tens of microns by using a sputtering method, an ion plating method or the like.
縁テープを構成し、これにより前記絶縁層を形成したこ
とを特徴とする請求項1ないし請求項3記載の超電導導
体。4. The superconducting conductor according to claim 1, wherein a thin film metal is coated with an inorganic insulating material to form an insulating tape, and the insulating layer is formed thereby.
グネット装置において、マグネット内に配置される部材
の絶縁材として前記部材と前記温度範囲で熱膨張率の等
しい無機絶縁材を使用し、かつ熱処理前に当該絶縁材を
施工して超電導線を形成したことを特徴とする超電導マ
グネット装置。5. A superconducting magnet device using a compound-based superconductor, wherein an inorganic insulating material having a thermal expansion coefficient equal to that of the member is used as an insulating material of a member arranged in the magnet, and heat treatment is performed. A superconducting magnet device, characterized in that the insulating material is applied before to form a superconducting wire.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5215382A JPH0765647A (en) | 1993-08-31 | 1993-08-31 | Superconducting conductor and superconducting magnet device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5215382A JPH0765647A (en) | 1993-08-31 | 1993-08-31 | Superconducting conductor and superconducting magnet device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0765647A true JPH0765647A (en) | 1995-03-10 |
Family
ID=16671378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5215382A Pending JPH0765647A (en) | 1993-08-31 | 1993-08-31 | Superconducting conductor and superconducting magnet device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0765647A (en) |
-
1993
- 1993-08-31 JP JP5215382A patent/JPH0765647A/en active Pending
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