JPH08150314A - Vapor-liquid contact device - Google Patents

Vapor-liquid contact device

Info

Publication number
JPH08150314A
JPH08150314A JP6294672A JP29467294A JPH08150314A JP H08150314 A JPH08150314 A JP H08150314A JP 6294672 A JP6294672 A JP 6294672A JP 29467294 A JP29467294 A JP 29467294A JP H08150314 A JPH08150314 A JP H08150314A
Authority
JP
Japan
Prior art keywords
gas
liquid
packing
filling
vapor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6294672A
Other languages
Japanese (ja)
Inventor
Masaki Iijima
正樹 飯島
Shigeaki Mitsuoka
薫明 光岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP6294672A priority Critical patent/JPH08150314A/en
Publication of JPH08150314A publication Critical patent/JPH08150314A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

PURPOSE: To obtain a vapor-liq. contact. device contg. packing for bringing vapor into efficient contact with a liq. CONSTITUTION: In this vapor-liq. contact device contg. packing (a), vapor fed from the bottom is brought into contact with a liq. allowed to flow down from the top on the surface of the packing (a). The packing (a) has vertical vapor passages and many through holes (b) each corresponding to the area of a circle of 0.1-2mm diameter in a direction perpendicular to the passages are formed.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は気体と液体とを効率よく
接触させる充填物を内蔵した気液接触装置に関し、より
詳細には、気体中の成分を液体に吸収させることを容易
にし、かつ、供給気体流の圧損を少なくして効率のよい
気液接触を可能とする充填物を内蔵した気液接触装置に
関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas-liquid contactor containing a filler for efficiently contacting a gas and a liquid, and more particularly, to facilitating absorption of a component in a gas into the liquid, and The present invention relates to a gas-liquid contactor containing a filling material that enables efficient gas-liquid contact by reducing pressure loss of a supply gas flow.

【0002】[0002]

【従来の技術】化学プラントでは気体中に含まれる特定
成分を除去するため、特定成分を吸収する液体と効率よ
く接触させる気液接触法が多用されている。例えば、火
力発電所ではボイラの燃焼排ガス中のCO2 の除去に利
用され、回収されたCO2 を大気へ放出することなく貯
蔵することが可能となっている。このような気液接触装
置には気液接触を促進させるため充填物が使用され、先
に当該出願人による特開平4−271809号公報も知
られている。ここに、前記公報掲載の充填物を図3に示
す。
2. Description of the Related Art In chemical plants, in order to remove a specific component contained in a gas, a gas-liquid contacting method in which a specific component is efficiently contacted with a liquid absorbing the specific component is widely used. For example, in a thermal power plant, it is used to remove CO 2 from the combustion exhaust gas of a boiler, and it is possible to store the recovered CO 2 without releasing it to the atmosphere. In such a gas-liquid contact device, a filler is used to promote the gas-liquid contact, and Japanese Patent Laid-Open No. 4-271809 by the applicant is also known. FIG. 3 shows the filling material disclosed in the above publication.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、前記充
填物は管状構造体の気液接触面が滑らかに鏡面処理され
ている場合には、気液接触面を流下する吸収液が表面張
力あるいは凝縮力により糸状をなして流れ、充填物表面
の全体に広がらず濡れ面積が少なくなり、この結果、気
液の接触面積効率が低下し気液接触による気体の吸収効
率が下がる場合がある。また、充填物は装置内で多数が
使用されるために気液接触効率の向上と共にその製作が
容易であることや多量の気体を効率よく処理するため
に、気体流に対して抵抗の少ないことが望まれる。かか
る現状から、気体中の成分の液体への移転をより向上さ
せ、しかも多量の気体を効率よく処理することのできる
充填物の開発が熱望されている。
However, when the gas-liquid contact surface of the tubular structure is smoothly mirror-finished, the absorbing liquid flowing down the gas-liquid contact surface has a surface tension or a condensing force. As a result, it flows in the form of filaments, does not spread over the entire surface of the filling material, and has a reduced wetted area. As a result, the gas-liquid contact area efficiency may decrease and the gas-liquid contacting gas absorption efficiency may decrease. In addition, since many packings are used in the equipment, the gas-liquid contact efficiency is improved and it is easy to manufacture, and in order to process a large amount of gas efficiently, there is little resistance to the gas flow. Is desired. Under these circumstances, there is an eager need to develop a packing material that can further improve the transfer of components in a gas to a liquid and efficiently process a large amount of gas.

【0004】[0004]

【課題を解決するための手段】本発明者らは上記問題点
に鑑み、充填物について詳細に検討した結果、充填物に
特定径の貫孔を設けることによりかかる問題点を解決し
うることを見いだし、本発明を完成した。すなわち、本
発明は充填物を内部に有し、下部から供給した気体と上
部から流下させた液体とを充填物表面で接触させる気液
接触装置内において、前記充填物が鉛直な気体通路を有
し、かつ前記通路と垂直方向に径0.1〜2mmの円形
面積に相当する多数の貫孔を有することを特徴とする気
液接触装置を提供するものである。また、充填物の通路
と垂直に形成された貫孔の開孔率が5〜70%であるこ
とを特徴とする前記気液接触装置を提供するものであ
る。さらに、充填物が隔置された複数の板状物からな
る、あるいは充填物の水平断面が碁盤の目状または波線
と平行線の組合わせ状であることを特徴とする前記気液
接触装置を提供するものである。
SUMMARY OF THE INVENTION In view of the above problems, the present inventors have made a detailed study on the filling material, and as a result, have found that such a problem can be solved by providing a through hole having a specific diameter in the filling material. Found and completed the present invention. That is, the present invention has a packing inside and in a gas-liquid contactor for contacting a gas supplied from the bottom with a liquid flowing down from the top on the packing surface, the packing has a vertical gas passage. In addition, the present invention provides a gas-liquid contactor characterized in that it has a large number of through holes corresponding to a circular area having a diameter of 0.1 to 2 mm in a direction perpendicular to the passage. Further, the present invention provides the gas-liquid contactor, wherein the through hole formed perpendicularly to the passage of the packing has an opening ratio of 5 to 70%. Furthermore, the gas-liquid contactor characterized in that the packing is composed of a plurality of plate-like objects spaced apart from each other, or the horizontal cross section of the packing is a grid pattern or a combination of wavy lines and parallel lines. It is provided.

【0005】[0005]

【作用】本発明の気液接触装置によれば、内蔵された充
填物が特定径の貫孔を有し、鉛直な気体通路を有するの
で気体流の圧損を少なくすることができるとともに、液
体が充填物の裏面まで貫孔を通って流れるため液下時間
が長くなり、しかも貫孔表面に液膜が形成されることか
ら気液接触面の低減を防止することができる。また、貫
孔が鉛直な気体通路と垂直に設けられるのも液体の滞留
時間を増す作用がある。なお、この貫孔を0.1〜2m
mの円形面積に相当するような面積にしたのは上述した
ように貫孔表面に液膜が形成されるようにするためであ
る。このため、気液の接触効率を著しく増大させること
が可能となる。さらに、最も簡単には貫孔を設けるのみ
であるため充填物の製作が容易である。
According to the gas-liquid contactor of the present invention, since the built-in filler has a through hole of a specific diameter and a vertical gas passage, the pressure loss of the gas flow can be reduced and the liquid Since the filling material flows to the back surface through the through hole, the liquid lowering time becomes long, and further, since a liquid film is formed on the surface of the through hole, reduction of the gas-liquid contact surface can be prevented. Further, the through hole is provided perpendicularly to the vertical gas passage, which also has the effect of increasing the residence time of the liquid. In addition, this through hole is 0.1-2 m
The area corresponding to the circular area of m is used to form a liquid film on the surface of the through hole as described above. Therefore, it is possible to significantly increase the gas-liquid contact efficiency. Further, the filling is easy to manufacture since the through hole is provided in the simplest manner.

【0006】以下、本発明の気液接触装置について詳細
に説明する。本発明の気液接触装置をCO2 吸収装置と
して使用した場合を図1に示し、本発明の一例として説
明する。まず、図1に示すごとく、気液接触装置は気液
接触反応を促進させるための充填物を内蔵する。図1に
は板状の充填物を示した。なお図1において1はCO2
吸収装置、2は複数枚を隔置した板状の充填物(貫孔は
図示省略)、3はCO2 吸収液を輸送するライン、4は
液体分散ノズル、5はCO2 を吸収した吸収液溜め部、
6はCO2 含有燃焼排ガス、7はCO2 を除去したクリ
ーン排ガスを示す。
The gas-liquid contactor of the present invention will be described in detail below. A case where the gas-liquid contactor of the present invention is used as a CO 2 absorber is shown in FIG. 1 and will be described as an example of the present invention. First, as shown in FIG. 1, the gas-liquid contactor incorporates a filler for promoting the gas-liquid contact reaction. FIG. 1 shows a plate-shaped packing. In FIG. 1, 1 is CO 2
Absorbing device, 2 is a plate-like packing in which a plurality of sheets are separated (through holes are not shown), 3 is a line for transporting a CO 2 absorbing liquid, 4 is a liquid dispersion nozzle, and 5 is an absorbing liquid having absorbed CO 2. Reservoir,
6 CO 2 containing flue gas, 7 denotes a clean exhaust gas to remove CO 2.

【0007】本発明の気液接触装置に内蔵される充填物
は装置下部から供給した気体が装置上方に向かって移動
できるように鉛直な気体通路を有する。充填物が板状で
ある場合には複数枚が鉛直に隔置されることが好まし
い。このように配置すれば、気体流が充填物の気液接触
面に対して平行に配置されることとなるため、気体の流
路に気体流の拡大や縮小、衝突や渦流の発生がなく、こ
れに起因する圧力損失を小さくすることができる。特に
処理気体量が多い場合には、気体流に対する圧損を最小
にすることにより気体供給のためのポンプ圧を最小にす
ることができる。
The filling material contained in the gas-liquid contact device of the present invention has a vertical gas passage so that the gas supplied from the lower part of the device can move toward the upper part of the device. When the packing is plate-shaped, it is preferable that a plurality of packings are vertically spaced. By arranging in this way, the gas flow will be arranged in parallel to the gas-liquid contact surface of the filling material, so there is no expansion or contraction of the gas flow in the gas flow path, collision or vortex generation, The pressure loss resulting from this can be reduced. Especially when the amount of treated gas is large, the pump pressure for gas supply can be minimized by minimizing the pressure loss to the gas flow.

【0008】本発明の充填物は前記した鉛直な気体通路
と垂直に形成された貫孔を有することが特徴である。孔
径は0.1〜2mmであることが好ましく、特に好まし
くは0.3〜1mmである。孔は、孔に形成される液膜
が安定することから好ましくは円形であるが、円形に限
定されず、上記貫孔で形成される開孔面積と同等の面積
となれば三角形、星形、楕円形などでもよい。孔径が前
記範囲にあるとき、気液接触効率が高くなるが、その理
由としては孔に液膜を張ることができ、実質的に表面積
を増やすことができるからであると推定される。具体的
には、装置上部から供給された液体が前記貫孔を有する
充填物表面に保持され、充填物表面に沿って流下する間
に気体流と接触し、気体中に含まれる特定成分を吸収さ
せることができると考えられる。また開孔率は5〜70
%の範囲であることが好ましく、より好ましくは10〜
40%である。この範囲で優れた気液接触効率を得るこ
とができる。
The filling material of the present invention is characterized in that it has through holes formed perpendicularly to the vertical gas passages. The pore size is preferably 0.1 to 2 mm, particularly preferably 0.3 to 1 mm. The hole is preferably circular because the liquid film formed in the hole is stable, but is not limited to a circle, and if the area is equivalent to the opening area formed by the through hole, a triangle, a star, It may be oval or the like. When the pore diameter is in the above range, the gas-liquid contact efficiency is high, and it is presumed that the reason is that the pores can be covered with a liquid film and the surface area can be substantially increased. Specifically, the liquid supplied from the upper part of the device is held on the surface of the packing having the through holes, and while flowing down along the surface of the packing, comes into contact with the gas flow and absorbs a specific component contained in the gas. It is thought that it can be made. The porosity is 5 to 70.
% Is preferable, and more preferably 10 to
40%. In this range, excellent gas-liquid contact efficiency can be obtained.

【0009】本発明の充填物の形状は板状でもよいが、
図2の斜視図に示したように貫孔bを有する充填物aの
断面が碁盤の目状のもの及び図3の水平断面図に示した
ような波線状板a′と平行線状板a″の組合わせ状でも
よい。さらに、充填物は一体物に限らず、同形状のもの
を複数組合わせて使用してもよい。
The packing of the present invention may be plate-shaped,
As shown in the perspective view of FIG. 2, the cross section of the filling a having the through holes b has a grid pattern, and the corrugated plate a ′ and the parallel line plate a as shown in the horizontal sectional view of FIG. In addition, the filling material is not limited to an integral material, and a plurality of packing materials having the same shape may be used in combination.

【0010】また、材質についても磁器、金属、シリカ
繊維などセラミックファイバ、並びにポリエチレンのよ
うなプラスチックスなど吸収液によって腐食、膨潤など
影響を受けないものなら何れでもよい。製造法について
も、板状物にパンチ孔を設け、板状のまま、あるいは図
4に示したごとく組合わせて成形することができる。ま
た他の充填物と成形充填物との組合わせや、コルゲート
マシン成形法などが適用され、形状、材質によって経済
的な製法が選定できる。
The material may be porcelain, metal, ceramic fiber such as silica fiber, or plastics such as polyethylene, as long as it is not affected by corrosion or swelling by the absorbing liquid. Also in the manufacturing method, punching holes may be provided in the plate-like material, and the plate-like material may be molded in the plate-like shape or in combination as shown in FIG. In addition, a combination of other filling and molding filling, a corrugated machine molding method, etc. are applied, and an economical manufacturing method can be selected depending on the shape and material.

【0011】本発明による気液接触装置をCO2 吸収装
置として、その使用例を図1を用いて説明する。貫孔を
有する板状の複数枚の充填物を、鉛直な気体通路を有す
るように気体流と平行に一段あるいは複数段に配設す
る。CO2 吸収装置1には、その上部の液分散ノズル4
と下部の吸収液溜め部5とをつなぐCO2 吸収液輸送ラ
イン3が接続されている。液分散ノズル4は輸送ライン
3を通って送られてきたCO2 吸収液を板状充填物2に
できるだけ均等に分散させるように設けられる。CO2
吸収装置1の下部には、板状充填物2を通って下方へ流
下しつつCO2 を吸収したCO2 吸収液を溜める前記吸
収液溜め部5が設けられる。CO2 吸収装置1の下部側
方にはCO2 含有燃焼排気体6を装置1内に導入するた
めの開口部が設けられ、装置1の上方には、板状充填物
2内を通って上方へ流れる間に吸収液によりCO2 が除
去されたクリーン排ガス7を外部へ排出するための開口
部が設けられている。板状充填物2はCO2 吸収装置1
内を下方から上方へ流れる燃焼排気体を、その貫孔を有
する板状の気液接触面と平行に通過させる一方、液分散
ノズル4から供給された吸収液をその気液接触面を通っ
て下方へ流下させるようになっている。
The gas-liquid contactor according to the present invention is used as a CO 2 absorber, and its use will be described with reference to FIG. A plurality of plate-like fillers having through holes are arranged in one or more stages in parallel with the gas flow so as to have a vertical gas passage. The CO 2 absorption device 1 has a liquid dispersion nozzle 4 above it.
A CO 2 absorbing liquid transport line 3 is connected to connect the absorbing liquid reservoir 5 to the lower portion. The liquid dispersion nozzle 4 is provided so as to disperse the CO 2 absorbing liquid sent through the transportation line 3 into the plate-shaped packing 2 as evenly as possible. CO 2
In the lower part of the absorption device 1, there is provided the above-mentioned absorption liquid storage portion 5 for collecting the CO 2 absorption liquid which has absorbed CO 2 while flowing down through the plate-shaped packing 2. An opening for introducing the CO 2 -containing combustion exhaust body 6 into the device 1 is provided on the lower side of the CO 2 absorption device 1, and above the device 1 through the plate-shaped packing 2 and above. An opening is provided for discharging the clean exhaust gas 7 from which CO 2 has been removed by the absorption liquid while flowing to the outside. The plate-shaped packing 2 is a CO 2 absorber 1
The combustion exhaust gas flowing from the lower side to the upper side is passed in parallel with the plate-shaped gas-liquid contact surface having the through hole, while the absorbing liquid supplied from the liquid dispersion nozzle 4 passes through the gas-liquid contact surface. It is designed to flow down.

【0012】[0012]

【実施例】本発明を実施例により、さらに詳細に説明す
る。ただし本発明はこれに限定されるものではない。
EXAMPLES The present invention will be described in more detail by way of examples. However, the present invention is not limited to this.

【0013】(実施例)径100mm、高さ1000m
mのCO2 吸収塔内に、板状の充填物を7mmのピッチ
で鉛直に設置し、気体にCO2 含有空気、液体にCO2
吸収液として30wt%モノメタノールアミン溶液を用
いて、気体と液体の量比を2.75リットル/m3 Nで
流下し、温度13〜19℃、入口CO2 4〜5vol%
の条件で、板状充填物に施した孔径の違いによるCO2
吸収性能を比較した。すなわち、本発明にかかる充填物
として、径0.5mmで開孔率23%の貫孔を有する平
板を用い、比較検討する他の充填物としては径3mmで
開孔率33%の貫孔を有する板を用いた。結果を図5に
示す。図の横軸はガスの流速(m/s)を、縦軸はCO
2 吸収率(%)を示す。
(Example) Diameter 100 mm, height 1000 m
the CO 2 absorption tower of m, CO 2 the plate-like filler is installed vertically at a pitch of 7 mm, the gas containing CO 2 air, the liquid
Using a 30 wt% monomethanolamine solution as the absorbing liquid, the gas and liquid were flowed down at a ratio of 2.75 liter / m 3 N, the temperature was 13 to 19 ° C., and the inlet CO 2 was 4 to 5 vol%.
CO 2 due to the difference in the hole diameter given to the plate-like packing under the conditions
The absorption performance was compared. That is, as the packing according to the present invention, a flat plate having a through hole with a diameter of 0.5 mm and a porosity of 23% was used, and as another packing to be compared and examined, a through hole with a diameter of 3 mm and a porosity of 33% was used. A plate having the same was used. Results are shown in FIG. The horizontal axis of the figure represents the gas flow velocity (m / s), and the vertical axis represents CO.
2 Indicates the absorption rate (%).

【0014】[0014]

【発明の効果】以上説明したように、本発明による充填
物によれば、気液接触面積を大きくとることができ、気
液接触効率を大幅に向上させることができる。しかも多
数が用いられる充填物として、貫孔を施すだけで製作可
能であることから製作上至便である。
As described above, according to the filling material of the present invention, the gas-liquid contact area can be made large, and the gas-liquid contact efficiency can be greatly improved. Moreover, it is convenient in terms of production since it is possible to produce a large number of fillers by simply forming through holes.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明による気液接触装置の一例を示す説明
図。
FIG. 1 is an explanatory view showing an example of a gas-liquid contact device according to the present invention.

【図2】本発明の気液接触装置に充填される他の充填物
の例の斜視図。
FIG. 2 is a perspective view of an example of another filling material filled in the gas-liquid contact device of the present invention.

【図3】本発明の気液接触装置のさらに他の充填物の例
の水平断面図。
FIG. 3 is a horizontal cross-sectional view of an example of still another filling material of the gas-liquid contacting device of the present invention.

【図4】従来のCO2 吸収装置内に設けられた充填物の
形状の一例を示す説明図。
FIG. 4 is an explanatory view showing an example of the shape of a filler provided in a conventional CO 2 absorption device.

【図5】充填物によるCO2 吸収率の相違を示す図表。FIG. 5 is a chart showing the difference in CO 2 absorption rate depending on the packing material.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B01J 10/00 102 9342−4D 19/32 9342−4D ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location B01J 10/00 102 9342-4D 19/32 9342-4D

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 充填物を内部に有し、下部から供給した
気体と上部から流下させた液体とを充填物表面で接触さ
せる気液接触装置内において、前記充填物が鉛直な気体
通路を有し、かつ前記通路と垂直方向に径0.1〜2m
mの円形面積に相当する多数の貫孔を有することを特徴
とする気液接触装置。
1. In a gas-liquid contactor which has a filling inside and in which a gas supplied from the lower part and a liquid flowing down from the upper part are brought into contact with each other on the surface of the filling, the filling has a vertical gas passage. And a diameter of 0.1 to 2 m in the direction perpendicular to the passage.
A gas-liquid contactor having a large number of through holes corresponding to a circular area of m.
【請求項2】 充填物の通路と垂直に形成された貫孔の
開孔率が5〜70%であることを特徴とする請求項1記
載の気液接触装置。
2. The gas-liquid contactor according to claim 1, wherein the through hole formed perpendicularly to the filling passage has an opening ratio of 5 to 70%.
【請求項3】 充填物が隔置された複数の板状物からな
ることを特徴とする請求項1または2記載の気液接触装
置。
3. The gas-liquid contactor according to claim 1 or 2, wherein the packing is composed of a plurality of plate-shaped members spaced apart from each other.
【請求項4】 充填物の水平断面が碁盤の目状または波
線と平行線の組合わせ状であることを特徴とする請求項
1または2記載の気液接触装置。
4. The gas-liquid contactor according to claim 1, wherein the filling has a horizontal cross section in the shape of a grid or a combination of wavy lines and parallel lines.
JP6294672A 1994-11-29 1994-11-29 Vapor-liquid contact device Pending JPH08150314A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6294672A JPH08150314A (en) 1994-11-29 1994-11-29 Vapor-liquid contact device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6294672A JPH08150314A (en) 1994-11-29 1994-11-29 Vapor-liquid contact device

Publications (1)

Publication Number Publication Date
JPH08150314A true JPH08150314A (en) 1996-06-11

Family

ID=17810814

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6294672A Pending JPH08150314A (en) 1994-11-29 1994-11-29 Vapor-liquid contact device

Country Status (1)

Country Link
JP (1) JPH08150314A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000071472A1 (en) * 1999-05-19 2000-11-30 Hitachi Zosen Corporation Method of decomposing organochlorine compound
JP2014214729A (en) * 2013-04-30 2014-11-17 株式会社デンソー Gas-liquid contact device for engine wet type post-processing device
JP2015136699A (en) * 2014-01-21 2015-07-30 イエフペ エネルジ ヌヴェルIfp Energies Nouvelles Distributor tray for gas/liquid exchange column with liquid deflector
CN106865743A (en) * 2017-03-22 2017-06-20 武汉理工大学 A kind of zero energy consumption oxygenate apparatus
CN114797744A (en) * 2022-04-11 2022-07-29 苏州弘利欣系统科技有限公司 Burr type mass transfer device suitable for wet waste gas treatment
JP2025095396A (en) * 2023-12-14 2025-06-26 株式会社豊田中央研究所 Packing for gas-liquid contact, gas-liquid contact device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000071472A1 (en) * 1999-05-19 2000-11-30 Hitachi Zosen Corporation Method of decomposing organochlorine compound
JP2014214729A (en) * 2013-04-30 2014-11-17 株式会社デンソー Gas-liquid contact device for engine wet type post-processing device
JP2015136699A (en) * 2014-01-21 2015-07-30 イエフペ エネルジ ヌヴェルIfp Energies Nouvelles Distributor tray for gas/liquid exchange column with liquid deflector
US10722851B2 (en) 2014-01-21 2020-07-28 IFP Energies Nouvelles Distributor tray for gas/liquid exchange column with liquid deflector
CN106865743A (en) * 2017-03-22 2017-06-20 武汉理工大学 A kind of zero energy consumption oxygenate apparatus
CN114797744A (en) * 2022-04-11 2022-07-29 苏州弘利欣系统科技有限公司 Burr type mass transfer device suitable for wet waste gas treatment
JP2025095396A (en) * 2023-12-14 2025-06-26 株式会社豊田中央研究所 Packing for gas-liquid contact, gas-liquid contact device

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