JPH0821018A - Heat insulation structure of wall panel and manufacture therefor - Google Patents
Heat insulation structure of wall panel and manufacture thereforInfo
- Publication number
- JPH0821018A JPH0821018A JP6189789A JP18978994A JPH0821018A JP H0821018 A JPH0821018 A JP H0821018A JP 6189789 A JP6189789 A JP 6189789A JP 18978994 A JP18978994 A JP 18978994A JP H0821018 A JPH0821018 A JP H0821018A
- Authority
- JP
- Japan
- Prior art keywords
- wall panel
- film
- urethane foam
- heat insulating
- foam resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000009413 insulation Methods 0.000 title description 7
- 239000006260 foam Substances 0.000 claims abstract description 49
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229920005989 resin Polymers 0.000 claims abstract description 40
- 239000011347 resin Substances 0.000 claims abstract description 40
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000007740 vapor deposition Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000853 adhesive Substances 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 4
- 230000005855 radiation Effects 0.000 abstract description 2
- 230000003014 reinforcing effect Effects 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 5
- 229920006327 polystyrene foam Polymers 0.000 description 4
- 229920006328 Styrofoam Polymers 0.000 description 3
- 239000008261 styrofoam Substances 0.000 description 3
- 239000003677 Sheet moulding compound Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- -1 aromatic isocyanate Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Building Environments (AREA)
- Panels For Use In Building Construction (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、特に寒冷地等において
使用される壁パネルの裏面側に、発泡ウレタン樹脂によ
る断熱層を設け、その表面側をフィルムて被覆すること
により、保温性を高めるようにし且つ外観上の見栄えを
良くするようにした壁パネルの保温構造及び壁パネルの
製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention enhances heat retention by providing a heat insulating layer of urethane foam resin on the back side of a wall panel used particularly in a cold region and covering the front side with a film. The present invention relates to a heat retaining structure for a wall panel and a manufacturing method of the wall panel, which are improved in appearance and appearance.
【0002】[0002]
【従来の技術】従来において、保温機能を有する壁パネ
ルとしては、図2に示すようなものがある。この壁パネ
ル1は、その裏面側に発泡ウレタン樹脂を吹き付けて発
泡硬化させ、断熱層2を形成したものである。また従来
にあっては、壁パネルの裏面側に発泡スチロールをブロ
ック状にして貼り付け、断熱層を形成するようにしたも
のもある。2. Description of the Related Art Conventionally, there is a wall panel having a heat retaining function as shown in FIG. The wall panel 1 has a heat insulating layer 2 formed by blowing urethane foam resin on the back surface thereof to foam and cure the resin. Further, in the related art, there is one in which styrofoam is attached in a block shape on the back surface side of the wall panel to form a heat insulating layer.
【0003】[0003]
【発明が解決しようとする課題】而して、前記発泡ウレ
タン樹脂による断熱層2を形成する壁パネル1にあって
は、発泡ウレタン樹脂自体が紫外線や空気中の酸素との
反応によって粉体化したり、黄変し、しかも表面が凹凸
状であるため、該凹凸面に塵埃等が堆積し、これを使用
した製品の外観上の見栄えが悪くなるという欠点があっ
た。Therefore, in the wall panel 1 forming the heat insulating layer 2 made of the urethane foam resin, the urethane foam resin itself is pulverized by the reaction with ultraviolet rays or oxygen in the air. However, since the surface is uneven and yellow, and dust is accumulated on the uneven surface, the appearance of the product using this is poor.
【0004】特に、前記壁パネル1を図3に示すユニッ
トバス3に使用した場合、北海道等の寒冷地において
は、工場で予めユニットバス3を組み立てた状態で出荷
し、これを現場の空き地へ搬入して置いておくことが多
々ある。ユニットバス3の壁パネル1は、その表面側が
室内に面しており、パネル裏面の断熱層2はユニットバ
ス3の外表面に面している。In particular, when the wall panel 1 is used for the unit bath 3 shown in FIG. 3, in a cold district such as Hokkaido, the unit bath 3 is shipped in a state where it is assembled in advance at a factory, and the unit bath 3 is shipped to a vacant lot on site. Often brought in and set aside. The surface side of the wall panel 1 of the unit bath 3 faces the room, and the heat insulating layer 2 on the back surface of the panel faces the outer surface of the unit bath 3.
【0005】そのため、壁パネル1の裏面側の発泡ウレ
タン樹脂による断熱層2が裏面側で露出し、公衆の目に
晒されるので外観上の見栄えが悪く、商品価値も低下す
るという問題があった。Therefore, the heat insulating layer 2 made of urethane foam resin on the back side of the wall panel 1 is exposed on the back side and is exposed to the public's eyes, so that there is a problem that the appearance is not good and the commercial value is lowered. .
【0006】一方、壁パネルの裏面側に、発泡スチロー
ルをブロック状に貼着する従来技術にあっては、壁パネ
ルと発泡スチロールとの間に間隙が形成され易く、その
分だけ保温性が失われるという欠点があった。また発泡
スチロールが分割してブロックごとに貼着されているた
め、貼着後の外観上の見栄えも悪くなるという欠点があ
った。On the other hand, in the conventional technique in which the polystyrene foam is adhered to the back surface of the wall panel in a block shape, a gap is easily formed between the wall panel and the polystyrene foam, and the heat retaining property is lost accordingly. There was a flaw. Further, since the styrofoam is divided and adhered to each block, there is a drawback that the appearance after adhesion is deteriorated.
【0007】更に、壁パネルの裏面側に、図2に示すよ
うなリブが形成される場合は、リブを避けて貼着しなけ
ればならず、発泡スチロール板をその大きさに応じて切
断する作業が必要であり、面倒であった。しかも、この
場合には、発泡スチロールの使用枚数が増えるという欠
点と、更には、切断した発泡スチロールを個別的に壁パ
ネルの裏面側に貼着しなければならないという欠点とが
あった。Further, when ribs as shown in FIG. 2 are formed on the back surface side of the wall panel, the ribs must be attached while avoiding the ribs, and the work of cutting the Styrofoam plate according to its size. Was necessary and tedious. Moreover, in this case, there is a drawback that the number of used polystyrene foam is increased, and furthermore, the cut polystyrene foam must be individually attached to the back surface side of the wall panel.
【0008】[0008]
【課題を解決するための手段】本発明は従来の前記課題
に鑑みてこれを改良除去したものであって、保温性と裏
面側の外観上の見栄えの良い壁パネルの保温構造及びそ
の製造方法を提供せんとするものである。SUMMARY OF THE INVENTION The present invention has been made by improving and removing the conventional problems in view of the above-mentioned problems, and has a heat insulating structure for a wall panel which has a good heat insulating property and a good appearance on the rear surface side, and a manufacturing method thereof. Is intended to be provided.
【0009】而して、前記課題を解決するために本発明
が採用した壁バネルの保温構造は、壁パネルの裏面にウ
レタンによる発泡断熱層を形成し、該発泡断熱層の裏面
にフィルムを貼り付けたことを特徴とするものである。In order to solve the above-mentioned problems, the heat insulation structure of the wall panel adopted by the present invention is such that a foam heat insulating layer made of urethane is formed on the back surface of the wall panel, and a film is attached to the back surface of the foam heat insulating layer. It is characterized by being attached.
【0010】また本発明が採用した壁パネルの製造方法
は、壁パネルの裏面に発泡ウレタン樹脂を吹き付け、該
発泡ウレタン樹脂が未硬化の状態でその上面にフィルム
を配置し、発泡ウレタン樹脂の発泡硬化に伴って発泡ウ
レタン樹脂の自己接着性によりフィルムを一体的に接着
するようにしたことを特徴とするものである。Further, in the method for manufacturing a wall panel adopted by the present invention, a urethane foam resin is sprayed on the back surface of the wall panel, and a film is placed on the upper surface of the urethane foam resin in an uncured state to foam the urethane foam resin. It is characterized in that the film is integrally bonded by the self-adhesiveness of the urethane foam resin as it is cured.
【0011】[0011]
【作用】本発明の壁パネルの保温構造は、壁パネルの裏
面側に発泡ウレタン樹脂による断熱層が形成され、更に
その表面側にフィルムが貼着されている。このフィルム
は、例えばカラーフィルム又はアルミ蒸着フィルムであ
り、発泡ウレタン樹脂が表面へ露出するのを隠蔽するの
で、外観上の見栄えがよい。またアルミ蒸着フィルムで
ある場合には、輻射熱が放散するのを防止する働きがあ
り、前記発泡ウレタン樹脂による断熱効果と相俟って優
れた保温性が得られる。According to the heat retaining structure of the wall panel of the present invention, a heat insulating layer made of urethane foam resin is formed on the back side of the wall panel, and a film is attached to the front side of the heat insulating layer. This film is, for example, a color film or an aluminum vapor-deposited film, and since it covers the exposure of the urethane foam resin to the surface, it has a good appearance. Further, in the case of an aluminum vapor-deposited film, it has a function of preventing radiant heat from dissipating, and an excellent heat retaining property is obtained in combination with the heat insulating effect of the urethane foam resin.
【0012】本発明の壁パネルの製造方法にあっては、
壁パネルの裏面側に発泡ウレタン樹脂を吹き付け、発泡
ウレタン樹脂がまだ未硬化の自己接着性を有している状
態でその表面側にフィルムを配置し、発泡硬化と同時に
フィルムを接着するようにしている。従って、別途、フ
ィルムを貼り付ける等の作業は不要である。極めて簡単
に発泡ウレタン樹脂を隠蔽することが可能である。In the wall panel manufacturing method of the present invention,
Spray the urethane foam resin on the back side of the wall panel, place the film on the front side of the urethane foam resin with the uncured self-adhesive property, and bond the film at the same time as the foam cure. There is. Therefore, a separate work such as attaching a film is unnecessary. It is possible to conceal the urethane foam resin very easily.
【0013】[0013]
【実施例】以下に、本発明の壁パネルの保温構造及び壁
パネルの製造方法を、図面に示す実施例に基づいて説明
すると次の通りである。図1の図(a)乃至図(b)
は、本発明の一実施例に係る壁パネル4の製造工程を示
す縦断面図である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The wall panel heat retaining structure and wall panel manufacturing method of the present invention will be described below with reference to the embodiments shown in the drawings. FIG. 1A to FIG. 1B
[Fig. 3] is a vertical sectional view showing a manufacturing process of the wall panel 4 according to an embodiment of the present invention.
【0014】この実施例にあっては、先ず、図1の図
(a)に示す如く、不飽和ポリエステル樹脂成形材料
(シートモールディングコンパウンド(SMC)ともい
う)をプレス成形し、厚みが2〜3mmの壁パネル4を
成形する。なお、この壁パネル4は、その裏面側に補強
用のリブ5が設けられている。そして、該壁パネル4の
裏面側の一端側に、両面テープ6を介してアルミ蒸着フ
ィルム7の一端側を接着しておく。In this embodiment, first, as shown in FIG. 1A, an unsaturated polyester resin molding material (also referred to as a sheet molding compound (SMC)) is press-molded to have a thickness of 2 to 3 mm. The wall panel 4 is molded. The wall panel 4 is provided with reinforcing ribs 5 on the back side thereof. Then, one end side of the aluminum vapor deposition film 7 is adhered to one end side of the back surface side of the wall panel 4 via the double-sided tape 6.
【0015】次に、同図の図(b)に示す如く、壁パネ
ル4の裏面側に硬質の発泡ウレタン樹脂8を吹き付け
る。発泡ウレタン樹脂は、I液とR液とよりなる二液混
合タイプであり、I液は粗製芳香族イソシアネート(M
DI)からなり、R液はポリオール,触媒(有機金属化
合物),整泡剤(シリコン系海綿活性剤),発泡剤(フ
レオン1I),燃焼抑制剤を混合したものである。Next, as shown in FIG. 3B, a hard urethane foam resin 8 is sprayed onto the back surface of the wall panel 4. The urethane foam resin is a two-liquid mixed type consisting of liquid I and liquid R, and liquid I is a crude aromatic isocyanate (M
The liquid R is a mixture of a polyol, a catalyst (organic metal compound), a foam stabilizer (silicon sponge activator), a foaming agent (Freon 1I), and a combustion inhibitor.
【0016】発泡ウレタン樹脂8の吹き付けが完了した
後は、図(c)に示すように、発泡ウレタン樹脂8が未
硬化の状態で、アルミ蒸着フィルム7の自由端側を持っ
て発泡ウレタン樹脂8の表面側に被せる。そして、手等
で軽く押さえて、発泡ウレタン樹脂8とアルミ蒸着フィ
ルム7を接触させる。After the spraying of the urethane foam resin 8 is completed, as shown in FIG. 3C, the urethane foam resin 8 is uncured, and the urethane foam resin 8 is held by holding the free end side of the aluminum vapor deposition film 7. Cover the front side of. Then, the urethane foam resin 8 and the aluminum vapor deposition film 7 are brought into contact with each other by lightly pressing them with a hand or the like.
【0017】この状態では発泡ウレタン樹脂8は、自己
接着性を有している。そのため、発泡ウレタン樹脂8
は、発泡硬化の進行と同時に、アルミ蒸着フィルム7を
その自己接着性により一体的に接着するようになる。従
って、アルミ蒸着フィムル7を別途、接着するための作
業は不要である。In this state, the urethane foam resin 8 has self-adhesiveness. Therefore, urethane foam resin 8
At the same time as the foam hardening progresses, the aluminum vapor deposition film 7 is integrally bonded due to its self-adhesiveness. Therefore, the work for separately bonding the aluminum vapor deposition film 7 is unnecessary.
【0018】図1の図(d)は、発泡ウレタン樹脂8の
発泡硬化が完了した状態を示すものである。この発泡硬
化の完了により、壁パネル4の裏面側に硬質の発泡ウレ
タン樹脂8による断熱層9が形成され、該断熱層9はそ
の表面側をアルミ蒸着フィルム7で被覆されることにな
る。FIG. 1D shows a state in which foaming and hardening of the urethane foam resin 8 is completed. Upon completion of the foaming and hardening, a heat insulating layer 9 made of hard urethane resin 8 is formed on the back surface side of the wall panel 4, and the heat insulating layer 9 is covered with the aluminum vapor deposition film 7 on the front surface side.
【0019】このように本実施例にあっては、壁パネル
4の裏面側に硬質の発泡ウレタン樹脂8を吹き付けて発
泡硬化させ、断熱層9を設けるようにしたから、断熱層
9は壁パネル4の裏面側に密着し、隙間を生じることが
ない。そのため、前記隙間によって断熱効果が失われる
ことはない。As described above, in this embodiment, since the hard urethane foam resin 8 is sprayed on the back surface of the wall panel 4 to foam and harden the heat insulation layer 9, the heat insulation layer 9 is provided. It adheres to the back surface side of No. 4 and no gap is generated. Therefore, the heat insulating effect is not lost by the gap.
【0020】また断熱層9の表面にはアルミ蒸着フィル
ム7が一体的に被覆されているので、壁パネル4の室内
側から前記断熱層9を透過する輻射熱がアルミ蒸着フィ
ルム7によって反射され、輻射熱の放散が抑止される結
果、保温効果に優れたものとなる。Further, since the surface of the heat insulating layer 9 is integrally covered with the aluminum vapor deposition film 7, the radiant heat passing through the heat insulating layer 9 from the indoor side of the wall panel 4 is reflected by the aluminum vapor deposition film 7 and the radiant heat is radiated. As a result, the heat insulation effect is excellent.
【0021】更に、前記アルミ蒸着フィルム7は、断熱
層9を隠蔽するので、断熱層9の表面凹凸部に塵埃等が
堆積して人目に触れる等のことはなく、外観上の見栄え
が良い。Further, since the aluminum vapor-deposited film 7 conceals the heat insulating layer 9, dust or the like does not accumulate on the surface irregularities of the heat insulating layer 9 and is not touched by the human eye, so that it has a good appearance.
【0022】ところで、本発明は上述した実施例に限定
されるものではなく、適宜の変更が可能である。例え
ば、アルミ蒸着フィルム7は、カラーフィムルであって
もよい。この場合には、断熱層9を隠蔽し、外観上の見
栄えを良くするという効果はあるものの、室内側からの
輻射熱の放散を防止するという効果は期待できない。Incidentally, the present invention is not limited to the above-described embodiment, but can be appropriately changed. For example, the aluminum vapor deposition film 7 may be a color film. In this case, although there is an effect that the heat insulating layer 9 is concealed and the appearance is improved, the effect of preventing the radiation heat from radiating from the indoor side cannot be expected.
【0023】[0023]
【発明の効果】以上説明したように本発明の壁パネルの
保温構造にあっては、壁パネルの裏面側に発泡ウレタン
樹脂による断熱層が形成され、更にその表面側にフィル
ムが貼着されており、発泡ウレタン樹脂による断熱層が
表面へ露出するのを隠蔽するので、外観上の見栄えがよ
い。また前記フィルムがアルミ蒸着フィルムである場合
には、輻射熱が放散するのを防止する働きがあり、前記
発泡ウレタン樹脂による断熱効果と相俟って優れた保温
性が得られる。As described above, in the heat insulating structure of the wall panel of the present invention, the heat insulating layer made of the urethane foam resin is formed on the back surface side of the wall panel, and the film is attached on the front surface side. Since the heat insulating layer made of urethane foam resin is hidden from being exposed to the surface, the appearance is good. When the film is an aluminum vapor-deposited film, it has a function of preventing radiant heat from dissipating, and in combination with the heat insulating effect of the urethane foam resin, excellent heat retention can be obtained.
【0024】一方、本発明の壁パネルの製造方法にあっ
ては、壁パネルの裏面側に発泡ウレタン樹脂を吹き付
け、発泡ウレタン樹脂がまだ未硬化の自己接着性を有し
ている状態でその表面側にフィルムを配置し、発泡硬化
と同時にフィルムを接着しているので、別途、フィルム
を貼り付ける等の作業は不要であり、極めて簡単に発泡
ウレタン樹脂による断熱層を隠蔽することが可能であ
る。On the other hand, in the method for manufacturing a wall panel of the present invention, a urethane foam resin is sprayed on the back surface side of the wall panel, and the urethane foam resin is uncured and has a self-adhesive surface. Since the film is placed on the side and the film is adhered at the same time as the foam hardening, there is no need to separately attach the film, and it is possible to conceal the heat insulation layer with the urethane foam resin very easily. .
【図1】図(a)〜図(d)はそれぞれ本発明の一実施
例に係る壁パネルの製造工程を示す縦断面図である。1A to 1D are vertical cross-sectional views showing a manufacturing process of a wall panel according to an embodiment of the present invention.
【図2】従来の壁パネルを示す縦断面図である。FIG. 2 is a vertical sectional view showing a conventional wall panel.
【図3】従来の壁パネルを用いたユニットバスの全体を
示す一部断面斜視図である。FIG. 3 is a partial sectional perspective view showing an entire unit bath using a conventional wall panel.
4…壁パネル 7…アルミ蒸着フ
ィルム 8…硬質の発泡ウレタン樹脂 9…断熱層4 ... Wall panel 7 ... Aluminum vapor deposition film 8 ... Hard urethane foam resin 9 ... Thermal insulation layer
Claims (4)
層を形成し、該発泡断熱層の裏面にフィルムを貼り付け
たことを特徴とする壁パネルの保温構造。1. A heat retaining structure for a wall panel, wherein a foamed heat insulating layer made of urethane is formed on the back surface of the wall panel, and a film is attached to the back surface of the foamed heat insulating layer.
を特徴とする前記請求項1に記載の壁パネルの保温構
造。2. The heat retaining structure for a wall panel according to claim 1, wherein the film is an aluminum vapor deposition film.
付け、該発泡ウレタン樹脂が未硬化の状態でその上面に
フィルムを配置し、発泡ウレタン樹脂の発泡硬化に伴っ
て発泡ウレタン樹脂の自己接着性によりフィルムを一体
的に接着するようにしたことを特徴とする壁パネルの製
造方法。3. A urethane foam resin is sprayed onto the back surface of a wall panel, and a film is placed on the upper surface of the urethane foam resin in an uncured state, and the urethane foam resin self-adhesiveness is accompanied by foam hardening of the urethane foam resin. The method for manufacturing a wall panel is characterized in that the film is integrally bonded by the method.
を特徴とする前記請求項3に記載の壁パネルの製造方
法。4. The method for manufacturing a wall panel according to claim 3, wherein the film is an aluminum vapor deposition film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6189789A JPH0821018A (en) | 1994-07-08 | 1994-07-08 | Heat insulation structure of wall panel and manufacture therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6189789A JPH0821018A (en) | 1994-07-08 | 1994-07-08 | Heat insulation structure of wall panel and manufacture therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0821018A true JPH0821018A (en) | 1996-01-23 |
Family
ID=16247236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6189789A Pending JPH0821018A (en) | 1994-07-08 | 1994-07-08 | Heat insulation structure of wall panel and manufacture therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0821018A (en) |
-
1994
- 1994-07-08 JP JP6189789A patent/JPH0821018A/en active Pending
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