JPH0815556B2 - ゼオライトの触媒活性の制御法 - Google Patents

ゼオライトの触媒活性の制御法

Info

Publication number: JPH0815556B2
Authority: JP; Japan
Prior art keywords: zeolite; silica; boron; metal; zeolites
Prior art date: 1986-02-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP62029933A

Other languages

English (en)

Japanese (ja)

Other versions

JPS62197151A (ja

Inventor

チユウポーチエン

Original Assignee

モ−ビルオイルコ−ポレ−シヨン

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-02-14

Filing date

1987-02-13

Publication date

1996-02-21

1987-02-13 Application filed by モ−ビルオイルコ−ポレ−シヨン filed Critical モ−ビルオイルコ−ポレ−シヨン

1987-08-31 Publication of JPS62197151A publication Critical patent/JPS62197151A/ja

1996-02-21 Publication of JPH0815556B2 publication Critical patent/JPH0815556B2/ja

2011-02-21 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims description 56
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 45
229910021536 Zeolite Inorganic materials 0.000 title claims description 43
238000000034 method Methods 0.000 title claims description 24
230000003197 catalytic effect Effects 0.000 title claims description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
229910052751 metal Inorganic materials 0.000 claims description 20
239000002184 metal Substances 0.000 claims description 20
229910052796 boron Inorganic materials 0.000 claims description 16
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 15
150000003839 salts Chemical class 0.000 claims description 15
239000000377 silicon dioxide Substances 0.000 claims description 15
239000011148 porous material Substances 0.000 claims description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
239000007864 aqueous solution Substances 0.000 claims description 5
239000000203 mixture Substances 0.000 claims description 5
150000002739 metals Chemical class 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
229910052738 indium Inorganic materials 0.000 claims description 3
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
229910052759 nickel Inorganic materials 0.000 claims description 3
230000000737 periodic effect Effects 0.000 claims description 3
239000010936 titanium Substances 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
229910052804 chromium Inorganic materials 0.000 claims 1
239000011651 chromium Substances 0.000 claims 1
229910052802 copper Inorganic materials 0.000 claims 1
229910052746 lanthanum Inorganic materials 0.000 claims 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
229910052706 scandium Inorganic materials 0.000 claims 1
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims 1
239000011135 tin Substances 0.000 claims 1
229910052718 tin Inorganic materials 0.000 claims 1
229910052719 titanium Inorganic materials 0.000 claims 1
229910052725 zinc Inorganic materials 0.000 claims 1
239000011701 zinc Substances 0.000 claims 1
229910052726 zirconium Inorganic materials 0.000 claims 1
230000000694 effects Effects 0.000 description 12
239000000243 solution Substances 0.000 description 12
229910052782 aluminium Inorganic materials 0.000 description 8
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
239000003054 catalyst Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
239000000463 material Substances 0.000 description 8
239000013078 crystal Substances 0.000 description 6
230000008569 process Effects 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
230000004913 activation Effects 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 4
238000006460 hydrolysis reaction Methods 0.000 description 4
229910052680 mordenite Inorganic materials 0.000 description 4
239000012266 salt solution Substances 0.000 description 4
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
238000006555 catalytic reaction Methods 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
238000006317 isomerization reaction Methods 0.000 description 3
125000004430 oxygen atom Chemical group O* 0.000 description 3
238000012360 testing method Methods 0.000 description 3
229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
239000003377 acid catalyst Substances 0.000 description 2
238000007792 addition Methods 0.000 description 2
230000029936 alkylation Effects 0.000 description 2
238000005804 alkylation reaction Methods 0.000 description 2
-1 borate ions Chemical class 0.000 description 2
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
239000004327 boric acid Substances 0.000 description 2
238000001354 calcination Methods 0.000 description 2
238000004517 catalytic hydrocracking Methods 0.000 description 2
230000020335 dealkylation Effects 0.000 description 2
238000006900 dealkylation reaction Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
238000007323 disproportionation reaction Methods 0.000 description 2
159000000014 iron salts Chemical class 0.000 description 2
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
239000002609 medium Substances 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000002411 thermogravimetry Methods 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910004283 SiO 4 Inorganic materials 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000009471 action Effects 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000033558 biomineral tissue development Effects 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
150000004673 fluoride salts Chemical class 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
238000010555 transalkylation reaction Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

JP62029933A 1986-02-14 1987-02-13 ゼオライトの触媒活性の制御法 Expired - Fee Related JPH0815556B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US82967786A	1986-02-14	1986-02-14
US829677		1986-02-14

Publications (2)

Publication Number	Publication Date
JPS62197151A JPS62197151A (ja)	1987-08-31
JPH0815556B2 true JPH0815556B2 (ja)	1996-02-21

Family

ID=25255216

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62029933A Expired - Fee Related JPH0815556B2 (ja)	1986-02-14	1987-02-13	ゼオライトの触媒活性の制御法

Country Status (5)

Country	Link
EP (1)	EP0234759B1 (da)
JP (1)	JPH0815556B2 (da)
CA (1)	CA1276611C (da)
DE (1)	DE3763991D1 (da)
DK (1)	DK166569B1 (da)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE968058C (de) *	1952-06-15	1958-01-09	Peddinghaus Paul Ferd Fa	Messerbefestigung fuer Profilstahlscheren
SG10201606435XA (en) *	2012-02-07	2016-09-29	Basf Se	Process For The Preparation Of A Zeolitic Material
US9168513B2 (en)	2012-02-07	2015-10-27	Basf Se	Process for preparation of zeolitic material
ES2899827T3 (es) *	2015-12-08	2022-03-14	Basf Se	Material zeolítico que contiene estaño y que tiene una estructura de marco BEA

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5437105A (en) *	1977-08-29	1979-03-19	Chiyoda Chem Eng & Constr Co Ltd	Two-stage hydrogenation of heavy oil
US4268420A (en) *	1978-04-18	1981-05-19	Standard Oil Company (Indiana)	Hydrocarbon-conversion catalyst and its method of preparation
CA1185953A (en) *	1981-06-30	1985-04-23	Muin S. Haddad	Method for manufacture of ams-1b crystalline borosilicate molecular sieve
NZ212649A (en) *	1984-07-16	1988-06-30	Mobil Oil Corp	Method for increasing zeolite catalytic activity

1987
- 1987-01-22 CA CA000527970A patent/CA1276611C/en not_active Expired - Lifetime
- 1987-01-30 EP EP19870300828 patent/EP0234759B1/en not_active Expired
- 1987-01-30 DE DE8787300828T patent/DE3763991D1/de not_active Expired - Lifetime
- 1987-02-13 JP JP62029933A patent/JPH0815556B2/ja not_active Expired - Fee Related
- 1987-02-13 DK DK72087A patent/DK166569B1/da not_active IP Right Cessation

Also Published As

Publication number	Publication date
DK72087A (da)	1987-08-15
EP0234759A1 (en)	1987-09-02
DK72087D0 (da)	1987-02-13
JPS62197151A (ja)	1987-08-31
CA1276611C (en)	1990-11-20
DE3763991D1 (de)	1990-09-06
DK166569B1 (da)	1993-06-14
EP0234759B1 (en)	1990-08-01

Legal Events

Date	Code	Title	Description
2004-02-21	LAPS	Cancellation because of no payment of annual fees

Publication	Publication Date	Title
US3766093A (en)	1973-10-16	Treatment of organic cationcontaining zeolites
US4605637A (en)	1986-08-12	Hydrothermal activation of acid zeolites with aluminum phosphates
US4912073A (en)	1990-03-27	Larger pore molecular sieves of controlled activity
EP0024930B1 (en)	1983-03-02	A method of preparing active ion-exchanged zeolite catalysts
US5047141A (en)	1991-09-10	Larger pore molecular sieves of controlled activity
JPS63162521A (ja)	1988-07-06	珪酸第二鉄型ゼオライトの新規合成方法、得られた物質およびそれらの用途
US4478950A (en)	1984-10-23	Activity enhancement of high silica zeolites by thermal treatment with alkaline aluminate
US7658909B2 (en)	2010-02-09	Process for preparing a beta zeolite
JPH0341408B2 (da)	1991-06-24
CA1239920A (en)	1988-08-02	Activation of zeolites
CA1182097A (en)	1985-02-05	Method of removing organic cations from zeolites
EP0169026B1 (en)	1989-01-25	Activation of zeolites
DE69029125T2 (de)	1997-03-13	Modifiziert kristalline Aluminosilikaten und Verfahren für die Herstellung derselben
JPH0815556B2 (ja)	1996-02-21	ゼオライトの触媒活性の制御法
JPS61153143A (ja)	1986-07-11	改良安定性をもつゼオライト触媒組成物
JPH0672012B2 (ja)	1994-09-14	表層脱アルミニウムゼオライトおよびその製造法
US5238675A (en)	1993-08-24	Gallium zeolites
EP0223345B1 (en)	1990-09-26	Process for the conversion of light olefins into heavier hydrocarbons
US5061466A (en)	1991-10-29	Synthesis of large pore zeolites containing gallium
CA1201703A (en)	1986-03-11	Hydrothermal zeolite activation
CA1251436A (en)	1989-03-21	Preparation of gallosilicate zeolites
JPS6247809B2 (da)	1987-10-09
JPS6033211A (ja)	1985-02-20	ゼオライトζｓｍ−１２の製法
JP2574105B2 (ja)	1997-01-22	有機化合物の接触転化触媒体及びそれを使用した接触転化反応方法。
JPS6215533B2 (da)	1987-04-08