JPH08119656A - Method for manufacturing multi-core fiber preform - Google Patents

Method for manufacturing multi-core fiber preform

Info

Publication number
JPH08119656A
JPH08119656A JP6250491A JP25049194A JPH08119656A JP H08119656 A JPH08119656 A JP H08119656A JP 6250491 A JP6250491 A JP 6250491A JP 25049194 A JP25049194 A JP 25049194A JP H08119656 A JPH08119656 A JP H08119656A
Authority
JP
Japan
Prior art keywords
core
quartz tube
fiber preform
gap
quartz
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6250491A
Other languages
Japanese (ja)
Inventor
Atsushi Abe
淳 阿部
Kazuo Kamiya
和雄 神屋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
Original Assignee
Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Priority to JP6250491A priority Critical patent/JPH08119656A/en
Publication of JPH08119656A publication Critical patent/JPH08119656A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/01205Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments
    • C03B37/01211Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments by inserting one or more rods or tubes into a tube
    • C03B37/01222Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments by inserting one or more rods or tubes into a tube for making preforms of multiple core optical fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2203/00Fibre product details, e.g. structure, shape
    • C03B2203/34Plural core other than bundles, e.g. double core
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02042Multicore optical fibres

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)

Abstract

(57)【要約】 (修正有) 【目的】 本発明は光の伝搬損失の小さいマルチコアフ
ァイバ母材を製造するマルチコアファイバ母材製造方法
の提供を目的とするものである。 【構成】 本発明によるマルチコアファイバ母材の製造
方法は、石英管内に複数個のコア部材を束ねて充填した
のち、該コア材とコア材、該コア材と該石英管とのすき
間に、SiO2を主原料とする物質あるいは屈折率が石英と
同程度の物質を充填してすき間をなくしてから、該石英
管を高温度でコラプスすることを特徴とするものであ
る。
(57) [Summary] (Modified) [Objective] The present invention aims to provide a multicore fiber preform manufacturing method for manufacturing a multicore fiber preform having a small propagation loss of light. A method of manufacturing a multi-core fiber preform according to the present invention comprises bundling a plurality of core members in a quartz tube and filling the quartz tube with the core material and the SiO 2 between the core material and the gap between the core material and the quartz tube. It is characterized in that a substance containing 2 as a main raw material or a substance having a refractive index similar to that of quartz is filled to eliminate a gap, and then the quartz tube is collapsed at a high temperature.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はマルチコアファイバ母材
の製造方法、特には複数のコア材を石英管内に束ねてコ
ラプスしても形状がひずまないので、光の伝搬損失を小
さくすることができるマルチコアファイバ母材を製造方
法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a multi-core fiber preform, and more particularly, since the shape is not distorted even if a plurality of core materials are bundled in a quartz tube and collapsed, the propagation loss of light can be reduced. The present invention relates to a method for manufacturing a multicore fiber preform.

【0002】[0002]

【従来の技術】マルチコアファイバ母材の製造は、図2
に示すように従来石英管内にコア材を束ねて充填し、こ
れをコラプスすることによって行なわれている。
2. Description of the Related Art Manufacturing of a multi-core fiber preform is shown in FIG.
As shown in FIG. 1, conventionally, it is performed by bundling and filling a core material in a quartz tube and collapsing it.

【0003】[0003]

【発明が解決しようとする課題】しかし、この従来法で
のマルチコアファイバ母材の製造については、図5
(a)に示したように、まず石英管11の中に複数個のコ
ア材12を束ねて充填すると、これには図示してあるよう
にコア材とコア材の間、またはコア材と石英管との間に
すき間13が生ずるため、これをコラプスするとでき上る
マルチコアファイバ母材14は図5(b)に示したように
コアがひずんだ状態となり、したがって光の伝搬損失の
大きいものになるという不利がある。
However, the manufacturing of the multi-core fiber preform by this conventional method is described with reference to FIG.
As shown in (a), first, a plurality of core materials 12 are bundled and filled in a quartz tube 11, and as shown in the drawing, between the core materials, or between the core materials and the quartz. Since a gap 13 is formed between the tube and the tube, the multi-core fiber preform 14 produced by collapsing this has a distorted core as shown in FIG. 5 (b), and thus has a large light propagation loss. There is a disadvantage that.

【0004】[0004]

【課題を解決するための手段】本発明はこのような不
利、問題点を解決したマルチコアファイバ母材の製造方
法に関するもので、これは複数のコアからなるマルチコ
アファイバ母材の製造方法において、石英管内に複数個
のコア材を束ねて充填したのち、該コア材とコア材、該
コア材と該石英管とのすき間に、SiO2を主原料とする物
質あるいは屈折率が石英と同程度である物質を充填して
すき間をなくしてから、該石英管を高温度でコラプスす
ることを特徴とするものである。
SUMMARY OF THE INVENTION The present invention relates to a method for producing a multi-core fiber preform which solves the above disadvantages and problems, and in the method for producing a multicore fiber preform having a plurality of cores, quartz is used. After bundling and filling a plurality of core materials in a tube, SiO 2 as a main raw material or a material having a refractive index similar to that of quartz in the gap between the core material and the core material and the quartz tube. It is characterized in that the quartz tube is collapsed at a high temperature after filling a certain substance to eliminate the gap.

【0005】すなわち、本発明者らは光の伝搬損失の小
さいマルチコアファイバ母材製造方法を開発すべく種々
検討した結果、これについては従来法に準じて石英管内
に複数個のコア材を束ねて充填するが、この充填ではコ
ア材とコア材との間、またコア材と石英管との間にすき
間が生ずるので、このすき間にSiO2を主原料とするも
の、あるいは石英と同程度の屈折率を有するものを充填
してすき間をなくしてから、この石英管を高温でコラプ
スすると、得られるマルチコアファイバ母材が真円に近
い形状となり、光の伝搬損失の小さいものになるという
ことを見出し、このすき間に充填する物質の種類、充填
方法などについての研究を進めて本発明を完成させた。
以下にこれをさらに詳述する。
That is, the present inventors have conducted various studies to develop a method for producing a multi-core fiber preform having a small light propagation loss. As a result, according to the conventional method, a plurality of core materials are bundled in a quartz tube. while filling, between the core material and the core material in the filling, also with the gap generated between the core member and the quartz tube, ones SiO 2 as a main raw material in this gap, or refraction comparable to quartz It was found that if the quartz tube is collapsed at a high temperature after filling with a material having a certain ratio to eliminate the gap, the resulting multicore fiber preform has a shape close to a perfect circle, and the propagation loss of light is small. The present invention has been completed by conducting research on the type of substance to be filled in the gap, the filling method, and the like.
This will be described in more detail below.

【0006】[0006]

【作用】この様なコア形状が光の伝搬損失にどのような
影響を与えるかを見るためにモデルを設定してシュミレ
ーションを行ってみた。モデルAとして図3(a)に示
すように真円の場合と、モデルBとして図3(b)に示
すようにドーナツ形状の場合についてシュミレーション
を行った。図4はその結果を示したもので、モデルA、
BについてE軸でカットした面の2次元的界面分布を求
めたものでこの結果から図4(a)に示すようにコア形
状が真円のモデルAの方が図4(b)に示すようにコア
形状がドーナツ形状のモデルBよりもマルチコアファイ
バとしての各コアの光の伝搬特性がすぐれており伝搬損
失の小さいものであることが判る。
[Operation] In order to see how such a core shape affects the propagation loss of light, a model was set up and a simulation was performed. Simulations were performed for a model A having a perfect circle as shown in FIG. 3A and a model B having a donut shape as shown in FIG. 3B. FIG. 4 shows the result, and the model A,
The two-dimensional interface distribution of the surface cut along the E axis is obtained for B. From this result, the model A having a perfect core shape as shown in FIG. 4 (a) is shown in FIG. 4 (b). It can be seen that the light propagation characteristics of each core as a multi-core fiber are superior to those of the model B having a donut shape, and the propagation loss is small.

【0007】本発明によるマルチコアファイバ母材の製
造方法は前記したように、石英管内に複数個のコア材を
束ねて充填すると、このコア材とコア材の間およびコア
材と石英管との間にすき間が生じるので、このすき間に
SiO2を主原料とする物質または石英と同程度の屈折率を
有する物質を充填してすき間を埋め、ついでコラプスす
るものであるが、これによればこのすき間がSiO2または
石英管と同質のもので充填されるので、これをコラプス
して得られたコアの形状が真円となり、シュミレーショ
ンでも確認された様に光の伝搬損失が小さくなるという
有利性が与えられることが判った。
As described above, according to the method for producing a multi-core fiber preform according to the present invention, when a plurality of core materials are bundled and filled in a quartz tube, the space between the core materials and the space between the core material and the quartz tube is filled. Because there is a gap in this gap,
The material is made of SiO 2 as a main raw material or a material having a refractive index similar to that of quartz is filled to fill the gap, and then collapse is performed. According to this, the gap has the same quality as SiO 2 or the quartz tube. It was found that the core was obtained by collapsing it into a perfect circle because it was filled with the material, and the advantage was obtained that the propagation loss of light became small as confirmed by the simulation.

【0008】本発明におけるマルチコアファイバ母材の
製造は、まず公知の方法にしたがって石英管1内に複数
個のコア材2を束ねて充填するのであるが、この石英
管、コア材は公知のものとすればよい。このものは例え
ば前記した図5(a)に示したように、石英管11にコア
材12を複数本束ねて充填すると、このコア材とコア材の
間およびコア材と石英管との間にすき間13ができるの
で、これをコラプスして得られるマルチコアファイバは
図5(b)に示したようにひずんだものとなり、光の伝
搬損失の大きいものとなる。
In the production of the multi-core fiber preform in the present invention, first, a plurality of core materials 2 are bundled and filled in a quartz tube 1 according to a known method. The quartz tube and the core material are known materials. And it is sufficient. For example, as shown in FIG. 5 (a) described above, when a plurality of core materials 12 are bundled and packed in a quartz tube 11, the space between the core materials and between the core material and the quartz tube is increased. Since the gap 13 is formed, the multi-core fiber obtained by collapsing this is distorted as shown in FIG. 5 (b), and the optical propagation loss is large.

【0009】そのため、本発明ではこのコア材とコア材
との間、コア材と石英管との間のすき間に、SiO2を主原
料とする材質物または屈折率が石英管と同程度の物質を
充填してこのすき間をなくすのであるが、これについて
は特に限定されるものではなくこの様な材質のものであ
ればよく例としてノンドープのシリカファイバやシリカ
粉末などが例示される。又、必要に応じて、副成分とし
てフッ素やホウ素を屈折率を下げるためにドープするこ
とが出来る。この充填は図1(a)に示したように石英
管1とコア材2とのすき間3、コア材とコア材とのすき
間3にこのSiO2を主原料とするもの4および/または屈
折率が石英管と同程度のものである充填剤4を充填すれ
ばよいが、この充填はこのすき間3にこれらのファイバ
や粉末を上部からつめ込めばよく、必要に応じ充填後上
から棒などでつついて埋め込むようにすればよい。
Therefore, in the present invention, a material containing SiO 2 as a main raw material or a material having a refractive index similar to that of the quartz tube is provided between the core material and the gap between the core material and the quartz tube. However, the material is not particularly limited, and non-doped silica fiber, silica powder or the like may be exemplified as long as it is made of such a material. Further, if necessary, fluorine or boron can be doped as a sub-component in order to lower the refractive index. As shown in FIG. 1 (a), this filling is made by using SiO 2 as a main raw material 4 in the gap 3 between the quartz tube 1 and the core material 2, the gap 3 between the core material 4 and / or the refractive index. It is sufficient to fill the filler 4 which is about the same as the quartz tube, but this filling can be done by filling these gaps 3 with these fibers and powders from the top, and after filling with a rod or the like from the top if necessary. It should be embedded by poking.

【0010】このようにして作られたすき間3に充填剤
4を充填した石英管とコア材とからなる管材はついでこ
れをコラプスすることによってマルチコアファイバ母材
とされるのであるが、このコラプスは例えば図2に示し
たようにこの石英管の片端をバーナー5で加熱して封止
し、必要に応じ減圧としたのち、このバーナー5を徐々
に他端にずらしてコラプスすればよく、これによればす
き間3が充填剤4で充填されているので、得られるマル
チコアファイバ母材は図1(b)に示したように真円状
のものとなり、光の伝搬損失が小さいものになるという
有利性が与えられる。
The tube material made of the quartz tube and the core material, which are filled with the filler 4 in the gap 3 thus formed, is then collapsed to form a multi-core fiber preform, which is collapsed. For example, as shown in FIG. 2, one end of the quartz tube is heated and sealed by a burner 5 and, if necessary, decompressed, and then the burner 5 is gradually shifted to the other end and collapsed. According to this, since the gap 3 is filled with the filler 4, the obtained multi-core fiber preform has a perfect circular shape as shown in FIG. 1 (b), and the propagation loss of light is small. Gender is given.

【0011】[0011]

【実施例】つぎに本発明の実施例、比較例をあげる。 実施例、比較例 内径6mmφの無水合成石英管内に内径2mmφのコア材7
本を束ねて充填したところ、石英管とコア材との間、コ
ア材とコア材との間にすき間が生じたので、このすき間
に外径 125μmの石英ファイバ(ノンドープ)を充填し
てすき間をなくし、その後この石英管の片端をバーナー
で加熱して封止したのち、もう一方の片端より減圧しな
がら封止側片側よりバーナーを徐々に他端にずらしてコ
ラプスを行なったところ、得られたマルチコアファイバ
母材は図1(b)に示したように真円のものとなった。
EXAMPLES Next, examples and comparative examples of the present invention will be described. Examples and Comparative Examples Core material 7 with an inner diameter of 2 mmφ in an anhydrous synthetic quartz tube with an inner diameter of 6 mmφ
When the books were bundled and filled, a gap was created between the quartz tube and the core material, and between the core materials. Therefore, a silica fiber (non-doped) with an outer diameter of 125 μm was filled in the gap to fill the gap. After erasing, one end of this quartz tube was heated and sealed with a burner, then, while depressurizing from the other end, the burner was gradually shifted from the sealing side to the other end, and a collapse was performed. The multicore fiber preform was a perfect circle as shown in FIG. 1 (b).

【0012】ついで、このマルチコアファイバ母材の光
の伝搬特性をしらべるために、これより線引して外径 1
25μmの光ファイバを製造し、又、比較例としてすき間
に石英ファイバを充填しないでコラプスした図5(b)
に示したように、ひずんだマルチコアファイバ母材を同
様に線引して外径 125μmの光ファイバとし、これらの
伝搬損失を求めたところ、このマルチファイバ母材につ
いてはコア形状が真円のもののほうが、ひずんでいるも
のに比べて伝搬損失の小さいものとなり、マルチコアフ
ァイバ母材としてすぐれたものであることが確認され
た。
Then, in order to examine the light propagation characteristics of the multi-core fiber base material, a wire was drawn from the base material to obtain an outer diameter 1
An optical fiber of 25 μm was manufactured, and as a comparative example, collapsed without filling silica fiber in the gap (FIG. 5B).
As shown in Fig. 5, a distorted multi-core fiber preform was drawn in the same way to make an optical fiber with an outer diameter of 125 μm, and the propagation loss of these was determined. It was confirmed that the propagation loss was smaller than that of the distorted one, and it was an excellent multicore fiber preform.

【0013】[0013]

【発明の効果】本発明によれば、コア形状が真円となる
ので光の伝搬損失の小さいマルチコアファイバ母材が得
られるという有利性が与えられる。
According to the present invention, since the core shape is a perfect circle, there is an advantage that a multi-core fiber preform having a small propagation loss of light can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】(a)は本発明における、すき間に充填剤を充
填した石英管とコア材とからなるコラプス前の石英管の
横断面図、(b)はこれをコラプスしたマルチコアファ
イバ母材の横断面図を示したものである。
FIG. 1 (a) is a cross-sectional view of a quartz tube before collapse made of a quartz tube filled with a filler in a gap and a core material according to the present invention, and FIG. 1 (b) is a multi-core fiber preform obtained by collapsing the same. It is a cross-sectional view.

【図2】石英管とコア材とからなる石英管のコラプス方
法の縦断面図を示したものである。
FIG. 2 is a vertical cross-sectional view of a collapse method for a quartz tube including a quartz tube and a core material.

【図3】(a)はシュミレーションにおけるモデルAの
コア形状を示した図、(b)はシュミレーションにおけ
るモデルBのコアの形状を示した図である。
FIG. 3A is a diagram showing a core shape of a model A in simulation, and FIG. 3B is a diagram showing a core shape of a model B in simulation.

【図4】(a)はモデルAのマルチコアファイバ母材の
シュミレーションによる光の2次元的界面図、(b)は
モデルBのマルチコアファイバ母材のシュミレーション
による光の2次元的界面図を示した図である。
4A is a two-dimensional interface diagram of light by simulation of a multicore fiber preform of model A, and FIG. 4B is a two-dimensional interface diagram of light by simulation of a multicore fiber preform of model B. It is a figure.

【図5】(a)は従来法における、すき間に充填剤を充
填しない公知の石英管とコア材とからなる石英管の横断
面図、(b)はこれをコラプスしたマルチコアファイバ
母材の横断面図を示したものである。
FIG. 5 (a) is a cross-sectional view of a conventional quartz tube comprising a core material and a quartz tube in which a filler is not filled in a gap in the conventional method, and FIG. It is a front view.

【符号の説明】[Explanation of symbols]

1,11…石英管 2,12…コア材 3,13…すき間 4…充填剤 5,14…マルチコアファイバ 6…バーナー 7…封止部 8…減圧方向 1, 11 ... Quartz tube 2, 12 ... Core material 3, 13 ... Gap 4 ... Filler 5, 14 ... Multi-core fiber 6 ... Burner 7 ... Sealing part 8 ... Decompression direction

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 複数のコアからなるマルチコアファイバ
母材の製造方法において、石英管内に複数個のコア部材
を束ねて充填したのち、該コア材とコア材、該コア材と
該石英管とのすき間に、SiO2を主原料とする物質あるい
は屈折率が石英と同程度の物質を充填剤として、充填し
てすき間をなくしてから、該石英管を高温度でコラプス
することを特徴とするマルチコアファイバ母材の製造方
法。
1. A method of manufacturing a multi-core fiber preform composed of a plurality of cores, wherein a plurality of core members are bundled and filled in a quartz tube, and then the core material and the core material and the core material and the quartz tube are packed. A multi-core, characterized in that a substance having SiO 2 as a main raw material or a substance having a refractive index similar to that of quartz is used as a filler in the gap to fill the gap to eliminate the gap, and then the quartz tube is collapsed at a high temperature. Manufacturing method of fiber preform.
【請求項2】 充填剤が、石英と同一材質あるいはそれ
に準ずる物質であることを特徴とする請求項1に記載し
たマルチコアファイバ母材の製造方法。
2. The method for producing a multi-core fiber preform according to claim 1, wherein the filler is the same material as quartz or a substance similar thereto.
JP6250491A 1994-10-17 1994-10-17 Method for manufacturing multi-core fiber preform Pending JPH08119656A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6250491A JPH08119656A (en) 1994-10-17 1994-10-17 Method for manufacturing multi-core fiber preform

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6250491A JPH08119656A (en) 1994-10-17 1994-10-17 Method for manufacturing multi-core fiber preform

Publications (1)

Publication Number Publication Date
JPH08119656A true JPH08119656A (en) 1996-05-14

Family

ID=17208663

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6250491A Pending JPH08119656A (en) 1994-10-17 1994-10-17 Method for manufacturing multi-core fiber preform

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Country Link
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999005550A1 (en) * 1997-07-25 1999-02-04 Corning Incorporated Multicore glass optical fiber and methods of manufacturing such fibres
US6154594A (en) * 1998-07-15 2000-11-28 Corning Incorporated Multicore glass optical fiber and methods of manufacturing such fibers
US7349611B2 (en) 2001-06-08 2008-03-25 Crystal Fibre A/S Photonic bandgap fibre, and use thereof
US8045259B2 (en) 2005-11-18 2011-10-25 Nkt Photonics A/S Active optical fibers with wavelength-selective filtering mechanism, method of production and their use
JP2013155109A (en) * 2013-04-22 2013-08-15 Kohoku Kogyo Kk Method for manufacturing optical fiber preform and optical fiber preform
JP2013177269A (en) * 2012-02-28 2013-09-09 Nippon Telegr & Teleph Corp <Ntt> Optical fiber preform manufacturing method
WO2014034726A1 (en) * 2012-08-29 2014-03-06 コニカミノルタ株式会社 Optical fiber coupling member and method for producing same
US9695079B2 (en) 2013-05-01 2017-07-04 Furukawa Electric Co., Ltd. Production method of optical fiber preform, and production method of optical fiber

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999005550A1 (en) * 1997-07-25 1999-02-04 Corning Incorporated Multicore glass optical fiber and methods of manufacturing such fibres
US6154594A (en) * 1998-07-15 2000-11-28 Corning Incorporated Multicore glass optical fiber and methods of manufacturing such fibers
US7349611B2 (en) 2001-06-08 2008-03-25 Crystal Fibre A/S Photonic bandgap fibre, and use thereof
US8045259B2 (en) 2005-11-18 2011-10-25 Nkt Photonics A/S Active optical fibers with wavelength-selective filtering mechanism, method of production and their use
JP2013177269A (en) * 2012-02-28 2013-09-09 Nippon Telegr & Teleph Corp <Ntt> Optical fiber preform manufacturing method
WO2014034726A1 (en) * 2012-08-29 2014-03-06 コニカミノルタ株式会社 Optical fiber coupling member and method for producing same
JPWO2014034726A1 (en) * 2012-08-29 2016-08-08 コニカミノルタ株式会社 Optical fiber coupling member and method of manufacturing optical fiber coupling member
JP2013155109A (en) * 2013-04-22 2013-08-15 Kohoku Kogyo Kk Method for manufacturing optical fiber preform and optical fiber preform
US9695079B2 (en) 2013-05-01 2017-07-04 Furukawa Electric Co., Ltd. Production method of optical fiber preform, and production method of optical fiber

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