JPH0769848A - Transparent gelatinous hair-treating agent composition - Google Patents
Transparent gelatinous hair-treating agent compositionInfo
- Publication number
- JPH0769848A JPH0769848A JP5243864A JP24386493A JPH0769848A JP H0769848 A JPH0769848 A JP H0769848A JP 5243864 A JP5243864 A JP 5243864A JP 24386493 A JP24386493 A JP 24386493A JP H0769848 A JPH0769848 A JP H0769848A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- gel
- agent composition
- hair treatment
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 229920006318 anionic polymer Polymers 0.000 claims abstract description 17
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract description 5
- 125000005037 alkyl phenyl group Chemical group 0.000 claims abstract description 5
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 5
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 19
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 19
- 230000003750 conditioning effect Effects 0.000 abstract description 12
- 229920002125 Sokalan® Polymers 0.000 abstract description 10
- 235000019864 coconut oil Nutrition 0.000 abstract description 5
- 239000003240 coconut oil Substances 0.000 abstract description 5
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 5
- 239000000194 fatty acid Substances 0.000 abstract description 5
- 229930195729 fatty acid Natural products 0.000 abstract description 5
- 238000013329 compounding Methods 0.000 abstract description 2
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- HWEYKFCKGRDHJZ-UHFFFAOYSA-M sodium;2,3-dihydroxypropyl sulfate Chemical compound [Na+].OCC(O)COS([O-])(=O)=O HWEYKFCKGRDHJZ-UHFFFAOYSA-M 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- -1 carboxyvinyl polymer Chemical class 0.000 description 7
- 239000003513 alkali Substances 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- IKXHOZXMTQSYQR-UHFFFAOYSA-N 2,3-dihydroxypropoxysulfonyl dodecanoate;sodium Chemical compound [Na].CCCCCCCCCCCC(=O)OS(=O)(=O)OCC(O)CO IKXHOZXMTQSYQR-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KKTUYEBVMFPISH-UHFFFAOYSA-N N(CCO)(CCO)CCO.S(=O)(=O)(OCCCCCCCCCCCCCCCCCC)OCC(O)CO Chemical compound N(CCO)(CCO)CCO.S(=O)(=O)(OCCCCCCCCCCCCCCCCCC)OCC(O)CO KKTUYEBVMFPISH-UHFFFAOYSA-N 0.000 description 1
- NOEIBORMTHQKSU-UHFFFAOYSA-N S(=O)(=O)(OC(CCCCCCCCCCC)=O)OCC(O)CO.[K] Chemical compound S(=O)(=O)(OC(CCCCCCCCCCC)=O)OCC(O)CO.[K] NOEIBORMTHQKSU-UHFFFAOYSA-N 0.000 description 1
- OYBAJEJMUZESCS-UHFFFAOYSA-N S(=O)(=O)(OCCCCCCCCCCCCCCCC)OCC(O)CO.[Na] Chemical compound S(=O)(=O)(OCCCCCCCCCCCCCCCC)OCC(O)CO.[Na] OYBAJEJMUZESCS-UHFFFAOYSA-N 0.000 description 1
- JYXHIBPSIQNPHZ-UHFFFAOYSA-N [Na].CCCCCCCCCCCCCCCCCCOS(=O)(=O)OCC(O)CO Chemical compound [Na].CCCCCCCCCCCCCCCCCCOS(=O)(=O)OCC(O)CO JYXHIBPSIQNPHZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229940046257 glyceryl phosphate Drugs 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は透明ゲル状毛髪処理剤
組成物に係り、その目的は手に取りやすく、直接髪に塗
布しやすい適度な粘性を有するなどゲル性能が良好で優
れた使用性を示し、しかも安全で、且つ毛髪に対してな
めらさ等のコンディショニング効果を与えることができ
る透明ゲル状毛髪処理剤組成物を提供することにある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transparent gel-like hair treatment composition, the object of which is that the gel performance is good and the usability is excellent such that it is easy to take by hand and has an appropriate viscosity to be applied directly to hair. The present invention is to provide a transparent gel-like hair treatment composition which is safe, and can impart conditioning effects such as smoothness to hair.
【０００２】[0002]
【従来の技術】一般にヘアスタイルを整えたり、或いは
毛髪に対してコンディショニング効果を付与する整髪料
等の毛髪処理剤は、対象とする髪質に応じて、或いは配
合成分等により複数の種類のものが存在しており、外観
上も透明状のものと不透明状のものとが存在している。
中でも、透明のゲル状毛髪処理剤は、見た目に美しく、
みずみずしい清涼感があり、且つ使用する際に楽しさが
ある等の利点を有し、若い世代を中心に広く消費者に受
け入れられている。この透明ゲル状毛髪処理剤は、通
常、使用者が直接手に取って、髪に塗布して使用するた
め、手から垂れ落ちたりしない程度の適度な粘性を備え
ていることが条件とされている。一般に透明ゲル状毛髪
処理剤においては、ゲル化剤或いは増粘剤として、カル
ボキシビニルポリマー等のアニオン性高分子化合物が用
いられていることが多い。これは、アニオン性高分子化
合物が少量でゲルを形成するため、べたつき感を与える
ことがなく、他の増粘剤を配合したものよりも良好な性
能を発揮することができるためである。2. Description of the Related Art Generally, a hair treatment agent such as a hair styling agent which prepares a hair style or imparts a conditioning effect to hair has a plurality of types depending on a target hair quality or a compounding ingredient. Exist, and there are transparent and opaque external appearances.
Among them, the transparent gel-like hair treatment agent looks beautiful,
It has a fresh and refreshing feeling and is fun to use, and is widely accepted by consumers, mainly in the younger generation. This transparent gel-like hair treatment agent is usually used by the user directly picking it up on his or her hand and applying it to the hair, so it is required to have an appropriate viscosity so that it does not drip from the hand. There is. Generally, in a transparent gel hair treatment agent, an anionic polymer compound such as carboxyvinyl polymer is often used as a gelling agent or a thickening agent. This is because the anionic polymer compound forms a gel with a small amount, so that it does not give a sticky feeling, and can exhibit better performance than those containing other thickeners.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、前記ア
ニオン性高分子化合物を配合したゲル状毛髪処理剤では
髪型の固定、即ち毛髪のセット剤としての機能を有する
ものは存在していたが、髪に光沢性や水分を付与し、保
湿性があり、しかも滑らかで櫛通りがよく、まとめやす
い髪に仕上げるといったコンディショニング性能を発現
するものは存在しなかった。従来、毛髪に対してコンデ
ィショニング効果を付与する頭髪用化粧料としては、ア
ンモニウムクロライドで代表される第４級アンモニウム
塩等のカチオン性界面活性剤を主成分としたものが知ら
れている。ところが、前記アニオン性高分子化合物を配
合したゲル状毛髪処理剤に、コンディショニング性能を
付与する目的で、第４級アンモニウム塩等のカチオン性
の界面活性剤を混合すると、このカチオン性界面活性剤
とアニオン性高分子化合物との間にイオンコンプレック
スが形成されてしまい、ポリマーが析出して不溶物質が
生じ、ゲルを形成させることができなくなってしまうと
いう課題が存在した。しかも、第４級アンモニウム塩等
のカチオン性界面活性剤は、一般に殺菌性が強く、毛髪
や頭皮に対する刺激性が懸念され、安全性に問題がある
という課題が存在した。However, there are gel-like hair treatment agents containing the above-mentioned anionic polymer compound, which have the function of fixing the hairstyle, that is, as a hair setting agent. There is no such thing that imparts gloss and moisture, has moisturizing properties, is smooth and combs well, and has conditioning properties such as finishing hair that is easy to put together. BACKGROUND ART Conventionally, as a cosmetic for hair that imparts a conditioning effect to hair, those containing a cationic surfactant such as a quaternary ammonium salt typified by ammonium chloride as a main component are known. However, when a cationic surfactant such as a quaternary ammonium salt is mixed with a gel-like hair treatment agent containing the anionic polymer compound for the purpose of imparting conditioning performance, the gel-like hair treatment agent is mixed with the cationic surfactant. There is a problem that an ion complex is formed between the polymer and the anionic polymer compound, the polymer is deposited and an insoluble substance is generated, and it becomes impossible to form a gel. In addition, cationic surfactants such as quaternary ammonium salts generally have strong bactericidal properties, and there is a concern that they may cause irritation to hair and scalp, resulting in a problem of safety.
【０００４】そこで、業界では、適度な粘性を有し、ア
ニオン性高分子化合物の有する優れたゲル性能を維持
し、ゲル状毛髪処理剤として優れた使用性を示すととも
に、毛髪に対しては水分を付与し、なめらかな仕上がり
感とすることができるなどコンディショニング性能をも
併せ持った安全で透明感の良好な優れたゲル状毛髪処理
剤の創出が望まれていた。Therefore, in the industry, the gel has an appropriate viscosity, maintains the excellent gel performance of an anionic polymer compound, exhibits excellent usability as a gel-like hair treatment agent, and has a moisture content for hair. It has been desired to create an excellent gel-like hair treatment agent which is excellent in safety and transparency and which also has conditioning performance such as giving a smooth finish.
【０００５】[0005]
【課題を解決するための手段】この発明では一般式２
（化２）にて示されるモノグリセライド型アニオン性界
面活性剤０．０５〜１重量％と、アニオン性高分子化合
物０．１〜１０重量％が配合されてなることを特徴とす
る透明ゲル状毛髪処理剤組成物を提供することにより、
前記従来の課題を悉く解消する。In the present invention, the general formula 2
A transparent gel-like hair comprising 0.05 to 1% by weight of a monoglyceride type anionic surfactant represented by (Chemical Formula 2) and 0.1 to 10% by weight of an anionic polymer compound. By providing a treating agent composition,
The above conventional problems are solved.
【化２】 〔但し、式中Ｒ1 は炭素数８〜２０の飽和又は不飽和の
アルキル基又はアルキルフェニル基であり、ＸはＯＳＯ
3 Ｙ、ＯＰＯ3 Ｙ又はＯ2 ＰＯ2 Ｙ（Ｙは水素原子、ア
ルカリ金属、アルカリ土類金属、アンモニウム基又はア
ルカノールアミンのうちのいずれか）を示す。〕[Chemical 2] [Wherein, R 1 is a saturated or unsaturated alkyl group having 8 to 20 carbon atoms or an alkylphenyl group, and X is OSO.
3 Y, OPO 3 Y or O 2 PO 2 Y (Y is any one of a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium group and an alkanolamine). ]
【０００６】[0006]
【作用】カルボキシビニルポリマー等のアニオン性高分
子化合物に、特定のモノグリセライド型アニオン性界面
活性剤を特定の比率で併用することにより、手のひらに
取っても垂れ落ちたりせず、直接毛髪に塗布できる程度
の適度な粘性を有する透明感の良好なゲル状毛髪処理剤
組成物を得ることができる。また、モノグリセライド型
アニオン性界面活性剤の作用により、毛髪になめらか感
やしっとり感等のコンディショニング効果を付与するこ
とができ、しかも従来のカチオン性のコンディショニン
グ剤に比べると、毛髪や頭皮に対する刺激性が低いた
め、安全性の高いゲル状毛髪処理剤組成物となる。[Function] By using a specific monoglyceride type anionic surfactant in a specific ratio in combination with an anionic polymer compound such as carboxyvinyl polymer, it can be directly applied to the hair without dripping even when taken by the palm. It is possible to obtain a gel-like hair treatment composition which has a moderate viscosity and a good transparency. In addition, the action of the monoglyceride type anionic surfactant can impart a conditioning effect such as smoothness and moisturizing feel to the hair, and is more irritating to the hair and scalp than conventional cationic conditioning agents. Since the amount is low, the gel-type hair treatment composition has high safety.
【０００７】[0007]
【発明の構成】以下、この発明に係る透明ゲル状毛髪処
理剤組成物の構成について詳述する。この発明において
は、一般式３（化３）にて示されるモノグリセライド型
アニオン性界面活性剤が必須成分の一つとして含有され
る。BEST MODE FOR CARRYING OUT THE INVENTION The constitution of the transparent gel hair treatment composition according to the present invention will be described in detail below. In the present invention, the monoglyceride type anionic surfactant represented by the general formula 3 (formula 3) is contained as one of the essential components.
【化３】 〔但し、式中Ｒ1 は炭素数８〜２０の飽和又は不飽和の
アルキル基又はアルキルフェニル基であり、ＸはＯＳＯ
3 Ｙ、ＯＰＯ3 Ｙ又はＯ2 ＰＯ2 Ｙ（Ｙは水素原子、ア
ルカリ金属、アルカリ土類金属、アンモニウム基又はア
ルカノールアミンのうちのいずれか）を示す。〕[Chemical 3] [Wherein, R 1 is a saturated or unsaturated alkyl group having 8 to 20 carbon atoms or an alkylphenyl group, and X is OSO.
3 Y, OPO 3 Y or O 2 PO 2 Y (Y is any one of a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium group and an alkanolamine). ]
【０００８】このモノグリセライド型アニオン性界面活
性剤としては、具体的にステアリルグリセリル硫酸ナト
リウム、セチルグリセリル硫酸ナトリウム、ラウロイル
グリセリル硫酸ナトリウム、パルミトイルグリセリル硫
酸ナトリウム、ヤシ油脂肪酸グリセリル硫酸ナトリウ
ム、硬化ヤシ油脂肪酸グリセリル硫酸ナトリウム、ステ
アリルグリセリル硫酸トリエタノールアミン、ラウロイ
ルグリセリル硫酸カリウム、パルミトイルグリセリルリ
ン酸ナトリウム、硬化ヤシ油脂肪酸グリセリルリン酸ナ
トリウム等が好適な実施例として例示されるが、特に限
定されるものではない。Specific examples of the monoglyceride type anionic surfactant include sodium stearyl glyceryl sulfate, sodium cetyl glyceryl sulfate, sodium lauroyl glyceryl sulfate, sodium palmitoyl glyceryl sulfate, sodium coconut oil fatty acid glyceryl sulfate, and hardened coconut oil fatty acid glyceryl sulfate. Sodium, stearyl glyceryl sulfate triethanolamine, potassium lauroyl glyceryl sulfate, sodium palmitoyl glyceryl phosphate, hydrogenated coconut oil fatty acid glyceryl sodium phosphate, etc. are exemplified as preferred examples, but not limited thereto.
【０００９】この発明では、上記したようなモノグリセ
ライド型アニオン性界面活性剤を必須成分として使用す
ることにより、後述するアニオン性ポリマーの備える優
れたゲル性能を阻害することなく、適度な粘性を発現す
ることができるとともに、毛髪に対してはなめらか感や
しっとり感などのコンディショニング効果を付与するこ
とができる安全で、透明感の良好な優れたゲル状毛髪処
理剤を得ることができる。このようなモノグリセライド
型アニオン性界面活性剤は、この発明において、ゲル状
組成物の全成分量に対して０．０５〜１重量％、より好
ましくは０．１〜０．５重量％配合される。この理由
は、配合量が０．０５重量％未満であると、この発明の
目的とする毛髪へのコンディショニング効果が充分に発
現されず、一方、１重量％を超えて配合されると、ゲル
状組成物の粘度が低くなりすぎて、手に取りにくくな
り、タレ等を起こしやすくなり、いずれの場合も好まし
くないからである。In the present invention, by using the monoglyceride type anionic surfactant as an essential component as described above, a suitable viscosity is exhibited without inhibiting the excellent gel performance of the anionic polymer described later. In addition, it is possible to obtain a safe and excellent gel-like hair treatment agent which is capable of imparting a conditioning effect such as a smooth feeling and a moist feeling to the hair and has a good transparency. In the present invention, such a monoglyceride type anionic surfactant is blended in an amount of 0.05 to 1% by weight, more preferably 0.1 to 0.5% by weight, based on the total amount of components of the gel composition. . The reason for this is that if the blending amount is less than 0.05% by weight, the effect of conditioning the hair, which is the object of the present invention, will not be sufficiently exhibited, while if it is blended in excess of 1% by weight, it will be gel-like. This is because the viscosity of the composition becomes too low, which makes it difficult to pick it up and causes sagging or the like, which is not preferable in any case.
【００１０】また、前記モノグリセライド型アニオン界
面活性剤とともにアニオン性高分子化合物も必須成分と
して含有される。このアニオン性高分子化合物として
は、特に限定されず、通常のゲル状組成物に使用される
公知のものが使用でき、例えばポリアクリル酸、アルギ
ン酸ナトリウム、カルボキシメチルセルロース、カルボ
キシビニルポリマー等が好適に使用でき、これらの中か
ら選択される任意の一種或いは二種以上の混合物が好適
に使用できる。中でも特に、カルボキシビニルポリマー
は、得られるゲルにべたつき感が少なく、細菌やカビに
害されず、少量で高い粘度とチキソトロピー性が得られ
るとともに安全性が高く、その上、水、アルコール等の
種々の溶剤に適用できる等の多くの利点を有しているた
め、より好ましく使用される。また、このようなカルボ
キシビニルポリマーを使用する場合には、予めアルカリ
で、部分的若しくは完全に中和し、塩の形態で増粘ゲル
化して配合することが必要とされる。使用されるアルカ
リとしては、水酸化ナトリウム、水酸化カリウム、水酸
化カルシウム等の無機アルカリ化合物或いはモノエタノ
ールアミン、ジエタノールアミン、トリエタノールアミ
ン、アミノメチルプロパノール等の有機アルカリ化合
物、アルギニン、リジン等の塩基性アミノ酸がいずれの
ものでも好適に使用される。Further, an anionic polymer compound is contained as an essential component together with the monoglyceride type anionic surfactant. The anionic polymer compound is not particularly limited, and known compounds used in ordinary gel compositions can be used. For example, polyacrylic acid, sodium alginate, carboxymethyl cellulose, carboxy vinyl polymer and the like are preferably used. It is possible to use any one kind or a mixture of two or more kinds selected from these. Among them, in particular, carboxyvinyl polymer is less sticky to the obtained gel, is not harmed by bacteria and mold, can obtain high viscosity and thixotropy in a small amount and is highly safe, and further, various kinds of water, alcohol, etc. Since it has many advantages such as being applicable to the above-mentioned solvent, it is more preferably used. When such a carboxyvinyl polymer is used, it is necessary to preliminarily partially or completely neutralize it with an alkali, thicken it in the form of a salt, and blend it. Examples of the alkali used include inorganic alkali compounds such as sodium hydroxide, potassium hydroxide and calcium hydroxide, organic alkali compounds such as monoethanolamine, diethanolamine, triethanolamine and aminomethylpropanol, and basic such as arginine and lysine. Any amino acid is preferably used.
【００１１】このようなアニオン性高分子化合物の使用
量は、必ずしも限定はされないが、ゲル状組成物の全成
分量に対し、０．１〜１０重量％、より望ましくは０．
５〜３．０重量％配合されるのが好ましい。この理由
は、アニオン性高分子化合物の配合量が０．１重量％未
満では、得られるゲル状毛髪処理剤のゲル強度が不充分
であり、一方１０重量％を超えて配合されると、逆にゲ
ルが強固になりすぎて使用性が悪くなるため、いずれの
場合も好ましくないからである。The amount of such anionic polymer compound used is not necessarily limited, but is preferably 0.1 to 10% by weight, more preferably 0.
It is preferable to add 5 to 3.0% by weight. The reason for this is that if the amount of the anionic polymer compound is less than 0.1% by weight, the gel strength of the obtained gel-like hair treatment agent is insufficient, whereas if it is more than 10% by weight, the reverse effect occurs. This is because the gel becomes too strong and usability deteriorates, which is not preferable in any case.
【００１２】尚、この発明では、上記したモノグリセラ
イド型アニオン性界面活性剤と、アニオン性高分子化合
物以外に、通常の頭髪用化粧料に使用される公知の成
分、すなわち非イオン系界面活性剤、油性物質、多価ア
ルコール、ガム質、天然水溶性性高分子化合物及びその
誘導体、防腐剤、キレート剤、酸化防止剤、殺菌剤、粘
度調製剤、抗フケ剤、紫外線吸収剤、色素、香料など
を、この発明の効果を損なわない範囲で適宜配合するこ
とが可能である。In the present invention, in addition to the above-mentioned monoglyceride type anionic surfactant and the anionic polymer compound, a known component used in ordinary hair cosmetics, that is, a nonionic surfactant, Oily substances, polyhydric alcohols, gums, natural water-soluble polymer compounds and their derivatives, preservatives, chelating agents, antioxidants, bactericides, viscosity modifiers, anti-dandruff agents, ultraviolet absorbers, pigments, fragrances, etc. Can be appropriately blended within a range that does not impair the effects of the present invention.
【００１３】[0013]
【実施例】以下、この発明の透明ゲル状毛髪処理剤組成
物を実施例を挙げることにより、一層詳細に説明する。
但し、この発明は以下の実施例により何ら限定されるも
のはない。EXAMPLES The transparent gel hair treatment composition of the present invention will be described in more detail below with reference to examples.
However, the present invention is not limited to the following examples.
【００１４】（実施例１及び比較例１〜４）表１の処方
に従って、実施例１及び比較例１〜４の透明ゲル状毛髪
処理剤組成物を調製した。調製は、まず精製水中にカル
ボキシビニルポリマーを溶解した後、トリエタノールア
ミンを用いて前記カルボキシビニルポリマーを中和し、
この精製水中にモノグリセライド型アニオン性界面活性
剤「硬化ヤシ油脂肪酸グリセリル硫酸ナトリウム〔商品
名；ＳＧＣ−８０Ｎ（日光ケミカルズ製）〕」、防腐
剤、香料、塩化ステアリルトリメチルアンモニウムをそ
れぞれ処方に従って溶解させたアルコールを添加して行
なった。(Example 1 and Comparative Examples 1 to 4) According to the formulations shown in Table 1, the transparent gel hair treatment compositions of Example 1 and Comparative Examples 1 to 4 were prepared. The preparation is carried out by first dissolving the carboxyvinyl polymer in purified water, then neutralizing the carboxyvinyl polymer with triethanolamine,
In this purified water, a monoglyceride type anionic surfactant "hardened coconut oil fatty acid glyceryl sodium sulfate [trade name; SGC-80N (manufactured by Nikko Chemicals)]", a preservative, a fragrance, and stearyltrimethylammonium chloride were dissolved according to the respective formulations. Alcohol was added.
【表１】 [Table 1]
【００１５】[0015]
【試験例】前記実施例１及び比較例１〜４で調製された
透明ゲル状毛髪処理剤組成物を用いて、以下に示す水
分保持能、毛髪のなめらか感、ゲル性、ゲル透明
性の各項目について試験した。尚、比較例３の組成物に
ついては、ゲル性を示さなかったので、水分保持能、毛
髪のなめらか感、ゲル透明性の評価は行なわなかった。
この結果をまとめて表２に示す。[Test Example] Using the transparent gel-like hair treatment composition prepared in Example 1 and Comparative Examples 1 to 4, each of the following water retention ability, smoothness of hair, gel property, and gel transparency was obtained. The item was tested. Since the composition of Comparative Example 3 did not exhibit gelling properties, the water retention ability, smoothness of hair and gel transparency were not evaluated.
The results are summarized in Table 2.
【表２】 [Table 2]
【００１６】（１）毛髪水分保持能 約１ｇ、約11cmの毛束に、前記実施例１及び比較例１〜
４で得られた透明ゲル状毛髪処理剤組成物をそれぞれ0.
25g ずつ塗布して乾燥させた後、アクアチェッカー（ビ
ヤンテットアクアチェッカー HC1000 ／ファインコスメ
ティック（株）製）を用いて、毛髪の水分量を測定し
た。水分量が９％以下であるものを×、１０〜１１％の
範囲内であるものを△、１２％以上であるものを〇と評
価した。(1) Moisture Retaining Ability of Hair For a hair bundle of about 1 g and about 11 cm, the above-mentioned Example 1 and Comparative Examples 1 to 1 were used.
The transparent gel-like hair treatment composition obtained in 4 above was added to each
After applying 25 g each and drying, the water content of the hair was measured using an Aqua Checker (Byantedt Aqua Checker HC1000 / manufactured by Fine Cosmetics Co., Ltd.). The water content of 9% or less was evaluated as x, the water content within the range of 10 to 11% was evaluated as Δ, and the water content of 12% or more was evaluated as ◯.
【００１７】（２）毛髪のなめらか感 約１g 、約11cmの毛束を用い、この毛束に前記実施例１
及び比較例１〜４で得られた透明ゲル状毛髪処理剤組成
物をそれぞれ0.25g ずつ塗布して乾燥させたものについ
て、表面性試験機（KES-SF／カトーテック（株）製）を
用いてそれぞれの平均摩擦係数を測定した。尚、前記実
施例及び比較例の透明ゲル状毛髪処理剤組成物に代えて
水のみで同様に処理した毛束についても同様に平均摩擦
係数を測定し、それぞれの摩擦係数の比を変化量として
表し、評価の指標とした。 変化量＝実施例及び比較例の組成物での処理毛の平均摩
擦係数／水で処理した毛髪の平均摩擦係数 変化量の値が０．８５未満のものを〇、０．９５〜０．
８５のものを△、０．９５以上のものを×とした。(2) Smoothness of hair A hair bundle of about 1 g and about 11 cm is used.
And about 0.25 g each of the transparent gel-like hair treatment composition obtained in Comparative Examples 1 to 4 and dried, a surface property tester (KES-SF / Kato Tech Co., Ltd.) was used. The average friction coefficient of each was measured. Incidentally, the average friction coefficient was similarly measured for hair bundles treated in the same manner with water instead of the transparent gel hair treatment composition of the above Examples and Comparative Examples, and the ratio of each friction coefficient was taken as the change amount. It was shown and used as an index for evaluation. Amount of change = average friction coefficient of hair treated with the compositions of Examples and Comparative Examples / average friction coefficient of hair treated with water. The amount of change of less than 0.85 is 0, 0.95 to 0.
A sample of 85 was evaluated as Δ and a sample of 0.95 or more was evaluated as x.
【００１８】（３）ゲル性評価 前記実施例及び比較例で得られた透明ゲル状毛髪処理剤
組成物のそれぞれのゲル性を目視評価し、良好なゲル性
を示しているものを〇、良好なゲル性を示していないも
のを△、保形性を示さないものを×と評価した。 （４）ゲル透明性評価 前記実施例及び比較例で得られた透明ゲル状毛髪処理剤
組成物のそれぞれのゲルの透明性を目視評価し、透明性
を示しているものを〇、やや透明性を示しているものを
△、透明性を示していないものを×と評価した。(3) Evaluation of gel property The gel properties of the transparent gel hair treatment compositions obtained in the above Examples and Comparative Examples were visually evaluated, and those showing good gel properties were evaluated as ◯ and good. The sample which did not exhibit such gel property was evaluated as Δ, and the sample which did not exhibit shape retention property was evaluated as ×. (4) Gel Transparency Evaluation The transparency of each gel of the transparent gel hair treatment composition obtained in the above-mentioned Examples and Comparative Examples was visually evaluated, and those showing transparency were evaluated as ◯, and slightly transparent. Was evaluated as Δ, and those not showing transparency were evaluated as x.
【００１９】表２の結果から明らかな如く、モノグリセ
ライド型アニオン性界面活性剤を配合しないゲル状毛髪
処理剤組成物（比較例１）では、得られるゲルの透明性
や性能は良好であるものの、毛髪に対する水分保持能や
なめらか感が劣ることが判る。また、モノグリセライド
型アニオン性界面活性剤の配合量が１重量％を超えたも
の（比較例２）では、ゲル性が良好ではなく、且つ毛髪
に対して充分ななめらか感を与えることができないこと
が判る。カルボキシビニルポリマーを全く配合しない組
成物（比較例３）では、ゲル性が示されていないことが
判る。モノグリセライド型アニオン性界面活性剤に代え
て、塩化ステアリルトリメチルアンモニウムを加えた組
成物（比較例４）では、得られるゲルの透明性がなく、
しかも充分な水分保持能、毛髪のなめらか感、ゲル性が
得られていないことが判る。As is clear from the results shown in Table 2, in the gel hair treatment composition not containing the monoglyceride type anionic surfactant (Comparative Example 1), the obtained gel has good transparency and performance, It can be seen that the water retention ability and the smooth feeling on the hair are inferior. Further, when the content of the monoglyceride type anionic surfactant exceeds 1% by weight (Comparative Example 2), the gel property is not good, and it is impossible to give a sufficient smooth feeling to the hair. I understand. It can be seen that the composition having no carboxyvinyl polymer (Comparative Example 3) does not show gelling property. The composition obtained by adding stearyl trimethyl ammonium chloride in place of the monoglyceride type anionic surfactant (Comparative Example 4) had no transparency of the obtained gel,
Moreover, it is understood that sufficient water retention ability, smooth feeling of hair, and gel property are not obtained.
【００２０】[0020]
【発明の効果】以上詳述した如く、この発明は一般式４
（化４）にて示されるモノグリセライド型アニオン性界
面活性剤０．０５〜１重量％と、アニオン性高分子化合
物０．１〜１０重量％が配合されてなることを特徴とす
る透明ゲル状毛髪処理剤組成物であるから、前記実施例
からも明らかな如く、透明性及びゲル性が良好で、適度
な粘性を有するため、垂れ落ちたりせず手に取りやす
く、直接髪に塗布しやすいなど優れた使用性を示し、し
かも安全で、毛髪に対してなめらさ等のコンディショニ
ング効果を与えることができるという優れた効果を奏す
る。As described above in detail, the present invention has the general formula 4
A transparent gel-like hair comprising 0.05 to 1% by weight of a monoglyceride type anionic surfactant represented by (Chemical Formula 4) and 0.1 to 10% by weight of an anionic polymer compound. Since it is a treating agent composition, as is clear from the above examples, it has good transparency and gelling property and has an appropriate viscosity, so it is easy to pick up without dropping and is easy to apply directly to hair. It exhibits excellent usability, is safe, and can impart conditioning effects such as smoothness to hair.
【化４】 〔但し、式中Ｒ1 は炭素数８〜２０の飽和又は不飽和の
アルキル基又はアルキルフェニル基であり、ＸはＯＳＯ
3 Ｙ、ＯＰＯ3 Ｙ又はＯ2 ＰＯ2 Ｙ（Ｙは水素原子、ア
ルカリ金属、アルカリ土類金属、アンモニウム基又はア
ルカノールアミンのうちのいずれか）を示す。〕[Chemical 4] [Wherein, R 1 is a saturated or unsaturated alkyl group having 8 to 20 carbon atoms or an alkylphenyl group, and X is OSO.
3 Y, OPO 3 Y or O 2 PO 2 Y (Y is any one of a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium group and an alkanolamine). ]
Claims (1)
セライド型アニオン性界面活性剤０．０５〜１重量％
と、アニオン性高分子化合物０．１〜１０重量％が配合
されてなることを特徴とする透明ゲル状毛髪処理剤組成
物。 【化１】 〔但し、式中Ｒ1 は炭素数８〜２０の飽和又は不飽和の
アルキル基又はアルキルフェニル基であり、ＸはＯＳＯ
3 Ｙ、ＯＰＯ3 Ｙ又はＯ2 ＰＯ2 Ｙ（Ｙは水素原子、ア
ルカリ金属、アルカリ土類金属、アンモニウム基又はア
ルカノールアミンのうちのいずれか）を示す。〕1. A monoglyceride type anionic surfactant represented by the general formula 1 (formula 1): 0.05 to 1% by weight
And 0.1 to 10% by weight of an anionic polymer compound, which is a transparent gel-like hair treatment composition. [Chemical 1] [Wherein, R 1 is a saturated or unsaturated alkyl group having 8 to 20 carbon atoms or an alkylphenyl group, and X is OSO.
3 Y, OPO 3 Y or O 2 PO 2 Y (Y is any one of a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium group and an alkanolamine). ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24386493A JP3285172B2 (en) | 1993-09-02 | 1993-09-02 | Transparent gel hair treatment composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24386493A JP3285172B2 (en) | 1993-09-02 | 1993-09-02 | Transparent gel hair treatment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0769848A true JPH0769848A (en) | 1995-03-14 |
| JP3285172B2 JP3285172B2 (en) | 2002-05-27 |
Family
ID=17110114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24386493A Expired - Fee Related JP3285172B2 (en) | 1993-09-02 | 1993-09-02 | Transparent gel hair treatment composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3285172B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6060195A (en) * | 1983-09-12 | 1985-04-06 | 日本サ−フアクタント工業株式会社 | Detergent composition |
| JPS62280297A (en) * | 1986-05-28 | 1987-12-05 | カネボウ株式会社 | Low irritant detergent composition |
| JPH0488099A (en) * | 1990-07-30 | 1992-03-19 | Lion Corp | Liquid detergent composition |
| JPH04120012A (en) * | 1990-09-10 | 1992-04-21 | Sakamoto Yakuhin Kogyo Kk | Transparent gelatinous cleaning agent |
-
1993
- 1993-09-02 JP JP24386493A patent/JP3285172B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6060195A (en) * | 1983-09-12 | 1985-04-06 | 日本サ−フアクタント工業株式会社 | Detergent composition |
| JPS62280297A (en) * | 1986-05-28 | 1987-12-05 | カネボウ株式会社 | Low irritant detergent composition |
| JPH0488099A (en) * | 1990-07-30 | 1992-03-19 | Lion Corp | Liquid detergent composition |
| JPH04120012A (en) * | 1990-09-10 | 1992-04-21 | Sakamoto Yakuhin Kogyo Kk | Transparent gelatinous cleaning agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3285172B2 (en) | 2002-05-27 |
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