JPH0826956A - Deodorant cosmetics - Google Patents

Abstract

(57) [Summary] [Purpose] To provide a deodorant cosmetic having an excellent deodorant effect. [Structure] A feature of the present invention is that a zeolite holding an antibacterial metal ion is mixed in the ion-exchangeable portion.
The amount of zeolite is preferably 0.1% by weight or more, the amount of zeolite is 1.0% by weight or more for spray type, and the amount of zeolite is 5.0% by weight for powder type, stick type or pressed powder type.
It is preferable to make the above.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a deodorant cosmetic composition.

[0002]

2. Description of the Related Art Deodorant cosmetics are cosmetics used to prevent the release or secretion of unpleasant body odor, or to eliminate the release or secretion. This product form is generally lotion, cream, powder, stick or aerosol.

Body odor is the main cause of decomposition of sweat, and there are the following methods for preventing body odor caused by sweat.

Deodorant action by astringent action A strong astringent action suppresses the generation of sweat and indirectly prevents body odor. For example, astringents such as zinc sulfocarbonate, citric acid, or various aluminum compounds are often used,
In addition, ethyl alcohol also has an astringent effect. Among these, an aluminum compound (aluminum hydroxy chloride) is particularly often used, and in the case of an aerosol type, a complex with propylene glycol having good compatibility with freon gas has been developed.

Deodorant effect due to bactericidal action It is due to the decomposing action of bacteria that sweat decomposes to generate odors, and the bactericidal agent prevents the growth of bacteria and decomposes sweat.
Directly prevent odor. For example, TMTD (tetramethylthiuram disulfide), benzalkonium chloride, halocarbane, etc. are often used, and other zinc white, essential oils, fragrances, chlorophyll compounds, etc. also have antibacterial effects.

Deodorant action by masking effect of perfume Since normal body odor can be sufficiently eliminated by perfume or cologne, there are some types in which the above-mentioned bactericidal agents are added to indirectly promote the deodorant effect. The purpose of use is almost the same as that of cologne.

By the way, as the conventional deodorant cosmetics, there are known deodorant cosmetics containing a protein astringent salt such as basic aluminum chloride, aluminum chloride or chlorozirconium oxide salt. Such conventional deodorant cosmetics suppress perspiration by the salt and indirectly deodorize.

However, the conventional deodorant cosmetics do not always have a good deodorant effect, and therefore, there is a demand for a deodorant cosmetic having a more excellent deodorant effect.

[0009]

DISCLOSURE OF THE INVENTION An object of the present invention is to provide a deodorant cosmetic having an excellent deodorant effect.

[0010]

Means for Solving the Problems The deodorant cosmetics for solving the above problems are characterized in that a zeolite having an antibacterial metal ion is mixed in an ion-exchangeable portion.

The structure of the present invention will be described in detail below.

(Zeolite) As the zeolite, both natural zeolite and synthetic zeolite can be used.

Zeolite is generally an aluminosilicate having a three-dimensional skeleton structure, and has a general formula of XM _{2 / n}
It is displayed as O · Al ₂ O ₃ · YSiO ₂ · ZH ₂ O. Here, M represents an ion-exchangeable ion, which is usually a monovalent or divalent metal ion. n is the valence of the (metal) ion. X and Y are metal oxide, silica coefficient,
Z represents the number of crystal waters.

Specific examples of the zeolite include, for example, A
-Type zeolite, X-type zeolite, Y-type zeolite, T-type zeolite, high silica zeolite, sodalite, mordenite, analcime, clinoptilolite, chabazite, erionite and the like can be mentioned. Of course, it is not limited to these.

The ion exchange capacities of these exemplified zeolites are as follows: A-type zeolite 7 meq / g, X-type zeolite 6.4 meq / g, Y-type zeolite 5 meq / g.
g, T-type zeolite 3.4 meq / g, sodalite 11.5 meq / g, mordenite 2.6 meq / g,
Anal Sime 5 meq / g, Clinoptilolite 2.6
Meq / g, chabazite 5 meq / g, and erionite 3.8 meq / g, all of which have a sufficient capacity for ion exchange with ammonium ions and silver ions.

The ion-exchangeable ions in the zeolite are, for example, sodium ion, calcium ion,
Examples thereof include potassium ion, magnesium ion, iron ion and the like.

Examples of antibacterial metal ions include silver, copper,
Zinc, mercury, tin, lead, bismuth, cadmium, chromium,
Alternatively, thallium ions, preferably silver, copper or zinc ions, etc. can be mentioned.

From the viewpoint of antibacterial properties, the above antibacterial metal ions are preferably contained in the zeolite in an amount of 0.1 to 15% by weight. An antibacterial zeolite containing 0.1 to 15% of silver ion and 0.1 to 8% of copper ion or zinc ion is more preferable. On the other hand, ammonium ion can be contained up to 20% in the zeolite, but from the viewpoint of effectively preventing discoloration of the zeolite, 0.5 to 5% in the zeolite is more preferable, and 0.5 to 2%. Is more preferable. In addition,% here is weight% of 110 degreeC dry standard.

(Method for Producing Antibacterial Zeolite) The antibacterial zeolite of the present invention is prepared by bringing the zeolite into contact with a previously prepared mixed aqueous solution containing antibacterial metal ions such as silver ions, copper ions and zinc ions, The ion-exchangeable ions of the above are replaced with the above-mentioned ions. Contact is performed at 10 to 70 ° C, preferably 40 to 60 ° C for 3 to 24 ° C.
It can be carried out by a batch method or a continuous method (for example, a column method), preferably for 10 to 24 hours. The pH of the mixed aqueous solution is 3 to 10, preferably 5 to 7.
It is appropriate to adjust to. By this adjustment, it is possible to prevent precipitation of silver oxide or the like on the zeolite surface or in the pores, which is preferable. In addition, each ion in the mixed aqueous solution is usually supplied as a salt. For example, silver ions are silver nitrate, silver sulfate, silver perchlorate, silver acetate, diammine silver nitrate, diammine silver sulfate, etc., and copper ions are copper nitrate (I
I), copper perchlorate, copper acetate, potassium tetracyanocuprate, copper sulfate, etc., zinc ion is zinc (II) nitrate, zinc sulfate, zinc perchlorate, zinc thiocyanate, zinc acetate, etc. Mercury chlorate, mercury nitrate, mercury acetate, tin ions are tin sulfate, etc., lead ions are lead sulfate, lead nitrate, etc., bismuth ions are bismuth chloride, bismuth iodide, etc., and cadmium ions are cadmium perchlorate, sulfuric acid. Cadmium, cadmium nitrate, cadmium acetate, and chromium ions can be used as chromium perchlorate, chromium sulfate, chromium ammonium sulfate, chromium nitrate, and thallium ions can be used, such as thallium perchlorate, thallium sulfate, thallium nitrate, and thallium acetate. .

The content of the antibacterial metal ion in the zeolite can be appropriately controlled by adjusting the concentration of each ion (salt) in the mixed aqueous solution. For example, when the antibacterial zeolite contains silver ions, the silver ion concentration in the mixed aqueous solution is 0.002M / l to 0.15M.
/ L, the silver ion content is 0.1 to 0.1 as appropriate.
It is possible to obtain 5% of antibacterial zeolite. When the antibacterial zeolite further contains copper ions and zinc ions, the copper ion concentration in the mixed aqueous solution is 0.1 M /
1 ~ 0.85M / l, zinc ion concentration is 0.15M / l
By setting it to 1.2 M / l, an antibacterial zeolite having a copper ion content of 0.1 to 8% and a zinc ion content of 0.1 to 8% can be obtained.

In the present invention, it is also possible to perform ion exchange by using an aqueous solution containing each ion alone in addition to the mixed aqueous solution as described above and sequentially bringing each aqueous solution into contact with zeolite. The concentration of each ion in each aqueous solution can be determined according to the concentration of each ion in the mixed aqueous solution.

The zeolite after the ion exchange is thoroughly washed and then dried. Drying is preferably performed at 105 to 115 ° C or under reduced pressure (1 to 30 Torr) at 70 to 90 ° C.

For ion exchange of ions or organic ions without suitable water-soluble salts such as tin and bismuth, a reaction is carried out using an organic solvent solution such as alcohol or acetone so that the hardly soluble basic salt does not precipitate. You can

(Amount of Antibacterial Zeolite) The amount of antibacterial zeolite is preferably 0.1% by weight or more. 0.1
If it is more than 5% by weight, the deodorizing effect becomes more remarkable.

From the viewpoint of improving the deodorizing effect, it is more preferable that the spray and lotion types have an amount of 1.0% by weight or more, and the powder type, the stick type and the pressed powder (powder molding type) have an amount of 5% by weight or more.

(Aluminum Compound) In the present invention, it is preferable to selectively blend an aluminum compound in order to further enhance the deodorizing effect by enhancing the antiperspirant effect.

In the present invention, the following aluminum compounds are preferably used.

Aluminum chloride, allantoin chlorohydroxyaluminum, aluminum sulfate, alum, aluminum hydroxychloride, allantoin dihydroxyaluminum, aluminum / zirconium chlorohydrates, organic complex salts of aluminum / zirconium (eg, Aluminum zirconium tetrachloro
hydrex gly, Zirconium aluminumglycine hydroxychlor
ide complex) Of these, aluminum hydroxy chloride is most preferable.

(Metal Oxide) It is preferable to add a metal oxide in order to enhance the deodorizing effect.

Examples of metal oxides that are preferable for blending in the present invention include zinc oxide, magnesium oxide, calcium oxide and the like. Magnesium oxide is preferable and zinc oxide is most preferable.

(Other Selective Blending Components) The following may be blended as other selective blending components.

1. Powder component (1) Inorganic powder Talc, carion, silica, mica, sericite, (sericite), muscovite, phlogopite, synthetic mica, phlogopite, biotite, lithia mica, permiculite, magnesium carbonate, calcium carbonate, silica Aluminum oxide, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calculated gypsum), calcium phosphate, fluoroapatite,
Hydroxyapatite, ceramic powder, metallic soap (zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc.

(2) Organic powder Polyamide resin powder (nylon powder), polyethylene powder, polymethylmethacrylate powder, polystyrene powder,
Copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, calcium alginate powder, etc.

(3) Inorganic pigment (4) Organic pigment (5) Dye (6) Natural pigment

2. Oily components (1) Fats and oils (liquid fats and oils) Avocado oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, wheat germ oil, castor oil, linseed oil, safflower oil, cottonseed oil , Soybean oil, peanut oil, tea seed oil, rice bran oil,
Jojoba oil, germ oil, triglycerin oil, glyceryl trioctanoate, glyceryl triisopalmitate, etc.

(2) Fats and oils (solid fats and oils) Cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, beef tallow, mutton fat, hardened beef tallow, palm kernel oil, pork fat, beef bone oil, mokuro kernel oil Hydrogenated oil, beef tallow, mokuro, hydrogenated castor oil, etc.

(3) Waxes Beeswax, candelilla wax, cotton wax, carnauba wax,
Bayberry wax, ivorot wax, whale wax, montan wax,
Nucalou, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid Polyethylene glycol, POE hydrogenated lanolin alcohol ether, etc.

(4) Hydrocarbons Liquid paraffin, ozokerite, squalene, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, etc.

3. Higher fatty acids Lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tallic acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA) , Docosahexaenoic acid (DHA), etc.

4. Higher alcohol (1) Linear alcohol Lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.

(2) Branched chain alcohol Monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldecanol, isostearyl alcohol, octyldodecanol, etc.

5. Esters Isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate,
Butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearyl, di-2- Ethyl glycol ethylhexylate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, di-2-
Glycerin heptylundecanoate, trimethylolpropane tri-2-ethylhexylate, trimethylolpropane triisostearate, pentaneerythritol tetra-2-ethylhexylate, glyceryl tri-2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethyl Hexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic acid oil, cetostearyl alcohol, acetoglyceride, 2-heptyl undecyl palmitate, Diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, di-2-heptyl undecyl adipate, ethyl laur Acetate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate. , Triethyl citrate, etc.

6. Anionic surfactant (1) Fatty acid soap Base for soap, sodium laurate, sodium palmitate, etc. (2) Higher alkyl sulfate ester sodium lauryl sulfate, potassium laurine sulfate, etc. (3) Alkyl ether sulfate ester salt

POE lauryl sulfate triethanolamine, POE sodium lauryl sulfate, etc. (4) N-acyl sarcosinate sodium lauroyl sarcosinate, etc. (5) Higher fatty acid amide sulfonate N-myristoyl-N-methyl taurine sodium, coconut oil fatty acid Methyl tauride sodium, lauryl methyl tauride sodium, etc. (6) Phosphate ester salt POE oleyl ether sodium phosphate, POE stearyl ether phosphoric acid, etc.

(7) Sulfosuccinate Di-2-ethylhexyl sodium sulfosuccinate, monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sodium sulfosuccinate, etc.

(8) Alkylbenzenesulfonate sodium linear dodecylbenzenesulfonate, triethanolamine linear dodecylbenzenesulfonate, linear dodecylbenzenesulfonic acid, etc. (9) N-acyl glutamate N-lauroyl glutamate monosodium, N-stearoyl Glutamate disodium, N-myristoyl-L-monosodium glutamate, etc. (10) Higher fatty acid ester sulfate ester hardened coconut oil fatty acid glycerin sodium sulfate, etc.

(11) POE alkyl ether carboxylic acid salt (12) POE alkyl allyl ether carboxylic acid salt (13) α-olefiin sulfonate (14) higher fatty acid ester sulfonate (15) secondary alcohol sulfate ester salt (16) Higher fatty acid alkylolamide sulfate (17) Others Lauroyl monoethanolamide sodium succinate,
N-palmitoyl aspartic acid ditriethanolamine, sodium caseinate, etc.

7. Cationic surfactant (1) Alkyltrimethylammonium salt stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc. (2) Dialkyldimethylammonium salt, distearyldimethylammonium chloride, etc. (3) Alkylpyridinium salt, poly (N, N'-dimethyl-chloride) 3,5-methylenepiperidinium), cetylpyridinium chloride, etc.

(4) Alkyl quaternary ammonium salt (5) Alkyl dimethyl benzyl ammonium salt (6) Alkyl isoquinolinium salt (7) Dialkyl morphonium salt (8) POE alkyl amine (9) Alkyl amine salt (10) ) Polyamine fatty acid derivative (11) Amyl alcohol fatty acid derivative (12) Quaternary ammonium salt benzalkonium chloride, benzethonium chloride, etc.

8. Amphoteric surfactant Amidobetaine-type amphoteric surfactant, amide sulfobetaine-type amphoteric surfactant, betaine-type amphoteric surfactant, sulfobetaine-type amphoteric surfactant, imidazolinium-type amphoteric surfactant, etc.

9. Nonionic Surfactant (1) Parental Nonionic Surfactant a. Sorbitan fatty acid ester sorbitan monooleate, sorbitan monoisostearate, salbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, trio Sorbitan oleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol solibitan, etc.

B. Glycerin or polyglycerin fatty acid monocotton seed oil fatty acid glycerin, glyceryl monoerucate, glycerin sesquioleate, glyceryl monostearate, diglyceryl monostearate, α, α-glyceryl pyroglutamate oleate, monosteering glycerin apple Acid, etc.

C. Propylene glycol fatty acid esters propylene glycol monostearate, propylene glycol monoraelic acid, etc. d. Hydrogenated castor oil derivatives e. Glycerin alkyl ethers

(2) Hydrophilic nonionic surfactant a. POE sorbitan fatty acid esters POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monolaurate, P
OE sorbitan tetraoleate, etc.

B. POE sorbit fatty acid esters POE sorbit monolaurate, POE sorbit monooleate, POE sorbit pentaoleate, P
OE sorbit monostearate, etc.

C. POE glycerin fatty acid esters POE glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate, etc. d. POE fatty acid esters POE monooleate, POE distearate, POE
Monodioleate, polyethylene glycol isostearate, etc.

E. POE alkyl ethers POE lauryl ether, POE oleyl ether, P
OE stearyl ether, POE behenyl ether, P
OE octyl dodecyl ether, POE cholestanol ether, etc. f. POE alkyl phenyl ethers POE octyl phenyl ether, POE nonyl phenyl ether, POE dinyl phenyl ether, etc.

G. POE, POP alkyl ethers POE / POP cetyl ether, POE / POP 2-decyl tetradecyl ether, POE, POP monobutyl ether, POE, POP hydrogenated lanolin, POE / PO
P glycerin ether, etc. h. Tetra POE / Tetra POP ethylenediamine condensates,

I. POE Castor oil or hydrogenated castor oil derivative POE castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisostearate, POE hydrogenated castor oil triisostearate, POE hydrogenated castor oil monopyroglutamic acid monoisostearate Diester, POE hydrogenated castor oil maleic acid, etc.

J. POE beeswax / lanolin derivatives POE sorbit beeswax, etc. k. Alkanol amides Coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc. l. POE Propylene glycol fatty acid ester m. POE alkylamine n. POE Fatty acid amide o. Sucrose fatty acid ester

10. Ultraviolet absorber (1) Benzoic acid type ultraviolet absorber Para-aminobenzoic acid (hereinafter abbreviated as PABA), PABA
Monoglycerin ester, N, N'-dipropoxy PA
BA ethyl ester, N, N'-diethoxy PABA ethyl ester, N, N'-dimethyl PABA ethyl ester, N, N'-dimethyl PABA butyl ester,
N, N'-dimethyl PABA ethyl ester, etc.

(2) Anthranilic acid type UV absorber homomenthyl-N-acetylanthranilate etc. (3) Salicylic acid type UV absorber amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p- Isopropanol phenyl salicylate, etc.

(4) Cinnamic Acid UV Absorber Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2-5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4- Diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylchihesyl-p-methoxycinnamate), 2- Ethoxyethyl-p-methoxyxinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β
-Phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2
-Ethylhexanoyl-diparamethoxycinnamate, etc.

(5) Benzophenone type ultraviolet absorber 2,4-dihydroxybenzophenone, 2,2-dihydroxy-4-methoxybenzophenone, 2,2-dihydroxy-4,4'-dimethoxybenzophenone, 2,
2,4,4-Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenyl Benzophenone, 2-ethylhexyl-4-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.

(6) Others 3- (4'-methylbenzylidene) -d, 1-camphor, 3-benzylidene-d, 1-camphor, urocanic acid, carocanic acid, ethyl ester, 2-phenyl-
5-methylbenzoxazole, 2,2-hydroxy-5
-Methylphenylbenzotriazole, 2- (2'-hydroxy-5-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenylbenzotriazole, dibenzalazine, dianisoylmethane, 4-methoxy- 4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one, etc.

11. Bactericides hinokitiol, chlorhexidine hydrochloride, phenoxytanol, hexachlorophene, 2,4,4 'trichloro-2'-hydroxydiphenyl ether, (triclosan), bithionol, 3,4,4' trichlorocarbanilide (TCC), benzalkonium chloride. , Talorhexidine hydrochloride, photosensitizer 201, photosensitizer 101, 1-hydroxypyridine-2-thione (zinc pyrithione), thiram (tetramethylthiuram disulfide), halocarban, salicylic acid, etc.

(Form) Examples of forms of the deodorant cosmetic of the present invention include spray type, roll-on type, powder type and pressed powder (molding powder) type,
Stick type etc. are mentioned.

In the case of the spray type, it can be obtained by storing it in a spray container together with a propellant such as liquefied gas and alcohol.

In the case of the roll-on type, it can be obtained by storing it in a roll-on container together with alcohol.

In the case of the powder type and the pressed powder type, they can be obtained by mixing them together with the powder component and the oil component, in the case of the powder type as they are, and in the case of the pressed powder type, they can be obtained by molding with various molding machines.

In the case of the stick type, the oil content (solid oil content,
It can be obtained by mixing with a liquid oil), filling a container and molding.

[0072]

【Example】

(Examples 1 to 16 and Comparative Examples 1 to 3) [Deodorant powder spray] Example 1 shown in Table 1
To 16 and Comparative Examples 1 to 3 were used to produce deodorant powder sprays by the following production method, and deodorant (armpit odor / foot odor)
Was evaluated by the following method. The evaluation results are also shown in Table 1.

(Production method) The powder portion was mixed with a kneader, the oil component and the dispersant were mixed with a blender, and each was sequentially charged into an aerosol glass container, and then a propellant was charged to obtain a deodorant powder spray.

(Evaluation Method) Deodorizing Effect Test (Axillary Odor) This is a method in which the judge makes a sensory evaluation using a panel of 20 men who are aware of the axillary odor during the summer when it is easy to sweat.

The test samples were randomly assigned to the right and left, and a double blind test was conducted in which one person other than the panel and the judge decided the sample and stored the key code.

The axilla of the panel is no longer smelly 70
Wipe with% ethanol and use the sample for 3 seconds from a distance of 10 cm. Bathing of each panel, use of a shower, and washing of the axilla were prohibited, and 24 hours later, the judge evaluated the degree of odor of the axilla on the left and right sides of the panel according to the following criteria.

(Deodorizing Effect Test: Evaluation Criteria) Evaluation was made by a 5-point method according to the following criteria, and the results were shown using the average value of the judgment results of a panel of 20 men. The higher the number, the stronger the odor.

◎: 2 points or more and less than 3 points ○: 3 points or more and less than 4 points △: 4 points or more and less than 5 points ×: 5 points or more

Deodorizing Effect Test (Foot Odor) This is a method in which the subjects themselves carry out a sensory evaluation of foot odors using 20 male subjects who are aware of foot odors in the summer when they easily sweat.

The test samples were randomly assigned to the right and left, and one person other than the subject performed a blind test in which the sample was assigned and the key code was stored.

The subject's feet were washed with a cosmetic stone until the foot odor disappeared, and then the sample was applied by spraying from a distance of 5 cm from the feet for 3 seconds so that the feet could be sufficiently adhered.

Bathing of each panel, use of a shower, and washing of the feet were prohibited, and after 24 hours, the test subject evaluated the degree of odor of the left and right feet on the same basis as the axillary odor.

[0083]

[Table 1] * Powder part in Table A: Zeolite carrying silver ion and zinc ion B: Zeolite C: Aluminum hydroxychloride D: Zinc oxide E: Spherical silica F: Talc

Oil G: Isopropyl myristate Dispersant H: Polyoxyethylene sorbitan monooleate Propellant I: Isopentane J: Liquefied petroleum gas

: Deodorizing property (armpit odor): Deodorizing property (foot odor)

As can be seen from the above Examples and Comparative Examples, the deodorant powder spray of the present invention is superior in deodorant property to the Comparative Examples.

Further, it can be seen that the deodorant property is further improved by further adding the antiperspirant component and the deodorant component.

(Examples 9 to 16 and Comparative Examples 4 to 6) [Deodorant body powder] Example 9 shown in Table 2
.About.16 and the deodorant body powders of Comparative Examples 4 to 6 were produced and evaluated for deodorant properties (armpit odor / foot odor).
The results are shown.

(Production Method) The following ingredients were sequentially mixed with a Henschel mixer to obtain a deodorant body powder.

(Evaluation method) The deodorizing properties (armpit odor) and deodorizing properties (foot odor) are the same as in Examples 1-8.

[0091]

[Table 2] * In Table 2, powder part A ': silver ion and zinc ion-supporting zeolite B': zeolite C ': aluminum hydroxy chloride D': zinc oxide E ': talc

Oil F ': Synthetic isoparaffin: Deodorant (armpit odor): Deodorant (foot odor)

(Examples 17 to 24, Comparative Examples 7 to 9) [Deodorant Stick] Examples 17 to 24 shown in Table 3
The deodorant sticks of Comparative Examples 7 to 9 were produced, and the deodorant properties (armpit odor) were evaluated by the following methods, and the results are shown. (Production method) After heating and dissolving the oil component and the dispersant and mixing,
In addition to the powder part separately mixed with a Henschel mixer, the mixture was filled in a container to obtain a deodorant stick.

(Evaluation method) The deodorizing property (armpit odor) is the same as in Examples 1-8.

[0095]

[Table 3] * In Table 3, powder part A ": silver ion and zinc ion supported zeolite B": zeolite C ": aluminum hydroxy chloride D": zinc oxide E ": talc

Oil component F ″: Stearyl alcohol G ″: Liquid paraffin Dispersant H ″: Sorbitan fatty acid ester (POE content 20
%, Viscosity 500 cst / 25 ° C.): Deodorant (armpit odor)

(Example 25) [Pressed powder type deodorant cosmetics] (Powder part) Silver ion-supporting zeolite 4.0% by weight Aluminum hydroxychloride 2.0 Zinc oxide 3.0 Talc 87.0 (oil) Liquid paraffin 4 .0 (Additive) Perfume Suitable amount

(Manufacturing method) The powder portion was mixed with a Henschel mixer, oil and additives were added to this mixture, and the mixture was crushed with a 5HP palpelizer (manufactured by Hosokawa Micron Co., Ltd.) and press-molded into an intermediate dish, A presto powder type deodorant cosmetic was obtained.

The pressed powder type deodorant cosmetics obtained did not have caking during use and had a sufficient deodorant effect.

(Example 26) [Deodorant powder] Aluminum hydroxy chloride 13.0% by weight Silver ion-supporting zeolite 7.0 Spherical nylon powder 5.0 Synthetic isoparaffin 2.0 Perfume proper amount Talc 73.0

(Production Method) The above ingredients were sequentially mixed with a Henschel mixer to obtain a deodorant powder. The deodorant powder obtained was excellent in deodorizing effect.

(Example 27) [Powder spray] (Powder part) Aluminum hydroxychloride 2.0% by weight Silver ion / copper ion supported zeolite 1.0 Talc 0.5 (oil) Isopropyl myristate 1.5 Perfume 0.1. 2 (Propellant) Isopentane 10.0 Liquefied petroleum gas 84.8

(Production method) The powder parts were mixed with a kneader, the oil components were mixed with a blender, and each was sequentially filled in a spray can, and then a propellant was sprayed into the can to obtain a powder spray.

The obtained powder spray was excellent in deodorizing effect.

(Example 28) [Powder spray] (Powder part) Silver ion- and zinc ion-supporting zeolite 2.0% by weight Zinc oxide 0.2 Silica 1.5 (oil) Polyoxyethylene nonylphenyl ether 0.5 Myristin Isopropyl acid 0.6 (Additive) Polyoxyethylene sorbitan monooleate 0.1 Perfume 0.1 (Propellant) Liquefied petroleum gas 95.0

(Production method) Powder parts were mixed with a kneader, oil was mixed with a blender, additives were added, and each was sequentially filled in a spray can, and further a propellant was filled in the can to obtain a powder spray.

The obtained powder spray was excellent in deodorizing effect.

(Example 29) [Compact deodorant powder] (Powder part) Copper ion- and zinc ion-supporting zeolite 20.0% by weight Talc 60.0 (oil) Liquid paraffin 20.0

(Production method) The powder portion was mixed with a Henschel mixer, oil was added to this mixture, and the mixture was crushed with a 5HP palpelizer (manufactured by Hosokawa Micron Co., Ltd.) and pressed into a medium dish to give a compact deodorant powder. Obtained.

The compact deodorant powder obtained had a sufficient deodorizing effect.

(Example 30) [Deodorant spray] (Powder part) Zinc ion-supporting zeolite 3.0% by weight Zinc oxide 2.0 (oil content) Isopropyl myristate 5.0 (Additive) Isopropyl myristate 0.5 Tetra -2-Ethylhexynoic acid diglycerol sorbitan 0.5 (propellant) n-butane 76.0 i-butane 13.0

(Production method) The powder portion was mixed with a kneader, the oil and the additive were mixed with a blender, and then the mixture was filled in a spray can and further filled with a propellant to obtain a deodorant spray.

The deodorizing spray obtained was excellent in deodorizing effect.

(Example 31) [Baby powder] (Powder part) Talc 80.3% by weight Calcium carbonate 17.0 Silver ion-supporting zeolite 2.0 (oil) Liquid paraffin 0.5 (additive) Preservative Two

(Manufacturing method) The above ingredients were well mixed with a blender to obtain baby powder.

The obtained baby powder had an excellent deodorizing effect.

Example 32 Deodorant Stick Isopropyl myristate 60.0% by weight Squalane 10.0 Hydrocarbon wax 10.0 Aluminum hydroxychloride 5.0 Zinc ion-supporting zeolite 15.0

(Production Method) A mixture of the above components was filled in a container to obtain a deodorant stick.

The obtained deodorant stick was excellent in deodorizing effect when applied to the armpit.

(Example 33) [Roll-on deodorant] Isopropyl myristate 67.0% by weight Ethanol 20.0 Solbit 4.0 Aluminum hydroxychloride 2.0 Magnesium oxide 2.0 Silver ion, copper ion-supporting zeolite 5.0

(Production Method) The above components were mixed and placed in a roll-on container to obtain a roll-on deodorant cosmetic.

The roll-on deodorant cosmetic composition thus obtained was excellent in deodorant effect.

(Example 34) [Powder spray] (Powder part) Aluminum hydroxychloride 2.0% by weight Zinc ion- and copper ion-supporting zeolite 1.0 Talc 0.5 (Oil) Isopropyl myristate 1.5 Perfume 0.1. 2 (Propellant) Isopentane 10.0 Liquefied petroleum gas 84.8

(Production Method) The powder parts were mixed with a kneader, the oil components were mixed with a blender, and each was sequentially filled in a spray can, and further filled with a propellant to obtain a powder spray. The obtained powder spray spreads well on the skin,
It had excellent anti-perspirant and deodorant effects.

(Example 35) [Powder spray] (Powder part) Silver ion- and copper ion-supporting zeolite 2.0% by weight Zinc oxide 0.2 Silica 1.5 (oil) Polyoxyethylene nonylphenyl ether 0.5 Myristin Isopropyl acid 0.6 (Additive) Polyoxyethylene sorbitan monooleate 0.1 Perfume 0.1 (Propellant) Liquefied petroleum gas 95.0

(Production Method) The powder portion was mixed with a kneader, the oil was mixed with a blender, and each was sequentially filled in a spray can, and further filled with a propellant to obtain a powder spray.
The obtained powder spray exhibited a sufficient deodorizing effect.

(Example 36) [Compact deodorant powder] (Powder part) Silver ion- and zinc ion-supporting zeolite 20.0% by weight Talc 60.0 (oil) Isopropyl myristate 10.0 Liquid paraffin 10.0

(Production method) The powder portion was mixed with a Henschel mixer, oil was added to this mixture, and the mixture was crushed with a 5HP palpelizer (Hosokawa Micron) and press-molded in a medium plate to obtain a compact deodorant powder. Obtained. The compact deodorant powder obtained had no caking during use, had a good feel on the skin, and had a sufficient deodorizing effect.

(Example 37) [Deodorant spray] (Propellant) n-butane 76.8% by weight i-butane 19.2 (powder part) Zinc ion-supporting zeolite 3.0 (additive) Isopropyl myristate 0. 5 Diglycerol sorbitan tetra-2-ethylhexanoate 0.5

(Production method) The powder parts were mixed with a kneader, the additives were mixed with a blender, then the mixture was filled in a spray can, and further the propellant was filled to obtain an odor preventing spray.

The deodorant spray thus obtained exhibited a sufficient deodorizing effect.

(Example 38) [Baby powder] (Powder part) Talc 80.0% by weight Calcium carbonate 17.0 Silver / copper ion supported zeolite 2.3 (oil) Isoparaffin 0.5 Preservative 0.2

(Manufacturing Method) The above ingredients were thoroughly mixed with a blender with stirring to obtain baby powder.

The obtained baby powder was also excellent in deodorizing effect.

Example 39 Deodorant Stick Squalane 70.0% by Weight Hydrocarbon Wax 10.0 Silver Ion, Copper Ion, Zinc Ion-Supporting Zeolite 20.0

(Production method) A mixture of the above components was filled in a container to obtain a deodorant stick.

When the obtained deodorant stick was applied under the armpit, the deodorant effect was good.

(Example 40) [Roll-on deodorant cosmetic] Isopropyl myristate 71.0% by weight Ethanol 20.0 Solbit 4.0 Copper ion-supported zeolite 5.0

(Production Method) The above components were mixed and placed in a roll-on container to prepare a roll-on deodorant cosmetic.

The obtained roll-on deodorant cosmetic composition was intended to make the skin silky smooth and had an excellent deodorant effect.

(Example 41) [Body detergent] N-lauryl-L-glutamic acid triethanolamine 6.0% by weight N-laurylmethyltaurine sodium 3.0 Laurate triethanolamine 9.5 Myristic acid triethanolamine 9 .5 Lauryl imidazolinium betaine 5.0 Lauryl diethanolamide 5.0 Propylene glycol 7.0 Silver ion supported zeolite 0.5 Isopropyl myristate 1.0 Purified water 53.38 Perfume 0.01 Preservative 0.1 Ethylene diamine tetra Acetic acid 0.01

(Manufacturing method) Purified water is heated to 70 ° C., and other components are sequentially added and dissolved by stirring. It was cooled to room temperature and filled in a resin bottle containing a stirring ball to obtain a body cleaning agent.

The above-mentioned body cleansing agent had good detergency and foaming power, and had good system stability and an excellent deodorizing effect.

(Example 42) [Carmine lotion] Ethanol 13.0% by weight (oil content) Isopropyl myristate 2.0 (moisturizer) Glycerin 2.0 1,3 Butylene glycol 2.0 (powder) Iron oxide ( Red iron oxide) 0.15 Zinc oxide 0.5 Silver ion-supporting zeolite 0.5 Kaolin 1.5 (Chemical) Camphor 0.2 Phenol 0.02 Perfume 0.01 Anti-fading agent 0.01 Purified water 78.11

(Production method) A perfume was added to ethanol, a moisturizing agent, and an oil and dissolved. Camphor and phenol were dissolved in purified water, and the powder agent, the anti-fading agent and the ethanol moisturizing agent phase were added thereto and stirred to wet-disperse the powder agent. 1
Carmine lotion was obtained by filtration through about 60 mesh.

The carmine lotion had an effect of calming hot flashes of the skin after sunburn, and an excellent deodorizing effect.

(Example 43) [Essence oil] (oil content) Olive oil 49.69% by weight Liquid paraffin 25.0 Squalane 20.0 (powder) Silver ion / zinc ion carrying zeolite 5.0 (others) Vitamin E acetate 0 .2 Antioxidant 0.1 Fragrance 0.01

(Manufacturing Method) An oil obtained by carbonizing a powdered medicine, an antioxidant and a fragrance with oil and stirring the mixture was filled in a resin bottle containing a stirring ball to obtain an essence oil.

The essence oil was excellent in deodorizing effect.

(Example 44) [Face cleanser] (Fatty acid) Stearic acid 10.0% by weight Palmitic acid 10.0 Myristic acid 10.0 Lauric acid 4.0 (Oil) Dimethylpolysiloxane 2.0 (Alkali) Water Potassium oxide 6.0 (moisturizer) PEG1500 10.0 glycerin 15.0 (surfactant) glycerol monostearate 2.0 POE (20) sorbitan monostearate 2.0 (powder) silver ion-supported zeolite 2. 0 Preservative 0.1 Ethylenediaminetetraacetic acid 0.05 Perfume 0.01 Purified water 26.84

(Production method) The fatty acid, oil, humectant and preservative were melted by heating and kept at 70 ° C. Purified water in which the alkali had been previously dissolved was added to the stirring oil phase. After the addition, the temperature was maintained at 70 ° C. for a while to complete the neutralization reaction. Next, the melted surfactant, chelating agent, fragrance, and powder were added, and the mixture was stirred and mixed, deaerated, filtered, and cooled to obtain a face wash.

(Evaluation Results) The above face wash was excellent in detergency and foaming property and was also excellent in deodorizing effect.

(Example 45) [Pack (peel-off type)] (Film forming agent) Polyvinyl acetate emulsion 15.0% by weight Polyvinyl alcohol 10.0 (Humectant) Sorbitol 5.0 PEG400 5.0 (oil) Jojoba oil 3.0 Squalane 1.0 (surfactant) POE sorbitan monostearate 1.0 (powder) titanium oxide 5.0 silver ion supported zeolite 3.0 talc 7.0 (alcohol) ethanol 8.0 perfume 0.0. 01 Preservative 0.1 Purified water 36.89

(Manufacturing Method) Powder was added to purified water and sufficiently dispersed, then a moisturizer was added, and after heating to 70 to 80 ° C., a film forming agent was added and dissolved. Perfume, preservatives, surfactants in ethanol,
Oil was added. This was added to the above aqueous phase and mixed. After degassing, filtering and cooling, a pack was obtained.

(Evaluation Results) The above pack was excellent in deodorizing effect.

(Example 46) [Pressed powder] (Powder) Aluminum hydroxychloride 5.0% by weight Zeolite carrying silver ions and zinc ions 5.0 Talc 87.0 (oil content) Liquid paraffin 3.0 Perfume proper amount

(Production Method) After the powder components were thoroughly mixed, the fragrance dissolved in the oil was uniformly sprayed and mixed. After crushing this powder, compression molding was performed to obtain a pressed powder.

(Evaluation Results) The pressed powder was excellent in deodorizing effect.

Example 47 [Soap] Sodium lauric acid monoglyceride sulfate 54.87% by weight Sodium lauryl sulfate 10.0 10.0 Sodium coconut oil fatty acid 30.0 Cetyl alcohol 4.0 Silver ion-supporting zeolite 1.0 Perfume 0 .01 Dye 0.01 Antioxidant 0.1 Ethylenediaminetetraacetic acid 0.01

(Manufacturing Method) The above ingredients were added to a mixer, mixed and stirred, then put on a roll and a plotter, kneaded and compressed, molded into a rod shape and extruded, and stamped to obtain soap.

(Evaluation Results) The above soap was excellent in deodorizing effect.

Example 48 [Emollient Lotion] (Oil) Cetyl alcohol 1.0% by weight Beeswax 0.5 Vaseline 2.0 Squalane 8.0 (Alcohol) Ethanol 5.0 (Humectant) Glycerin 4.0 1 , 3 Butylene glycol 4.0 (surfactant) POE (10) monooleate 1.0 glycerol monostearate 1.0 (mucus) Quinceseed extract (5% aqueous solution) 20.0 (powder) silver Ion, copper ion, zinc ion-supported zeolite 2.0 Preservative 0.05 Coloring agent 0.01 Perfume 0.01 Purified water 51.43

(Manufacturing method) A moisturizer and a coloring agent were added to purified water, and
The temperature was adjusted to 0 ° C. A surfactant and a preservative were added to the oil, and the temperature was adjusted to 70 ° C. This was added to the above aqueous phase to carry out preliminary emulsification. A quince seed extract, powder and ethanol were added to this, and the mixture was stirred, and the emulsion particles were homogenized with a homomixer, then deaerated, filtered and cooled to obtain an emollient lotion.

(Evaluation Results) The emollient lotion was excellent in deodorizing effect.

(Example 49) [Oil gel (emulsion type)] (Oil) Liquid paraffin 10.0 wt% Glycerol tri-2-ethylhexanoate 52.0 (Humectant) Sorbitol 10.0 PEG400 5.0 (Surfactant) Acyl methyl taurine 5.0 POE octyldodecyl alcohol ether 10.0 (powder) Silver ion- and zinc ion-supporting zeolite 2.0 Perfume 0.01 Purified water 5.99

(Manufacturing method) A moisturizing agent and acylmethyl taurine were added to purified water and the temperature was adjusted to 70 ° C. POE octyldodecyl ether and a fragrance were added to the oil, and the temperature was adjusted to 70 ° C. This and powder were gradually added to the previous aqueous phase. After homogenizing the emulsified particles with a homomixer, deaeration, filtration and cooling were performed to obtain an oily gel.

(Evaluation Results) The above oil-based gel was excellent in deodorizing effect.

(Example 50) [Cream] (Oil) Cetyl alcohol 5.0% by weight Stearic acid 4.0 Vaseline 4.0 Squalane 9.0 Glycerol tri-2-ethylhexanoate 7.0 (Humectant) Di Propylene glycol 5.0 Glycerin 5.0 (surfactant) Propylene glycol monostearate 3.0 POE (20) Cetyl alcohol ether 3.0 (alkali) Triethanolamine 1.0 (powder) Silver ion supported zeolite 1 0.0 Preservative 0.1 Antioxidant 0.05 Perfume 0.01 Purified water 52.84

(Production method) A moisturizer and an alkali were added to purified water to adjust the temperature to 70 ° C. After heating and dissolving the oil, a surfactant, a preservative, an antioxidant and a fragrance were added to adjust the temperature to 70 ° C. This was added to the above aqueous phase for preliminary emulsification. After adding the powder and homogenizing the emulsified particles with a homomixer, deaeration, filtration and cooling were performed.

(Evaluation Results) The above cream had an excellent deodorizing effect.

[0171]

EFFECTS OF THE INVENTION According to the present invention, a deodorant cosmetic having a far superior deodorizing effect as compared with the conventional one can be obtained.

Claims (8)

[Claims] 1. A deodorant cosmetic composition, characterized in that zeolite having antibacterial metal ions is blended in the ion-exchangeable portion. 2. The blending amount of the zeolite is 0.1% by weight.
The deodorant cosmetic composition according to claim 1, wherein the deodorant cosmetic composition is as described above. 3. The deodorant cosmetic according to claim 1, wherein the deodorant cosmetic is a spray type. 4. The deodorant cosmetic composition according to claim 3, wherein the content of the sex zeolite is 1.0% by weight or more. 5. The deodorant cosmetic according to claim 1, wherein the deodorant cosmetic is a powder type, a stick type or a pressed powder type. 6. The blending amount of the zeolite is 5.0% by weight.
The deodorant cosmetic composition according to claim 5, wherein the deodorant cosmetic composition is as described above. 7. The deodorant cosmetic composition according to claim 1, which further comprises an aluminum compound. 8. The deodorant cosmetic composition according to claim 1, further comprising a metal oxide.