JPH08504847A - 触媒組成物の製造方法 - Google Patents

触媒組成物の製造方法

Info

Publication number: JPH08504847A
Authority: JP; Japan
Prior art keywords: transition metal; compound; carrier; catalyst; ethylene
Prior art date: 1992-10-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP6510330A

Other languages

English (en)

Japanese (ja)

Inventor

ミンク，ロバート・アイ

ナウリン，トーマス・エドワード

Original Assignee

モービル・オイル・コーポレーション

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-19

Filing date

1993-10-19

Publication date

1996-05-28

1993-10-19 Application filed by モービル・オイル・コーポレーション filed Critical モービル・オイル・コーポレーション

1996-05-28 Publication of JPH08504847A publication Critical patent/JPH08504847A/ja

Status Pending legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 47
239000000203 mixture Substances 0.000 title claims description 18
238000004519 manufacturing process Methods 0.000 title claims description 15
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 39
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 20
229910052723 transition metal Inorganic materials 0.000 claims abstract description 19
150000003624 transition metals Chemical class 0.000 claims abstract description 19
239000000377 silicon dioxide Substances 0.000 claims abstract description 18
238000009826 distribution Methods 0.000 claims abstract description 16
229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 16
239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 16
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 6
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims abstract description 6
229910003902 SiCl 4 Inorganic materials 0.000 claims abstract 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 36
239000005977 Ethylene Substances 0.000 claims description 35
238000000034 method Methods 0.000 claims description 35
239000011347 resin Substances 0.000 claims description 29
229920005989 resin Polymers 0.000 claims description 29
150000002901 organomagnesium compounds Chemical class 0.000 claims description 24
239000004711 α-olefin Substances 0.000 claims description 20
239000007788 liquid Substances 0.000 claims description 18
239000011777 magnesium Substances 0.000 claims description 15
150000003623 transition metal compounds Chemical class 0.000 claims description 15
238000006116 polymerization reaction Methods 0.000 claims description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
229910052719 titanium Inorganic materials 0.000 claims description 9
239000010936 titanium Substances 0.000 claims description 9
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 8
229910052749 magnesium Inorganic materials 0.000 claims description 8
150000003609 titanium compounds Chemical class 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 7
150000002681 magnesium compounds Chemical class 0.000 claims description 7
239000007787 solid Substances 0.000 claims description 7
150000002902 organometallic compounds Chemical class 0.000 claims description 6
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 claims description 4
239000002243 precursor Substances 0.000 claims description 4
230000003213 activating effect Effects 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
BRDWIEOJOWJCLU-LTGWCKQJSA-N GS-441524 Chemical compound C=1C=C2C(N)=NC=NN2C=1[C@]1(C#N)O[C@H](CO)[C@@H](O)[C@H]1O BRDWIEOJOWJCLU-LTGWCKQJSA-N 0.000 claims 1
239000012018 catalyst precursor Substances 0.000 abstract description 11
239000002904 solvent Substances 0.000 abstract description 10
229910052751 metal Inorganic materials 0.000 abstract description 2
239000002184 metal Substances 0.000 abstract description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 24
229920001577 copolymer Polymers 0.000 description 21
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
229920000642 polymer Polymers 0.000 description 14
239000000047 product Substances 0.000 description 13
239000002002 slurry Substances 0.000 description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
150000001875 compounds Chemical class 0.000 description 12
239000000243 solution Substances 0.000 description 10
239000000126 substance Substances 0.000 description 10
239000012876 carrier material Substances 0.000 description 9
-1 polyethylene Polymers 0.000 description 9
238000010438 heat treatment Methods 0.000 description 8
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
239000012190 activator Substances 0.000 description 7
239000007789 gas Substances 0.000 description 7
239000012454 non-polar solvent Substances 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
238000010348 incorporation Methods 0.000 description 5
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
238000002347 injection Methods 0.000 description 4
239000007924 injection Substances 0.000 description 4
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
150000002736 metal compounds Chemical class 0.000 description 4
238000003756 stirring Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
238000001035 drying Methods 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
239000000155 melt Substances 0.000 description 3
239000000178 monomer Substances 0.000 description 3
125000002734 organomagnesium group Chemical group 0.000 description 3
239000002245 particle Substances 0.000 description 3
239000011148 porous material Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
229910008051 Si-OH Inorganic materials 0.000 description 2
229910006358 Si—OH Inorganic materials 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000969 carrier Substances 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
229920001038 ethylene copolymer Polymers 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000012429 reaction media Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000005245 sintering Methods 0.000 description 2
241000894007 species Species 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
230000007704 transition Effects 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
238000005406 washing Methods 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920008712 Copo Polymers 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
241001529936 Murinae Species 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000004703 alkoxides Chemical group 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001728 carbonyl compounds Chemical class 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
230000008602 contraction Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
150000001924 cycloalkanes Chemical class 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N dimethylbutene Natural products CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
125000001033 ether group Chemical group 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
229920001684 low density polyethylene Polymers 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
238000005325 percolation Methods 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
229920013716 polyethylene resin Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
125000005372 silanol group Chemical group 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP6510330A 1992-10-19 1993-10-19 触媒組成物の製造方法 Pending JPH08504847A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US96255592A	1992-10-19	1992-10-19
US962,555		1992-10-19
PCT/US1993/009953 WO1994009040A1 (en)	1992-10-19	1993-10-19	Process for preparing a catalyst composition

Publications (1)

Publication Number	Publication Date
JPH08504847A true JPH08504847A (ja)	1996-05-28

Family

ID=25506061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6510330A Pending JPH08504847A (ja)	1992-10-19	1993-10-19	触媒組成物の製造方法

Country Status (5)

Country	Link
EP (1)	EP0664815B1 (de)
JP (1)	JPH08504847A (de)
AU (1)	AU666239B2 (de)
DE (1)	DE69320357T2 (de)
WO (1)	WO1994009040A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5258345A (en) *	1992-11-20	1993-11-02	Mobil Oil Corporation	High-activity polyethylene catalysts
US5661097A (en) †	1994-08-12	1997-08-26	The Dow Chemical Company	Supported olefin polymerization catalyst
WO2003004537A1 (en) *	2001-07-02	2003-01-16	Borealis Technology Oy	Process for preparing a procatalyst for olefin polymerization

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3062482D1 (en) *	1979-01-10	1983-05-05	Ici Plc	Olefine polymerisation catalyst and the production and use thereof
US4252670A (en) *	1979-01-10	1981-02-24	Imperial Chemical Industries Limited	Olefine polymerization catalyst
US4558024A (en) *	1984-08-06	1985-12-10	Exxon Research & Engineering Co.	Polymerization catalyst, production and use
US4558025A (en) *	1984-08-06	1985-12-10	Exxon Research & Engineering Co.	Polymerization catalyst, production and use
US4833111A (en) *	1988-01-14	1989-05-23	Mobil Oil Corporation	Catalyst composition for polymerizing alpha-olefin polymers of narrow molecular weight distribution
IT1250706B (it) *	1991-07-25	1995-04-21	Enichem Polimeri	Catalizzatore per la polimerizzazione di olefine
US5258345A (en) *	1992-11-20	1993-11-02	Mobil Oil Corporation	High-activity polyethylene catalysts

1993
- 1993-10-19 AU AU53636/94A patent/AU666239B2/en not_active Expired
- 1993-10-19 JP JP6510330A patent/JPH08504847A/ja active Pending
- 1993-10-19 EP EP93923929A patent/EP0664815B1/de not_active Expired - Lifetime
- 1993-10-19 WO PCT/US1993/009953 patent/WO1994009040A1/en not_active Ceased
- 1993-10-19 DE DE69320357T patent/DE69320357T2/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
WO1994009040A1 (en)	1994-04-28
DE69320357D1 (de)	1998-09-17
DE69320357T2 (de)	1998-12-10
EP0664815A1 (de)	1995-08-02
EP0664815A4 (de)	1996-04-17
AU5363694A (en)	1994-05-09
EP0664815B1 (de)	1998-08-12
AU666239B2 (en)	1996-02-01

Publication	Publication Date	Title
EP0612327B1 (de)	1997-12-29	Polyethylenkatalysatoren mit hoher aktivität hergestellt mittels alkoxysilanreagentien
CA2174661C (en)	2009-05-12	Catalyst composition for copolymerizing ethylene
AU666248B2 (en)	1996-02-01	Catalyst composition for use in the production of lldpe resin products
CA2174452C (en)	2007-04-24	Binary cocatalyst compositions for activating heterogeneous polymerization catalysts
HK1008745B (en)	1999-05-14	High activity polyethylene catalysts prepared with alkoxysilane reagents
JP3670010B2 (ja)	2005-07-13	触媒組成物の製造方法
EP0701575B1 (de)	1999-09-01	Hochaktive polyethylenkatalysatoren
US5939348A (en)	1999-08-17	Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
JPH08504847A (ja)	1996-05-28	触媒組成物の製造方法
JP4331262B2 (ja)	2009-09-16	狭い分子量分布を持ったポリエチレンの製造用触媒