JPH0811272B2 - Mold coating method - Google Patents

Mold coating method

Info

Publication number
JPH0811272B2
JPH0811272B2 JP1757888A JP1757888A JPH0811272B2 JP H0811272 B2 JPH0811272 B2 JP H0811272B2 JP 1757888 A JP1757888 A JP 1757888A JP 1757888 A JP1757888 A JP 1757888A JP H0811272 B2 JPH0811272 B2 JP H0811272B2
Authority
JP
Japan
Prior art keywords
mold
coating material
casting
coating
fluidized bed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP1757888A
Other languages
Japanese (ja)
Other versions
JPH01192443A (en
Inventor
隆一 升田
芳郎 林
健治 甲斐田
雄二 榊原
隆敏 鈴木
宏明 林
保夫 高田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Toyota Central R&D Labs Inc
Original Assignee
Toyota Motor Corp
Toyota Central R&D Labs Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp, Toyota Central R&D Labs Inc filed Critical Toyota Motor Corp
Priority to JP1757888A priority Critical patent/JPH0811272B2/en
Priority to DE88114298T priority patent/DE3870774D1/de
Priority to EP88114298A priority patent/EP0306841B1/en
Priority to US07/238,848 priority patent/US4934440A/en
Publication of JPH01192443A publication Critical patent/JPH01192443A/en
Priority to US08/145,468 priority patent/US5372179A/en
Publication of JPH0811272B2 publication Critical patent/JPH0811272B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は金型鋳造用鋳型の製造時に鋳物の精度および
外観を良好にするために行う鋳型の被覆方法に関する。
Description: TECHNICAL FIELD The present invention relates to a method of coating a mold for improving the accuracy and appearance of a casting mold when manufacturing the mold.

(従来の技術) 金型鋳造用鋳型、たとえば砂型では通気性および強度
上の理由から、砂型を構成する砂の粒子は比較的粗いも
のを使用している。このため、鋳造時には第5図に示す
ように、溶湯31が鋳型32の内壁すなわち鋳型砂33の粒子
間に侵入して、34に示す『めざし』と呼ばれるものが生
じる。上記めざし34によって鋳物の型離れがしにくくな
り、さらに鋳型砂の粒子の粗さも手伝い鋳肌が荒れるこ
とになる。したがって、良品質のきめが細かい表面を有
する鋳物を得られない。
(Prior Art) In molds for molding dies, for example, sand molds, relatively coarse sand particles are used for the reasons of air permeability and strength. Therefore, at the time of casting, as shown in FIG. 5, the molten metal 31 penetrates into the inner wall of the mold 32, that is, between the particles of the mold sand 33, and what is called “aim” is generated at 34. The above aim 34 makes it difficult for the casting to be released from the mold, and further the roughness of the particles of the molding sand will help to roughen the casting surface. Therefore, it is impossible to obtain a casting having a fine texture and a fine surface.

そこで、きめの細かい鋳肌の製品を得るために、第6
図に示す鋳型32の表面に、粉状の含水性物質または微粒
な砂を被覆して、めざし34の発生を防止している(特願
昭62-222646号公報参照)。この粉状の含水性物質は被
覆材35として直接、また微粒な砂は水、アルコール、バ
インダなどとともにスラリ状の被覆材35に加工したの
ち、刷毛、スプレー、浸漬などの手段によって鋳型32の
表面に被覆されていた。
Therefore, in order to obtain a product with a fine casting surface,
The surface of the mold 32 shown in the figure is coated with a powdery hydrous substance or fine sand to prevent the aim 34 from occurring (see Japanese Patent Application No. 62-222646). The powdery hydrous substance is directly used as the covering material 35, and fine sand is processed into a slurry-like covering material 35 together with water, alcohol, binder, etc., and then the surface of the mold 32 is applied by a brush, a spray, a dipping means or the like. Was covered with.

しかしながら、前記被覆材には水分が含まれているた
めに鋳型の乾燥作業が必要であり、この乾燥作業中に前
記被覆材に割れやブリスタなどが生じ、前記被覆材が鋳
型表面から剥離し易くなる。また、前記乾燥作業が充分
に行われない場合には、当該鋳型を使用した鋳造作業中
に前記被覆材に含まれていた水分が気化して気泡にな
り、鋳物(製品)の表面に影響をおよぼす。
However, it is necessary to dry the mold because the coating material contains water, cracks and blisters occur in the coating material during the drying operation, and the coating material easily peels from the mold surface. Become. If the drying operation is not sufficiently performed, the water contained in the coating material during the casting operation using the mold is vaporized to form bubbles, which may affect the surface of the casting (product). Extend.

したがって、良好な品質の製品が得られない。同様
に、被覆材が吸湿性の大きい材質である場合、前記乾燥
作業に多くの時間を要し、作業性および生産性の劣化と
コスト上昇とを招くという問題があった。さらに、被覆
材が表面張力によって鋳型のエッジ部付近で盛り上がる
ためタレ36を生じ、被覆材の厚さが均等になりにくい。
これにより、鋳型精度に影響して製品の寸法精度が劣化
する。
Therefore, a product of good quality cannot be obtained. Similarly, when the covering material is a material having a high hygroscopicity, there is a problem that the drying operation requires a lot of time, resulting in deterioration of workability and productivity and an increase in cost. Furthermore, since the coating material rises near the edge of the mold due to surface tension, sagging 36 occurs and it is difficult for the coating material to have a uniform thickness.
As a result, the precision of the mold is affected and the dimensional precision of the product deteriorates.

このため、粉末状の被覆材の流動層中に鋳型を配置し
たのち、当該鋳型を前記流動層の中を上下動させること
によって、第2図に示すように被覆材を鋳型に被覆する
方法が提案された(特願昭62-233575号公報参照)。こ
れにより、鋳型の乾燥作業が不要になった。
Therefore, a method of coating the coating material on the mold as shown in FIG. 2 by arranging the mold in the fluidized bed of the powdery coating material and then moving the mold up and down in the fluidized bed is proposed. Proposed (see Japanese Patent Application No. 62-233575). This eliminates the need to dry the mold.

(発明が解決しようとする課題) しかしながら、特願昭62-233575号公報に開示された
技術は、被覆材が鋳型を構成する鋳型砂の間隙深部まで
充分到達しないので、きめの細かい鋳型表面を形成する
ことができず、また鋳型表面に付着した被覆材が飛散し
易い。このため、被覆材の厚さが均等にならないので鋳
型精度が劣化するとともに、きめの細かい鋳肌の鋳物を
得ることができなかった。
(Problems to be Solved by the Invention) However, in the technique disclosed in Japanese Patent Application No. 62-233575, since the coating material does not sufficiently reach the deep part of the gap of the mold sand constituting the mold, a fine textured mold surface can be obtained. It cannot be formed, and the coating material adhered to the mold surface easily scatters. For this reason, the thickness of the coating material is not uniform, the mold precision is deteriorated, and it is not possible to obtain a casting having a fine-grained casting surface.

そこで、本発明は乾燥作業が不要であり、良好な製品
を得るための鋳型の被覆方法を提供することを目的とす
る。
Therefore, an object of the present invention is to provide a method of coating a mold for obtaining a good product, which does not require a drying operation.

(課題を解決するための手段) 本発明は上記目的を達成するために、粉末状の被覆材
10の流動層12中に鋳型8を配置し、鋳型8の表面に摺接
自在な毛状材13を有する補助材11を摺接させて被覆材10
を鋳型8に被覆することを特徴とするものである。
(Means for Solving the Problems) In order to achieve the above object, the present invention provides a powdery coating material.
The casting mold 8 is arranged in the fluidized bed 12 of 10 and the auxiliary material 11 having the bristle material 13 slidable on the casting mold 8 is slidably contacted with the covering material 10
Is coated on the mold 8.

(作用) 本発明は上記のように構成したので、流動層12中の被
覆材10を補助材11の毛状材13によって鋳型8の表面に摺
接させ、鋳型8表面の粒子間深部まで被覆材10を充填さ
せる。さらに、被覆材10には水分が混合または含有して
いないため、乾燥作業は不要である。
(Function) Since the present invention is configured as described above, the coating material 10 in the fluidized bed 12 is slidably contacted with the surface of the mold 8 by the hair material 13 of the auxiliary material 11 to cover the deep part between particles on the surface of the mold 8. Fill the material 10. Furthermore, since the covering material 10 does not contain or contain water, no drying operation is required.

(実施例) 以下に、本発明の一実施例を図面に基いて詳細に説明
する。
(Example) Below, one Example of this invention is described in detail based on drawing.

第1図において、1は本発明の方法を実施するための
鋳型の被覆装置である。本装置1は筒状の本体2と、本
体2を取付けるための基台3と、本体2と基台3との間
に配置した多孔板4とを主構成とし、本体2は多孔板4
とともに基台3にボルト固定してある。
In FIG. 1, reference numeral 1 is a mold coating apparatus for carrying out the method of the present invention. The main body of this device 1 is a cylindrical main body 2, a base 3 for mounting the main body 2, and a perforated plate 4 arranged between the main body 2 and the base 3.
At the same time, it is bolted to the base 3.

多孔板4には設置部材9が設けてあり、設置部材9は
図示を省略した固定治具によって、鋳型11を本体2の内
側に設置する。
The perforated plate 4 is provided with an installation member 9, and the installation member 9 sets the mold 11 inside the main body 2 by a fixing jig (not shown).

基台3は多孔板4とともに内側に空間を形成し、この
空間と本体2内部とは、多孔板4に複数穿設された細孔
6によって連通する。また、基台3の側壁には貫通孔5
が設けてあり、貫通孔5には空気などからなる流動ガス
を基台3内部に流入させるノズル7が嵌挿してある。
The base 3 forms a space inside with the porous plate 4, and the space and the inside of the main body 2 are communicated with each other by the pores 6 formed in the porous plate 4. In addition, a through hole 5 is formed in the side wall of the base 3.
Is provided, and a nozzle 7 for allowing a flowing gas such as air to flow into the base 3 is fitted into the through hole 5.

本体2内部には円筒形状をなす補助材8が配設してあ
り、補助材8は図示を省略した駆動装置によって回転軸
lを中心に回転駆動されながら、上下動など所定の方向
に移動される。また、補助材8の内壁には毛状材13が植
立して、ブラシを形成し、毛状材13は前記駆動装置によ
って設置部材9に固定された鋳型11の表面に摺接する。
また、この毛状材13は鋳型11表面にキズをつけないよう
に柔らかく、かつ鋳型11に被覆材10をこすりつけて鋳型
11表面の鋳型砂の粒子間深部に押込みうる弾力を備えた
ものである。
A cylindrical auxiliary member 8 is disposed inside the main body 2, and the auxiliary member 8 is moved in a predetermined direction such as vertical movement while being rotationally driven about a rotation axis 1 by a drive device (not shown). It Further, the bristles 13 are erected on the inner wall of the auxiliary member 8 to form a brush, and the bristles 13 slide on the surface of the mold 11 fixed to the installation member 9 by the driving device.
Further, this bristle material 13 is soft so that the surface of the mold 11 is not scratched, and the covering material 10 is rubbed on the mold 11 to mold it.
11 It has elasticity that allows it to be pushed into the deep part between the particles of the mold sand on the surface.

被覆材10は鋳型11表面の粒子間または、くぼみに入り
込むように、200μm以下の粒子径を有する粉末状また
は顆粒状のもので、本体2の内部に備えられてある。被
覆材10はきめの細かい鋳肌の製品を得るためのもので、
粘土鉱物、天然鉱物、人造鉱物または活性炭を使用す
る。前記粘土鉱物としてセピオライト、パリゴルスカイ
ト、珪藻土、ゼオライト、バーミキュライトなど、天然
鉱物として珪砂、クロマイトサンド、ジルコンサイド、
シリカフラワーなど、人造鉱物としてアルミナ、合成ム
ライト、溶融シリカなどがある。なお、被覆材10は上記
の各種素材のうち1種または複数種使用してもよい。被
覆材10はノズル7から基台3の内部に導かれ、細孔6か
ら本体2の内部に流入する前記流動ガスによって流動さ
せられ、本体2の内部に被覆材10と前記流動ガスとで流
動層12を形成する。
The coating material 10 is in the form of powder or granules having a particle size of 200 μm or less so as to enter between the particles on the surface of the mold 11 or into the depressions, and is provided inside the main body 2. The coating material 10 is for obtaining a product with a fine-grained casting surface,
Use clay minerals, natural minerals, artificial minerals or activated carbon. Sepiolite, palygorskite, diatomaceous earth, zeolite, vermiculite and the like as the clay mineral, silica sand, chromite sand, zircon side as the natural mineral,
Artificial minerals such as silica flour include alumina, synthetic mullite, and fused silica. The coating material 10 may be one or more of the above various materials. The coating material 10 is guided from the nozzle 7 to the inside of the base 3 and is made to flow by the flowing gas flowing into the main body 2 from the pores 6, and is flowed inside the main body 2 by the coating material 10 and the flowing gas. Form layer 12.

つぎに、上記構成に係る装置を使用し、本発明の方法
を説明する。
Next, the method of the present invention will be described using the apparatus having the above-mentioned configuration.

まず、設置部材9に鋳型11を固定するとともに、補助
材8を鋳型11に被覆させたのち、ノズル7から前記流動
ガスを導入する。これにより、前記流動ガスが細孔6か
ら本体2内部に導かれ、本体2内部に流動層12を形成す
る。この際、被覆材10が流動層12中の気体に含まれた水
分を吸収しないように、乾燥した空気、熱風などを流動
ガスに使用してもよい。
First, the mold 11 is fixed to the installation member 9, the mold 11 is covered with the auxiliary material 8, and then the flowing gas is introduced from the nozzle 7. As a result, the fluidized gas is introduced into the body 2 through the pores 6 and forms the fluidized bed 12 inside the body 2. At this time, dry air, hot air, or the like may be used as the flowing gas so that the coating material 10 does not absorb the water contained in the gas in the fluidized bed 12.

つぎに、前記駆動装置を操作すると補助材8が回転軸
lを中心に回転し、毛状材13が鋳型11の表面に摺接す
る。このため、鋳型11表面の粒子間には流動層12中の被
覆材10がこすりつけられ、被覆材10の被覆作業が開始さ
れる(第2図参照)。
Next, when the driving device is operated, the auxiliary material 8 rotates about the rotation axis l, and the hair material 13 comes into sliding contact with the surface of the mold 11. Therefore, the coating material 10 in the fluidized bed 12 is rubbed between the particles on the surface of the mold 11, and the coating operation of the coating material 10 is started (see FIG. 2).

つづいて、補助材8は前記駆動装置によって回転軸l
を中心に回転しながら所定方向に往復移動される。これ
により、流動層12中の被覆材10は鋳型11表面の粒子間お
よび間隙の深部に押込め充填されるので、流動層12中の
被覆材10は鋳型11の表面全体を均一に被覆する。(第3
図および第4図参照)。
Subsequently, the auxiliary member 8 is rotated by the drive unit to rotate the rotary shaft l.
It is reciprocated in a predetermined direction while rotating around. As a result, the coating material 10 in the fluidized bed 12 is pressed and filled between the particles on the surface of the mold 11 and deep in the gap, so that the coating material 10 in the fluidized bed 12 uniformly covers the entire surface of the mold 11. (Third
(See Figure and Figure 4).

この被覆作業が終了したのち、設置部材9から鋳型11
を外し、次工程に当該鋳型11を搬送する。なお、当該鋳
型11には乾燥作業を施さない。
After the covering work is completed, the installation member 9 is moved to the mold 11
Then, the mold 11 is conveyed to the next step. The mold 11 is not dried.

つぎに、上記方法によって鋳型11に被覆材10を被覆し
た具体例を以下に説明する。
Next, a specific example in which the mold 11 is coated with the coating material 10 by the above method will be described below.

まず、鋳型11としては、樹脂被覆鋳物砂(珪砂100重
量部、フェノール樹脂2重量部、粒6号)を使用して、
上部外径73mm、下部外径80mm、高さ110mm、厚さ10mm、
の中空円筒体を作成し、他方、被覆材10としては粒子径
50μm以下のセピオライトを使用した。
First, as the mold 11, resin-coated molding sand (100 parts by weight of silica sand, 2 parts by weight of phenol resin, No. 6 grain) was used.
Upper outer diameter 73 mm, lower outer diameter 80 mm, height 110 mm, thickness 10 mm,
The hollow cylindrical body of
Sepiolite of 50 μm or less was used.

また、鋳型の被覆装置1は本体2が縦330mm、横350m
m、高さ400mmの寸法を有するものを使用して、前記中空
円筒体(鋳型)に本発明の方法を実施した。
Further, the mold coating apparatus 1 has a main body 2 with a length of 330 mm and a width of 350 m.
The method of the present invention was carried out on the hollow cylinder (mold) using a material having a size of m and a height of 400 mm.

そして、補助材8の回転数は0rpm、30rpm、60rpmの3
種を、設置部材9による鋳型11の上下動回数は10回、20
回、30回の3種を、それぞれについてサンプルNo.1ない
しサンプルNo.9として実験した。各Noの被覆材10の被覆
量(g/m2)は以下に示した表1に示すとおりである。
The rotation speed of the auxiliary material 8 is 0 rpm, 30 rpm, and 60 rpm.
The seeds are moved up and down 10 times by the installation member 9
3 times, 30 times, were tested as sample No. 1 to sample No. 9, respectively. The coating amount (g / m 2 ) of each No. 10 coating material is as shown in Table 1 below.

表1に示すように、鋳型11に被覆される被覆材10の単
位面積当りの量は、補助材8による回転数が大きい程、
また設置部材9による鋳型11の上下動回数が多い程、少
しづつ多くなる傾向がある。
As shown in Table 1, the amount of the coating material 10 coated on the mold 11 per unit area increases as the rotation speed of the auxiliary material 8 increases,
Further, the larger the number of vertical movements of the casting mold 11 by the installation member 9 is, the more it tends to increase little by little.

つぎに、上記方法によって鋳型11に被覆材11を被覆し
て鋳造した場合と、被覆することなく鋳造した場合と
を、上記の表1中の『サンプルNo.5』を例にとり、以下
に鋳肌の比較をする。この鋳物は前記中空円筒体に700
℃のアルミニウム合金(JIS AC2B)を鋳込み鋳造したも
のである。
Next, the case of casting with the coating material 11 coated on the mold 11 by the above method, and the case of casting without coating, taking "Sample No. 5" in Table 1 above as an example, Compare the skin. This casting is 700
It is made by casting aluminum alloy (JIS AC2B) at ℃.

その結果、被覆材11を被覆することなく鋳造した鋳物
の粗さが90μmであるのに対して、『サンプルNo.5』に
よる鋳物の粗さは32μmであり、約1/3の値を示した。
As a result, the roughness of the casting cast without coating the coating material 11 is 90 μm, while the roughness of the casting according to “Sample No. 5” is 32 μm, which is about 1/3. It was

(発明の効果) 本発明は以上説明したように、乾燥作業を行うことな
く、鋳型表面の粒子間深部まで被覆材を充填させること
ができる。このため、被覆材の厚さが均等になるので、
鋳型精度が良好になり製品の寸法精度が向上するととも
に、きめの細かい鋳肌を得ることができる。
(Effects of the Invention) As described above, the present invention can fill a coating material to a deep part between particles on a mold surface without performing a drying operation. For this reason, since the thickness of the covering material becomes even,
The mold precision is improved, the dimensional precision of the product is improved, and a fine-grained casting surface can be obtained.

【図面の簡単な説明】[Brief description of drawings]

第1図は、本発明の方法を実施するため装置の断面図、 第2図は、第1図に示す流動層内に鋳型を配置させた状
態を示す断面図、 第3図は、第2図の被覆材と鋳型と補助材との状態を示
す断面図、 第4図は、本発明の方法を実施後の被覆材と鋳型との状
態を示す断面図、 第5図は、従来の鋳型を使用した鋳造の状態を表した断
面図、 第6図は、従来の鋳型と被覆材との被覆状態を表した断
面図である。 1……鋳型の被覆装置、2……本体 3……基台、4……多孔板 5……貫通孔、6……細孔 7……ノズル、8……補助材 9……設置部材、10……被覆材 11……鋳型、12……流動層 13……毛状材、l……回転軸
FIG. 1 is a sectional view of an apparatus for carrying out the method of the present invention, FIG. 2 is a sectional view showing a state in which a mold is placed in the fluidized bed shown in FIG. 1, and FIG. FIG. 4 is a sectional view showing the state of the covering material, the mold and the auxiliary material in the figure, FIG. 4 is a sectional view showing the state of the covering material and the mold after carrying out the method of the present invention, and FIG. FIG. 6 is a cross-sectional view showing the state of casting using, and FIG. 6 is a cross-sectional view showing the state of coating of the conventional mold and the coating material. 1 ... Mold coating device, 2 ... Main body 3 ... Base, 4 ... Perforated plate 5 ... Through hole, 6 ... Pores 7 ... Nozzle, 8 ... Auxiliary material 9 ... Installation member, 10 …… Coating material 11 …… Mold, 12 …… Fluidized bed 13 …… Bristles, l …… Rotating shaft

フロントページの続き (72)発明者 甲斐田 健治 愛知県豊田市トヨタ町1番地 トヨタ自動 車株式会社内 (72)発明者 榊原 雄二 愛知県愛知郡長久手町大字長湫字横道41番 地の1 株式会社豊田中央研究所内 (72)発明者 鈴木 隆敏 愛知県愛知郡長久手町大字長湫字横道41番 地の1 株式会社豊田中央研究所内 (72)発明者 林 宏明 愛知県愛知郡長久手町大字長湫字横道41番 地の1 株式会社豊田中央研究所内 (72)発明者 高田 保夫 愛知県愛知郡長久手町大字長湫字横道41番 地の1 株式会社豊田中央研究所内 (56)参考文献 実開 昭47−12211(JP,U)Front page continued (72) Inventor Kenji Kaida 1 Toyota Town, Toyota City, Aichi Prefecture Toyota Motor Co., Ltd. (72) Inventor Yuji Sakakibara 41, Nagakute Town, Aichi-gun, Aichi Prefecture Toyota Corporation 1 41 Yokomichi In the Central Research Laboratory (72) Inventor Takatoshi Suzuki, Aichi Prefecture, Nagakute Town, Aichi Prefecture, Nagacho, Yoko 41 1 In the Toyota Central Research Institute Co., Ltd. (72) Inventor Yasuo Takada 1 in 41, Yokoshiro, Nagakute-cho, Aichi-gun, Aichi-gun 1 In Toyota Central Research Institute Co., Ltd. (56) References , U)

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】粉末状の被覆材の流動層中に鋳型を配置
し、該鋳型の表面に摺接自在な毛状材を有する補助材を
摺接させて被覆材を鋳型に被覆することを特徴とする鋳
型の被覆方法。
1. A mold is placed in a fluidized bed of a powdery coating material, and an auxiliary material having a bristle material slidably contacting the surface of the mold is slidably contacted to coat the coating material on the mold. A characteristic method for coating a mold.
JP1757888A 1987-09-05 1988-01-28 Mold coating method Expired - Lifetime JPH0811272B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP1757888A JPH0811272B2 (en) 1988-01-28 1988-01-28 Mold coating method
DE88114298T DE3870774D1 (en) 1987-09-05 1988-09-01
EP88114298A EP0306841B1 (en) 1987-09-05 1988-09-01 Mold surface treatment process and mold
US07/238,848 US4934440A (en) 1987-09-05 1988-09-01 Mold surface treatment process and mold
US08/145,468 US5372179A (en) 1987-09-05 1993-10-22 Mold surface treatment process and mold

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1757888A JPH0811272B2 (en) 1988-01-28 1988-01-28 Mold coating method

Publications (2)

Publication Number Publication Date
JPH01192443A JPH01192443A (en) 1989-08-02
JPH0811272B2 true JPH0811272B2 (en) 1996-02-07

Family

ID=11947792

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1757888A Expired - Lifetime JPH0811272B2 (en) 1987-09-05 1988-01-28 Mold coating method

Country Status (1)

Country Link
JP (1) JPH0811272B2 (en)

Also Published As

Publication number Publication date
JPH01192443A (en) 1989-08-02

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