JPH0852476A - Superoxidized water forming device - Google Patents
Superoxidized water forming deviceInfo
- Publication number
- JPH0852476A JPH0852476A JP21075494A JP21075494A JPH0852476A JP H0852476 A JPH0852476 A JP H0852476A JP 21075494 A JP21075494 A JP 21075494A JP 21075494 A JP21075494 A JP 21075494A JP H0852476 A JPH0852476 A JP H0852476A
- Authority
- JP
- Japan
- Prior art keywords
- water
- salt
- super
- salts
- oxidized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 150000003839 salts Chemical class 0.000 claims abstract description 65
- 239000008399 tap water Substances 0.000 claims description 12
- 235000020679 tap water Nutrition 0.000 claims description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 abstract description 60
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 12
- 239000010446 mirabilite Substances 0.000 abstract description 10
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 abstract description 4
- 239000011780 sodium chloride Substances 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 238000000746 purification Methods 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001502 supplementing effect Effects 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910004809 Na2 SO4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は超酸化水生成装置に関
し、特に洗浄水、殺菌水として、食品用、衛生用および
医療用等に用いることのできる超酸化水の生成装置に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an apparatus for producing super-oxidized water, and more particularly to an apparatus for producing super-oxidized water which can be used as washing water and sterilizing water for food, sanitation, medical use and the like.
【０００２】[0002]
【従来の技術】周知のように、ｐＨで約３以上の超酸化
水は、陽極と陰極を備えた電解槽に食塩水を供給し、両
電極に直流電圧を印加することにより製造することがで
きる。従来の超酸化水を製造する装置としては、(1) 予
め所定の濃度の食塩水を作っておき、これを電解槽に入
れて電気分解するものがある。また、他の装置として
は、(2) 高濃度の食塩水を作っておき、一定量の高濃度
食塩水を水道水で希釈しながら、これを電解槽に送り、
電気分解するものがある。2. Description of the Related Art As is well known, super-oxidized water having a pH of about 3 or more can be produced by supplying saline to an electrolytic cell having an anode and a cathode and applying a DC voltage to both electrodes. it can. As a conventional device for producing super-oxidized water, there is (1) a device in which a salt solution having a predetermined concentration is prepared in advance, and this is put into an electrolytic cell and electrolyzed. In addition, as another device, (2) high-concentration saline solution is prepared in advance, and a certain amount of high-concentration saline solution is diluted with tap water and sent to the electrolytic cell.
Some are electrolyzed.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、前記し
た(1) の装置では、所定の濃度の食塩水を電解槽に入れ
て電気分解するため、大量の超酸化水を作ろうとする
と、大容量の電解槽が必要になり、装置が大型化して家
庭用あるいは医療用としては現実的でないという問題が
あった。逆に、小容量の電解槽を用いると、超酸化水の
生成量が極めて少ないという問題、多量の超酸化水を得
ようとすると、何回も、所定濃度の食塩水を作り、これ
を電解槽に入れて電気分解をしなければならず、手間が
掛かると共に、超酸化水の生産性が悪いという問題があ
った。However, in the above-mentioned device (1), since a salt solution having a predetermined concentration is placed in the electrolytic cell and electrolyzed, when a large amount of super-oxidized water is produced, a large volume of super-oxidized water is generated. There is a problem that an electrolytic cell is required and the apparatus becomes large in size, which is not practical for home use or medical use. On the contrary, when a small capacity electrolyzer is used, the amount of super-oxidized water produced is extremely small.When trying to obtain a large amount of super-oxidized water, a salt solution with a predetermined concentration is made many times, and this is electrolyzed. Since it has to be put in a tank and electrolyzed, it is troublesome and the productivity of super-oxidized water is poor.
【０００４】また、前記した(2) の装置においても、高
濃度食塩水を溜めておくタンクが大型になり、一般家庭
用あるいは医療用には不向きであるという問題があっ
た。Also, in the above-mentioned apparatus (2), the tank for storing the high-concentration saline solution becomes large in size, which is not suitable for general household use or medical use.
【０００５】本発明の目的は、前記した従来技術の問題
点を除去し、小型の装置であるにかかわらず、生産性よ
く超酸化水を生成することのできる超酸化水生成装置を
提供することにある。他の目的は、家庭用あるいは医療
用に適した小型の超酸化水生成装置を提供することにあ
る。An object of the present invention is to eliminate the above-mentioned problems of the prior art, and to provide a super-oxidized water producing apparatus capable of producing super-oxidized water with high productivity regardless of the size of the apparatus. It is in. Another object is to provide a small-sized super-oxidized water generator suitable for household use or medical use.
【０００６】[0006]
【課題を解決するための手段】前記目的を達成するため
に、本発明は、水道水に塩類を添加し、該塩類を添加さ
れた水を電気分解して超酸化水を得るようにした超酸化
水生成装置において、粉状あるいは粒状の塩類を収納で
き、その底部に該塩類を落下させるパイプを備えた容器
と、該パイプに、弁を介して接続されたアスピレータ
と、前記弁の開口角を制御する制御部とを具備した点に
特徴がある。また、本発明は、前記塩類として、食塩ま
たは芒硝を用いた点、前記容器に、塩類を補給できるよ
うにした点に特徴がある。In order to achieve the above object, the present invention provides a super-oxidized water by adding salt to tap water and electrolyzing the salt-added water. In the oxidizing water generator, a container that can store powdery or granular salt and has a pipe at the bottom for dropping the salt, an aspirator connected to the pipe through a valve, and an opening angle of the valve It is characterized in that it is provided with a control unit for controlling. Further, the present invention is characterized in that salt or salt cake is used as the salt, and that the container can be supplemented with salt.
【０００７】[0007]
【作用】本発明によれば、前記容器の弁の開口角を制御
部で制御し、かつ前記アスピレータにより容器から弁を
通して落下した塩類を、アスピレータを通過する水道水
に混入することができる。この結果、該アスピレータを
通過する水に、所定量の塩類を添加し、該水の塩分濃度
を所定範囲内の濃度とすることができる。また、前記塩
類として芒硝を用いると、電解槽から得られた超酸化水
を浄化せずとも、塩素臭がなく、ステンレス部材に適用
しても６価クロムを溶出しない超酸化水を得ることかで
きる。さらに、前記容器に、塩類を補給することによ
り、何時間も連続的に超酸化水を生成することができる
ようになる。According to the present invention, the opening angle of the valve of the container can be controlled by the controller, and the salt dropped from the container by the aspirator through the valve can be mixed into the tap water passing through the aspirator. As a result, a predetermined amount of salt can be added to the water passing through the aspirator to bring the salt concentration of the water to a concentration within a predetermined range. In addition, if Glauber's salt is used as the salt, there is no chlorine odor without purifying the superoxidized water obtained from the electrolytic cell, and it is possible to obtain superoxidized water that does not elute hexavalent chromium when applied to a stainless steel member. it can. Furthermore, by supplementing the container with salt, super-oxidized water can be continuously produced for many hours.
【０００８】[0008]
【実施例】以下に、図面を参照して、本発明を詳細に説
明する。図１は本発明の一実施例の超酸化水生成装置の
概略の構成を示すブロック図である。図において、１は
原水である水道水を供給するための水道水供給部であ
り、例えば、水道の蛇口に直接取り付けられている。１
ａ〜１ｅは水の通路を示し、１ｆ、１ｆ´は本実施例に
より生成された超酸化水、１ｇは超アルカリ水を示す。
２は第１の浄化部であり、水道水に含まれている塩素を
吸着脱臭する。該第１の浄化部２として、具体的には、
筒形状の網で構成され、その内部に活性炭や活性炭繊維
等が入れられたフィルタを用いることができる。３は第
１の電気伝導率測定部である。該電気伝導率測定部３と
しては、周知の電気伝導率センサを用いることができ、
これを通路中の水の中に入れることにより測定すること
ができる。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to the drawings. FIG. 1 is a block diagram showing a schematic configuration of an apparatus for producing super-oxidized water according to an embodiment of the present invention. In the figure, reference numeral 1 denotes a tap water supply unit for supplying tap water which is raw water, and is directly attached to, for example, a tap of a water supply. 1
Reference numerals a to 1e indicate water passages, 1f and 1f 'indicate super-oxidized water produced in this example, and 1g indicates super-alkaline water.
Reference numeral 2 is a first purifying unit that adsorbs and deodorizes chlorine contained in tap water. As the first purification unit 2, specifically,
It is possible to use a filter which is composed of a cylindrical net and in which activated carbon, activated carbon fibers or the like are put. Reference numeral 3 is a first electric conductivity measuring unit. A well-known electric conductivity sensor can be used as the electric conductivity measuring unit 3,
This can be measured by putting it in the water in the passage.
【０００９】４は本発明の要部たる塩類添加部である。
該塩類添加部４の構成は、図２により後で詳述するが、
本実施例の塩類添加部４によれば、小型に構成できると
共に、容易に塩類の補給をすることができる。また、食
塩水の濃度が所定範囲になるように容易に制御すること
ができ、またその濃度の食塩水を長時間連続して得るこ
とができる。５は第２の電気伝導率測定部である。該第
２の電気伝導率測定部５は、塩類の添加された水の電気
伝導率を測定するものであり、前記第１の電気伝導率測
定部３と同様に、周知の電気伝導率センサを用いること
ができる。Reference numeral 4 is a salt addition part which is a main part of the present invention.
The structure of the salt addition unit 4 will be described later in detail with reference to FIG.
According to the salt adding unit 4 of the present embodiment, the size can be reduced and the salt can be easily replenished. Further, the concentration of the saline solution can be easily controlled so as to fall within a predetermined range, and the saline solution having that concentration can be continuously obtained for a long time. Reference numeral 5 is a second electric conductivity measuring unit. The second electric conductivity measuring unit 5 is for measuring the electric conductivity of water to which salts are added, and like the first electric conductivity measuring unit 3, a well-known electric conductivity sensor is used. Can be used.
【００１０】６は陽極と陰極とそれらの間に設けられた
隔膜とを備えた電解槽であり、供給された所定範囲の濃
度の食塩水を電気分解し、超酸化水１ｆと超アルカリ水
１ｇとを生成する。７は第２の浄化部であり、超酸化水
１ｆ中に含まれている塩素を除去する働きをする。な
お、この第２の浄化部は、後述の説明から明らかになる
ように、必ずしも必要ではない。Reference numeral 6 denotes an electrolytic cell provided with an anode, a cathode and a diaphragm provided therebetween, which electrolyzes the supplied saline solution having a concentration within a predetermined range to give 1f of super-oxidized water and 1g of super-alkaline water. Produces and. Reference numeral 7 is a second purifying unit, which works to remove chlorine contained in the super-oxidized water 1f. In addition, this 2nd purification | cleaning part is not necessarily required so that it may become clear from later description.
【００１１】次に、８は超酸化水生成装置の始動・停止
スイッチであり、９は表示部である。この表示部９は、
所定のｐＨの酸化水が生成されているか否かを報知する
表示灯、あるいは生成されている酸化水のｐＨを示す表
示部分を有している。１０は電源である。１１は制御部
（例えば、ＣＰＵ）であり、前記第１、第２の電気伝導
率測定部３、５で測定した電気伝導率から塩類の添加さ
れた水の塩分濃度を測定し、その濃度が所定の範囲の濃
度になるように、塩類添加部の塩類添加量を調節する。
また、電解槽６の動作の制御、表示部９に送出する信
号、表示データ等の作成、あるいは図示されていない安
全対策のための制御（例えば、装置の転倒あるいは漏電
の検出、転倒あるいは漏電の検出時の電源の遮断等）等
を行う。Next, 8 is a start / stop switch of the super-oxidized water generator, and 9 is a display section. This display unit 9
It has an indicator lamp for notifying whether or not the oxidizing water having a predetermined pH is generated, or a display portion for indicating the pH of the oxidizing water being generated. 10 is a power supply. Reference numeral 11 denotes a control unit (for example, a CPU), which measures the salt concentration of water to which salts are added from the electric conductivity measured by the first and second electric conductivity measuring units 3 and 5, and The salt addition amount of the salt addition section is adjusted so that the concentration is within a predetermined range.
In addition, control of the operation of the electrolytic cell 6, generation of signals to be sent to the display unit 9, display data, etc., or control for safety measures not shown (for example, detection of overturning or leakage of the device, overturning or leakage) The power is cut off at the time of detection).
【００１２】次に、図２を参照して、前記塩類添加部４
の一実施例の構成を説明する。図において、２１は粉状
あるいは粒状の塩類２１ａを収容する容器であり、２２
は電磁弁やバタフライバルブ等により構成された弁であ
る。また、２３はアスピレータ（吸気器）である。１
ｃ、１ｄは図１と同一物を示し、水の通路例えばパイプ
を示す。今、パイプ１ｃ、１ｄに水道水が流されると、
アスピレータ２３は減圧され、パイプ２４からの空気を
吸入する。この時、前記制御部１１により、弁２２の開
口角が制御されると、該開口から落下した塩類は、前記
空気流に従ってアスピレータ２３の方へ運ばれ、パイプ
１ｃを通って流れて来た水道水に混入する。この結果、
パイプ１ｄでは所定濃度の食塩水となる。Next, referring to FIG. 2, the salt addition section 4
The configuration of one embodiment will be described. In the figure, reference numeral 21 denotes a container for containing powdery or granular salts 21a.
Is a valve composed of a solenoid valve, a butterfly valve, or the like. Reference numeral 23 is an aspirator. 1
c and 1d show the same thing as FIG. 1, and show a water passage, for example, a pipe. Now, when tap water is poured into the pipes 1c and 1d,
The aspirator 23 is decompressed and sucks air from the pipe 24. At this time, when the opening angle of the valve 22 is controlled by the control unit 11, the salts dropped from the opening are carried to the aspirator 23 according to the air flow, and the water flowing through the pipe 1c flows. Mix in water. As a result,
In the pipe 1d, the saline solution has a predetermined concentration.
【００１３】本実施例の塩類添加部４によれば、前記容
器２１の上部は開いているまたは容易に脱着できる蓋で
閉じられているから、利用者は必要に応じて塩類を追加
することができる。このため、容器２１は小型のもので
よく、従来から超酸化水生成装置の大型化の原因となっ
ていた容器を小形化することができる。また、塩類の追
加は自由にかつ容易にできるので、利用者に大した負担
をかけることなく、大量の超酸化水あるいは超アルカリ
水を提供することができる。なお、塩類２１ａの追加
は、自動的に行えるようにしてもよい。According to the salt adding section 4 of this embodiment, the upper portion of the container 21 is opened or closed with the lid which can be easily attached and detached, so that the user can add salt as necessary. it can. Therefore, the container 21 may be small in size, and the container which has conventionally been a cause of increasing the size of the super-oxidized water generator can be downsized. Moreover, since it is possible to add salt freely and easily, it is possible to provide a large amount of super-oxidized water or super-alkaline water without imposing a heavy burden on the user. The salt 21a may be added automatically.
【００１４】本実施例の塩類添加部４は、図３(a) に示
されているように、第１の浄化部２と電解槽６との間に
直接挿入してもよいし、同図(b) のように、第１の浄化
部２と電解槽６との間の側路に挿入してもよい。また、
同図(c) のように、電解槽の＋側電極の通路に設けても
よい。The salt addition section 4 of this embodiment may be directly inserted between the first purification section 2 and the electrolytic cell 6 as shown in FIG. 3 (a). As in (b), it may be inserted in a side path between the first purifying section 2 and the electrolytic cell 6. Also,
As shown in FIG. 7C, it may be provided in the passage of the positive electrode of the electrolytic cell.
【００１５】次に、図１の制御部１１の動作を、図４の
フローチャートを参照して説明する。ステップＳ１で
は、超酸化水精製装置の始動スイッチ８がオンにされた
か否かの判断がなされ、この判断が肯定の時には、ステ
ップＳ２に進んで、第１の電気伝導率の測定を行う。な
お、該ステップＳ１の判断が否定の時には、ステップＳ
１０に進んで、通常の水道水の使用となる。ステップＳ
３に進むと、塩類添加部４の弁２２が予め定められた角
度まで開かれ、ステップＳ４で塩類が添加された水の第
２の電気伝導率が測定される。続いて、制御部１１は前
記第１および第２の電気伝導率とから、水の塩分濃度を
算出し、ステップＳ５において、この濃度が所定範囲の
濃度（ｐｐｍ）であるか否かを判定する。Next, the operation of the control unit 11 of FIG. 1 will be described with reference to the flowchart of FIG. In step S1, it is determined whether or not the start switch 8 of the super-oxidized water purifier has been turned on. If the determination is affirmative, the process proceeds to step S2 to measure the first electrical conductivity. When the determination in step S1 is negative, step S
Proceed to 10 to use normal tap water. Step S
Proceeding to 3, the valve 22 of the salt adding unit 4 is opened to a predetermined angle, and the second electric conductivity of the salt-added water is measured in step S4. Subsequently, the control unit 11 calculates the salt concentration of water from the first and second electric conductivities, and determines in step S5 whether or not this concentration is within a predetermined range (ppm). .
【００１６】ステップＳ５の判断が肯定の場合には、ス
テップＳ６に進んで、電解槽６を起動し、電解を開始す
る。ステップＳ７では、停止スイッチ８がオンにされた
か否かを判断し、この判断が否定の場合には、ステップ
Ｓ４に戻って、前記第２の電気伝導率の測定を続行す
る。ステップＳ５で、パイプ１ｄ中を流れる水の塩分濃
度が所定範囲内の濃度でなくなったと判断されると、ス
テップＳ１１に進み、該塩分濃度が濃くなり過ぎている
かあるいは淡くなり過ぎているかの判断をする。前者の
場合には、ステップＳ１２に進んで、弁２２を所定角度
だけ絞る動作が行われ、一方、後者の場合には、ステッ
プＳ１３に進んで、弁２２を所定角度だけ開く動作が行
われる。そして、前記ステップＳ４に戻り、再び第２の
電気伝導率が測定される。以上の動作により、電解槽６
には、所定範囲内の塩分濃度の水が電解槽６に連続的に
供給されることになり、該電解槽６からは、所定の超酸
化水１ｆと超アルカリ水１ｇが連続的に得られることに
なる。If the determination in step S5 is affirmative, the process proceeds to step S6, the electrolyzer 6 is activated, and electrolysis is started. In step S7, it is determined whether or not the stop switch 8 is turned on. If the determination is negative, the process returns to step S4 and the measurement of the second electric conductivity is continued. When it is determined in step S5 that the salt concentration of the water flowing through the pipe 1d is not within the predetermined range, the process proceeds to step S11, and it is determined whether the salt concentration is too thick or too light. To do. In the former case, the operation proceeds to step S12, where the valve 22 is throttled by a predetermined angle, while in the latter case, the operation proceeds to step S13, where the valve 22 is opened by a predetermined angle. Then, returning to step S4, the second electric conductivity is measured again. By the above operation, the electrolytic cell 6
Therefore, water having a salt concentration within a predetermined range is continuously supplied to the electrolytic cell 6, and from the electrolytic cell 6, predetermined super-oxidized water 1f and super-alkaline water 1g are continuously obtained. It will be.
【００１７】前記ステップＳ７において、停止スイッチ
８がオンにされたと判断されると、ステップＳ８におい
て、制御部１１は電解槽６に電解停止の指示をし、続い
てステップＳ９において、塩類添加部４の弁２２を閉じ
る動作をする。When it is determined in step S7 that the stop switch 8 is turned on, the control section 11 instructs the electrolytic cell 6 to stop electrolysis in step S8, and subsequently in step S9, the salt addition section 4 is added. The valve 22 is closed.
【００１８】以上のように、本実施例によれば、小型の
超酸化水生成装置であるにかかわらず、生産性よく超酸
化水を生成することができる。また、このため、本実施
例の超酸化水生成装置を家庭用あるいは医療用に使用す
ると好適である。As described above, according to the present embodiment, it is possible to produce superoxidized water with high productivity regardless of the small-sized superoxidized water producing apparatus. Further, for this reason, it is preferable to use the super-oxidized water generator of this embodiment for home use or medical use.
【００１９】さて、前記の実施例では、塩類添加部４か
ら食塩（ＮａＣｌ）を添加するとして説明したが、食塩
を使用すると、電解槽６から得られた超酸化水１ｆに多
量の残留塩素が混入する。すなわち、電解槽６の陽極で
は、下記の化学式の反応が生じ、超酸化水１ｆに塩素が
混入する。 ２Ｃｌ−→Ｃｌ2 ＋２ｅ− この残留塩素は、塩素臭となり、安全衛生上問題となる
ばかりでなく、金属部品を腐食する。例えば、ステンレ
ス（ＳＵＳ３０４、ＳＵＳ３１６Ｌ）に作用すると、６
価クロムを溶出する。このため、医療用器具等の殺菌に
は不適であるという問題があり、本実施例では、第２の
浄化部７を用いて前記残留塩素を除去した。In the above-mentioned embodiment, it is explained that salt (NaCl) is added from the salt adding section 4. However, when salt is used, a large amount of residual chlorine is contained in the super-oxidized water 1f obtained from the electrolytic cell 6. mixing. That is, in the anode of the electrolytic cell 6, the reaction of the following chemical formula occurs, and chlorine is mixed in the super-oxidized water 1f. 2Cl - → Cl2 + 2e - This residual chlorine becomes a chlorine odor, not only the safety and health problems, corrosion of metal parts. For example, when acting on stainless steel (SUS304, SUS316L), 6
Elute the valent chromium. Therefore, there is a problem that it is not suitable for sterilization of medical instruments and the like, and in the present example, the residual chlorine was removed using the second purifying unit 7.
【００２０】一方、本発明者の実験により、塩類添加部
４から芒硝（Ｎａ2 ＳＯ4 ）を添加すると、前記残留塩
素の問題はなく、第２の浄化部７は不用であることが分
かった。すなわち、水道水に芒硝を添加して、所定範囲
の濃度にし、電解槽６に蓄積して電気分解すると、その
陽極では下記の化学式の反応が生じて、超酸化水１ｆを
生成することができる。 ２ＳＯ4 2-→Ｓ2 Ｏ8 2-＋２ｅ- 以上のように、塩類添加物として芒硝を用いると、塩素
臭が全くなく、しかもステンレスから６価クロムを溶出
しない、かつ殺菌性が極めて高い超酸化水を生成するこ
とができるようになる。On the other hand, according to the experiments conducted by the present inventor, it was found that when Glauber's salt (Na2 SO4) was added from the salt addition section 4, there was no problem of the residual chlorine and the second purification section 7 was unnecessary. That is, when sodium mirabilite is added to tap water to have a concentration within a predetermined range, which is accumulated in the electrolytic cell 6 and electrolyzed, a reaction of the following chemical formula occurs at the anode to generate superoxidized water 1f. . 2SO4 2- → S2 O8 2- + 2e - As described above, the use of sodium sulfate as a salt additive, chlorine odor without any, yet does not elute the hexavalent chromium from the stainless steel, and the bactericidal extremely high acid water Will be able to generate.
【００２１】次に、本発明の超酸化水生成装置を用い
て、超酸化水を生成した時の実験結果を、図５のグラフ
により説明する。図の左側の縦軸はｐＨを、右側の縦軸
は食塩または芒硝の濃度（ｐｐｍ）を示し、横軸は時間
を示している。また、図中の実線イは生成された超酸化
水のｐＨを示し、点線ロは塩類添加部４から食塩または
芒硝を水道水に添加することによって得られた食塩水ま
たは芒硝水の濃度を示す。また、幅ハは、許容される塩
分濃度を示す。Next, the experimental results when superoxidized water is produced using the superoxidized water producing apparatus of the present invention will be described with reference to the graph of FIG. The vertical axis on the left side of the figure shows pH, the vertical axis on the right side shows the concentration (ppm) of salt or mirabilite, and the horizontal axis shows time. In addition, the solid line (a) in the figure indicates the pH of the generated super-oxidized water, and the dotted line (b) indicates the concentration of salt solution or mirabilite water obtained by adding salt or mirabilite from the salt addition section 4 to tap water. . Further, the width c indicates an allowable salt concentration.
【００２２】図から明らかなように、本発明の超酸化水
生成装置によれば、容器２１（図２参照）に食塩あるい
は芒硝を補給し続ければ、何時までも食塩水または芒硝
水の濃度は幅ハで示される範囲内に制御することがで
き、また、電解槽６から得られる超酸化水のｐＨも約３
程度に保持できた。一方、従来の超酸化水生成装置によ
れば、電解槽に予め入れておいた所定濃度の食塩水の分
量に対応する超酸化水しか得ることができず、本発明の
ように、３０分、１時間といった長時間の運転はできな
かった。As is clear from the figure, according to the apparatus for producing super-oxidized water of the present invention, if the container 21 (see FIG. 2) is continuously replenished with salt or mirabilite, the concentration of the salt solution or mirabilite water will be forever. It can be controlled within the range indicated by the width C, and the pH of the super-oxidized water obtained from the electrolytic cell 6 is about 3.
I was able to hold it to a certain degree. On the other hand, according to the conventional super-oxidized water generator, it is possible to obtain only super-oxidized water corresponding to the amount of saline solution having a predetermined concentration, which has been put in the electrolytic cell in advance. I could not drive for a long time, such as one hour.
【００２３】[0023]
【発明の効果】以上の説明から明らかなように、本発明
によれば、超酸化水生成装置を小型に形成でき、かつ簡
単に所望量の超酸化水を生成することができるという効
果がある。また、本発明の超酸化水生成装置を小型に形
成できるので、家庭用、医療用に用いると好適である。As is apparent from the above description, according to the present invention, it is possible to form a super-oxidized water generator in a small size and easily generate a desired amount of super-oxidized water. . Further, since the super-oxidized water generator of the present invention can be formed in a small size, it is suitable to be used for household and medical purposes.
【００２４】また、塩類添加物として芒硝を用いると、
電解槽から得られた超酸化水を浄化せずとも、塩素臭が
なく、ステンレス部材に適用しても６価クロムを溶出せ
ず、かつ殺菌性の高い超酸化水を得ることができる。When Glauber's salt is used as a salt additive,
Even if the super-oxidized water obtained from the electrolytic cell is not purified, there is no chlorine odor, hexavalent chromium does not elute even when applied to a stainless steel member, and super-oxidized water with high sterilization can be obtained.
【００２５】さらに、塩類を収納する容器に、塩類を補
給することにより、何時間でも連続的に超酸化水を生成
することができる。Further, by supplementing the salt in the container for storing the salt, the super-oxidized water can be continuously produced for many hours.
【図１】 本発明の一実施例の構成の概略を示すブロッ
ク図である。FIG. 1 is a block diagram showing a schematic configuration of an embodiment of the present invention.
【図２】 本発明の塩類添加部の一実施例を示す図であ
る。FIG. 2 is a diagram showing an example of a salt addition unit of the present invention.
【図３】 塩類添加部の挿入位置の変形例を示す図であ
る。FIG. 3 is a diagram showing a modified example of the insertion position of the salt adding portion.
【図４】 本発明の一実施例の動作を示すフローチャー
トである。FIG. 4 is a flowchart showing the operation of the embodiment of the present invention.
【図５】 本実施例により得られる塩類濃度と超酸化水
のｐＨを示すグラフである。FIG. 5 is a graph showing the salt concentration and the pH of super-oxidized water obtained in this example.
１…水道水供給部、２…第１の浄化部、３…第１の電気
伝導率測定部、４…塩類添加部、５…第２の電気伝導率
測定部、６…電解槽、７…第２の浄化部、８…始動・停
止スイッチ、９…表示部、１０…電源、１１…制御部、
２１…容器、２２…弁、２３…アスピレータ、２４…パ
イプ。DESCRIPTION OF SYMBOLS 1 ... Tap water supply part, 2 ... 1st purification part, 3 ... 1st electrical conductivity measurement part, 4 ... Salt addition part, 5 ... 2nd electrical conductivity measurement part, 6 ... Electrolyte tank, 7 ... Second purification section, 8 ... Start / stop switch, 9 ... Display section, 10 ... Power supply, 11 ... Control section,
21 ... Container, 22 ... Valve, 23 ... Aspirator, 24 ... Pipe.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 宮本 幹 東京都八王子市狭間町1463番地 蛇の目ミ シン工業株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Miki Miyamoto 1463, Sakuma-cho, Hachioji-shi, Tokyo Janome Eye Machinery Co., Ltd.
Claims (3)
れた水を電気分解して超酸化水を得るようにした超酸化
水生成装置において、 粉状あるいは粒状の塩類を収納でき、その底部に該塩類
を落下させるパイプを備えた容器と、 該パイプに、弁を介して接続されたアスピレータと、 前記弁の開口角を制御する制御部とを具備し、 該アスピレータを通過する水に、所定量の塩類を添加
し、該水の塩分濃度を所定範囲内の濃度とするようにし
たことを特徴とする超酸化水生成装置。1. A super-oxidized water generator in which salt is added to tap water and the salt-added water is electrolyzed to obtain super-oxidized water, in which powdery or granular salts can be stored, A container provided with a pipe for dropping the salt at its bottom, an aspirator connected to the pipe through a valve, and a control unit for controlling the opening angle of the valve, and water passing through the aspirator is provided. A super-oxidized water generator, characterized in that a predetermined amount of salt is added to the above so that the salt concentration of the water falls within a predetermined range.
酸化水生成装置。2. The super-oxidized water producing apparatus according to claim 1, wherein the salt is salt or sodium sulfate.
おいて、 前記容器に、塩類を補給できるようにしたことを特徴と
する超酸化水生成装置。3. The super-oxidized water generating apparatus according to claim 1, wherein the container can be supplemented with salts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21075494A JPH0852476A (en) | 1994-08-12 | 1994-08-12 | Superoxidized water forming device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21075494A JPH0852476A (en) | 1994-08-12 | 1994-08-12 | Superoxidized water forming device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0852476A true JPH0852476A (en) | 1996-02-27 |
Family
ID=16594579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21075494A Pending JPH0852476A (en) | 1994-08-12 | 1994-08-12 | Superoxidized water forming device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0852476A (en) |
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| US9168318B2 (en) | 2003-12-30 | 2015-10-27 | Oculus Innovative Sciences, Inc. | Oxidative reductive potential water solution and methods of using the same |
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-
1994
- 1994-08-12 JP JP21075494A patent/JPH0852476A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7090753B2 (en) | 2001-09-14 | 2006-08-15 | Oculus Innovative Sciences, Inc. | Electrolytic cell for producing charged anode water suitable for surface cleaning or treatment, and method for producing the same and use of the same |
| US7442288B2 (en) | 2001-09-14 | 2008-10-28 | Oculus Innovative Sciences, Inc. | Electrolytic cell for producing charged anode water suitable for surface cleaning or treatment, and method for producing the same and use of the same |
| US9168318B2 (en) | 2003-12-30 | 2015-10-27 | Oculus Innovative Sciences, Inc. | Oxidative reductive potential water solution and methods of using the same |
| US9642876B2 (en) | 2003-12-30 | 2017-05-09 | Sonoma Pharmaceuticals, Inc. | Method of preventing or treating sinusitis with oxidative reductive potential water solution |
| US10016455B2 (en) | 2003-12-30 | 2018-07-10 | Sonoma Pharmaceuticals, Inc. | Method of preventing or treating influenza with oxidative reductive potential water solution |
| US8840873B2 (en) | 2005-03-23 | 2014-09-23 | Oculus Innovative Sciences, Inc. | Method of treating second and third degree burns using oxidative reductive potential water solution |
| US9498548B2 (en) | 2005-05-02 | 2016-11-22 | Oculus Innovative Sciences, Inc. | Method of using oxidative reductive potential water solution in dental applications |
| US8834445B2 (en) | 2006-01-20 | 2014-09-16 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing peritonitis with oxidative reductive potential water solution |
| US9072726B2 (en) | 2006-01-20 | 2015-07-07 | Oculus Innovative Sciences, Inc. | Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution |
| US9782434B2 (en) | 2006-01-20 | 2017-10-10 | Sonoma Pharmaceuticals, Inc. | Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution |
| US10342825B2 (en) | 2009-06-15 | 2019-07-09 | Sonoma Pharmaceuticals, Inc. | Solution containing hypochlorous acid and methods of using same |
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