JPH082099A - Fabric ink ribbon - Google Patents
Fabric ink ribbonInfo
- Publication number
- JPH082099A JPH082099A JP13583694A JP13583694A JPH082099A JP H082099 A JPH082099 A JP H082099A JP 13583694 A JP13583694 A JP 13583694A JP 13583694 A JP13583694 A JP 13583694A JP H082099 A JPH082099 A JP H082099A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- fabric
- ink ribbon
- ribbon
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 29
- 239000005011 phenolic resin Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000003086 colorant Substances 0.000 claims abstract description 7
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000012860 organic pigment Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 46
- 239000000049 pigment Substances 0.000 description 21
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- 229920003987 resole Polymers 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- -1 sorbitan fatty acid esters Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- KWORKYDIARWARF-UHFFFAOYSA-N N-(4-chloro-2-methylphenyl)-4-[(4-chloro-2-methylphenyl)diazenyl]-3-hydroxynaphthalene-2-carboxamide Chemical compound Cc1cc(Cl)ccc1NC(=O)c1cc2ccccc2c(N=Nc2ccc(Cl)cc2C)c1O KWORKYDIARWARF-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000001042 pigment based ink Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- JEVGKYBUANQAKG-UHFFFAOYSA-N victoria blue R Chemical compound [Cl-].C12=CC=CC=C2C(=[NH+]CC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JEVGKYBUANQAKG-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Duplication Or Marking (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
Abstract
(57)【要約】
【目的】 高温多湿環境下で保存してもインクの流動性
が劣化せず、印字寿命が影響を受けないファブリックイ
ンクリボンを提供すること。
【構成】 少なくとも有機および／または無機顔料を含
む着色剤、および油剤を必須成分として含有するインク
がファブリックリボン生地に含浸されてなるファブリッ
クインクリボンにおいて、前記インクがさらにフェノー
ル樹脂を含有することを特徴とするファブリックインク
リボン。(57) [Summary] [Purpose] To provide a fabric ink ribbon in which the fluidity of the ink does not deteriorate even when stored in a high temperature and high humidity environment, and the printing life is not affected. A fabric ink ribbon in which a colorant containing at least an organic and / or an inorganic pigment, and an ink containing an oil agent as essential components are impregnated in a fabric ribbon material, wherein the ink further contains a phenol resin. And fabric ink ribbon.
Description
【０００１】[0001]
【産業上の利用分野】本発明はインパンクトプリンタな
どに使用するファブリックインクリボンに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric ink ribbon used for an impact printer or the like.
【０００２】[0002]
【従来の技術および発明が解決しようとする課題】従来
より、ワイヤドットプリンタ、タイプライタなどのイン
パクトプリンタには、着色剤および油剤からなる液状イ
ンクをファブリックリボン生地に含浸させたものが使用
されている。2. Description of the Related Art Conventionally, a fabric ribbon cloth impregnated with a liquid ink composed of a coloring agent and an oil agent has been used for an impact printer such as a wire dot printer or a typewriter. There is.
【０００３】このファブリックインクリボン用の液状イ
ンクには、着色剤として、有機または無機顔料を使用す
る顔料系、染料を使用する染料系、および顔料と染料を
併用する染顔料系がある。The liquid ink for the fabric ink ribbon includes a pigment type using an organic or inorganic pigment, a dye type using a dye, and a dye-pigment type using a pigment and a dye together as a colorant.
【０００４】しかしながら、顔料系および染顔料系のイ
ンクを含浸させたファブリックインクリボンのばあい、
高温多湿の環境下で保存すると、インクの流動性が劣化
し、印字寿命が短かくなるという欠点があった。However, in the case of a fabric ink ribbon impregnated with pigment-based and dye-pigment-based inks,
When stored in a hot and humid environment, the fluidity of the ink deteriorates and the printing life becomes short.
【０００５】本発明は、前記の点に鑑みて、高温多湿環
境下で保存してもインクの流動性が劣化せず、印字寿命
が影響を受けないファブリックインクリボンを提供する
ことを目的とする。In view of the above points, an object of the present invention is to provide a fabric ink ribbon in which the fluidity of the ink does not deteriorate even when stored in a high temperature and high humidity environment and the printing life is not affected. .
【０００６】[0006]
【課題を解決するための手段】本発明は、少なくとも有
機および／または無機顔料を含む着色剤、および油剤を
必須成分として含有するインクがファブリックリボン生
地に含浸されてなるファブリックインクリボンにおい
て、前記インクがさらにフェノール樹脂を含有すること
を特徴とするファブリックインクリボンを提供する。The present invention provides a fabric ink ribbon in which a fabric ribbon material is impregnated with an ink containing a colorant containing at least an organic and / or inorganic pigment and an oil agent as essential components. Further comprises a phenolic resin, which provides a fabric ink ribbon.
【０００７】本発明はさらに、前記フェノール樹脂がパ
ラアルキルフェノール樹脂であるファブリックインクリ
ボンを提供する。The present invention further provides a fabric ink ribbon in which the phenolic resin is a para-alkylphenolic resin.
【０００８】本発明はさらに、前記パラアルキルフェノ
ール樹脂のアルキル基がｔ−ブチル基であるファブリッ
クインクリボンを提供する。The present invention further provides a fabric ink ribbon in which the alkyl group of the paraalkylphenol resin is a t-butyl group.
【０００９】[0009]
【作用および実施例】本発明のファブリックインクリボ
ンにおいては、そのインクとして、顔料を含む着色剤と
油剤に加えてフェノール樹脂を含有するものを使用す
る。このフェノール樹脂の作用効果はつぎのとおりであ
る。FUNCTION AND WORKING EXAMPLE In the fabric ink ribbon of the present invention, an ink containing a phenol resin in addition to a coloring agent containing a pigment and an oil agent is used as the ink. The effects of this phenol resin are as follows.
【００１０】本発明者らが、従来のファブリックインク
リボンを高温多湿の環境下で保存したばあいにインクの
流動性が劣下する原因を考察したところ、高温多湿の環
境下では親水性基を有する顔料粒子の表面に水分が付着
され、それが原因で顔料粒子同士が凝集し、流動性が劣
下するものと推察された。The inventors of the present invention have examined the cause of poor fluidity of ink when a conventional fabric ink ribbon is stored in a hot and humid environment, and a hydrophilic group is found in the hot and humid environment. It was speculated that water adhered to the surface of the pigment particles contained therein, which caused the pigment particles to aggregate with each other, resulting in poor fluidity.
【００１１】しかるに、前記インク中にフェノール樹脂
を配合せしめることによって、該フェノール樹脂はその
親水部が親水性基を有する顔料粒子の表面に対して親和
性が高いため、顔料粒子表面に付着し、顔料粒子表面を
包み込んでしまう。この包み込みにより顔料粒子の表面
はフェノール樹脂の親油性基で覆われ、それにより水分
の顔料粒子表面への付着が防止されるため、顔料粒子同
士が凝集するのが防止され、もってインクの流動性の劣
化が防止されるものと推定されている。However, when the phenol resin is mixed in the ink, since the phenol resin has a high affinity for the surface of the pigment particle having a hydrophilic group, the phenol resin adheres to the surface of the pigment particle, Wraps the surface of the pigment particles. By this encapsulation, the surface of the pigment particles is covered with the lipophilic group of the phenol resin, which prevents water from adhering to the surface of the pigment particles, preventing the pigment particles from aggregating with each other, and thus the fluidity of the ink. It is estimated that the deterioration of
【００１２】本発明に用いるフェノール樹脂としては、
レゾール型のものが好ましく、顔料との親和性が高くか
つ油剤との相溶性が良好な点からレゾール型パラアルキ
ルフェノール樹脂がとくに好ましい。このレゾール型パ
ラアルキルフェノール樹脂はたとえば一般式（Ｉ）：As the phenol resin used in the present invention,
Resol type resins are preferable, and resol type paraalkylphenol resins are particularly preferable in terms of high affinity with pigments and good compatibility with oil agents. This resol-type paraalkylphenol resin has, for example, the general formula (I):
【００１３】[0013]
【化１】 Embedded image
【００１４】（式中、Ｒは炭素原子数が１〜４個の直鎖
または分岐状アルキル基、ｎは５〜３０の整数である）
で示されるものである。Ｒで表わされるアルキル基とし
ては、メチル、エチル、ｎ−プロピル、イソプロピル、
ｎ−ブチル、イソブチル、ｔ−ブチルなどがあげられ
る。(In the formula, R is a linear or branched alkyl group having 1 to 4 carbon atoms, and n is an integer of 5 to 30.)
It is shown by. Examples of the alkyl group represented by R include methyl, ethyl, n-propyl, isopropyl,
Examples thereof include n-butyl, isobutyl and t-butyl.
【００１５】これらレゾール型パラアルキルフェノール
樹脂は単独で使用してもよく、混合して使用してもよ
い。These resol type paraalkylphenol resins may be used alone or in combination.
【００１６】前記レゾール型パラアルキルフェノール樹
脂の中でも、レゾール型パラ−ｔ−ブチルフェノール樹
脂がとくに好ましい。Among the above-mentioned resol type para-alkylphenol resins, the resol type para-t-butylphenol resin is particularly preferable.
【００１７】前記フェノール樹脂のインク中における含
有量は３〜３０％（重量％、以下同様）の範囲が好まし
い。フェノール樹脂の含有量が前記範囲より少ないと、
顔料の表面を充分に包み込むことができず、高温多湿条
件下で顔料が凝集し、インクの粘度が高くなる傾向にあ
る。一方前記範囲より多いと、インクの初期粘度が高く
なりすぎ、インクリボン用のインクとして適さなくなる
傾向にある。The content of the phenol resin in the ink is preferably in the range of 3 to 30% (% by weight, the same applies hereinafter). When the content of the phenol resin is less than the above range,
There is a tendency that the surface of the pigment cannot be sufficiently wrapped, the pigment aggregates under high temperature and high humidity conditions, and the viscosity of the ink increases. On the other hand, if it is more than the above range, the initial viscosity of the ink tends to be too high, and it tends to be unsuitable as an ink for an ink ribbon.
【００１８】本発明における着色剤としては有機および
／または無機の顔料が使用される。顔料に加えて染料を
併用してもよい。Organic and / or inorganic pigments are used as the colorant in the present invention. A dye may be used in combination with the pigment.
【００１９】無機顔料としては、たとえばカーボンブラ
ック、四三酸化鉄などがあげられる。有機顔料として
は、たとえばシアニンブルー、フタロシアニンブルー、
ビクトリアブルーベース、ハンザイエロー、ベンジジン
イエロー、レーキレッド、パーマネントカーミン、ペリ
レンレッド、アニリンブラック、ペリレンブラックなど
があげられる。これら有機、無機の顔料は単独でまたは
混合して使用できる。染料としてはニグロシンベース、
メチルバイオレット、オイルブルー、オイルイエローな
どの油溶性染料の１種または２種以上が使用できる。Examples of the inorganic pigments include carbon black and ferric tetroxide. Examples of organic pigments include cyanine blue, phthalocyanine blue,
Examples include Victoria blue base, Hansa yellow, Benzidine yellow, lake red, permanent carmine, perylene red, aniline black, and perylene black. These organic and inorganic pigments can be used alone or in combination. Nigrosine base as dye,
One or more oil-soluble dyes such as methyl violet, oil blue and oil yellow can be used.
【００２０】本発明における油剤としては、たとえばナ
タネ油、ヒマシ油、大豆油、牛脂油などの動植物油、ビ
トリアオイル、パラフィン系オイルなどの鉱油、イソス
テアリン酸、オレイン酸などの高級脂肪酸、ジオクチル
アゼレート、ジオクチルフタレートなどの可塑剤などの
１種または２種以上が使用できる。Examples of the oil agent in the present invention include animal and vegetable oils such as rapeseed oil, castor oil, soybean oil and beef tallow oil, mineral oils such as vitoria oil and paraffin oil, higher fatty acids such as isostearic acid and oleic acid, and dioctyl azelate. , One or more plasticizers such as dioctyl phthalate can be used.
【００２１】本発明においては前記成分に加えて顔料分
散剤を配合してもよい。顔料分散剤としては、たとえば
ソルビタン脂肪酸エステル、リン酸エステルなどの非イ
オン性界面活性剤、レシチン、ポリエステル系分散剤な
どがあげられる。In the present invention, a pigment dispersant may be blended in addition to the above components. Examples of pigment dispersants include nonionic surfactants such as sorbitan fatty acid esters and phosphoric acid esters, lecithin, and polyester dispersants.
【００２２】本発明におけるインクは、前記各成分をイ
ンク全量に対して、つぎに示す割合（％）で配合するの
が好ましい。In the ink of the present invention, it is preferable to mix the above components in the following proportions (%) with respect to the total amount of the ink.
【００２３】 成 分 ％ 顔料 ３〜３０ 染料 ０〜１５ 油剤 ３０〜９０ フェノール樹脂 ３〜３０ 顔料分散剤 ０〜１０ （好ましくは１〜６） 前記インクには、本発明の目的を損なわない範囲内で、
防腐剤、防カビ剤などの添加剤を適宜配合することがで
きる。Component% Pigment 3 to 30 Dye 0 to 15 Oil agent 30 to 90 Phenolic resin 3 to 30 Pigment dispersant 0 to 10 (preferably 1 to 6) The ink is within a range that does not impair the object of the present invention. so,
Additives such as preservatives and fungicides can be appropriately added.
【００２４】前記インクは、通常の調製法で調製でき、
たとえば前記成分をロールミル、サンドミルなどで混練
することにより調製できる。The ink can be prepared by a usual preparation method,
For example, it can be prepared by kneading the above components with a roll mill, a sand mill or the like.
【００２５】本発明のファブリックインクリボンは前記
インクをファブリックリボン生地に含浸させたものであ
るが、ファブリックリボン生地としては、ナイロン６、
ナイロン６６、ポリエステル、絹、綿などの繊維の織布
で、坪量３０〜８０ｇ／ｍ2程度のものが好ましく使用
できる。インクの含浸量は通常５〜２５ｇ／ｍ2 程度が
適当である。The fabric ink ribbon of the present invention is a fabric ribbon material impregnated with the above-mentioned ink. The fabric ribbon material is nylon 6,
A woven fabric of fibers such as nylon 66, polyester, silk, and cotton, having a basis weight of about 30 to 80 g / m 2 can be preferably used. An appropriate amount of ink impregnated is usually about 5 to 25 g / m 2 .
【００２６】つぎに実施例をあげて本発明を説明する。The present invention will be described below with reference to examples.
【００２７】実施例１〜４および比較例１ 表１に示す処方に従って各材料を混合し、３本ロールミ
ルで混練してインクを調製した。Examples 1 to 4 and Comparative Example 1 Inks were prepared by mixing the materials according to the formulation shown in Table 1 and kneading with a three-roll mill.
【００２８】えられた各インクを６５℃、９０％ＲＨの
環境下で９６時間保存した。この保存処理の前後におけ
るインクの粘度を測定し、さらに保存処理前の粘度に対
する保存処理後の粘度の増加率（％）を求めた。インク
の粘度はロドビスコ粘度計で測定した。結果を表１に示
す。The obtained inks were stored for 96 hours in an environment of 65 ° C. and 90% RH. The viscosity of the ink before and after the storage treatment was measured, and the increase rate (%) of the viscosity after the storage treatment with respect to the viscosity before the storage treatment was determined. The viscosity of the ink was measured with a Rhodovisco viscometer. The results are shown in Table 1.
【００２９】また前記調製直後の各インクを幅１３ｍ
ｍ、坪量６５ｇ／ｍ2 のナイロン６６生地に１３ｇ／ｍ
2 の割合で含浸させ、６０ｍのメビウス環としたものを
リボンカッセトに装填し、６５℃、９０％ＲＨの環境下
で９６時間保存した。この保存処理の前後のインクリボ
ンを用いて印字を行ない、印字寿命を求めた。印字寿命
は印字濃度（ＰＣＳ値）が０．４になるまでに印字でき
た文字数で表わした。印字は２４ピンワイヤドットプリ
ンタで白色連票紙に行ない、印字濃度（ＰＣＳ値）はマ
クベス社製濃度計ＰＣＭ−IIを用いて測定した。結果を
表１に示す。Width of each ink immediately after preparation is 13 m
13g / m for nylon 66 fabric with m and basis weight 65g / m 2.
The ribbon cassette was impregnated with a ratio of 2 and made into a Mobius ring of 60 m, and the ribbon cassette was loaded and stored in an environment of 65 ° C. and 90% RH for 96 hours. Printing was performed using the ink ribbon before and after this storage treatment, and the printing life was obtained. The print life was represented by the number of characters that could be printed before the print density (PCS value) reached 0.4. The printing was performed on a white continuous paper with a 24-pin wire dot printer, and the print density (PCS value) was measured using a densitometer PCM-II manufactured by Macbeth. The results are shown in Table 1.
【００３０】[0030]
【表１】 [Table 1]
【００３１】表１の結果から明らかなように、フェノー
ル樹脂を含有するインク（実施例１〜４）のばあいは、
高温多湿条件下での保存処理によるインク粘度の増加率
が４〜１０％程度であり、印字寿命に変化がないのに対
して、フェノール樹脂を含有しないインク（比較例１）
のばあいは保存処理によるインク粘度の増加率が５４％
であり、印字寿命が短かくなった。なお、保存処理によ
るインク粘度の増加率が１０％程度以下であれば印字寿
命にほとんど影響がない。As is clear from the results shown in Table 1, in the case of the inks containing the phenol resin (Examples 1 to 4),
The ink viscosity increase rate due to the storage treatment under high temperature and high humidity conditions is about 4 to 10%, and the printing life does not change, whereas the ink does not contain a phenol resin (Comparative Example 1).
In this case, the increase rate of ink viscosity due to storage treatment is 54%.
Therefore, the printing life was shortened. If the increase rate of the ink viscosity due to the storage treatment is about 10% or less, there is almost no effect on the printing life.
【００３２】[0032]
【発明の効果】ファブリックインクリボンにおいて、イ
ンクにフェノール樹脂を配合することによって、高温多
湿環境下で保存してもインクの流動性が劣下せず、印字
寿命が影響を受けない。EFFECTS OF THE INVENTION In a fabric ink ribbon, by blending an ink with a phenol resin, the fluidity of the ink does not deteriorate even when stored in a high temperature and high humidity environment, and the printing life is not affected.
Claims (3)
を含む着色剤、および油剤を必須成分として含有するイ
ンクがファブリックリボン生地に含浸されてなるファブ
リックインクリボンにおいて、前記インクがさらにフェ
ノール樹脂を含有することを特徴とするファブリックイ
ンクリボン。1. A fabric ink ribbon obtained by impregnating a fabric ribbon fabric with a colorant containing at least an organic and / or inorganic pigment and an oil agent as essential components, wherein the ink further contains a phenol resin. Fabric Ink Ribbon.
ノール樹脂である請求項１記載のファブリックインクリ
ボン。2. The fabric ink ribbon according to claim 1, wherein the phenol resin is a paraalkylphenol resin.
キル基がｔ−ブチル基である請求項２記載のファブリッ
クインクリボン。3. The fabric ink ribbon according to claim 2, wherein the alkyl group of the paraalkylphenol resin is a t-butyl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13583694A JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13583694A JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH082099A true JPH082099A (en) | 1996-01-09 |
| JP3209476B2 JP3209476B2 (en) | 2001-09-17 |
Family
ID=15160907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13583694A Expired - Lifetime JP3209476B2 (en) | 1994-06-17 | 1994-06-17 | Fabric ink ribbon |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3209476B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012508796A (en) * | 2008-11-12 | 2012-04-12 | アーチャー ダニエルズ ミッドランド カンパニー | Lecithin and plasticizer compositions and methods |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000077575A1 (en) | 1999-06-10 | 2000-12-21 | Alliedsignal Inc. | Spin-on-glass anti-reflective coatings for photolithography |
| US6824879B2 (en) | 1999-06-10 | 2004-11-30 | Honeywell International Inc. | Spin-on-glass anti-reflective coatings for photolithography |
| US8053159B2 (en) | 2003-11-18 | 2011-11-08 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
| US8642246B2 (en) | 2007-02-26 | 2014-02-04 | Honeywell International Inc. | Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof |
| US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
| US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
-
1994
- 1994-06-17 JP JP13583694A patent/JP3209476B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012508796A (en) * | 2008-11-12 | 2012-04-12 | アーチャー ダニエルズ ミッドランド カンパニー | Lecithin and plasticizer compositions and methods |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3209476B2 (en) | 2001-09-17 |
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